Professional Documents
Culture Documents
TABLE OF CONTENTS
Section
______
Page
____
Introduction
11
12
Bibliography
26
INTRODUCTION
Page 1
INTRODUCTION
The liquefaction of natural gas, which reduces its volume by a
factor of over 600, has made the storage and transportation of this
fuel economically attractive. However, this liquefaction technique
has also served to increase the amount of energy in storage,
process and transportation equipment by the same amount.
This tremendous concentration of energy has not been overlooked
by the gas utilities, nor gone unnoticed by the authorities and the
general public. The safety of natural gas, especially from the fire
protection standpoint, has been the subject of considerable
research in recent years, and many techniques have been refined
in the overall fire protection approach to the hazard.
As with any other potential hazard, the fire protection for a natural
gas facility consists of three elements: fire prevention, fire control,
and fire extinguishment. Figure 1 illustrates these elements as
they relate to LNG (Liquefied Natural Gas) processes.
Fire Protection
Fire Prevention
Fire Control
Exposure Protection
Fire Extinguishment
Construction Material
Operation Criteria
Vapor Dispersion
Provisions of NFPA
Standard 59A
Industry Standards
Water
Dry Chemicals
FIGURE 1
OVERALL FIRE PROTECTION APPROACH
003380
8399%
113%
0.1 3%
0.21.0%
Physical
Properties
_________________
Normal Boiling Point
Density liquid at NBP
(Normal Boiling Point)
Density vapor at NBP (compared
with air at 70 F (21.2 C))
Liquid to vapor expansion
Heat of vaporization
Theoretical vaporizing capability
of 1 cu. ft. (0.3 m2) of:
Dry earth
Wet earth
Water
Air
Combustion
Properties
____________________
Flammable range
Heat of combustion
Burn rate, steady state pool
Pool fire flame height
255 to 263 F
(160 to 164 C)
3 1/2 to 4 lb/gal
(0.42-0.48 kg/L)
1.47
600 to 1
220-248 Btu/lb
(512-577 kj/kg)
5-14% (methane at
normal temperatures)
6-13% (methane near
minus 260 F)
22,000 Btu/lb
(51,172,000 J/kg)
0.2-0.6 in./minute
3 times base dimensions
of pool (slight wind)
FIGURE 2
Approximate Properties of Natural Gas2
003381
Preburn: The length of time that a fire has burned in an impinging jet situation will proportionately increase the extinguishing
agent application rate that is required.
A. State: The natural gas at the source of the fire problem will be
in either the vapor or the liquid state.
Within a contained volume, an important variable to be considered is that other flammables (refrigerants, etc.) may be
present. These other flammables could behave quite differently than natural gas with regard to flammable and explosive
limits.
The behavior of LNG (Liquefied Natural Gas) in a spill situation
is an important consideration in determining extinguishing
agent application requirements. The characteristics of the
surface on which a spill occurs will influence the initial rate of
vaporization. However, an approximation of the initial rate of
vaporization on both solid surfaces and water can be said to
be in the range of 50 ft3 per minute of vapor per ft2 (15.24 m3
per minute per m2) of LNG surface area.
Natural Gas
State
Configuration
Variables
Liquid
Vapor
Pressure
Impingement
Preburn
Obstructions
Contained
Pressure/Pool
Spill
Other
Flammables
Impingement
Preburn
Vaporization
Rate
Obstructions
Obstructions
FIGURE 3
Definition of the Natural Gas Fire
003382
Natural Gas
State
Configuration
Best Solution
Liquid
Vapor
Pressure
Dry Chemical
Contained
Carbon
Dioxide
Pressure/Pool
Spill
Dry Chemical
or
Dry Chemical
and
High Expansion
Foam
Dry Chemical
or
Dry Chemical
and
High Expansion
Foam
FIGURE 4
The ANSUL Concept
003382
Site
___
Date _____
Tests
____
Longview,
Texas7
1951 91
Types of
Tests
_____
Agents
Tested
______
Vapor-Nonlmpinging Jet
Sodium
Bicarbonate
Vapor-Horizontal
Impinging Jet
Vapor-Downward
Impinging Jet
Vapor-Split Pipe
Impinging Jet
Six Lakes,
Michigan8
1965 48
Vapor-Nonlmpinging Jet
Sodium
Bicarbonate
1969 107
Vapor-Nonlmpinging Jet
Potassium
Bicarbonate
Sodium
Bicarbonate
Potassium
Bicarbonate
High Expansion
Foam
Monoammonium
Phosphate
1973 100
Norman,
Oklahoma17
The 1969 Six Lakes program established the potassium bicarbonate base agent requirements for low flow rate (200-1600 ft3/sec
(5.7-45.3 m3/sec)) gas fires and also served to compare the relative fire extinguishing effectiveness of potassium bicarbonate and
potassium chloride base dry chemicals.
Monoammonium
Phosphate
Potassium
Chloride
Marinette,
1972 43
Wisconsin10
The 1965 Six Lakes program was conducted to compare the effectiveness of potassium bicarbonate, monoammonium phosphate
and sodium bicarbonate base dry chemicals on two of the four gas
transmission hazards tested in the Longview program. From this
experimentation, definite design criteria for the potassium bicarbonate base agent were developed for the two hazards tested,
and correlations between the relative extinguishing effectiveness
of sodium and potassium bicarbonate base agents produced the
potassium bicarbonate base agent design criteria for the other two
hazards.
Vapor-Horizontal Potassium
Impinging Jet
Bicarbonate
Six Lakes,
Michigan9
Sodium
Bicarbonate
Potassium
Bicarbonate
High Expansion
Foam
FIGURE 5
ANSUL Large Scale Natural Gas Fire Testing Programs
EXTINGUISHING TIME
(t sec)
tminute
Rminute
(R lb/sec (kg/sec))
003385
FIGURE 6
General Relationship of Agent Rate and Extinguishing Time
AGENT QUANTITY
(Q lb)
Rmin has been found to be in the range of 0.4 to 0.5 Ropt, which
accounts for the 2.0 factor of safety usually put on Rminute to
arrive at a design rate. If the agent is applied at a rate greater than
Ropt, the time of extinguishment is usually not reduced to any
significance (as shown in Figure 6) resulting essentially in the
wasting of agent (Q >> Qminute).
Qminute
Rminute
Ropt
003386
(R lb/sec (kg/sec))
FIGURE 7
General Relationship of Agent Rate and Quantity
THE SPECIFIC AGENT FLOW RATE REQUIREMENTS FOR NATURAL GAS FIRES
Page 11
F. In the combined use of high expansion foam and dry chemicals, the high expansion foam application must be continued
until the dry chemical has completely extinguished all flames.
For the graphs in Figures 8 through 15, the criteria shown in solid
lines are based on actual experimentation and those shown in
dashed lines are correlations (based on relative extinguishing
effectiveness of the agents) or extrapolations. The design information on LNG pressure fires are theoretical and it assumes that
the LNG completely and immediately flashes to a vapor at 70 F
(21 C). upon exiting the failure point. The dry chemical rates are
then based on the free volume of natural gas using an expansion
factor of 600. This approach is justified on the basis of reported
correlations attained in experimentation with gaseous and liquid
propane.14
70
(31.8)
60
(27.2)
50
(22.7)
Y
FT
FI
US
PL
40
(18.1)
30
(13.6)
K
lep
r
Pu
20
(9.1)
10
(4.5)
0
0
500
(14.2)
1000
(28.3)
1500
(42.5)
2000
(56.6)
2500
(70.8)
500 (1893)
1000 (3785)
1500 (5678)
LNG Flow Rate gal/minute (liters/minute)
FIGURE 8
003387
70
(31.8)
60
(27.2)
40
(18.1)
PL
US
-FI
FT
Y
50
(22.7)
30
(13.6)
20
(9.1)
K
lep
ur
P
10
(4.5)
0
0
200
(5.7)
400
(11.3)
600
(17)
800
(22..7)
1000
(28.3)
200 (757)
400 (1514)
600 (2271)
LNG Flow Rate gal/minute (liters/minute)
FIGURE 9
003388
70
(31.8)
50
(22.7)
40
(18.1)
PLU
S-FIF
TY
60
(27.2)
30
(13.6)
20
(9.1)
-K
e
l
p
ur
P
10
(4.5)
0
0
100
(2.8)
200
(5.7)
300
(8.5)
400
(11.3)
500
(14.2)
100 (378.5)
200 (757.1)
300 (1135.7)
LNG Flow Rate gal/minute (liters/minute)
FIGURE 10
003389
30
Minimum Purple-K
25
Purple-K
20
Minimum PLUS-FIFTY
15
PLUS-FIFTY
10
PLUS-FIFTY Design Application Rate
0.01
(0.05)
0.02
(0.10)
0.03
(0.15)
0.04
(0.2)
0.05
(0.24)
0.06
(0.29)
0.07
(0.34)
0.07
(0.34)
0.06
(0.29)
0.05
(0.24)
TY
FIF
US
PL
0.04
(0.2)
0.03
(0.15)
K
plePur
0.02
(0.10)
0.01
(0.05)
0
0.5
(1.27)
1.0
(2.5)
1.5
(3.81)
1000
(453.6)
500
(226.8)
300
(136.1)
200
(90.7)
100
(45.4)
50
(22.7)
30
(13.6)
20
(9.1)
10
(4.54)
5
(2.27)
3
(1.36)
2
(0.91)
1 (0.45)
10
(0.9)
50
(4.6)
100
(9.3)
500
(46.5)
1000
(92.9)
5000
(464.5)
10000
(929)
1000
(453.6)
500
(226.8)
300
(136.1)
100
(45.4)
50
(22.7)
30
(13.6)
P
ur
pl
eK
PL
US
-F
IF
TY
200
(90.7)
20
(9.1)
10
(4.54)
5
(2.27)
3
(1.36)
2
(0.91)
1 (0.45)
10
(0.9)
50
(4.6)
100
(9.3)
500
(46.5)
1000
(92.9)
5000
(464.5)
10000
(929)
300
250
Six (6) ft3/minute/ft2 (1.83 m3/minute/m2)
is a generally accepted minimum
design rate.
200
150
100
50
0
0
5
6
(1.5) (1.83)
10
(3.05)
15
(4.6)
(Based on Recommended
Application Rates and
Seconds
Effective
30
Discharge Time)
1400
(635)
PL
US
-F
IF
TY
1200
(544.3)
1000
(453.6)
800
(362.9)
K
el
p
ur
P
600
(272.2)
400
(181.4)
200
(90.7)
0
0
500
(14.2)
1000
(28.3)
1500
(42.5)
2000
(56.6)
2500
(70.8)
500 (1893.7)
1000 (3785.4)
1500 (5678.1)
LNG Flow Rate gal/minute (liters/minute)
FIGURE 16
003395
(Based on Recommended
Application Rates and
Seconds
Effective
30
Discharge Time)
1400
(635)
1200
(544.3)
800
(362.9)
PLU
S-FI
FTY
600
(272.2)
P
ur
pl
eK
1000
(453.6)
400
(181.4)
200
(90.7)
0
0
200
(5.7)
4000
(11.3)
600
(17)
800
(22.7)
1000
(28.3)
200 (757.1)
400 (1514.2)
600 (2271.2)
LNG Flow Rate gal/minute (liters/minute)
FIGURE 17
003396
(Based on Recommended
Application Rates and
Seconds
Effective
30
Discharge Time)
1400
(635)
1200
(544.3)
PLUS
-FIFT
Y
800
(362.9)
600
(272.2)
400
(181.4)
P
ur
pl
eK
1000
(453.6)
200
(90.7)
0
0
100
(2.8)
200
(5.7)
300
(8.5)
400
(11.3)
500
(14.2)
100 (378.5)
200 (757.1)
300 (1135.6)
LNG Flow Rate gal/minute (liters/minute)
FIGURE 18
003397
1000
(453.6)
PL
US
-F
IF
P
TY
ur
pl
eK
10000
(4536)
100
(45.4)
10 (4.5)
10
(0.9)
100
(9.3)
1000
(93)
10000
(929)
1000
(453.6)
PL
US
-F
IF
P
TY
ur
pl
eK
10000
(4536)
100
(45.4)
10 (4.5)
10
(0.9)
1000
(93)
100
(9.3)
10000
(929)
Generator
________
JET-X-2A
Generator Inlet
Pressure
psi
(bar)
____________
Foam Output
cfm
(cmm)
____________
Solution Flow
gpm
(lpm)
____________
50
75
100
(3.45)
(5.17)
(6.89)
2,240
3,200
3,735
(63)
(91)
(106)
35
42
50
(132.5)
(159)
(189.3)
Expansion
_________
465:1
555:1
545:1
JET-X-15A (LNG)
50
75
100
(3.45)
(5.17)
(6.89)
12,625
14,495
18,240
(357)
(410)
(516)
180
220
260
(681.4)
(832.8)
(984.2)
525:1
495:1
525:1
JET-X-20
40
50
75
100
(2.76)
(3.45)
(5.17)
(6.89)
13,443
16,034
21,145
24,301
(381)
(454)
(599)
(688)
212
238
294
338
(802.5)
(900.9)
(1112.9)
(1279.5)
474:1
504:1
538:1
538:1
B. Dry Chemical: A complete line of dry chemical extinguishment systems have been designed specifically for natural gas
and flammable liquid applications. Figure 21 summarizes the
ANSUL dry chemical product line, illustrating the flow rates,
which can be related to the data contained in this report.
Category
Agents
Extinguisher Capacity
Flow Rate
Hand Portable
PLUS-FIFTY
10, 20, 30 lb
(4.5, 9, 13.6 kg)
1.5-2.5 lb/sec
(0.7-1.1 kg/sec)
Purple-K
9, 18, 27 lb
(4.1, 8.2, 12.2 kg)
PLUS-FIFTY
Purple-K
PLUS-FIFTY
4.5-10.0 Ib/sec
(2-4.5 kg/sec)
for hand lines
Vehicle Mounted
Purple-K
25-100 Ib/sec
(11.3-45.4 kg/sec)
for turrets for 1350 lb (612.4 kg)
capacity and larger
Wheeled
Engineered
Systems
BIBLIOGRAPHY
Page 26
BIBLIOGRAPHY
1. National Fire Protection Association, Storage and Handling of
Liquefied Natural Gas (LNG), NFPA Standard 59A.
2. Walls, W. L., LNG: A Fire Service Appraisal, FIRE
JOURNAL, January, 1972.
3. National Fire Protection Association, Standard For Low-,
Medium-, and High-Expansion Foams, NFPA 11.
4. REMOVED
5. REMOVED
6. REMOVED
7. Natural Gas Fire Tests, Technical Bulletin Number 32, Ansul
Incorporated, Marinette, Wisconsin.
8. Fire Tests With Natural Gas Jets Six Lakes, Ansul
Incorporated, Marinette, Wisconsin.
9. Fire Tests With Natural Gas Jets Six Lakes, Ansul
Incorporated, Marinette, Wisconsin (1969).
10. LNG Fire Control, Fire Extinguishment and Vapor Dispersion
Tests, University Engineers, 1972.
11. REMOVED
12. Guise, A. B., and Lindlof, J. A., A Dry Chemical Extinguishing
System, NFPA QUARTERLY, Volume 49, Number 1, July,
1955.
13. REMOVED
14. Guise, A. B., Fire Tests Made On LP Gas, LP GAS, May,
1948.
15. REMOVED
16. REMOVED
17. An Experimental Study on the Mitigation of Flammable Vapor
Dispersion and Fire Hazards Immediately Following LNG
Spills On Land, For AGA by University Engineers, February,
1974.
ANSUL INCORPORATED
MARINETTE, WI 54143-2542
715-735-7411