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I. Introduction
In recent years, the lithium bromide/water absorption
system has become prominent in refrigeration for air
conditioning. It possesses several advantages over the
other types of absorption systems, such as:
(l) It is limited to relatively high evaporating temperatures since the refrigerant is water. This means that
evaporation temperature above 0C must generally
be satisfied to prevent flow freezing.
247
(2) Crystallization of LiBr salt at moderate concentrations ( >0.65 kg LiBr/Kg solution) will tip off the
cycle range of operation.
(3) The systems have to be designed in hermetically
sealed units since they operate at vacuum pressures. Improper operation would result if leakage
of air into the system occurred.
Irrespective of its drawbacks, the LiBr/water unit is
still considered the most economical for this kind of
refrigeration technique. It has been selected as a candidate refrigeration system in connection with a proposed
solar assisted equipment for application in Goldstone
energy conservation projects.
This article describes and analyzes the computer
modeling of such units. The modeling procedure is generalized to enable those concerned with use or evaluation
of cycles employing this material to save considerable
time and effort required for calculations.
it contains a smaller amount of refrigerant. The refrigerant vapor leaving the generator is condensed (state 8)
in the condenser and is directed to the evaporator through
an expansion valve (state 9). The weak solution flows
back to the absorber through the liquid-liquid heat exchanger as a spray (state 6) to complete the cycle.
The thermodynamic cycle is sketched on the equilibrium temperature-pressure-concentration chart as shown
in Fig. 2. It is bounded by two constant concentration
lines: X 1 and X4 for the absorber and generator concentration, respectively, and two constant pressure lines:
Pe and Pc for the evaporator and condenser pressures,
respectively.
For an efficient air conditioning application, the evaporator temperature te should be low enough to dehumidify
the air. In practice, it ranges from 4.5 to 10C according
to the load conditions. The heat rejection temperatures ta
and tc for the absorber and the condenser, respectively,
vary according to the type of cooling medium (air, water),
ambient conditions of dry and wet bulb temperatures,
and whether their cooling lines are connected in series or
parallel with each other.
The generator temperature tu depends on the source of
heat available, i.e., solar, gas or steam. However, a minimum temperature of 80C should be maintained to provide efficient operation.
The operational function of the liquid-liquid heat exchanger in the cycle will be the reduction of the weak
solution temperature t 4 , leaving the generator and increasing the strong solution temperature t 1 leaving the absorber.
The result is that it reduces the heat input necessary to
the generator while reducing the heat rejected from the
absorber by heat exchanging between the two solutions.
This heat exchanger does increase the coefficient of performance of the system and is, therefore, always desirable.
tC
= (t- 25)
kcal!kg
(1)
+ 0.417 t)
kcal/kg
(2)
= 572.8
0.043 t.
_
_ 1555 _ 11.2414 X 1{)4
Iogto P mm H g - 7.8553
T
T2
kcal!kg
(3)
kcal!kg
solution
(4)
+ 416.67 X
kcal/kg
solution
(5)
(6) The enthalpy of LiBr/water solution of concentra-
Hx,2s
+ Cx(t- 25)
+ 404.67 X2 )
1.23 X + 0.48 X (t)
= (42.81 - 425.92 X
(8)
oc
oc
or
+-(1.01 -
(8) The saturated vapor pressure P in mm Hg corresponding to saturation temperature TK for pure
water is given by (Ref. 5)
t.)
c. = 1.01 -
(7)
134.65 + 0.47 tm
= (572.8
(6)
A. Absorber Concentration
X1
+ (1.125 -
0.47 X) (tm C}
= X = X = X stron~ =
2
solutwn
49.04 + 1.125 ta - te
134 .65 + 0.47 ta
kg LiBr/kg solution
(9)
249
B. Generator Concentration
X4
= Xs = Xs = X weak
solution
49.04 + 1.125 tg - tc
134.65 + 0.47 tg
kg LiBr/kg solution
where mR is the refrigerant flow rate, equals the difference between the strong and weak solution rates. By
using Eq. (15)
(10)
(17)
kg LiBr/kg solution
(11)
for the pure water flow in the condenser and evaporator.
and by using Eqs. (11) and (17), then
C. Pressure Limits in the Cycle
(18)
= P1 = Ps = P9 = P1o in mm Hg is given by
(19)
Pevavorator,
P.
log10 P. = 7.8553 - t.
1555
+ 273 .15
11.2414 X 1Q4
(t. + 273.15) 2
(12)
= P2 = Pa = P4 = Ps =
+ 273.15)
11.2414 X 104
(tc + 273.15) 2
(13)
D. Flow Rates
Hs = (tc- 25)
kcal!kg
(15)
+ 0.417 te
(16)
_ tg- t 5
EL - - - tg- ta
(20a)
X4
(27)
Using Eqs. (17), (18), (19), and (27), it is possible to write
+ 0.48Xi (
1.23 x. + 0.48 X~ ~
c = 1.01 -
(22)
Qa as
QE
Equations (20) and (21) are rewritten using Eqs. (18) and
(19) to give the temperatures t 3 and t 5 as:
Qa = (H 1o
[ X1Hs
Hs) (X.- X1)
H7
X.Hl
(X. - X1)
J
(28)
(20b)
(21b)
and
+ 404.67 XI)
1.23 x1 + 0.48 xn. (ta)
H 1 = (42.81 - 425.92 X1
+ (1.01 -
H 5 = (42.81 - 425.92 X4
(23a)
QE
[ X1Hs
H
X.Hl
QA = (H 10 - Hs) (X 4 - X1) + 10 - (X.- X1)
(29)
Equations (25b) and (29) are governed by the first law
of thermodynamics in the form
+ 404.67 X!)
(30)
5)
(23b)
G. Coefficient of Performance (COP)
This is defined as
+ 0.46 fg
refrigeration effect
extemal heat input
COP=---=~--~--
QE
Qa
(24)
0.043 fc
(31)
(32)
Heat balance for the combined generator and heat
exchanger control volume gives
(26)
JPL DEEP SPACE NETWORK PROGRESS REPORT 4232
The ratio
(COP)actual
(COP)m=
(2) Using the combined effectiveness/number of exchanger heat transfer units N tu, the latter defined
as (Ref. 6).
VII. Summary
N tu =
VA
-:::---;;-;--~-----__..,..-.,--
(33)
Input Data
(1) t 0 , C, generator temperature
(2) t., C, evaporator temperature
(3) tc, C, condenser temperature
(4) ta, C, absorber temperature
(5) EL, exchanger effectiveness
(6) QE, kcal/hr, load
Steps of Analysis
( ) X = (49.04 + 1.125ta- te)
1
1
(134.65 + 0.47 ta)
(2)
x4 =
IF 0.5
(3) Hs
+ 1.125 tu - tc)
(134.65 + 0.47 t 0 )
(49.04
< (X
and X4)
= (tc- 25)
QE
kg LiBr/kg solution
kcal/kg
+ 0.417t.)
(Hlo- Hs)
kg LiBr/kg solution
kcal/kg
kg/hr
EL = 0.8
kglhr
EL(t11
+ [EL ;
kglhr
ta)
+ 0.48X~
+ 0.48Xi
~.,4
(t11
kcal/kgC
kcal/kgC
ta)]
+ 404.67 xn
+ (1.01 - 1.23 x1 + 0.48 xn (t.. )
(42.81- 425.92X4 + 404.67 Xi)
kcal/kg
+ (1.01 -
kcal/kg
(14) H 7 = (572.8
+ 0.46t11 -
+ 0.48 X!) (t
0.043tc)
5)
H 10
+ mRH1 - m.H1)
(m,.,H 5 + mRH1o- m.H1)
(17) QA =
kcal/kg
kcal/hr
kcal/hr
(te
(19) (COP),...., = (t11
+ 273.15) (t11 -
ta)
+ 273.15) (tc - t.)
= 575.72, kcal/kg
mR = 5.3931, kg/hr
m. = 59.9199, kg/hr
kcal/hr
(16) Qo = (m,.,H 5
H s = 15, kcal/kg
.,1
1.23 X4
Calculation Steps
oc
kcal/hr
1555
+ 273.15
ll.2414 X 104
- (t. + 273.15) 2 mmHg
1555
(22) Pc = antilog [ 7.8553 - tc + 273 .15
11.2414 X 104 ]
- (tc + 273.15) 2 mmHg
mw = 54.5268, kg!h,r
t 5 =50, C
Cx1 = 0.46677, kcal!kgoc
Cx4 = 0.42982, kcal/kgC
t 3 = 73.52, C
H 1 = -49.9124, kcal/kg
H 5 = -43.9594, kcal/kg
H 1 = 612.48, kcal!kg
Qc = 3222.3, kcal/hr
Qa = 3896.9, kcal/hr
QA = 3698.6, kcal/hr
COP= 0.776
(COP).,....,= 1.1689
relative
performance
ratio = 0.664
Pe = 7.45 mmHg
Input Data
t, = 90C
t. = 7C
tc = 40C
ta = 40C
JPL DEEP SPACE NETWORK PROGRESS REPORT 42-32
Pc = 55.37 mmHg
The temperature profile of each heat exchanger is
sketched as shown in Fig. 5. Having established an analytical procedure for the performance characteristics of a
lithium bromide/water absorption system enables the
study of further changes in the thermodynamic cycle.
Examples of these changes are the temperature of entering
heating fluid to the generator, the cooling load at the
evaporator, and the temperature of entering cooling fluid
at the condenser or absorber.
253
Definition of Symbols
U overall conductance coefficient, kcal/(hr-m 2 -C)
Subscripts
a,A absorber
c,C condenser
e,E evaporator
p pressure, mm Hg
Q
g,G generator
t temperature, o C
s "strong" solution
w
"weak" solution
References
1. Ellington, R. T., Kunst, G., Peck, R. E., and Reed, J. F., "The Absorption Cooling Process." Institute of Gas Technology Research Bulletin No 14, Chicago,
Ill., Aug. 1957.
2. Lackey, R. S., "Solar Heating and Cooling of Buildings," Westinghouse Electric
Corporation Report to the National Science Foundation, NSF-74-C584-1-2,
Appendix J., May 1974.
3. Threlkeld,
J. L.,
4. San Martin, R. L., and Couch, W. A., "Modeling of Solar Absorption Air Conditioning," Institute of Environmental Science Proceedings, Vol. 1, 1975,
pp. 186-189.
5. Pennington, W., "How to Find Accurate Vapor Pressures of LiBr-Water Solutions," Refrigeration Engineering, May 1955.
6. Kays, W. M., and London, A. L., Compact Heat Exchangers, McGraw Hill
Book Co., ~nc., 1958.
7. Wilbur, P. J., and Mitchell, C. E., "Solar Absorption Air Conditioning Alternatives," Solar Energy, Vol. 17, 1975, pp. 19.'3-199.
254
GENERATOR
t
mR
CONDENSER
t
8
3
'mR
1
nn
ABSORBER
t
mR
10
EVAPORATOR
t
'
255
100
760
600
(a)
400
200
80
Ol
w'
J:
...;
"'
"'w
"'
100
0..
:J
60
""
40
20
0..
60
""
:J
1-
""00..
~
w
11-
40
~
w
0
0<
20
u..
w
10
6
4
""
2
-20
-20
SOLUTION TEMPERATURE, C
CONSTANT
CONCENTRATION
(b)
0
...;
E
E
w'
""
"'"'
""
10..
""
0..
8 /
~
w
0
0<
u..
""
/
/
,/
// //
',';,")(__x
11-
, / / / _,-::,/"'
~
w
u..
w
WATER//
~
w
p
c
0
0<
1-
""
:J
:J
w
X 1 LINE~I~
Ol
J:
/
/
LINE
,/~
~/
~ ~
t
SOLUTION TEMPERATURE, C
256
mw, x4
(a) CONDENSER
""
:::>
,_
(b) ABSORBER
t = 40C
MAXIMUM RANGE
~
w
= (t 9 -
0..
w
,_
"STRONG" SOLUTION
ms' xl
tl
ta)
_l
~~~c
10C
COOLING FLUID
a
30C
I
L
37"C
10C
30C
(c) GENERATOR
= 40C
(d) EVAPORATOR
100C
10C
L '------:----'
t
(a) CONDENSER
CONDENSER
(b) ABSORBER
TEMPERATURE~
OUT~
0
M
INLET
= 90C
13C
93C
t
= 7C
I
L
OUT~
,c.T i
t.T
COOLING FLUID
73.52C
INLET
4(JoC1
10C
(c) GENERATOR
(d) EVAPORATOR
INLET
t.T.
GENERATOR
_j_
t.To
TEMPERATURE~
INLET
t.T.
_l
t.To
EVAPORATOR
TEMPERATURE~
257