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Innovations in Chemical
Admixture Technology as Related
to Sustainability, Part 2
ACI Spring 2012 Convention
March 18 21, Dallas, TX
OUTLINE
Sustainableconcrete
Materialsforchemicaladmixtures
CombinationsofLignosulfonatesandPolycarboxylate
Ethers
Experimentalwork
Resultsanddiscussions
Conclusions
Pathforward
CONCRETE
C ombination of
O rganic (Synthetic) and
N atural ingredients
C ast and Cured with / without
R einforcement in the
E nvironment using
T echnology and
E ffective human resources
SUSTAINABLECONCRETE
6/8/2012
ROLEOFCONCRETEADMIXTURES
HOWTO
Reduced
cement
Optimization
ofmaterials
Improvement
and
optimizationof
structures
SUSTAINABLE
CONCRETE
Recyclingand
waste
management
Innovationin
materialsand
processes
Reduced
W:Bratio
ReducedCO2
emission
Reduces
CONCRETE
Permeability
ADMIXTURES
Increased
workability
retention
Increased
compressive
strength
Reduces
element
mass
Reduces
rejections/
repairs
LIGNOSULFONATES(LS)
Green and sustainable chemical
CO
Carbon content of LS is 400 gm. / kg.
1.5 kg of CO is withdrawn from
atmosphere/kg of LS
Steric + Electrostatic repulsion.
Excellent compatibility with SNF, SMF and PCEs.
Most grades are compatible with Alternative Cementitious
Materials.
2
1.5
kg
MATERIALS
SULFONATEDNAPTHALENE
FORMALDEHYDE(SNF)
POLYCARBOXYLATEETHERS(PCE)
MadeusingNapthelene,FormaldehydeandHSO.
Workswellforconcretesupto60MPa.
BetterinitialslumpthanLS.
CompatiblewithmostretardersandLS
Longretentionofslumpispossible.
GenerallynotcompatiblewithPCEs.
6/8/2012
ASPECTS
COMBINATIONSOF
LIGNOSULFONATEANDPCEs
Synergy
Cost
Versatility
Foamingtendency
Compatibility
Workability
Strengthdevelopment
Cementcompatibility
SCOPE
StudyCaLSandNaLScombinationswithPCWR.Theresults
arecomparedwithSNF:LScombinations
NaLSfrom2differentsources,PCEsfrom3differentsources
andCaLSfromsinglesource
Concretetrialsattwodifferentdosages
CONCRETEPROPORTIONS
EXPERIMENTALWORK
COMBINEDGRADATION
6/8/2012
Sample1
Sample2
PhysicalProperties
Admixture Formulations
(%)
56
24
20
100
%NVM
40.33
1.1
SG@250C
pH@250C
6.52
VISCOSITYFCB4
250C
52
1.5
2.5
3.5
Timeinhour
7Day
0.90%
300
250
200
150
100
50
0
@0.7%
Dosage
28day
0.5
Sample3
(%)
24
30
46
100
VISCOSITYFCB4
250C
1.5 2 2.5 3
Timeinhour
TestMix
PCWR1
NaLignoB
Water
Total
3.5
70
60
50
40
30
20
10
0
1Day
7Day
0.70%
0.90%
Dosage%
(%)
40
21.6
38.4
100
VISCOSITYFCB4
250C
1.5
VISCOSITYFCB4
250C
0.5
1.5
2.5
52
Compatibility
ViscosityAfter24
Hrsat250C
52
ViscosityAfter7
0
55
Daysat25 C
ViscosityAfter30
55
Daysat250C
CompressiveStrengthAnalysis
@0.7%
Dosage
@0.9%
Dosage
3
3.5
Timeinhour
28day
2.5
Timeinhour
54
Compatibility
ViscosityAfter24
54
Hrsat250C
ViscosityAfter7
54
Daysat250C
ViscosityAfter30
0
Daysat25 C
55
AdmixtureFormulations
TestMix
(%)
PCWR1
40
NaLigno R
Water
Total
80
60
40
20
0
1Day
7Day
0.70%
0.90%
28day
Dosage%
3.5
70
60
50
40
30
20
10
0
1Day
7Day
0.70%
0.90%
Dosage%
PhysicalProperties
%NVM
39.93
1.13
SG@250C
5.6
pH@250C
21.6
38.4
100
VISCOSITYFCB4
250C
28day
300
250
200
150
100
50
0
@0.7%
Dosage
@0.9%
Dosage
0
0.5
1.5
65
Compatibility
ViscosityAfter24
65
Hrsat250C
ViscosityAfter7
71
Daysat250C
ViscosityAfter30
0
Daysat25 C
70
CompressiveStrengthAnalysis
WorkabilityChart
Slumpinmm
@0.9%
Dosage
CompressiveStrengthin
MPA
Slumpinmm
@0.7%
Dosage
@0.9%
Dosage
PhysicalProperties
%NVM
40.12
SG@250C
1.12
pH@250C
6.03
(%)
56
12.8
31.2
100
300
250
200
150
100
50
0
CompressiveStrengthAnalysis
300
250
200
150
100
50
0
0.5
3.5
Sample6
PhysicalProperties
%NVM
39.81
1.14
SG@250C
5.77
pH@250C
WorkabilityChart
WorkabilityChart
Sample5
AdmixtureFormulations
TestMix
PCWR1
CaLignoB
Water
Total
2.5
AdmixtureFormulations
Slumpinmm
@0.9%
Dosage
CompressiveStrengthin
MPA
Slumpinmm
@0.7%
Dosage
1
32
Compatibility
ViscosityAfter24
Hrsat250C
32
ViscosityAfter7
0
35
Daysat25 C
ViscosityAfter30
34
Daysat250C
CompressiveStrengthAnalysis
WorkabilityChart
150
100
50
0
0.5
Sample4
PhysicalProperties
%NVM
39.97
SG@250C
1.15
pH@250C
5.3
AdmixtureFormulations
1.5
Timeinhour
Dosage%
TestMix
PCWR1
NaLigno
Water
Total
45
Compatibility
ViscosityAfter24
Hrs at250C
45
ViscosityAfter7
0
Daysat25 C
47
ViscosityAfter30
Daysat250C
46
WorkabilityChart
1Day
0.70%
VISCOSITYFCB4
250C
CompressiveStrengthin
MPA
80
60
40
20
0
(%)
40
21.6
38.4
100
2.5
Timeinhour
3.5
CompressiveStrengthin
MPA
0.5
CompressiveStrengthin
MPA
Slumpinmm
@0.7%
Dosage
0
TestMix
PCWR1
NaLigno B
Water
Total
CompressiveStrengthAnalysis
WorkabilityChart
300
250
200
150
100
50
0
PhysicalProperties
%NVM
40.54
SG@250C
1.13
pH@250C
5.62
AdmixtureFormulations
Slumpinmm
TestMix
PCWR1
PCSR1
Water
Total
Compatibility
ViscosityAfter24
Hrsat250C
52
ViscosityAfter7
0
52
Daysat25 C
ViscosityAfter30
52
Daysat250C
70
60
50
40
30
20
10
0
1Day
7Day
0.70%
0.90%
28day
Dosage%
6/8/2012
Sample7
Sample8
21.6
45.2
100
VISCOSITYFCB4
250C
44
1.5
NaLigno
Water
Total
2.5
3.5
Timeinhour
80
60
40
20
0
7Day
0.90%
21.6
38.4
100
@0.7%
Dosage
28day
0.5
VISCOSITYFCB4
250C
@0.9%
Dosage
3.5
@0.7%
Dosage
@0.9%
Dosage
2
2.5
3.5
Timeinhour
SNF (42%)
Water
Total
60
50
40
30
20
10
0
1Day
7Day
0.70%
0.90%
66.8
20.4
100
VISCOSITYFCB4
250C
100
80
60
40
20
0
@0.7%
Dosage
0.5
28day
1.5
2.5
3.5
@0.9%
Dosage
Timeinhour
VISCOSITYFCB4
250C
51
Compatibility
ViscosityAfter24
51
Hrsat250C
ViscosityAfter7
51
Daysat250C
ViscosityAfter30
0
51
Daysat25 C
AdmixtureFormulations
TestMix
(%)
PCSR1
80
Water
Total
@0.7%
Dosage
2
2.5
Timeinhour
3.5
Slumpinmm
Slumpinmm
300
250
200
150
100
50
0
1.5
70
60
50
40
30
20
10
0
1Day
7Day
0.70%
0.90%
28day
Dosage%
PhysicalProperties
%NVM
40.01
1.1
SG@250C
6.51
pH@250C
20
100
VISCOSITYFCB4
250C
38
Compatibility
ViscosityAfter24
38
Hrsat250C
ViscosityAfter7
38
Daysat250C
ViscosityAfter30
0
38
Daysat25 C
WorkabilityChart
WorkabilityChart
17
Compatibility
ViscosityAfter24
17
Hrsat250C
ViscosityAfter7
18
Daysat250C
ViscosityAfter30
Daysat250C
18
Sample12
PhysicalProperties
%NVM
40.2
1.1
SG@250C
6.5
pH@250C
20
100
0.5
0.90%
CompressiveStrengthAnalysis
WorkabilityChart
Sample11
AdmixtureFormulations
TestMix
(%)
PCWR1
80
28day
0.70%
PhysicalProperties
%NVM
39.98
1.2
SG@250C
6.15
pH@250C
Dosage%
Water
Total
7Day
Dosage%
AdmixtureFormulations
TestMix
(%)
Na Ligno
12.8
Slumpinmm
140
120
100
80
60
40
20
0
1.5
18
Compatibility
ViscosityAfter24
18
Hrsat250C
ViscosityAfter7
19
Daysat250C
ViscosityAfter30
Daysat250C
20
CompressiveStrengthAnalysis
CompressiveStrengthin
MPA
Slumpinmm
WorkabilityChart
2.5
1Day
70
60
50
40
30
20
10
0
Sample10
PhysicalProperties
%NVM
40.41
1.2
SG@250C
6.6
pH@250C
47.6
30.8
100
0.5
Timeinhour
Sample9
AdmixtureFormulations
TestMix
(%)
NaLigno
21.6
1.5
43
Compatibility
ViscosityAfter24
43
Hrsat250C
ViscosityAfter7
44
Daysat250C
ViscosityAfter30
Daysat250C
44
CompressiveStrengthAnalysis
300
250
200
150
100
50
0
Dosage%
SNF(42%)
Water
Total
VISCOSITYFCB4
250C
WorkabilityChart
1Day
0.70%
PhysicalProperties
%NVM
40.36
1.14
SG@250C
5.12
pH@250C
CompressiveStrengthin
MPA
CompressiveStrengthin
MPA
Slumpinmm
@0.7%
Dosage
@0.9%
Dosage
0.5
AdmixtureFormulations
TestMix
(%)
PCWR3
40
CompressiveStrengthAnalysis
WorkabilityChart
300
250
200
150
100
50
0
0
Compatibility
ViscosityAfter24
44
Hrsat250C
ViscosityAfter7
45
Daysat250C
ViscosityAfter30
Daysat250C
43
Slumpinmm
NaLigno
Water
Total
PhysicalProperties
%NVM
40.28
1.14
SG@250C
4.79
pH@250C
CompressiveStrengthin
MPA
AdmixtureFormulations
TestMix
(%)
PCWR2
33.2
300
250
200
150
100
50
0
@0.7%
Dosage
0
0.5
1.5
2.5
3.5
Timeinhour
6/8/2012
SETTINGTIMES
AT0.7%DOSAGE
SETTINGTIMES
AT0.9%DOSAGES
WORKABILITY
ATO.7%DOSAGE
WORKABILITY
AT0.9%DOSAGE
COMPRESSIVESTRENGTHS
AT0.7%DOSAGE
COMPRESSIVESTRENGTHS
AT0.9%DOSAGE
6/8/2012
MARSHCONERESULTS
AIRCONTENT
COMPATIBILITY,SETTINGTIMEANDWORKABILITY
RESULTS&DISCUSSION
CompatibilityofPCWRandLScombinationshasbeen
established.
At250C,allformulationsat0.7and0.9%dosagesarenearto
therequirementofASTMC494typeG,forsettingtime.
Asthedosageislowretardationisundercontrol.
At0.7%PCWR:PCSRandtheircombination,givesgood
workabilityretention.
50:50combinationsofPCWRandNALsgivegoodinitial
workabilitybuttheslumpdropsquicklyafter30minutes.
COMPATIBILITY,SETTINGTIMEANDWORKABILITY
COMPRESSIVESTRENGTHANDAIRCONTENT
PCWR:NALs75:25combinationretainsslightlybetterthan
50:50combination.
At0.9%bothPCWRandNaLSaswellasCaLSprovidegood
retention.
NaLScombinationgivesbetterretention.
PCWRandNaLS75:25combinationprovidesbestslump
retention.
ItisobviousthattheretentionofSNF:NaLScombinationsis
nowaynearPCWR:NaLScombination.Thiscouldbedueto
averylowW/Bratioof0.3.
Bestcompressivestrengthachieved@0.7%
dosage.
Compressivestrengths
At0.7%dosage
PurePCEs>75:25PCE:LS>50:50PCE:LS.
At0.9%dosage
75:25PCE:NaLS>50:50PCE:NaLS
25:75PCWR:NaLS>75:25SNF:NaLS
Aircontentofallthemixeshasnotvaried
muchduetolowerdosages.
6/8/2012
CONCLUSIONS
PATHFORWARD
WorkInProgress
StudyinvolvingGGBFSanddifferentcementbrands.
TocheckotherPCEmolecules.
FurtherStudies
Longtermcompatibilityandcompatibilitywithvarious
cementtypes.
AthigherdosagesandhigherW/Bratios.
ACKNOWLEDGEMENTS
ACIINTERNATIONAL
MyOrganization CHEMBONDCHEMICALSLIMITED
MycolleaguesacrosstheorganizationatChembond
forsupportingmystudyinvariouscapacities
BorregaardIndiaLimitedforprovidingsamplesand
detailsonLS
Ultratechcementforprovidingvaluablesupportin
testingcementsamples
THANK YOU
Deepak Kanitkar, DGM - Technology & Business Development
Chembond Chemicals Ltd. India
ACI Spring Convention 2012 Dallas - USA