S L V ACADEMY 22. Mention the uses of Sodium hydroxide?

PART – C
Old Widia School Premises, Opp to H.K.R Choultry, Hesaraghatta Main Road, Nagasandra
I Answer any TWO of the following 2 5 =10
Post, Bengaluru –73
23. a) Describe the manufacture of ammonia by Haber’s process.
II PUC CHEMISTRY I PREPARATORY EXAMINATION b) What is Oleum? 4 +1
24. a) Mention the Postulates of Werner’s theory.
Marks = 90 Time: 3 hrs b) Write the general electric configuration of d-block elements? 4 +1
25. a) Describe Ramsay – Rayleigh-s method of isolating mixture of noble
PART – A gases from air.
I. Answer the following 1 10 =10 b) Calculate the EAN of Iron in K4[Fe(CN)6 ]. 3 +2

1. Which noble gas is not adsorbed by charcoal? II. Answer any THREE of the following 3 5 = 15
2. Name the reagent used in dehydrohalogenation reaction. 26. a) Explain the mechanism of Sulphonation of Benzene.
3. Define angle strain. b) Define the term Plane of symmetry. 4+1
4. Give the I.U.P.A.C name of [Fe (CN)6]4– 27.a) Explain the mechanism of SN1 reaction with an example.
5. Write the E.C of Cr (Z = 24). b) Acetophenone does not give white crystals with NaHSO3.
6. Sodium hydroxide is always stored in air tight bags or bottles. Give Give reason. 4+1
reason. 28. a) Explain the isolation of Phenol from coal tar.
7. Write the chemical name of picric acid. b) What is the effect of electron withdrawing group – Cl on the acidity
8. What is inductive effect? of carboxylic acids? 4+1
9. What is Hydronium ion? 29. a) Explain Clemensen’s reduction with an example.
10. What is the conjugate base of HSO4–? b) What is carbylamine reaction? Give an example.
c) Mention any two uses of Ethanoic acid. 2+2+1
PART – B
Answer any TEN of the following 2 10 =20
11. How is ethanol obtained from methanol? III Answer any THREE of the followings 3 5 = 15
12. Mention any two demerits of Arrhenius theory.
13. State Faraday’s II law of electrolysis. 30.a) Derive the expression k= log
14. What are Enantiomers? b) What is an electrolyte? 4+1
15. Explain linkage isomerism with an example. 31. a) Mention the postulates of Arrhenius theory of Electrolytes.
16. Explain Aldol condensation with an example. b) Give an example for Zero order reaction 4+1
17. Explain Carbyl amine reaction with an example. 32. a) Mention the differences between metallic and electrolytic conductors
18. Give two tests to distinguish b/w aldehydes and ketones? b) What is conjugate acid – base pair?
19. How is acetic acid prepared from ethanol?
20. Give two differences between inductive effect and electromeric effect. c) What is amphoteric substance? 2 + 2 +1
21. How does sulphuric acid react with magnesium? Give equation. 33. a) State Faraday’s I law of Electrolysis
 b) Mention any two limitations of Arrhenius theory.
c) What is a strong electrolyte 2+2+1
34. a) Define the terms. a) Equivalent Conductance
b) Specific Conductance.
b) What is the conjugate acid of NH3?

PART – D
D1 Answer any ONE of the following 1 10 =10
35. a) Explain the chemical reactions that occur during the extraction of
Iron from Haematite.
b) Explain the extraction of phenol from coal tar
c) Explain the mechanism of nitration of benzene. 3+3+4
36. a) on the basis of VBT explain hybridization, geometrical shape and
magnetic property in cuprammonium sulphate.
b) Explain the structural elucidation of glucose.
c) Explain Bronsted-Lowry concept of acids and bases. 4+4+2

D2 Answer any TWO of the following 2 5 = 10

37. a) Explain the laboratory preparation of p – Bromoacetanilide from
Acetanilide
b) Explain the test for polysaccharide 3+2
38. a) Explain the determination of rate constant for the acid hydrolysis of
methyl acetate 4 +1
39. Describe the experiment to determine the mass of Mohr’s salt crystals
in 250ml solution by using standard potassium dichromate solution.
Give the equation for the reaction.