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groundwater , ,
TECHNICAL FACETS
pre-filter
,,
post-filter
,,
clear water
reservoir
, , water tower , ,
consumers
Example
4.5
Aeration
and gas
transfer
Table 4
QualitydataoftherawandtreatedwateratSt.
Jansklooster pumping station (Overijssel)
Parameter
Temperature
pH
EGV
SI
Unit
Raw water
Clear water
10.5
10.5
6.9
7.6
51
48
-0.4
0.2
mS/m
Turbidity
FTU
Na-
mg/l
23
21
K-
mg/l
Ca'"
mg/l
82
77
Mg J *
mg/l
5.2
6.3
ci-
mg/l
41
41
HC0 3 -
mg/l
267
241
SO,*
mg/l
18
21
NO,
mg/l
0.07
1.6
mg/l
10.7
<0.05
<0.1
the water (deep well aerators, plate aerators, c o m pressor aerators). Technically, these systems can
be realized in a great number of ways.
CH,
CO,
mg/l
mg/l
63
11
Fe 2 -
mg/l
8.8
0.04
Win2"
mg/l
0.3
<0.01
NH/
mg/l
2.2
<0.01
DOC
mg/l
n/100 ml
Bentazon
MS"
Chloroform
M9"
Bromate
M9/I
E-Coli
272
because the remaining content will affect the postfilters. The removal of C 0 2 has to be controlled
because its level influences the pH and with that the
SI. Table 5 gives a global indication of the effects
of the various aeration systems.
TECHNICAL FACETS
Table 5
GROUNDWATER
Favorable effect
Potential system
Input of 0 2
All systems
Low removal of CO ?
Spraying
High removal of CO ?
Tower aeration
High removal of CH 4
Kinetics
Gases are, to some extent, soluble in water. The
concentration of a gas in the water phase is in
equilibrium linear to the concentration of the gas
in the air phase (equilibrium in conformance with
Henry's Law). This equilibrium concentration is also
called the "saturation concentration." Saturation
means "at a fixed concentration of the gas in the
air phase." This situation is obtained with a continuous replacement of the air phase. For oxygen
in water that is in equilibrium with air, a saturation
concentration of 12 mg/l can be calculated (10C,
2 1 % oxygen, 1 bar).
400
800
1,200
time (sec)
saturation concentration
concentration
(c."co)
The equilibrium isn't achieved at once with intensive contact between water and air. Rather, the
gas exchange takes place at a rate which is linear
to the driving force. This driving force is the difference between the actual concentration and the
equilibrium concentration:
dc,
= k 2 -(c,-c,)
dt
in which:
c, = concentration of a gas in water
at time t
cs = equilibrium concentration of that
gas in water
k, = gas transfer coefficient
(g/m3)
in which:
c0 = concentration of a gas in water
at time t = 0
The profile of the oxygen concentration in an aeration device is shown in Figure 31. The oxygen
content initially rises quickly and then increases
less because of the reduced driving force.
Efficiency
The efficiency of aeration can be defined as the
achieved decrease in the driving force divided by
the possible decrease in the driving force:
(g/m 3 )
(s-<)
The gas transfer coefficient depends on the magnitude of the contact surface between water and air
(greater surface area, higher k2), and on the rate
at which this surface is replaced (greater replacement, higher k ).
(g/m3)
K=
(CS-C^)-(Cs-Col
= 1-e~
in which:
K = efficiency of gas transfer
cm = concentration of the gas before
aeration
cM= concentration of the gas after
aeration
(-)
(g/m3)
(g/m3)
273
GROUNDWATER
TECHNICAL FACETS
RQ = ^ in which:
RQ = air-water ratio
Qg
= air (gas) flow
Qw
= water flow
(-)
(m3/s)
(m3/s)
274
Figure 32 - Downward spraying with plate nozzles (Dresden nozzles) over a sand filter at Schiermonnikoog pumping station (Friesland)
GROUNDWATER
TECHNICAL FACETS
second aeration.
1 . 5 - 4 m in total).
275
GROUNDWATER
TECHNICAL FACETS
' = V2-g-h
in which:
v = fall rate
h = fall height
g = gravity acceleration
(m/s)
(m)
(9.81 m/s2)
The efficiency per step remains at 33%, but the absolute increase in the oxygen content decreases
more and more (from 4 mg/l per step to 1.2 mg/l per step).
276
GROUNDWATER
TECHNICAL FACETS
B air supply
of the venturi.
Oxygen c a n be added to this system, but gas
Deep well aeration
Plate aeration
277
GROUNDWATER
TECHNICAL FACETS
water
^J
A influent
B packing
C air supply
D effluent
E air outlet
278
pumping
4.6
Filtration
Filtration of groundwater is a process similar to the
filtration of surface water. Both consist of a filter
(sand) bed of 1 - 2 m through which water flows.
The filter is backwashed (almost) daily, cleaned