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concentration of flammable gas in air at atmosphere pressure capable of being ignited. Upper
Explosive Limit (UEL) is the highest concentration of flammable gas in air at atmospheric pressure
capable of being ignited. A concentration of flammable gas in air at atmospheric pressure, above
which combustion will not occur. Any mixture within these limits will combust. The limits vary from
product to product, but for hydrocarbons the typical range is from 1 12 % vapour to air.
Flash Point and Auto Ignition Temperature
Petroleum products will burn in air under certain conditions of temperature and vapour mixture. Flash
point is defined as the lowest temperature of a liquid sample at which application of a test flame
causes vapour of the sample to ignite under specific test conditions of test. Flash point is important for
legislation and safety. Flash point is a vital measure for safe handling of hydrocarbon products, and
can also be used to check for cross contamination. Products are classified according to Flash Point and
these classifications carry legal consequences. Below is the classification of petroleum products by
flash point.
Class
Class I
Characteristics
Liquids which have a
Remarks
Class II and Class III liquids may be sub-divided further.
Class II
inclusive.
Liquids which have a
flash point greater than
55C up to and including
100C.
point temperature.
Class II (2) Liquids handled ad stored at or above their
flash point temperature.
Class III products may be similarly sub divided.
Liquids with flash points above 100C are not classified.
Liquefied Petroleum Gas (LPG) is a separate class (Class
The laboratory method of measuring the vapour pressure of petrol in products is by means of
the Reid Vapour Pressure Bomb. The standard test method is covered by ANSI/ASTM D 323. Results
are expressed as Reid Vapour Pressure (RVP) which differs slightly from true vapour pressure (TVP)
due to some small sample vaporisation and the preserved water vapour and air in the confined space.
Viscosity
Viscosity is a measure of resistance to movement or flow within a liquid and it is temperature
dependent. Viscosity is important for pump ability and performance. It affects the operation of fuel
injection equipment from the customers perspective meanwhile it is important for line sizing and
pumping from an operational perspective. Very low viscosity can cause excessive wear, reduced
power and/or hot start problems. Too high viscosity can cause flow restriction, lead to poor
combustion and excessive crankcase dilution as the fuel is hard to atomise.
The rate of flow of a product in a pipeline will depend upon its viscosity. Product movement
of high viscous liquids at low temperature required special design of pumps of high cost requiring
large capacity motors with consequent high power consumption. Product become less viscous with
temperature increases. This is taken into consideration when pumping heavy fuel oils and bitumen
when product heating can be used to lower (reduce) viscosities to economic advantage.
The standard test method for measuring the kinematic viscosity of petroleum products is
ANSI-ASTM D445 which equates to IP 71.
Pour Point
At low temperatures, certain products, because of composition will no longer flow. The product
cannot be then be pumped until heated sufficiently. Pour point is defined as the lowest temperature,
expressed as a multiple of 3C (5F), at which the oil is observed to flow when cooled and examined
under prescribed conditions. A suitable test method is described under ANSI/ASTM D97 which
equates to IP15.
Conductivity
Conductivity is a measure of fluids ability to carry an electrical charge and is a vial to allow any static
charge to dissipate. It is the inverse of resistance and generally the purer the oil will have lower
conductivity. In between, the chemical composition affects the conductivity, for example the polar
species improve the conductivity, any metallic compound or trace metals. Conductivity is increased
by water or other contaminants such as dirt. It is measured by using a portable safe meter and is
temperature dependent. The units are Pico Siemens per meter (S/m) or often abbreviated to CF
(mho/cm). If the products have a value of less than 10pS, it is considered a low and unsafe level; the
typical minimum specification of the product is 50pS.
Research Octane Number (RON) and Motor Octane Number (MON). RON was the original 1930
test engine and is low speed 600 rpm and low load. MON is a modification of the original method to
stimulate higher speed and higher load (900rpm and changeable spark advance). Although both
methods are normally used to specify the fuel performance, RON is the well-known and most quoted
method.