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COMPRESSIBLE FLOW
T-s Diagram
Tt9
t9
4
Tt4
t5
Tt5
Tt3
Tt0=Tt2
T0
Is it possible to change p
with dynamic pressure?
Modulus Bulk
=
=
/
K water
5 x 10-10 m2/N
K air
1 x 10-5 m2/N
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State Condition
Perfect gas :
Intermolecular forces are neglected
= pressure [/2 ]
= [kg/3 ]
Repulsive
force (+)
10 x molecule diameter
= []
= constant
= 287 [2 / 2 ]
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1st Law: dU = dQ + dW
o Find more useful expression for dw, in
terms of p and r (or v = 1/r)
= =
=
=
Change in
Volume (-)
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= + = +
Differentiate
= + +
= + +
= + +
=
= +
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dq
dT
dq
J
c
kgK
dT
Specific heat is heat added per unit change in temperature of system
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dq
J
c
kgK
dT
Different materials have different specific heats
Balloon filled with He, N2, Ar, water, lead, uranium, etc
For a fixed dq, resulting dT depends on type
of process
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dq
dT
dq
J
c
kgK
dT
dq
cv
dT constant volume
dq cv dT
du cv dT
u cvT
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dq
dT
dq
J
c
kgK
dT
dq
cp
dT constant pressure
dq c p dT
dh c p dT
h c pT
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Real Gas
Intermolecular forces
P = 1000 atm
T = 30K
For air
Calorically PG
0-800 Ok
Thermally PG
800-2500 OK
Chemically reacting
2500-9000 OK
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= (, )
= (, )
For thermally PG
For calorically PG
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= +
=
1
=
1
19
Entropy
+ =
Helmholtz function :
maximum work that can be obtained from a system
Gibbs function :
maximum useful work that can be obtained from a system
+ =
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