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speed of forward
reaction
a increases
does not change
speed of backward
reaction
increases
does not change
b
c decreases
decreases
increases
does not change
d
11. In the graph, curve X represents the results of the reaction between 1.0 g of granulated zinc
and an excess of acid at 30oC.
20. Most fuels contain small amounts of sulphur. When they burn, a gas which pollutes the
atmosphere and causes acid rain is formed. it is called
a. carbon monoxide
b. carbon dioxide
c. sulphur dioxide
d. sulphur trioxide
21. Methane (CH4) is the main constituent of natural gas. When it burns, it produces 890 kJ of heat
per mole. How much heat would be produced if 64 g of methane were burnt?
[Ar of C = 12, Ar of H = 1]
a. 890 kJ
b. 1780 kJ
c. 2670 kJ
d. 3560 kJ
22. Which of these reactions would you expect to be endothermic?
a. 4K (s) + O2 (s) --> 2K2O (s)
b. H2 (g) --> 2H (g)
c. 2NaOH (aq) + H2SO4 (aq) --> Na2SO4 (aq) + 2H2O (l)
d. 2H2 (g) + O2 (g) --> 2H2O (l)
23. An endothermic reaction is one in which
a. the reaction vessel gets hot
b. light is given out
c. the products contain more energy than the reactants
d. chemical bonds are made
24. Which pair of elements, described by their proton number, will react together most
exothermically?
a. 2 and 8
b. 12 and 16
c. 3 and 10
d. 19 and 9
25. A fuel is a device for
a. converting electrical energy efficiently into chemical energy
b. converting chemical energy efficiently into electrical energy
c. recharging accumulators
d. burning a fuel efficiently
26. The formation of hydrogen iodide from hydrogen and iodine is an endothermic reaction.
H-H + I-I ---> H-I + H-I
What may be deduced from this information?
a. The number of bonds broken is greater than the number of bonds formed.
b. The formation of H-I bonds absorbs energy.
c. The products possess less energy than the reactants.
d. The total energy change in bond formation is less than that in bond breaking.
27. Methane gas reacts extremely slowly with air at room temperature. If a piece of warm platinum
is held in a methane-air mixture, the methane ignites. What differences are there between the
reaction with the platinum and the reaction without the platinum?
For the reaction with the platinum:
I. The activation energy is lower.
II. The energy change is greater.
III. The energy of the reactants is higher.
IV. The rate of reaction is greater.
a. I and II only
b. I and III only
c. I and IV only
d. II and IV only
28. The graph shows how the total volume of hydrogen produced changes when iron fillings
reacted with excess dilute sulphuric acid.
Experiment B: 100 cm3 of 5.0 mol/dm3 hydrochloric acid added to an excess of limestone.
The initial rate of evolution of carbon dioxide and the total volume of carbon dioxide evolved were
measured in each experiment. How do the results in experiment A compare with those in
experiment B when all other conditions are identical?
Rate of evolution of carbon dioxide
a.
It is slower in A than in B.
b.
It is faster in B than in A.
It is greater in B than in A.
c.
It is slower in B than in A.
It is greater in B than in A.
d.
It is greater in A than in B.
MCQ Answers
1. c
2. d
3. b
4. b
5. b
6. c
7. a
8. a
9. d
10. a
11. c (since the total vol of H2 collected is about half of X, the mass of Zn used should be halved. The
steeper gradient of Y suggests a faster rate of reaction eg higher temperature)
12. b
13. c
14. c
15. d (there are no gaseous reactants in the reaction)
16. c
17. c
18. b
19. a
20. c
21. d
22. b
23. c
24. d
25. b
26. d
27. c
28. b
29. a
30. b
Worked Solutions
1. A metallic element forms compounds in which its oxidation states are II and III. The element is
displaced from solutions of its salts by copper.
a. Using the symbol El for the element, write the formulae for the chlorides and oxides of this
element.
chlorides ______ and ________
oxides _______ and _________
b. Why is it necessary for the symbols of the majority of the elements to consist of two letters
rather than one only?
c. Would you expect this element El to react with dilute sulphuric acid? Explain your answer.
d. Write an equation to show the reduction of an ion of this element El from oxidation state III to
oxidate state II
Solution
a. chlorides: ElCl2 and ElCl3
oxides: ElO and El2O3
b. There are elements with names that start with the same letter eg. copper (Cu) and carbon (C)
c. No. Because copper does not react with dilute sulphuric acid and El is less reactive than copper.
ai. Ozone molecules O3 decompose when heated into O2 molecules. Construct the equation for
this decomposition.
aii. What volume of oxygen O2 is formed when 40cm3 of ozone O3 is decomposed, both volumes
being measured at the same temperature and pressure?
b. Ozone is an oxidizing agent. Describe the color change you expect to see when ozone is
bubbled into aqueous potassium iodide.
color before:
color after:
Solution
ai. O3 (g) --> 3/2 O2 (g)
aii. 60 cm3
bi. colorless
bii. brown
5a. Ammonia is made in the Haber process by the reversible reaction between nitrogen and
hydrogen.
i. How is nitrogen obtained from liquid air for use in this process?
ii. State the name of the catalyst and the conditions used in the Haber process.
b. Ethanol can be manufactured by reacting ethene and steam in the presence of phosphoric acid
as a catalyst.
The reaction is reversible and forms an equilibrium mixture.
C2H4 (g) + H2O <--> C2H5OH (g)
i. Predict how increasing the pressure will change the percentage of ethanol present at
equilibrium. Explain your answer.
ii. The table shows how the percentage of ethanol present at equilibrium changes with
temperature at a pressure of 60 atmospheres.
temperature/oC
percentage of ethanol
produce/%
200
49
260
38
320
34
6. The table below shows some bond energies, measured in kilojoules per mole. Bond energy is
the energy required to break the bonds between pairs of atoms
bond
bond energy in
kJ/mol
bond
bond energy in
kJ/mol
H-H
436
Cl -
242
Cl
H - Cl
431
C-H
412
C=C
612
C-C
348
N=N
409
N-N
163
7. In the Contact process for the manufacture of sulphuric acid, sulphur dioxide is converted into
sulphur dioxide.
2SO2 (g) + O2 (g) <---> 2SO3 (g) H = - 98 kJ/mol
a. The reaction reaches a dynamic equilibrium. Explain the term.
b. A mixture of sulphur dioxide, oxygen, and sulphur trioxide was allowed to reach equilibrium,
then the temperature was raised. Predict the effect of raising the temperature on
i. the composition of the equilibrium mixture
ii. the rate of reaction
Explain your answers.
c. Describe how you would prepare a pure dry sample of sodium sulphate starting with dilute
sulphuric acid.
Solution
7a. At dynamic equilibrium for a reversible reaction, the forward rate of reaction is equal to the backward
rate of reaction, and both rates are not equal to zero.
7bi. Amount of SO3 decreases. When temperature is raised, the equilibrium shifts to the left where heat is
absorbed (backward reaction is endothermic) so as to counteract the temperature change.
7bii. Faster rate of reaction. Since temperature is raised, both forward and backward rates of reaction are
increased.
7c. First, perform a titration on 25.0 cm3 of aqueous NaOH, with dilute sulphuric acid using a suitable
indicator such as phenolphthalein. The volume of acid used is noted at the end point when the colour of
the indicator changes. Repeat the experiment but without the indicator. The final solution will be sodium
sulphate solution. Crystalise sodium sulphate by evaporation. The crystals are filtered, washed with water,
and dried with filter paper and dessicator.
8. In the future, fuel cells may be used to power cars. In a fuel cell, the overall reaction is
represented by the equatin
2H2 (g) + O2 (g) --> 2H2O (l)
8a.
8aiii. The amount of energy released when covalent bonds in the water molecules are formed is greater
than the energy required to break covalent bonds in the hydrogen and oxygen molecules. Hence, there is
a net amount of energy released.
8b. Titanium, because transition metals are good catalysts.
9. Methane, CH4, is used as a fuel. The complete combustion of methane can be represented by
the equation below
a. Explain why this reaction is exothermic in terms of the energy changes that take place during
bond breaking and bond forming.
b. Calculate the energy released when 4.0g of methane is completely combusted.
c. Draw the energy profile diagram for the complete combustion of methane.
Solution
9a. The reaction is exothermic because the heat of reaction, H, has a negative value. The energy
released during formation of covalent bonds in products is greater than the energy absorbed to break
covalent bonds in reactants. Hence, the overall reaction is exothermic. A total of 890 kJ of energy is
released.
9b. Mr of CH4 = 16
No. of mol of CH4 = 4/16 = 0.25
Energy released = 0.25 x 890 = 225 kJ
9c.
10. Methane is a fuel. It completely burns to form carbon dioxide and water. When 1 mole of
methane is burned, 890 kJ of energy is released.
i. Suggest why liquid hydrogen, rather than hydrogen gas is carried by space rockets.
ii. Explain what is meant by an exothermic reaction.
iii. Which bonds are broken in this reaction.
iv. What type of energy change occurs when bonds are formed?
v. When 1 mole of hydrogen molecules reacts with oxygen, the energy H = -285kJ
Calculate the energy change which occurs when 100g of hydrogen reacts with oxygen.
Solution
11a. Hydrogen is formed from the reaction between steam and methane.
H2O (g) + CH4 (g) --> CO (g) + 3H2 (g)
bi. Liquid hydrogen occupies a smaller volume and so is easier to transport.
bii. Exothermic reactions are those where heat energy is released in the course of the reaction.
biii. H-H and O=O bonds
biv. Heat is released. Chemical energy is converted into heat energy, sometimes with the emission of
light.
bv. 100g of H contains 100/2 = 50 moles of H
Energy changes = 50(-285) = -14250kJ