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DESALINATION
Kai-Uwe Hoehn1, Robert Chu2, Jimmy Wei2, Markus Busch3, Angela Yeung4
1. Dow Water & Process Solutions, Sydney, Australia
2. Dow Water & Process Solutions, Shanghai, China
3. Dow Water & Process Solutions, Rheinmuenster, Germany
4. Dow Water & Process Solutions, Minneapolis, USA
ABSTRACT
In recent years low pressure ultrafiltration (UF) and
microfiltration (MF) pre-treatment technologies have
increasingly been employed to improve the
economics of seawater reverse osmosis (SWRO)
desalination plants and attract a great deal of
attention for integrated or dual membrane
systems in SWRO.
2)
3)
INTRODUCTION
Over the past decade, ultrafiltration (UF) has
gained much interest as an alternative pretreatment technology for seawater desalination;
those systems are often referred to as integrated
or dual membrane system. In the last decade
approximately 10 to 15 sizable SWRO installations
have adapted UF or MF as a pre-treatment (for
example Addur in Bahrain, numerous power plants
in China and also Adelaide and the Southern
Seawater Desalination Plant in WA) and an
increasing number of UF-SWRO pilot tests were
studied extensively. The main reasons to use UF as
pre-treatment for SWRO are typically:
1) The ability to handle challenging seawater
qualities: Growing coastal urbanisation and
industrialisation have led to increased ocean
pollution levels which can post an operational
challenge when trying to maintain a stable
SWRO plant performance. Even for regions
with better water quality, there are still potential
4)
5)
coagulation
and
clarification
processes.
Alternatively, ultrafiltration can be used to reduce
the workload. Characteristics of the two alternative
processes are:
Characteristics of traditional dual media filter (DMF):
1) Widely adopted in many projects.
2) Permeate quality is able to meet the basic
requirement of RO feed.
3) Coagulation and clarification or double pass
DMFs are often used to ensure 100% ROready permeate quality water.
4) Flocculation or coagulation aid and pH
adjustment acids are often used to maintain the
required filtered water quality. This adds
chemical and sludge discharge costs.
5) Backwash waste water from the filters needs to
be treated before discharge, operational
expenses for coagulating the backwash waste
water and for sludge dewatering need to be
taken into account.
6) Downstream RO flux is controlled at typically
<14 LMH.
7) High recovery, backwash can be done with
concentrate from the first pass RO. Filter
recovery can then reach 100%.
Characteristics of ultrafiltration (UF):
1) Only a single pass system is needed to 100%
fulfil the RO feed requirement.
2) Widely implemented in many small to medium
seawater desalination projects in the past 10
years. UF is progressing into larger scale
desalination projects: for example Yuhuan
China (30,000 m3/d), Fukuoka Japan (50,000
m3/d), Palm Jumeirah UAE (64,000 m3/d) and
Carlsbad California (132,000 m3/d).
3) Significantly reduce, if not completely eliminate,
the chemical dosages and thus costs for
flocculation/coagulant aids and inorganic acids
and consequently reduce the costs for
coagulation
and
sedimentation
sludge
treatment.
4) If the UF/MF system is not dosed with any
chemicals, the backwash waste water could be
discharged into the sea directly, without further
treatment.
5) Downstream RO flux can be increased by over
15% to around <16 LMH.
6) Typical UF recoveries in seawater pretreatment applications are around 90%-96%.
7) UF systems significantly reduce the footprint
required.
PRE-TREATMENT FOR THE UF SYSTEM
When using UF as pre-treatment for seawater
desalination projects one has to ask, would
coagulation and clarification (sedimentation or DAF)
and chemical dosing still be needed? Coagulation
and clarification processes can often be eliminated
with UF membrane pre-treatment and the chemical
Chemical
Dosing
Seawater
Open feed
Coagulation
Clarification
Bypass
Bypass
Static Mixing
Sedimentation
Filtration
SWRO
P-DMF
P-DMF
1. Acid
2. Coagulants
3. Flocculants
P-DMF
G-DMF
Enhanced
Mixing
P-DMF: Pressurised Dual Media Filter
G-DMF: Gravity Dual Media Filter
P-UF: Pressurised UF
S-UF: Submerged UF
DAF: Dissolved Air Floatation
DAF
G-DMF
Screen
Screen
P-DMF
S-UF
P-UF
2860 @ 60 LMH
11,680,251
937,254
1,224,438
2,161,692
1.64
2.01
3.65
100.00%
2860 @ 75LMH
2880 @ 60 LMH
9,633,180
10,837,942
772,991
869,664
1,055,375
1,206,926
1,828,367
2,076,591
1.35
1.52
1.73
1.98
3.09
3.50
84.52%
95.98%
32%
25%
35%
2880 @ 75 LMH
8,745,564
701,767
1,018,308
1,720,075
1.23
1.67
2.90
79.44%
6%
5%
5%
19%
3%
7%
15%
0% 5%
0% 5% 0%
7%
0%
36%
26%
5%
3%
23%
34%
6%
5%
4%
14%
8%
0% 4%
0%
3%
19%
8%
Chemical
Power
UF Module Replacement
0%
4%
0%
3%
3%
3
10.6
21
smokeless coal + quartz sand
10 m/h
6.5-7.0
5ppm FeCl3,
0.2 ppm PAM
24 hr
10%
3
10.6
17
smokeless coal + quartz sand
single pass: 10 m/h,
double pass: 12 m/h
6.5-7.0
5ppm FeCl3
0.2 ppm PAM
single pass: 24 hr, double pass: 38 hr
10%
10
5,410,378
434,143
1,275,815
1,709,959
0.76
2.23
2.99
TCO of 1P-DMF
10%
3%
1%
1%
3%
0%
3% 4%
25%
2%
3%
2%
43%
TCO of 2P-DMF
3%
1%
15%
30%
1%
2%
0%
2%
3%
1%
3%
3%
36%
DMF Units(Excluding filermedia)
Feed & Backwash pumps & Blowers
Original Cartridge filters
Electrical & control
Installation & Commissioning
Power
Cartridge Filter Replacement
14 LMH /
0.7
15.5 LMH /
0.75
17 LMH /
0.8
56,830,221
54,566,518
52,711,918
Amortisation (US$)
4,560,204
4,378,559
4,229,740
9,334,591
9,337,347
9,347,234
13,894,795
13,715,906
13,576,975
Design
Concept
UF
conservative
SWRO
conservative
UF new design
SWRO
conservative
UF new
design
SWRO
aggressive
Pre-treatment
System
SFP2860
60 LMH
SFP2880
75 LMH
SFP2880
75 LMH
SWRO System
14 LMH
FF 0.75
15.5 LMH
FF 0.75
17 LMH
FF 0.8
2P-DMF
conservative
SWRO
conservative
double pass
DMF
2P-DMF
14 LMH
FF 0.7
2P-DMF
conservative
SWRO
aggressive
double pass
DMF
2P-DMF
15.5 LMH
FF 0.75
single pass
DMF
DMF
14 LMH
FF 0.7
20.66
19.75
19.16
20.14
19.43
19.41
41.04
40.28
40.28
42.14
42.15
41.23
61.70
60.03
59.45
62.27
61.58
60.64
101.75%
98.99%
98.04%
102.69%
101.55%
100.00%
6
SWRO
standard
design