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Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 1
ENGINEERING THERMODYNAMICS
It is defined as the amount of heat energy required to raise or lower the temperature of unit mass of
the substance through one degree when volume kept constant.
9. What is meant by surroundings?
Any other matter out side the system boundary is called as surroundings.
10. What is boundary?
System and surroundings are separated by an imaginary line is called boundary.
Extensive Properties
--
ENGINEERING THERMODYNAMICS
(a) Mechanical Equilibrium :- Pressure remains constant
(b) Thermal equilibrium :- Temperature remains constant
(c) Chemical equilibrium : There is no chemical reaction.
17. State the First law of thermodynamics applied to a cycle .
First of thermodynamics states that when system undergoes a cyclic process the net heat transfer is
equal to work transfer.
18. Define: PMM of first kind
PMM of first kind delivers work continuously without any input.
It violates first law of
thermodynamics, It is impossible to construct an engine working with this principle.
19. Define the term process
It is defined as the change of state undergone by a fluid due to energy flow.
20. Define the term Cycle:
When a system undergoes a series of processes and return to its initial condition, it is known as cycle.
ENGINEERING THERMODYNAMICS
follows continuous series of equilibrium states.
reversible process.
ENGINEERING THERMODYNAMICS
Isentropic process is also called as reversible adiabatic process. It is a process which follows the law of
pV = C is known as isentropic process. During this process entropy remains constant and no heat
enters or leaves the gas.
34. Explain the throttling process.
Throttling process involves the passage of a higher pressure fluid through a narrow constriction. The
effect is the reduction in pressure and increase in volume. This process is adiabatic as no heat flows
from and to the system, but it is not reversible. It is not an isentropic process. The entropy of the fluid
actually increases
35. What is the work done in a free expansion process ?
Zero
36. Define free expansion process.
When a gas expands suddenly into a vacuum through a large orifice is known as free expansion
process.
37. Which property is constant during throttling?
Enthalpy
38. If in the equation PVn = C, the value of n =INFINITY then the process is called _______
Constant Volume process
39. The polytropic index (n) is given by ________
n = log (P2/P1)/ log (V1/V2)
40. Work transfer is equal to heat transfer in case of ________ process.
Isothermal process.
41. Write down the characteristic gas equation.
Characteristic gas equation is pV = mRT
Where,
p = pressure
V = Volume
R = Characteristic gas constant
T = Temperature.
42. What is meant by steady flow process?
If the rate of flow of mass and energy across the boundary remains constant during a process , it is
known as steady flow process.
43. What is the difference between steady flow and non flow process?
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 5
ENGINEERING THERMODYNAMICS
During the steady flow process the rate of flow of mass and energy across the boundary remains
constant.
A process may be non-flow in which a fixed mass within the defined boundary is undergoing a change
of state. Example : A substance which is being heated in a closed cylinder undergoes a non-flow
process
ENGINEERING THERMODYNAMICS
52.What is an adiabatic system ?
An adiabatic system is one which is thermally insulated from its surroundings. It can,however,
exchange work with its surroundings. If it does not, it becomes an isolated system.
53.Distinguish classical (macroscopic ) and statistical (microscopic ) thermodynamics .
In this approach a certain quantity of matter is considered without taking into account the events
occurring at molecular level. In other words this approach to thermodynamics is concerned with gross
or overall behaviour. This is known as classical thermodynamics.
The approach considers that the system is made up of a very large number of discrete particles
known as molecules. These molecules have different velocities and energies. The values of these
energies are constantly changing with time. This approach to thermodynamics which is concerned
directly with the structure of the matter is known as statistical thermodynamics
54.Define Irreversible process and give examples .
The process is said to be an irreversible process if it cannot return the system and the surroundings to
their original conditions when the process is reversed. The irreversible process is not at equilibrium
throughout the process. An irreversible process is usually represented by a dotted (or discontinuous)
line joining the end states to indicate that the intermediate states are indeterminate .
Examples.
(i) Relative motion with friction (ii) Combustion(iii) Diffusion (iv) Free expansion(v) Throttling (vi)
Electricity flow through a resistance(vii) Heat transfer (viii) Plastic deformation.
55.Discuss external and internal irreversibilities with examples.
External irreversibilities. These are associated with dissipating effects outside the working fluid.
Example. Mechanical friction occurring during a process due to some external source.
Internal irreversibilities. These are associated with dissipating effects within the working fluid.
Example. Unrestricted expansion of gas, viscosity and inertia of the gas.
56. Prove that for an isolated system, there is no change in internal energy.
For any isolated system, there is no heat, work and mass transfer.
Q=W=0
According to the first law of thermodynamics.
Q=W+U
U=0
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 7
ENGINEERING THERMODYNAMICS
ENGINEERING THERMODYNAMICS
Perpetual motion machine of second kind draws heat continuously from single reservoir and
converts it into equivalent amount of work. Thus it gives 100% efficiency.
6. What is the difference between a heat pump and a refrigerator?
Heat pump is a device which operating in cyclic process, maintains the temperature of a hot
body at a temperature higher than the temperature of surroundings.
A refrigerator is a device which operating in a cyclic process, maintains the temperature of a
cold body at a temperature lower than the temperature of the surroundings.
7. What is meant by heat engine?
A heat engine is a device which is used to convert the thermal energy into mechanical energy.
8. Define the term COP?
Co-efficient of performance is defined as the ratio of heat extracted or rejected to work input.
a. COP
b.
9. Write the expression for COP of a heat pump and a refrigerator?
Source Temperatur e
Source Temperatur e - Sink Temperatur e
COP of Refrigerat or
Source Temperatur e
Source Temperatur e - Sink Temperatur e
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 9
ENGINEERING THERMODYNAMICS
13. Why a heat engine cannot have 100% efficiency?
For all the heat engines there will be a heat loss between system and surroundings. Therefore we
cant convert all the heat input into useful work.
14. When will be the Carnot cycle efficiency is maximum?
Carnot cycle efficiency is maximum when the initial temperature is 0K.
15. What are the processes involved in Carnot cycle.
Carnot cycle consist of
Reversible isothermal compression
isentropic compression
reversible isothermal expansion
isentropic expansion
16. State carnot theorem?
No heat engine operating in a cyclic process between two-fixed temperatures can be more
efficient that a reversible engine operating between the same temperature limits.
17. Define PMM of second kind?
Perpetual motion machine of second kind draws heat continuously from single reservoir and
converts it into equivalent amount of work, Thus it gives 100 percentage efficiency.
18. What is meant by heat engine?
A heat engine is a device, which is used to convert the thermal energy into mechanical energy.
19. Define the term absolute entropy?
The change in entropy of the system with respect to ambient conditions or any other standard
reference condition is known as absolute entropy.
The part where the heat to be rejected to work absorbing or work developing device is
called source.
Sink: The part which receives heat from work absorbing or work developing device is called sink.
Reservoir:
The part which supplies or receives heat continuously without change in its
ENGINEERING THERMODYNAMICS
In statistical thermodynamics, entropy is associated with the notion of disorder and the second
law statement that the entropy of an isolated system undergoing a spontaneous process tends
to increase is equivalent to saying that the disorder of the isolated system tends to increase.
Entropy is an index of unavailability or degradation of energy.
23. Is the second law is independent of first law? Explain.
Yes. The second law is independent of first law. The second law speaks about the quality of
energy.
24. Define change of entropy. How is entropy compared with heat transfer and absolute
temperature?
The measure of irreversibility when the energy transfer takes place within the system or
between the system and surrounding is called as change of entropy. It is simply known as
unaccounted heat loss.
25. State corollaries of carnot theorem?
The thermal efficiency of an irreversible power cycle is always less than the thermal
efficiency of a reversible power cycle when each operates between the same two thermal
reservoirs.
All reversible power cycles operating between the same two thermal reservoirs have the
same thermal efficiency.
28. Why the performances of refrigerator and heat pump are given in terms of C.O.P and
not in terms of efficiency?
The performance of any device is expressed in terms of efficiency for work developing machines.
But heat pump and refrigerator are work absorbing machines. So, the performance of those
devices based on C.O.P only.
29. Comment on the statement The entropy of universe tends to be maximum?
If the entropy of universe tends to be maximum, the irreversibility will be more due to friction
between moving parts.
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 11
ENGINEERING THERMODYNAMICS
30. For compression process between same states, which will consume more work
reversible or irreversible.
Irreversible work will be more in the compression process. Generally for compression, the actual
work given will be higher than the calculated work.
31. What are the assumptions made in working of Carnot Engine ?
The assumptions made for describing the working of the Carnot engine are as follows :
The piston moving in a cylinder does not develop any friction during motion.
The walls of piston and cylinder are considered as perfect insulators of heat.
The cylinder head is so arranged that it can be a perfect heat conductor or perfect heat
insulator.
The transfer of heat does not affect the temperature of source or sink.
Working medium is a perfect gas and has constant specific heat.
Compression and expansion are reversible.
ENGINEERING THERMODYNAMICS
where Q represents the heat transfer at a part of the system boundary during a portion of the
cycle, and T is the absolute temperature at that part of the boundary. The subscript b serves
as a reminder that the integrand is evaluated at the boundary of the system executing the
cycle. The integral symbol indicates that the integral is to be performed over all parts of the
boundary and over the entire cycle.
39.
The third law of thermodynamics states When a system is at zero absolute temperature,
the entropy of system is zero.
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 13
ENGINEERING THERMODYNAMICS
40. What is available energy ?
Available energy is the maximum portion of energy which could be converted into useful work by
ideal processes which reduce the system to a dead state (a state in equilibrium with the earth and
its atmosphere).
Or
The available energy (A.E.) or the available part of the energy supplied is the maximum work
output obtainable from a certain heat input in a cyclic heat engine .
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 14
ENGINEERING THERMODYNAMICS
4. Define Dryness fraction (x).
The term dryness fraction is related with wet steam. It is defined as the ratio of the mass of
actual dry steam to the mass of steam containing it.
5. What is pure substance?
Pure substance is a substance which has a fixed chemical composition throughout its mass.
Examples: Water, nitrogen, carbon-di-oxide, and helium. A pure substance does not have to be
of a single chemical element or compound. A mixture of various chemical elements or
compounds is also called as pure substance as long as the mixture is homogeneous.
6. What is saturation temperature and saturation pressure?
At a given pressure, the temperature at which a liquid boils is called saturation temperature.
At the given temperature, the pressure at which the liquid boils is called saturation pressure.
It is also called as vapour pressure.
7. Define latent heat of vaporization?
The amount of heat added during heating of water from boiling point to dry saturated stage is
called as latent heat of vaporization or enthalpy of vaporization or latent heat of steam.
8. Define the terms boiling point and melting point
Boiling point: It is the temperature at which the liquid starts to change its state from liquid to
vapour.
Melting point: It is the temperature at which the solid starts to change its state from solid to
liquid.
9. Define sensible heat of water?
The amount of heat required to raise the temperature of unit mass of water from 0C to the
saturation temperature under a constant pressure. It is denoted by hf.
10. Define the term superheat enthalpy.
The heat supplied to the dry steam at saturation temperature, to convert it into superheated
steam at the temperature Tsup is called superheat enthalpy.
ENGINEERING THERMODYNAMICS
If the dry steam is further heated, then the process is called superheating and steam obtained
is known as superheated steam.
Uses:Superheated steam has more heat energy and more work can be obtained using it.
Thermal efficiency increases as the temperature of superheated steam is high.
13. Define triple point and critical point for pure substance?
Triple point:
Triple point is the state at which all the three phases that is, solid, liquid and
vapour are said to exist in equilibrium. The triple point is merely the point of intersection of
sublimation and vapourisation curves. It must be understood that only on p-T diagram is the
triple point represented by a point.
Critical point:
It represents the highest pressure and temperature at which the liquid and
vapour phases coexist in equilibrium. At the critical point the liquid and vapour phases are
indistinguishable that is liquid directly converted into vapour.
14. Explain the terms: Degree of superheat, Degree of subcooling.
Degree of superheat: It is the difference between superheated temperature and saturated
temperature at the same pressure.
Degree of subcooling:It is the amount by which the water is cooled beyond the saturated
temperature at the same pressure.
15. Define Saturation temperature and saturation pressre
The phase change temperature corresponding to the saturation pressure. Sometimes called the
boiling temperature.
The pressure at which phase change occurs is called saturation pressure.
16. What is Compressed liquid ?
Liquid whose temperature is lower than the saturation temperature is called compressed liquid.
Sometimes it is called as a sub-cooled liquid.
17. What is Saturated liquid ?
It is the liquid at the saturation temperature corresponding to the saturation pressure. That is
liquid about to commence evaporating.
18. What is Dry (saturated) vapour , wet vapour and superheated vapour ?
Dry Vapour is the vapour which has just completed evaporation. The pressure and temperature
of the vapour are the saturation values.
Wet vapour is the mixture of saturated liquid and dry vapour during the phase change.
Superheated vapour is the vapour whose temperature is greater than the saturation
temperature corresponding to the pressure of the vapour.
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 16
ENGINEERING THERMODYNAMICS
Work ratio is defined as the ratio of network transfer to the positive work transfer.
Work ratio affects the actual efficiency comparing two cycles with the same ideal
efficiency, the cycle having smaller work ratio would have smaller actual efficiency.
Higher the work ratio, the SSC is lower, resulting in smaller size plant for the given
output.
23. What are the effects of condenser pressure on the Rankine cycle?
By
lowering the condenser pressure, we can increase the cycle efficiency.The main
disadvantage is lowering the back pressure increases the wetness of steam. Isentropic
compression of a very wet vapour is very difficult.
24. A vapour cycle inherently has two advantages over gas power cycle. What are they?
25. Mention the improvements made to increase the ideal efficiency of ranking cycle.
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 17
ENGINEERING THERMODYNAMICS
26. Name the different components in steam power plant working on a rankine cycle.
Boiler, Turbine, Cooling Tower or Condenser, and Pump.
27. What are disadvantages of reheating?
The cost of plant increases due to the reheater and its long connections. It also increases the
condenser capacity due to increased dryness fraction.
28. What are the disadvantages of bleeding?
Cost of the plant increases and the work done per kg of steam is reduced which results in
higher boiler capacity for given output.
Compiled by Abubakkar A
Deparment of Mechanical Engineering Page 18