ORBIT

a) 3 b) 5 c) 6 d) 7
MBBS PREPARATION 18. A system consists of N particles, which have independent k relations among one another. The
number f degrees of freedom should be:
Kinetic Theory of Gases (Set-I) a) 3N – k b) 3N + k c) 3N k d) 3N/k
1. If N be the Avogadro’s number and R be the gas constant, then Boltzman constant is given by: 19. The molar specific heat at constant pressure Cp is related to internal energy U and absolute temperature T as:
a) RN b) R/N c) N/R d) 1/RN
U dU dU
2. Two gases at the same temperature T, pressure P and Volume V are mixed. The mixture has volume of a) b) c) R d) none of the above
temperature T. what is the pressure of the mixture? T dT dT
a) P/2 b) P c) 2P d) 4P 20. The molar specific heat at constant pressure (Cp) for a monoatomic gas is:
3. Brownian motion has played a convincing role in establishing:
a) kinetic theory of gases b) mechanical equivalent of heat 3 5 7
a) R b) R c) R d) none of the above
c) elastic nature of molecular collisions d) none of the above 2 2 2
4. Which of the following is NOT an assumption of kinetic theory of gases? 21. Gases deviate from perfect gas behaviour because their molecules:
a) All molecule of a gas are identical b) Gas molecules are like rigid balls a) are polyatomic b) do not attract each other
c) All gases are perfect gases d) Duration of molecular collision is NOT negligible. c) interact with each other through intermolecular forces
5. In kinetic theory of gases one assumes that the collision between the molecules are: d) are of very small size
a) perfectly elastic 22. One mole of a gas at a pressure 2Pa and temperature 27C is heated till both pressure and volume are
b) perfectly doubled. What is the temperature of the gas?
c) partly inelastic a) 300 K b) 600 K c) 900 K d) 1200 K
d) may be perfectly elastic or perfectly inelastic depending on nature of gas. 23. What is the value of pV/T for one mole of ideal gas?
6. Brownian motion is due to: -1
a) 8.4 cal mol K -1 -1 -1
b) 4.2 cal mole K
a) collision of suspended particles with the liquid molecules c) 2 cal mol-1 K-1 d) None of the above
b) collision of suspended particles with each other 24. The internal energy of a perfect gas depends only on:
c) intermolecular forces a) pressure b) temperature c) volume d) none of the above
d) Some reason other than those mentioned above 25. The internal energy of a perfect gas is:
7. What cause Maxwellian distribution of molecular speed? a) wholly kinetic
a) Spherical shape of the molecules b) Elastic nature of the molecular collision b) wholly potential
c) Small size of the molecules d) none of the above c) sum of potential and kinetic energies of the molecules
8. Kinetic theory of gases shows that at given temperature the molecules of all gases have same mean: d) difference of kinetic and potential energies of the molecules.
a) speed b) velocity c) momentum d) kinetic energy 26. Which of the following states of matter have two specific heats?
9. ‘P’ is the pressure and ‘d’ is the density of gas at constant temperature, then: a) Solid b) Gas c) Liquid d) Fluid
a) P  d b) P  1/d c) P  d d) P  1/ d 27. The rms speed of hydrogen at 27C is v. What will be the rms speed of oxygen at 300 K?
a) 4v b) 2v c) v/2 d) v/4
10. The rms speed of the molecules of a gas at a pressure 105 Pa and temperature 0C is 0.5 km/s. if the pressure
28. Given that for a gas E= average kinetic energy per molecule, p= pressure and N= Avogadro’s number. Then E
is kept constant but temperature is raised to 819C, the velocity will become: is given by:
a) 1 km/s b) 1.5 km/s c) 2 km/s d) 5 km/s
11. If the r.m.s. velocity of the molecules of a gas in a container be doubled, then pressure of gas will 3 pN 3 pV 2 pN 3 pV
a) become 4 times of its previous value b) become 2 times of its previous value a) b) c) d)
2 V 2 N 3 V 2 N
c) remain same d) become ¼ of its previous value
29. The mean rotational kinetic energy of a diatiomic molecule at temperature T is:
12. Which of the following laws can be the basis of separating a mixture of gases?
a) Avogadro’s law b) Graham’s law of diffusion 1 5
c) Boyle’s law d) Charle’s law a) kT b) kT c) 2 kT d) kT
2 2
13. In gases of diatomic molecules, the ratio of the two specific heats of gases Cp/Cv is
30. For the same rise in temperature of two moles of gas at constant pressure the heat required for tri atomic gas
a) 1.66 b) 1.40 c) 1.33 d) 1.00
is k times that required for monoatomic gas. What is the value of k?
14. The energy associated with each degree of freedom of a gas molecule is:
1 3 3 5 8 8
a) b) c) d)
a) Zero b) kT c) kT d) kT 2 2 3 5
2 2
31. Supposing the distance between the atoms of a diatomic gas to be constant. Its specific heat at constant
15. A closed bottle containing water is opened on the moon. What will happen?
volume per mole (gram mole) is:
a) The water will freeze b) The water will boil
c) The water will remain as before d) The water will decompose into H2 and O2 5 3 1
16. A man is climbing up a spiral type stair case. His degree of freedom are: a) R b) R c) R d) R
2 2 2
a) 1 b) 2 c) 3 d) more than 3
17. What are the degree of freedom of an ideal monoatomic molecule?
32. A sample of an ideal gas occupies a volume V at a pressure p and absolute temperature T. The mass of each
molecule is m. Which of the following expression gives the density of the gas?
a) mkT b) pm/kt c) p/kTV d) p/kT
33. Pressure exerted by a gas is
a) independent of density of the gas
b) inversely proportional of the density of the gas
c) directly proportional to the square of the density of the gas
d) directly proportional to the density of the gas.
34. In a perfect gas of mass M, the internal energy depends only upon
a) temperature b) pressure c) volume d) average intermolecular distance.
R
35. If for a gas,  0.67 , this gas is made up of molecules which are
C
v
a) diatomic b) mixture of diatomic and polyatiomic molecules
c) monoatomic d) polyatomic
36. Boyle’s law is applicable in
a) Isochoric process b) Isothermal process
c) isobaric process d) Isotonic process
37. For hydrogen gas Cp – Cv = a and for oxygen gas Cp – Cv = b, sot the relation between a and b is given by
a) a= 16b b) 16b=a c) a= 4b d) a = b
38. The product of the pressure and volume of an ideal gas is
a) a constant
b) approximately equal to the universal gas constant
c) directly proportional to its temperature
d) inversely proportional to its temperature.
39. An equation is given here
 a  
P  2   B
 V  V
Where P=pressure, V= volume,  = Absolute temperature, a and B are constants. What will be the
dimensional formula of ‘a’?
a) ML5T-2 b) M-1L5T2 c) ML-5T-1 d) ML5T1
40. What is the ratio of r. m. s. velocity for O2 and H2?
1
a) b) 4 c) 4 :1 d) 1: 4
4
41. R.M.S velocity of a particle is V at pressure P. If pressure increases by two times, then R.M.S. velocity
becomes
a) 2V b) 3V c) 0.5V d) V
42.