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Fig.1: a) Ti4AlN3 before and b) after decomposition in vacuum at 1600C for 7 h, c) Oxidized Ti3SiC2 and d) Ti2AlC
at 1450C for 1 h.
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1.1.2
Microstructural Design of FunctionallyGraded Alumina/Aluminium-Titanate Composites
A study has been conducted on the depth-profiling of
composition,
residual
strains,
mechanical
characteristics and the evaluation of indentation
responses in a layer-graded material (LGM) of
alumina/aluminium-titanate. An infiltration route
fabricates LGM samples with a homogeneous layer of
alumina and a graded layer of heterogeneous
alumina/aluminium-titanate. Depth profiling of
Vickers hardness shows that the hardness of the LGM
is depth dependent with a relatively soft graded layer
but a hard homogeneous layer. The micro-hardness of
the graded layer is load dependent with 5.6 GPa as
the asymptotic value at high loads. Similarly, the
elastic modulus and residual strains are depthdependent. The graded layer exhibits a distinctive
softening in the stress-strain curve, indicating a
micro-scale quasi-plasticity which can be associated
with grain debonding, grain sliding, diffuse microcracking, grain push-out, and grain bridging. No
contact-induced cracks are observed in the graded
layer and the micro-damage is widely distributed
within the shear-compression zone around and below
the contacts. The capability of the LGM to absorb
energy from the loading system and to distribute
damage is strongly influenced by the existence of
residual strains, which is somewhat akin to that of
ceramics with heterogeneous microstructures. These
materials are suitable for high temperature
applications where thermal shock resistance and
thermal insulation is required, such as components of
internal combustion engines, exhaust port liners,
metallurgy, and thermal barriers. This work was
funded by an ARC Discovery and an ARC LinkageInternational grant.
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1.1.3
Characterisation
of
Nanostructured
TiO2 for Photocatalysis Applications
The primary focus of this project is to characterize
TiO2 nanotubes and nanofibres for use as
photocatalysts for various applications such as
sensors, hydrogen production and treatment of wastewater. The functional properties of nanostructured
TiO2 as potential photocatalysts have been
investigated. A variety of analytical techniques such
as scanning electron microscopy, transmission
electron microscopy, ion-beam analysis and x-ray
diffraction have been used in the project (Figure 2).
1.1.4
Geopolymer Research
Prof. Arie van Riessen (a.vanriessen@curtin.edu.au)
Geopolymer research has been undertaken at Curtin
for many years, starting in Civil Engineering under
Vijay Rangans leadership and expanding to Applied
Physics some years later. Arie van Riessen leads the
current Geopolymer research activities in Physics
with a strong emphasis on development of
geopolymers for fire resistant applications. Alkali
activation of a various Australian fly ashes has
revealed that the composition of the glass phase and
the presence of iron oxides greatly influence the
thermal properties of the subsequent geopolymers.
Fivefold increase in strength after exposure to 1000
o
C (Figure 3) has been achieved in samples made
from fly ashes with a desirable composition. The
research team concentrates on characterisation of the
precursor fly ashes as well as the geopolymer to gain
an improved understanding of the geopolymerisation
process to facilitate further optimisation of fire
resistant products. Collaboration with industry and
researchers from Italy and Korea has created a strong
interest in utilisation of industrial residue for
manufacture of alkali activated binders.
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Fig. 3: a) Geopolymer being exposed to high temperature, b) Foamed geopolymer before (left) and after (right)
exposure to 1000oC. Courtesy William Rickard.
MONASH UNIVERSITY
2.1
Department of Materials Engineering
2.1.1
Structural and Functional Ceramics
http://www.eng.monash.edu.au/materials/research/ca
pability/ceramics.html
Professor Yi-Bing Cheng(yibing.cheng@monash.edu)
Dr Jeffrey Sellar (jeff.sellar@monash.edu)
Research projects have been carried out in processing
and characterisation of advanced structural ceramics,
including silicon nitride, sialons, silicon carbide,
boron carbide, titanium boride and their composites.
Through controlled processing, Ca alpha-sialon
ceramics with elongated grain morphology were first
developed by the team at Monash. The materials have
enhanced fracture toughness combining with their
intrinsic high hardness. Collaboration with
researchers in Shanghai Institute of Ceramics,
Chinese Academy of Sciences has led to the
development of a novel SHS (self-propagating hightemperature synthesis) technique for producing
advanced alpha-sialon ceramics using blast furnace
slag as a starting material (Figure 4). Ceramic wear
parts made of the slag derived sialon have showed
excellent anti erosion and wear performance in onsite
tests.
Ceramic-polymer composites have shown many
interesting properties. The Ceramic Group is involved
in the development of novel ceramifiable polymerceramic composites for fire-performance cables
(Figure 5), supported by the Polymer CRC. Unlike
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2.1.2.4 Tensile
Enhancement
of
Cements
Utilising Carbon Nanotubes OPC is brittle & prone
to cracking. Embellishment with carbon nanotubes
enhances tensile properties, creating. slender concrete
structures. This work has overcome one key
difficulty, the uniformity of carbon nanotubes
dispersion during mixing within OPC.
University of Melbourne
4.1
Chemical and Biomolecular Engineering
(http://www.chemeng.unimelb.edu.au/ceramics/)
4.1.1
Ceramic Powder Processing Shape
forming
The research in our group uses the fundamental
understanding of the interactions between particles,
which can be controlled by polymers, ions and
surfactants, to develop novel methods of producing
complex shaped ceramic components. The most
significant of these innovations developed within
Australia include, a novel GelCasting process (Figure
7) and an aqueous based tape casting process. These
technologies enable reduced cost and improved
reliability manufacturing of advanced ceramic
materials. Current activities include the work of Dr.
Carolina Tallon and students Silvia Leo and Stephen
Tanurdjaja supported by the Australian Research
Council (http://www.arc.gov.au/) and Defence
Materials
Technology
Centre
(DMTC)
(http://dmtc.com.au/). The DMTC sponsors our work
on Ultra High Temperature Ceramics for Hypersonic
rocket applications and Ceramic Protective Systems
for protection of our soldiers.
new
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particles to become hydrophobic so that they stabilise
air bubbles introduced by beating. It was found that
the microstructure transforms from a closed pore
(bubble) morphology, at low surfactant concentration
to opened pore (granular) morphology at high
surfactant concentration. The change in morphology
is related to the surface hydrophobicity and
aggregation of the particles which controls the
stability of the bubbles. The fired ceramic foams
contain between about 50 and 80% porosity with
average pore size ranging from about 100 to 400
microns depending on the formulation (Figure 8).
The use of polyvinyl alcohol and a temperature
activated crosslinking agent as a gelcasting system
minimized drying related cracking so that large and
complex shaped components may be fabricated. The
ceramic foams have compressive strength in the range
of about 15 to 40 MPa depending on the formulation.
Dr. Chayuda Chuanuwatanakul recently completed
her PhD on this topic.
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4.1.3
Metal Oxide Surface Structure and
Charging
More than 10 years has been dedicated to
investigating the difference in charging behaviour of
alpha alumina powders and single crystals. The
difference is due to the different types of surface
hydroxyl groups on the two surfaces. Work in
collaboration with Prof Yang Gan (Harbin Institute of
Technology) has also produced some of the best high
resolution images ever published of the sapphire basal
plane in water and air (Figure 9). A few years ago we
were invited to submit a Feature Review article
published in the Journal of the American Ceramic
Society, in 2007. The recent PhD work of Nathan
Nicholas supported by the Australian Research
Council has focused on the Zinc Oxide surface. His
work details the role of small shape controlling
molecules (such as citrate) in the growth of ZnO by
hydrothermal processing at atmospheric pressure and
temperature below the boiling point of water.
4.1.4
Materials Modelling
Multi-scale modelling of material and component
behaviour ranging from the sub atomic to the
macroscopic scale is emerging as a useful tool in
improving understanding and prediction of material
performance in different applications particularly in
extreme environments. Three PhD students have
joined the group to help develop capability in
materials modelling. Catherine Sutton is using
Density Functional Theory to study molecular scale
interactions at the Zinc Oxide aqueous solution
interface. Mike Wang is using discrete particle
mechanics
to
investigate
particle
packing
microstructures and random walk modelling to
investigate composite material thermal properties.
Paul Mignone is applying Finite Element Analysis to
two phase and functionally graded materials to
predict component performance. These projects are
supported by the Australian Research Council and
Defence Materials Technology Centre.
Fig. 9: High resolution atomic force microscopy has been used to characterize the surface of alumina in aqueous
solutions.
&
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Epitaxy system for the fabrication and interface
engineering of complex oxide heterostructures. The
laboratory is equipped with world-class instruments
with a total value of $8 million including 8 ARC
LIEF grants over the last 6 years and the research
projects are funded by ARC, ASI and Industries etc.
Dr. Nakaruk Auppatham
(a.auppatham@unsw.edu.au)
The critical research area involves the processing of
thin films of metal oxides (SnO2, In2O3, ZnO, CeO2,
WO3, MnO2, and TiO2). These thin films have the
potential to be used in solar energy conversion and in
environmental applications. The conventional thin
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film fabrication methods include spin coating (figure
10), spray pyrolysis (figure 11), aerosol spraying, and
ultrasonic spray pyrolysis. For characterisation and
analyses of the properties of these films, sophisticated
analytical techniques such as glancing angle X-ray
diffraction, laser Raman microspectroscopy, laser
Raman
photoluminescence,
UV-VIS
spectrophotometry, photoluminescence, and photobleaching of organic compounds are used. The focus
of the research is the optimisation of the
photocatalytic properties through the modification of
energy band and microstructural characteristics in
order to improve the performance.
Fig. 10: The image shows that the films, which were fabricated by spin coating, are highly transparent and
homogenous.
Fig. 11: The images shows the surface morphology and cross-section of anatase and anatase-rutile thin films, which
were fabricated by ultrasonic spray pyrolysis at 400C.
57
School of Chemistry
(http://sydney.edu.au/science/chemistry/)
Ralston,
Director
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58
8.2
Faculty of Science
Prof. Besim Ben-Nissan (B.Ben-Nissan@uts.edu.au)
Fig. 12: Micro tensile testing of Zirconia sol gel derived nanocoatings (70nm)
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RESEARCH
Science
and
(ANSTO)
synrocANSTO (http://www.synrocansto.com)
10.2
Commonwealth Scientific and Industrial
Research Organisation (CSIRO)
CSIRO
Future
Manufacturing
Flagship
Geopolymer R&D Group
Dr Kwesi Sagoe-Crentsil
(Kwesi.Sagoe-Crentsil@csiro.au)
The CSIRO Future Manufacturing Flagship
Geopolymer R&D Group has developed extensive
expertise and IP position within the Inorganic
Polymer/Geopolymer technology domain over the
past decade. The specific fields of activity relate to
Geopolymer binder applications covering building
products manufacture and mining applications. The
group has partnered several Australian SMEs and
multi-nationals geopolymer R&D activities. The team
continues to provide both strategic and consulting
R&D services to industry leveraging its track record
of feedstock material processing, field testing and
monitoring through to product durability and tests for
code and standards compliance.
The groups strategic work on Geopolymer systems
builds on existing capabilities in the chemistry of
cements and mix design of cementitious binders.
Current R&D activities on Geopolymer binder
synthesis cover: i) feedstock selection, beneficiation
and reactivity ii) the role of key oxide components i.e.
Al203, SiO2, Na2O, H2O, iii) control of dissolution and
condensation reaction kinetics, and iv) optimization
of Geopolymer process parameters. Coupled with a
very strong process engineering capability, this
provides the group with a differentiated advantage
that enables science concepts to be realised through
the internal value chain into applied technology. The
latter is enhanced through the very strong linkages
that the Group has with innovative SMEs who are
typically mid-tier OEMs who play a vital role in
systems integration and applied engineering.
The group has capabilities and extensive facilities
covering all aspects of binder mix design, accelerated
and specialist test facilities that meet most Australian
Standards protocols as well as prototype scale
batching and mixing plant for manufacturing and
testing large scale building product elements. The
group has a long standing history of active
participation in several Australian Standards
committees.
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Fig. 14: The Single Source Chemical Vapour Deposition (SSCVD) method used to produce complex metal oxide
thin films.
10.2.1
10.2.2
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INDUSTRY
11.1
Austral Bricks
(www.australbricks.com.au)
10.2.6 Mesoporous
Ceramics
Electrochemical Storage and Thin
Applications
for
Film
Research
&
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11.2
Austral Precast
(www.australbrick.com.au)
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11.6
Morgan Technical Ceramics Australia Pty
Ltd (http://www.mtcmelbourne.com)
4 Redwood Drive, Notting Hill
Melbourne, VIC.
Steve Thompson, General Manager
(steve.thompson@morganplc.com)
Stuart Pratt, Sales and Marketing
(stuart.pratt@morganplc.com )
Manager
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Fig. 24: Various components (left) and Metal forming tooling (right)
applications demanding high levels of mechanical
reliability. Typical products are, Valve & Pump
Components including complete butterfly valve
assemblies (Z-Max Valves), Can Tooling
(ProSeamers), Battery Tooling, Shell Bearings (ZBearings) and Metal Forming Components.
Internal R&D activity at Morgan Technical Ceramics,
Australia is focused on process, product and
applications development.
11.7
Morgan Thermal Ceramics
(A division of Morganite Australia Pty Ltd)
(www.morgarnthermalceramics.com)
10-14 Toogood Avenue
Beverley, South Australia
Gary Latter National Sales Manager
(Gary.Latter@morganplc.com)
Gerald Ng Business Development Manager
(Gerald.Ng@morganplc.com
Fiona Leyonhjelm Customer Services Manager
(Fiona.Leyonhjelm@morganplc.com)
Morgan Thermal Ceramics designs, manufactures and
installs a broad range of thermal insulation products
that significantly reduce energy consumption and
emissions in a variety of high temperature processing
applications.
Our manufacturing plant is based in Beverley South
Australia produces our patented Superwool high
temperature fibre insulation, Vermiclulite Boards, and
a range of customised insulation components.
Globally, Thermal Ceramics manufactures an
extensive range of insulating refractorory products
including: Insulating Firebricks, Dense and Insulating
Monolithics, Microporous Insulation, Fired Alumina
Shapes and High Temperature Textiles. By nature of
our wide product range, we service a diverse
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Consultants
Dr. Laurie Aldridge, (laurie.aldridge@gmail.com)
12.1
24 Balmer Crescent
Woonona, NSW 2517
Monitoring Applications of Durability
Worldwide billions of dollars are spent annually to
replace defective infrastructure that needs
replacement only because of concrete failing to attain
its expected service life. In addition costly
maintenance is another outcome in the lack of
durability of concrete. For example in 1979 a survey
of large (greater than three story) residential buildings
erected in the previous 15 years in North Sydney
found that; 69% of the buildings showed some
incidence of durability distress, the younger buildings
shown increase frequency of distress than those 10 15 years old. Good quality concrete is durable and
service lives of over a hundred years can be achieved
with: (1) dequate mixing, (2) Proper composition
(with special emphasis both on amount of water and
the addition of supplementary cementitious materials
to blends with pulverized fuel ash (PFA), ground
granulated blast furnace slag GGBFS, or silica fume),
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(3) Proper curing, (4) Proper compaction, and (5)
Adequate cover. Yet there exist little in situ testing
protocols to cheaply determine if placed concrete is in
fact properly cured, properly compacted, with defined
composition, and the adequate cover specified. Many
specifications are in fact prescriptive based on
experience and the development of performance
specifications is of some importance with the recent
need to develop cementitious binders that required
less carbon dioxide emission during production.
This project was set up with private money to develop
and evaluate the monitoring of performance of
cementitious binders with the aim of predicting
durability from the performance of the concrete by
in-situ testing. Collaborative work is being carried
out with the Niels Bohr Institute Copenhagen
Denmark, Frank Collins & Will Gates Department of
Civil Engineering, Monash University, Kapila
Fernando ANSTO, Kirk Vessalas & Paul Thomas
UTS. This work has led to a number of publications
on water movement and chloride ingress through
cementitious binders and concretes. Continuing work
aims to use our data to estimate service life of
concrete used as cover in built structures.