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I. I NTRODUCTION
Small in size and showing unique resonance
properties, metallic nanoparticles have been used
in applications like cancer treatment and chemical
sensing [1], and each application and setting poses
its own constraints and requirements on the performance of the particle. It is therefore desirable to
have as much degrees of freedom in the nanoparticle
used so that the varying requirements in different contexts can be met. Tunability of nanoparticles stem from the dependence of the resonance
properties on different factors such as size and
shape, where, for example, the resonance properties of nanoshells and nanorods depend on their
aspect ratios [1], [2]. Asymmetry has been proposed
to add more degrees of freedom, thus increasing
the tunability of nanoparticles; the properties of a
nanoshell with non-concentric dielectric core and
shell depends, in addition to the aspect ratio, on
the displacement of the inner core with respect to
the center of the shell [3].
With the wide range of settings in which
nanoaprticles are used, developing efficient method978-1-4244-8897-1/10/$26.00 2010 IEEE
267
2
+ Aout
2 r1 3(3cos1 1)
(1)
1out
1m
out
|r=b = m
|r=b
(6)
2m
2d
|r=a =
|r=a
(7)
1out
1
|r=b = m m |r=b
(8)
out
2m
2
|r=a = d d |r=a
(9)
r
r
together with (4) and the condition that at large
distances from the particle, the electric potential
is equal to the potential of the incident field
(limr out = inc ), the coefficients in the potential expansions in (1),(2), and(3) are solved for.
In solving for the coefficients, we use the fact that
the Legendre functions of order 1 and 2, cos and
3cos 1, are orthogonal ( [76]) so that each of
the boundary conditions yields 2 equations for the
coefficients, totaling to 8 equations. The condition
at infinity gives B1out = Eo where Eo is the
incident field, so that the 8 equations obtained from
the boundary conditions contain 8 unknowns (Aout
1 ,
out
m
m
m
m
d
d
A2 , B1 , A1 , B2 , A2 , B1 , and B2 ).
m
(3)
1out
1m
|r=b =
|r=b
268
3.5
(a)
v/(ba)
Field Enhancement
0
0.5
0.99
2.5
1.5
0.5
200
400
600
800
1000
1200
1400
Wavelength (nm)
9
(b)
8
v/(ba)
0
0.5
0.99
Field Enhancement
7
6
5
4
3
2
1
0
200
400
600
800
1000
1200
1400
Wavelength (nm)
15
(c)
Field Enhancement
v/(ba)
0
0.5
0.99
10
0
200
400
600
800
1000
1200
1400
Wavelength (nm)
Asymmetrical nanoparticles offer to play an important role in many applications involving resonatFig. 1. Field enhancement for a nanoegg with an outer radius of ing particles such as sensing due to the added de20nm and inner radius of (a) 13nm, (b) 16nm, and (c) 19nm, and for
different core displacements. The enhancement is at the point with grees of freedom resulting from symmetry braking.
angle 0 on the surface of the nanoegg
Insuring the best performance of such nanoparticles with added tunability requires efficient design
methodologies for nanoparticle based sensors and
field enhancement as a function of the displacement systems, which in turn requires efficient modeling
of the dielectric core and the aspect ratio (ratio of techniques. In this paper we presented an analytical
the core radius to shell radius). The nanoegg we formulation, which is efficient and accurate, for
used consists of a gold shell and a silica core. Figure nanoeggs in the quasistatic regime. The formulation
(1) shows the field enhancement for a nanoegg with is based on solving Laplaces equation in spherical
269
coordinates utilizing translation theorems of spherical harmonics. The translation theorems are key to
achieve simple and analytically solvable formulation
for the potential function. We demonstrated how
our formulation can be used to study the resonant
properties of nanoeggs.
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