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Abstract
In recent years, limited advances have been made in drill
pipe recovery services technology. Depending on the size,
weight per foot, and type of pipe stuck in the well, the options
available to separate the pipe string, have remained the same
for over a decade. These include:
1.
2.
3.
4.
SPE/IADC 52824
Historical Background
The field of pyrotechnics is very broad. It encompasses
the field of chemistry, thermodynamics, and the art of
pyrotechnics. For the purpose of this paper discussion will be
limited to the reaction of aluminum and iron-oxide and a
radial cutting tool design.
When powdered aluminum and iron-oxide are mixed and
ignited a vigorous and highly exothermic reaction occurs;
2 A1 + Fe203 1Fe + A1203 + H .
This is known as the thermite or Goldschmidt reaction. The
temperature of the reaction can raise the mixture to about
1,649C which iron and aluminum become liquid.
The Goldschmidt3 reaction;
8 A1( soldi ) + 3Fe204( soid ) 4 A1203(solid ) + 9 Fe(liquid ) ,
is the oldest gasless heating mixture. Patented in 1895, it
was used for repairing cast iron equipment, butt welding and
general railway repairs.
The classical work of Spice and Staveley4 established the
connection between pyrotechnics and solid-state chemistry,
when two materials are placed in intimate contact, something
must cross the boundary for a reaction to occur. Spice and
Staveley proved that two reactions were occurring during a
self-propagating reaction: ignition and pre-ignition. The preignition is necessary for the bulk, self-propagating reaction
rate. If one can control the pre-ignition rate and the slope of
its self-heating curve, then one can control the bulk reaction.
The Pyronol torch was developed in the 1970s for use at
sea by salvage crews. A 1971 study5 of the Pyronol torch
showed it could cut through 4 inches of stainless steel in 0.025
seconds at a depth of 2000 feet. The overall reaction is;
2 A1 + Ni + Fe203 A1203 + Ni 0 + 2 Fe .
The report concluded that an alloying reaction,
Ni 2 A1 A12 Ni ,served a dual role to preheat the reactants
and to control the burning rate and subsequent heat output.
Discussion - Thermite Mixture
The radial torch contains a heat generating source of
thermite material. This thermite material is a powdered
mixture of aluminum, iron oxide and fluorocarbon. This
powdered mixture is pressed into solid donut-shaped pellets,
which are then stacked into the torch body. The centered
holes in the pellets are then filled with the loose powdered
mixture of the same thermite mix. Upon initiation, a
deflagration reaction occurs within the elongated torch
housing. The resulting liquid iron and aluminum oxide are
forced through the nozzle system at high velocities by
internally generated gas pressure. This gas pressure is
generated by the decomposition of the fluorocarbon.
450oC
700oC
C 2 F 4)n gas (CF 3) 2C = CF 2
CF 3CF = CFCF 3
CF 3CF = CF 2
This decomposition occurs during the thermite reaction and
creates the necessary internal pressure to eject the molten iron
The ignitor initiates thedeflagration system. A temperature
(or heat-flux) boundary first encounters the isothermal surface
of the thermite mixture. When the heat generated raises the
temperature of the aluminum to 660C the phase change
(partial reaction) begins. The phase change is the breakdown
of the thermite mixture as the melting aluminum ignites the
iron oxide. Total reaction (liquid state) finally follows as the
aluminum and iron oxide mixture is converted to iron and
aluminum oxide.
If the heat-flux boundary produces heat faster than heat is
dispatched, the temperature of the solid material rises. The
temperature rises increases the reaction rate, which in turn,
increases the rate of heat generation. The process is
accelerated until total reaction occurs or is slowed down by
the decrease in available reactants.
Figure 1 shows the stages of the deflagrating system.
Figure 2 shows the temperature versus time relationship for
the exothermic reaction of the radial torch.
Discussion - Molten Metal Jet
The igniter initiates a deflagration reaction, between the
aluminum and iron oxide, that is exothermic. This reaction
will take place without external support of oxygen. The only
requirement for initiation of the reaction is that a portion of the
loose powder mixture reached the melting point of aluminum
(660C). Once the aluminum has ignited a phase change
establishes a self-propagating thermochemical reaction. The
temperature of the molten products cause the Teflon powder in
the mixture to decompose. The resultant gaseous product
expands, forcing the molten metals through a nozzle. These
molten metals then form a high velocity liquid jet, traveling in
the order of 200-250 meters/second.
SPE/IADC 52824
(P 0C 0 )(PsCs)
P 0C 0 + PsCs
SPE/IADC 52824
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References
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SPE/IADC 52824
Figure 1
T
e
m
p
e
r
a
t
u
r
e
Propagation
Total Reaction
(liquid State)
Phase
Change
Heat
Flux
Isothermal
Surface
Axial Position
(exaggerated for illustration)
Figure 2
3766
3228
Plastic Flow
2690
(35% of Material)
Cutting Range
4
3
2152
Heat Up
(40% of Material)
Cooling Range
(25% Material Left in Tool)
1614
1076
538
10
15
Time (milliseconds)
20
25
Temperature (C)
SPE/IADC 52824
Figure 3
Housing
Thermite
Protective
Shield
Conical Head
Nozzle
Nozzle Sleeve
Diverter
Radial Exit
Port (Sealed)
Radial Exit
Port (Exposed)
Nozzle Sleeve
(Shifted)
Before Firing
A
Figure 4
After Firing
B