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distribution of the charges of fast ions moving in solid and gaseous media. In agreement
with the experimental data, the number of ions in a beam containing different charges
is assumed to depend on two parameters and to be described by a Gaussian curve. To
evaluate the mean charge and width of the equilibrium distribution, the generalized Bohr
criterion is employed in conjunction with the statistical model of the ion and with some
concrete experimental data.
1. INTRODUCTION
WHEN fast multiply-charged ions pass through
matter, their charge fluctuates as a result of electron
loss and capture, and a dynamically stable
charge distribution is established in the ion beam
even before a noticeable slowing down of the fast
particle takes place. This distribution does not
depend on the initial ion charge and is determined
solely by the cross sections for the loss and capture
of electrons.
Information on the equilibrium charge distribution
in ion beams is needed for the analysis of
heavy particles produced in nuclear reactions, to
solve problems involved in the production of fast
multiply-charged ions in accelerators, and for
other problems in nuclear physics. However, a
consistent theoretical derivation of the equilibrium
charged state of ion beams from the cross sections
for the loss and capture of electrons is quite
cumbersome, and at the present time it apparently
cannot give sufficiently accurate results, owing to
the difficulties involved in the calculation of the
cross sections. Consequently, great importance
is attached to approximate methods of solving the
equilibrium distribution, which do not require calculations
of the cross section.
We propose here a simple semi-empirical
method, based on established laws governing the
equilibrium charge distribution and using concrete
experimental data. This method can be used to
calculate the charge composition of a beam of ions
of arbitrary elements with atomic numbers Z > 2,
at ion velocities v > v0 = eo/n = 2.19 x 108 em/sec.
2. FORM OF EQUILIBRIUM CHARGE DISTRIBUTION
In view of the relative smallness of the cross
sections for simultaneous loss and capture of
several electrons, the distribution of the ions
among the most intense charge groups is determined
essentially by the cross sections for the
loss and capture of a single electron [12J, so that
if the relative number of ions with charge i is
denoted by Fi ( ~iFi = 1 ), then
(1)
where o-ik-cross section of the process whereby
an ion with charge i is converted into an ion with
charge k. Inasmuch as the dependence of the
ratios Ui,i +1/o-i +1,i on i is nearly exponential, we
have
Fi+l / Fi ~
for the light group and ~ 0.4 for the heavy group.
To interpolate and extrapolate the values of i
to the region of v and Z for which there are no
direct experimental data, we make use of the
Bohr criterion [18 19], according to which the ion
retains only those electrons whose orbital velocity
Ve exceeds the ion velocity v. As applied to real
atoms and ions, this criterion leads, however, to
results that differ appreciably from the experimental
data [16 20J. Thus, if the values of i were
to be determined only by v e then a sharp decrease
in the dependence of i on v would occur
on going from the ionization of one electron shell
to the ionization of another shell, and minima
would appear on the i vs. Z curve. Actually, the
shell structure is not so distinctly manifest and
the dependence of i on v and Z is smoother.
This is connected with the fact that the electron
loss and capture cross sections, and consequently
also the values of the average charge, depend not
only on ve but also on the number of electrons
in the outer shell of the atom, on the degree of
its filling, and on the effective charge of the
[1 2 21 22] h wn ' ' ' . T e actwn of each of these factors
leads to a smoothing of the curves of i against v
and against Z. Consequently, the Bohr criterion
agrees best with experiment if the statistical
model of the atomic particle is used for the description
of the ion; according to this model [23,4]
0
zat ( i I Z) , (5)
where f ( i/Z) is a monotonically increasing function
of i/Z, and the exponent a can range from
%to%. depending on the assumptions made.
Since the Bohr criterion should similarly yield
the ion vel~city v at which the average degree of
ionization i/Z assumes a specified value, it
follows from (5) that log v is a linear function of
log Z:
De ~
lg v = a lg Z
lg f (lIZ). (6)*
The experimental values of log v as functions of
log Z for a series of equidistant values of i/Z
from 0.2 to 0.9, obtained by measuring the average
charge of ions in solids, are shown in Fig. 1.
Since the values of i/Z for Z > 3 in different
solids with atomic numbers Z ~ 5-50 differ by
not more than 2-5% [S,t7J, Fig. 1 shows the results
of measurements for all solids. Figure 2 gives
analogous values for nitrogen and argon-gases
for which the most data are available.
As can be seen from Figs. 1 and 2, for ions of
different elements with Z :S 50 the experimental
values of log v actually lie near straight lines.
However, the slopes of the lines are not constant
and decrease monotonically with decreasing i;z.'
In gases this effect is small: when i/Z changes
[1 + ~J-1
+ F;+l F;+l
0.8
0.7
Q5
0.5
0,4
0.3
o.z
0.1