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Q.1 Fluorine, chlorine, bromine and iodine are elements in Group VII of the Periodic Table.
Scientists are trying to synthesise a new element in Group VII with a proton number of 117.
(a) How many valency electrons will be present in one atom of this new element?
......................................................................................................................................[1]
(b) Complete the following table about an isotope of this new element.
nucleon number
280
number of protons
number of neutrons
[2]
(c) Predict two physical properties of this new element.
1 .......................................................................................................................................
2 ...................................................................................................................................[2]
(d) Fluorine reacts with magnesium to form magnesium fluoride.
(i)
[1]
(ii)
Give both the electronic configuration and the charge on the ions which are present
in magnesium fluoride.
[2]
2
(e) Trifluorochloromethane, CF3Cl, is a covalent compound.
(i)
[2]
(ii)
(iii)
with
the
presence
of
..............................................................................................................................[1]
[Total: 12]
3
Q-2 Blue diamonds are an impure form of carbon. Part of the structure of a blue diamond is
shown below.
= carbon atom
= boron atom
blue diamond
Blue diamonds have a high melting point and can conduct electricity.
(a) Explain, in terms of structure and bonding, why blue diamonds have a high melting
point.
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..........................................................................................................................................
..........................................................................................................................................
......................................................................................................................................[2]
(b) Normal diamonds are a pure form of carbon. They do not conduct electricity.
(i)
Explain, in terms of structure and bonding, why normal diamonds do not conduct
electricity.
..................................................................................................................................
..............................................................................................................................[1]
(ii)
(c) Graphite is another pure form of carbon. Suggest two reasons why graphite is often
used as an electrode in electrolysis.
1 .......................................................................................................................................
2 ...................................................................................................................................[2]
[Total: 6]
4
Q-3 Choose from the following elements to answer the questions below.
barium
calcium
carbon
copper
helium
hydrogen
iron
lead
lithium
sulfur
zinc
Each element can be used once, more than once or not at all.
Name an element which
(a) forms two acidic oxides,
..................................................................................................................................... [1]
(b) has an ion which, in aqueous solution, reacts with aqueous sodium hydroxide to give a
green precipitate,
..................................................................................................................................... [1]
(c) has an atom with an electronic configuration with only four occupied shells,
..................................................................................................................................... [1]
(d) has two giant molecular structures,
..................................................................................................................................... [1]
(e) has an ion which, in aqueous solution, is used to test for sulfate ions,
..................................................................................................................................... [1]
(f)
5
Q-4 Aluminium is a metal and both iodine and bromine are non-metals.
aluminium does not corrode very easily.
(a) How does the number of valency electrons help to explain why aluminium is a metal and
iodine and bromine are non-metals?
..........................................................................................................................................
............................................................................................................................. [1]
..........................................................................................................................................
Explain why aluminium does not corrode very easily.
..........................................................................................................................................
..................................................................................................................................
.....................................................................................................................................
[2]
..................................................................................................................................
(b) At room
temperature iodine is a solid and bromine is a liquid.
.............................................................................................................................
[2]
Describe the difference between both the arrangement and the motion of particles in a
solid and a liquid.
..........................................................................................................................................
..........................................................................................................................................
..................................................................................................................................... [2]
(c) Iodine and bromine form the compound iodine bromide, IBr.
Draw the dot-and-cross diagram for IBr.
Only draw the outer shell electrons.
[1]
(d) Describe how bromine is used to test for unsaturation in organic compounds.
..........................................................................................................................................
..................................................................................................................................... [1]
(e) Aluminium is used to make alloys for the aircraft industry. One reason for this is that
6
5
Solid sodium chloride and magnesium oxide have the same structure and bonding.
This is the structure of sodium chloride.
Key
Na+
Cl
melting point / C
2852
801
What are the formulae for a magnesium ion and an oxide ion?
............................................................................................................................. [1]
(ii)
Suggest why magnesium oxide has a much higher melting point than
sodium chloride.
..................................................................................................................................
............................................................................................................................. [1]
(b) (i)
Explain why pure sodium chloride can be electrolysed at 1000 C but not at 600 C.
..................................................................................................................................
..................................................................................................................................
............................................................................................................................. [2]
(ii)
7
Q-6 (a) Define the term compound.
...................................................................................................................................... [1]
(b) Choose from the following compounds to answer the questions below.
calcium carbonate
carbon dioxide
carbon monoxide
ethane
glucose
methane
propane
sodium oxide
sucrose
water
zinc oxide
Each compound can be used once, more than once or not at all.
Which compound
(i)
is a product of fermentation,
.............................................................................................................................. [1]
(ii)
(iii)
reacts with hydrochloric acid to form a gas which turns limewater milky,
.............................................................................................................................. [1]
(iv)
(v)
(vi)
[2]
8
Q.9 Glass contains silicon(IV) oxide and a number of metal oxides.
(a) The structure of silicon(IV) oxide is shown below.
Key:
silicon atom
oxygen atom
(i)
(ii)
(iii)
(b) Old wine glasses often appear cloudy because they have many small cracks on their
surface.
small cracks
on the surface
The cracks are caused by differences in the rate of diffusion of sodium ions and
hydrogen ions in the glass.
(i)
(ii)
Suggest why sodium and hydrogen ions do not diffuse at the same rate.
.............................................................................................................................. [1]
9
(c) Sodium oxide is an ionic compound.
Draw a dot-and-cross diagram to show
[3]
Q-10 Choose from the following elements to answer the questions below.
chlorine
hydrogen
iron
lithium
nickel
nitrogen
oxygen
potassium
silver
sulfur
vanadium
zinc
Each element can be used once, more than once or not at all.
Which element
(a) is liberated at the anode when an aqueous solution of potassium sulfate is electrolysed,
...................................................................................................................................... [1]
(b) is used as a catalyst in the manufacture of margarine,
...................................................................................................................................... [1]
(c) is a non-metallic solid, an atom of which contains only six valency electrons,
...................................................................................................................................... [1]
(d) is higher than sodium in the reactivity series,
...................................................................................................................................... [1]
(e) is in Period 5 of the Periodic Table,
...................................................................................................................................... [1]
(f)
10
Q-11 Silicon is an element in Group IV of the Periodic Table.
(a) Give the electronic configuration for a silicon atom.
...................................................................................................................................... [1]
(b) Silicon has three naturally occurring isotopes.
Complete the following table for two of these isotopes.
isotope
28Si
30Si
number of protons
number of electrons
number of neutrons
[3]
(c) Silicon reacts with chlorine on heating to form silicon(IV) chloride, SiCl4.
Construct an equation for this reaction.
[1]
(d) Silicon(IV) chloride is a simple molecular compound.
(i)
[2]
12
(e) Silicon(IV) chloride reacts with water to form silicon(IV) oxide.
Part of the structure of silicon(IV) oxide is shown below.
Key
silicon atom
oxygen atom
Explain, in terms of structure and bonding, why silicon(IV) oxide has a very high melting
point.
..........................................................................................................................................
..........................................................................................................................................
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...................................................................................................................................... [2]
[Total: 11]