Professional Documents
Culture Documents
Product identity :
9504000000
Product type :
Curing agent
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application :
Ready-for-use mixture :
Identified uses :
Company details :
HEMPEL A/S
Lundtoftegrdsvej 91
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue :
26 May 2015
21 May 2015.
Mixture
R10
Xn; R20/21
Xi; R41, R38
R43
N; R51/53
See Section 16 for the full text of the R-phrases declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms :
Signal word :
Danger
Hazard statements :
Precautionary statements :
General :
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If medical advice is needed, have product container or label at hand. Keep out of reach of children.
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9504000000
Wear protective gloves/protective clothing/eye protection/face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking.
Response :
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage :
Keep cool.
Disposal :
Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazardous ingredients :
polymer of C18-unsatd. fatty acids dimers with tall-oil fatty acids and triethylenetetramine
triethylenetetramine
Not applicable.
Not applicable.
None known.
Product/ingredient name
Identifiers
%
67/548/EEC
EC: 500-191-5
CAS: 68082-29-1
xylene
n-butanol
>=50 - <75
ethylbenzene
triethylenetetramine
CAS: 100-41-4
Index: 601-023-00-4
EC: 203-950-6
CAS: 112-24-3
Index: 612-059-00-5
>=3 - <5
Classification
Regulation (EC) No.
1272/2008 [CLP]
Type
[1]
[1] [2]
[1]
[1] [2]
[1] [2]
[1]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
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9504000000
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation :
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Skin contact :
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion :
If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to
decomposition products may cause a health hazard. Serious effects may be delayed following
exposure.
Skin contact :
Ingestion :
Over-exposure signs/symptoms
Eye contact :
Inhalation :
No specific data.
Skin contact :
Ingestion :
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician :
If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat
symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments :
No specific treatment.
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9504000000
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material
must be contained and prevented from being discharged to any waterway, sewer or drain.
Decomposition products may include the following materials: carbon oxides nitrogen oxides
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Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
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Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / 4H gloves, polyvinyl alcohol (PVA), Viton
Not recommended: nitrile rubber, neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl
chloride (PVC)
Body protection :
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Respiratory protection :
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. Be sure to use an approved/certified respirator or
equivalent.
Liquid.
Color :
Clear.
Odor :
Solvent-like
pH :
Flash point :
Evaporation rate :
Flammability :
Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Flammable in the presence of the following materials or conditions: oxidizing materials.
Slightly flammable in the presence of the following materials or conditions: reducing materials.
Vapor pressure :
0.01 kPa This is based on data for the following ingredient: polymer of C18-unsatd. fatty acids dimers
with tall-oil fatty acids and triethylenetetramine
Vapor density :
Relative density :
0.924 g/cm
Solubility(ies) :
Partially soluble in the following materials: cold water and hot water.
Auto-ignition temperature :
Decomposition temperature :
Viscosity :
Explosive properties :
Highly explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties :
Weighted average: 39 %
Water % by weight :
Weighted average: 0 %
VOC content :
355.8 g/l
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9504000000
Solvent Gas :
Result
Species
Dose
Exposure
Rat
Rat
Rat
Rat
Rabbit
Rat
Rat
5000 ppm
6350 ppm
4300 mg/kg
24000 mg/m
3400 mg/kg
790 mg/kg
>6193 mg/m
4 hours
4 hours
4 hours
4 hours
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
Rabbit
Rat
Rabbit
Rat
Rabbit
Rat
>3160 mg/kg
8400 mg/kg
>5000 mg/kg
3500 mg/kg
550 mg/kg
2500 mg/kg
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9504000000
ATE value
Oral
Dermal
Inhalation (gases)
Inhalation (vapors)
12168.9 mg/kg
5132.7 mg/kg
21565 ppm
37.64 mg/l
Irritation/Corrosion
Product/ingredient name
polymer of C18-unsatd. fatty acids
dimers with tall-oil fatty acids and
triethylenetetramine
xylene
n-butanol
solvent naphtha (petroleum), light
arom.
ethylbenzene
triethylenetetramine
Result
Species
Score
Exposure
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
24 hours 5 milligrams
24 hours 500 milligrams
24 hours 2 milligrams
24 hours 20 milligrams
24 hours 100 microliters
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
24 hours 15 milligrams
24 hours 20 milligrams
24 hours 5 milligrams
Sensitizer
Product/ingredient name
polymer of C18-unsatd. fatty acids
dimers with tall-oil fatty acids and
triethylenetetramine
triethylenetetramine
Route of exposure
Species
Result
skin
Mouse
Sensitizing
skin
Guinea pig
Sensitizing
Category
Route of exposure
n-butanol
Category 3
Not applicable.
Category 3
Category 3
Not applicable.
Not applicable.
Target organs
Respiratory tract irritation and Narcotic
effects
Respiratory tract irritation
Respiratory tract irritation
Category
ethylbenzene
Category 2
Route of exposure
Target organs
Not determined
ears
Aspiration hazard
Product/ingredient name
Result
ethylbenzene
solvent naphtha (petroleum), light arom.
Contains Fatty acids, C18-unsatd., dimers, oligomeric reaction products with tall-oil fatty acids and
triethylenetetramine, triethylenetetramine. May produce an allergic reaction.
Other information :
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9504000000
Result
Species
Algae
72 hours
Daphnia
Fish
Daphnia
Fish
Algae - Pseudokirchneriella subcapitata
(green algae)
Daphnia - Daphnia magna
Fish - Oncorhynchus mykiss (rainbow
trout)
Algae - Pseudokirchneriella subcapitata
Algae
Daphnia
Fish
48 hours
96 hours
96 hours
96 hours
96 hours
Exposure
48 hours
96 hours
96 hours
72 hours
48 hours
96 hours
Test
Dose
Inoculum
Product/ingredient name
polymer of C18-unsatd. fatty acids
dimers with tall-oil fatty acids and
triethylenetetramine
xylene
n-butanol
solvent naphtha (petroleum), light
arom.
ethylbenzene
Result
Photolysis
Biodegradability
Not readily
Readily
Readily
Readily
Readily
LogPow
BCF
Potential
10.34
high
3.12
1
3.6
-1.66 - -1.4
8.1 - 25.9
3.16
10 - 2500
-
low
low
high
low
low
Mobility :
Not applicable.
vPvB :
Not applicable.
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9504000000
ADR/RID
Class
14.1
UN no.
14.2
Proper shipping name
UN1263
PAINT
14.3
Transport hazard class(es)
3
14.4
PG*
III
14.5
Env* Additional information
Yes. The environmentally
hazardous substance mark
is not required when
transported in sizes of 5 L
or 5 kg.
Special provisions
640 (E)
Tunnel code
(D/E)
IMDG
Class
UN1263
III
IATA
Class
UN1263
PAINT
III
No.
The environmentally
hazardous substance mark
may appear if required by
other transportation
regulations.
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9504000000
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E2: Hazardous to the aquatic environment - Chronic 2
C6: Flammable (R10)
C9ii: Toxic for the environment
F - Highly flammable
C - Corrosive
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
H225
H226
H302 (oral)
H304
H312
H312 (dermal)
H314
H315
H317
H318
H319
H332 (inhalation)
H335 (Respiratory
tract irritation)
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9504000000
May cause respiratory irritation. May cause drowsiness and dizziness. (Respiratory
tract irritation and Narcotic effects)
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification
FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SKIN SENSITIZATION - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 2
Justification
On basis of test data
Calculation method
Calculation method
Calculation method
Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
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