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Abstract
This article is concerned with the application of the Boundary Element Method to cathodic protection problems of submerged structures
using polarization curves depending upon time and formation potential. These curves have been adjusted from potentiostatic data obtained
from in-situ experiments, yielding a nonlinear functional representation. The solution technique adopts stepwise linearized polarization
curves and is employed for sufficiently small time steps. The influence of varying formation potential is introduced into the analysis under
two alternative hypotheses here designated fictitious time and fictitious potential. q 1999 Elsevier Science Ltd and Civil-Comp Ltd. All
rights reserved.
Keywords: Boundary elements; Cathodic protection; Dynamic polarization curves; Potential
1. Introduction
The physical, chemical and biological phenomena, taking
place on a cathodic surface in seawater is quite complex,
being presently subject to study in many research centres
around the world. The parameters which have major influence in this phenomenon are potential, electric current, time,
temperature, pressure, seawater chemistry, relative water
velocity close to the cathodic surface and surface conditions
[1].
For offshore structures, the behavior of cathodic surfaces
is modeled by a time dependent polarization curve, different
at each surface point, which describes the nonlinear relation
between potential and current density.
Dynamic polarization curves are influenced by scale
deposition, which is strongly influenced by the current
potential history on the surface. This history may be quite
complex, being impossible to cover all of the existing situations by experiments. However, information about the
polarization curve can be retrieved from potentiostatic
polarization data (or galvanostatic polarization data),
obtained from experiments in which a potential (or current
density) is maintained constant in time. These curves can be
used with adequate time marching schemes to simulate the
time history of the varying potential and current density
during the life of the cathodic protection system.
* Corresponding author.
72 f 0
f f
a:2
i
on G1 ;
on G2 ;
i vf 1 d
i Fff f; t
0965-9978/99/$ - see front matter q 1999 Elsevier Science Ltd and Civil-Comp Ltd. All rights reserved.
PII: S0965-997 8(98)00121-5
on G3 ;
on G4 ;
664
3. Numerical analysis
In order to solve numerically Eq. (4), the boundary G is
discretized into a number of boundary elements whose
geometry, current density and potential are approximated
as functions of the nodal values. The following algebraic
system is obtained [5]:
Hf Gi:
When the boundary conditions are of type (a) of Eq. (2), Eq.
(6) can be reorganized and written as Eq. (7) whose solution
gives the vector of unknowns y
Ay f:
Fig. 1. Polarization curve.
2fX
2nX
X[G
Z
G
f*j; XiXd GX 2
Z
G
where f *(j ,X) and i*(j ,X) are the fundamental potential
and current density, in which the electric conductivity is
already incorporated. The coefficient c(j ) depends on the
boundary geometry at the source point j .
The application of Eq. (4) to external problems in infinite
regions (e.g., seawater) requires a careful examination of the
behavior of the functions involved over the boundary at
infinity [6]. In this case, a term f 0 representing a constant
potential at infinity should be added to the right side of Eq.
(4), with the contour representing only the internal boundaries of the region. The inclusion of the unknown potential
f 0 makes it possible to impose a self-equilibrated current
density between the anodes and cathodes of the problem.
This is automatically obtained by satisfying the condition,
Z
G
iXdGX 0
X[G
9a
f Gd:
9b
2i
2f
10
k21
665
2Ffkfj
2Ffkfj
2t
2f
fk21
; tjk21 fkj 2 fk21
j
j
fk21
; tjk21 Dt:
j
14
2Fff
fs ; ts t 2 ts :
2t
bk21 ) bk21
j
2Ffkfj
2t
fk21
; tjk21
j
16
2Ffkfj
2fm
fk21
; tjk21 ;
j
Dfk fk 2 fk21 :
2Fff
fs ; ts f 2 fs
i Fff f; t Fff fs ; ts 1
2f
1
15
17
18
Hfk Gik :
19
20
21
2Ffkfj
2Ffkfj
2t
2f
fk21
; tjk21 fkj 2 fk21
j
j
fk21
; tjk21 tjk 2 tjk21 ;
j
12
where,
ikj Ffkfj fkj ; tjk ;
13a
Ffkfj fk21
; tjk21 :
ik21
j
j
13b
22
666
4
5
6
7
8
9
Initial stage (k 0)
Initialization of vectors
t0 0
i0 0
f 0 fc u, fc is the corrosion potential of the
material in seawater
n0
nn11
Compute matrix
n21 ; tj0
An21 ) an21
mj 2F 0 =2fm f j
fj
10
11
n21
1n Gn21 2 Hf
n
n21
D H 2 GA
12
13
14
15
16
17
18
19
n 1n to
Solve system of linear equations Dn Df
n
obtain Df
n Df
n 1 f
n21
f
n
n21
n21 n
1 A Df
Repeat steps 814, until Df n ) 0
n
f0 f
0
n
i
Compute parameters (tO2 ; tH2 ; and f ) dependent
on the formation potential
t0O tO2 f0
t0H tH2 f0
20
21
22
23
24
25
26
27
f 0 f f0
Subsequent stages
Initial Time ) t^k21 , Final Time ) tk
^t0 0
Do k 1 until Nt
Update vectors
fkf fk21
k21
tk ^t
1 Dtu
k
t0 tk21
0
tkH tk21
H
f k f k21
667
668
35
36
37
38
39
tk0 tO2 fk
tkH tH2 fk
f k f fk
Find fictitious time t^kj as a nonlinear solution to
ikj Ffkj fkj ; t^kj for a fixed pair fkj ; ikj and a
formation potential fkj
End Do
Step
13
28
Compute matrix
Ak21 ) ak21
mj
29
33
34
2fm
fk21
; tjk21
j
Compute vector
bk21 ) bk21
j
30
31
32
2Ffk fj
2Ffkfj
2t
fk21
; tjk21
j
fkfj
fkj
ikj
f^ kj
t^kj
ikcj
.
5. Application
The application presented was the simplest possible so as
to better illustrate the behavior of the time dependent variables. More elaborate engineering applications will be
carried out in future works.
5.1. Cylindrical tank
669
6. Conclusions
In this article the fictitious time and fictitious potential
hypothesis were used in order to simulate actual dynamic
polarization curves in cathodic protection systems of
offshore structures. Physical characteristics of the seawater
were represented by dynamic polarization curves for
constant polarization potential fitted from potentiostatic
in-situ experiments.
The new solution techniques presented stem from a linearization of the cathodic polarization curve, with respect to
time, in much the same way as originally done for the
670
Fig. 7 (continued).
nonlinear potential relationship [2]. This produces a stepwise linear boundary condition with respect to both, time
and potential.
The solution techniques studied indicate no special
Acknowledgements
Fig. 8. The CPU time for alternative techniques.
[5]
[6]
[7]
References
[1] Hartt WH, Culberson CH, Smith SW. Calcareous deposits on metal
surfaces in seawatera critical review. Corrosion 1984;40(11):609
618.
[2] Santiago JAF, Telles JCF. On boundary elements for simulation of
cathodic protection systems with dynamic polarization curves. International Journal for Numerical Methods in Engineering 1997;8:7678.
[3] Santiago JAF. Static and dynamic simulation of cathodic protection
systems with boundary element method (in Portuguese). D. Sc.
Thesis, Rio de Janeiro, RJ: COPPE/UFRJ, 1991.
[4] Mansur WJ, Telles JCF, Santiago JAF. PROCAT system: recent
advances and future developments in numerical simulation of
cathodic protection problems boundary element techniques.
[8]
[9]
[10]
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