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6, 2007
.
( Fe3C)
.(Chunky morphology) ( Acicular morphology)
( X-ray diffraction pattern)
.(Fe3C)
The widespread applications of
Hadfield steel urged intensive studies
during the past decades [3, 4]. Several
researchers focused their attention on
studying
the
work
hardening
mechanism of Hadfield manganese
steel [5-9], while others concentrated
their studies on wear properties [1013]. However, producing satisfactory
properties of manganese steel that are
casted in sand moulds requires a
solution heat treatment at high
temperature and long time which in
1. Introduction
Austenitic manganese steel, also
called Hadfield steel has a chemical
composition of 1.2C and 12Mn
according to the grades of ASTM
A128. Hadfield steel can be considered
as one of the most important alloys that
has outstanding properties [1]. It is an
extremely tough, non-magnetic alloy in
which
the
usual
hardening
transformation has been suppressed by
the high manganese content and rapid
cooling from a high temperature [1, 2].
808
2. Experimental Details
Different series of Hadfield
manganese steels were cast in this
work using RF induction furnace type
Elotherm. The chemical composition
of the casts is controlled during
melting to have suitable percentages
with aid of optical emission
spectrometer (OES) type thermo ARL
3460. Raw materials used as starting
material were low carbon steel,
ferrosilicon,
ferromanganese
and
graphite. Six samples were fabricated
with different silicon contents (0.05,
0.66, 0.99, 2.15, 2.91 and 3.51%).
These samples were denoted by S0.05,
S0.66, S0.99, S2.15, S2.91 and S3.51 where
the subscripts represent the silicon
content. The chemical composition of
the as-cast samples is tabulated in
Table (I). All ingots were cast at 1500
o
C with dimensions of 32 mm diameter
and 8 mm height, in a metallic mould
to study the rapid cooling on the phase
transformations of the manganese
steels. Before metallographic study, all
specimens that were cut from ingots
were ground using 250, 350, 500 and
1000 SiC emery papers respectively.
The ground specimens were primarily
polished using slurry of alumina with
particle size of 50 m. Final polishing
809
Chapter
66,
Austenitic
Manganese Steel, American
Welding Society, 1968.
[3] Simons, E.N., Metal Wear-A Brief
Outline,
Frederick
Muller
Limited London 1972.
[4] Mashloosh, K.M. and Eyer, T.S.,
Abrasive
Wear
and
its
Application to Digger Teeth,
Tribo. Intern., 259, 18,1985.
[5] Zharov, A.I., Rybalko, F.P. and
Mikhalev, M.S., The Work
Hardening of Hadfield Steel,
Phys. Met. Metall., 202, 38, 1974.
[6] Dastur, Y.N. and Leslie, W.C.,
Mechanism of Work Hardening
in Hadfield Manganese Steel,
Metall. Trans. A, 749, 12A,1981.
[7] Shtremel, M.A. and Kovalenko,
I.A., On the Work Hardening
Mechanism of Hadfield Steel,
Phys. Met. Metall., 158, 63, 1987.
[8] Zuidema, B.K., Subramanyam,
D.K. and Leslie, W.C., The
Effect of Aluminum on the Work
Hardening and Wear Resistance
of Hadfield Manganese Steel,
Metall. Trans. A, 1629, 18A,
1987.
[9] Zakharova, E.G., Kireeva, I,
Chumlyakov, Y.I, Shul'mina, A.,
Sehitoglu, H. and Karaman, I.,
The Effect of Aluminium on
Mechanical
Properties
and
Deformation Mechanisms of
Hadfield Steel Single Crystals, J.
Phys., 243, 115, 2004.
[10] Jost, N. and Schmidt, I., FrictionInduced
Martensitic
Transformation in Austenitic
Manganese Steel, Wear, 377.
111, 1986.
[11] Qichuan, J., Zhenming, H.,
Donghuan, C., Shoushi, W. and
4. Conclusions
Metallic mould can give proper
Hadfield steel without post-heat
treatment; this can contribute to
reducing the production cost. Among
the various crucial restrictions in the
production of Hadfield manganese
steel, silicon content is very restricted
parameter and it is preferred to use
silicon in moderate percentage. Silicon
changes the Fe3C phase from acicular
to chunky through several stages. Two
phases are presented in the matrix of
Hadfield manganese steel regardless of
silicon content which are austenite and
Fe3C.
Furthermore,
remarkable
changes in the hardness value can be
recognized with increasing silicon
content.
References
[1] Metals Handbook, Desk Edition,
Wear
Resistant
Austenitic
Manganese Steel, Edited by
Davis, J.R. & Associates,
American Society for Metals,
Metals Park, Ohio, 1998.
[2] Welding Handbook, Section 4,
Metals and Their Weldability,
811
Table (I). Chemical Composition of the As-Cast Samples Obtained from OES.
Sample
C%
Si%
Mn%
P%
S%
Cr%
Ni%
Mo%
Fe%
S0.05
1.26
0.05
13.85
0.05
0.03
0.13
0.07
0.04
Re.
S0.66
1.24
0.66
13.56
0.05
0.03
0.14
0.07
0.04
Re.
S0.99
1.25
0.99
13.49
0.05
0.03
0.14
0.07
0.04
Re.
S2.15
1.23
2.15
13.23
0.05
0.03
0.14
0.07
0.04
Re.
S2.91
1.23
2.91
12.98
0.05
0.03
0.14
0.07
0.04
Re.
S3.51
1.28
3.51
12.92
0.05
0.02
0.16
0.06
0.04
Re.
812
100
100
(200) -phase
Fe3C
90
90
80
80
70
60
50
40
30
S0.05
20
70
60
50
40
30
S0.66
20
10
10
0
20
30
40
50
60
70
80
90
20
30
40
100
100
90
90
80
80
70
60
50
40
30
S0.99
20
50
60
70
80
90
A n g le , 2 (d e g re e )
A n g le , 2 ( d e g r e e )
70
60
50
40
30
S2.15
20
10
10
0
20
30
40
50
60
70
80
90
20
30
40
A n g le , 2 ( d e g r e e )
50
60
70
80
90
A n g le , 2 (d e g re e )
100
160
90
140
50
40
30
20
S2.91
10
-phase
120
100
80
60
-phase
60
Fe3C
70
Fe3C
80
40
S3.51
20
0
20
30
40
50
60
70
80
90
A n g le , 2 ( d e g r e e )
20
30
40
50
60
70
80
A n g le , 2 (d e g re e )
Figure (1). XRD Spectra of Manganese Steel with Different Silicon Contents.
813
90
S0.66
S0.05
29 m
29 m
S2.15
S0.99
29 m
29 m
S3.51
S2.91
29 m
29 m
Hardness, HB
300
250
200
150
0
Silicon Content, %
814