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Heat of Solution
Nieva, Aileen D.1, Arceo, Mary Anne V., Cuales, Jelline C., Kim, Sung Min, Ngan, Emil Joseph T., Rivera, Jainie Lynne
B.2
Professor, School of Chemical Engineering, Chemistry and Biotechnology, Mapua Institute of Technology; 2Student (s), CHM170L/A41, School of Chemical Engineering,
Chemistry and Biotechnology, Mapua Institute of Technology
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ABSTRACT
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highlights from each of the sections: introduction (including purpose), methods, results, and discussion. To reflect the content
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complete, although it is placed at the beginning of the paper. Begin the abstract with a brief, but specific, background
statement to introduce your report. State your main purpose or objective and hypothesis. Describe the important points of your
methodology (species/reagents/ingredients, the number of subjects or samples, and techniques or instruments used to make
measurements). Summarize the main results numerically and qualitatively (include standard errors and p values as required).
Summarize the major points from the discussion/conclusion. Focus on the points that directly relate to your
hypothesis/question. For each type of information, use the same tense as in each corresponding section (i.e., past tense for
methods and results, present tense for theory and conclusions).
Keywords: albumin, casein, invertase, Bradford Assay, Warburg-Christian Assay, Benedicts reagent
INTRODUCTION
The enthalpy change of solution (or heat of solution) is
the enthalpy change associated with the dissolution of a
substance in a solvent at constant pressure.
The enthalpy change of solution is one of the three
dimensions of solubility analysis. It is most often
expressed in kJ/mol at constant temperature. Just as the
energy of forming a chemical bond is the difference
between electron affinity and ionization energy, the heat
of solution of a substance is defined as the sum of the
energy absorbed, or endothermic energy (expressed in
"positive" kJ/mol), and energy released, or exothermic
energy (expressed in "negative" kJ/mol).
Because heating decreases the solubility of a gas,
dissolution of gases is exothermic. Consequently, as a
gas continues to dissolve in a liquid solvent, temperature
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METHODOLOGY
Experimental Procedure:
Heat of Solution Measurement using Parr 1455 Solution
Calorimeter
A. Heat of Solution of Different States
1. Measurement at least 0.5000 g of sodium
chloride and place it in the Teflon dish.
2. Measure 100 ml of distilled water and place it
in the Dewar flask.
3. Set-up the Parr 1455 Solution Calorimeter.
Press F1 to begin the initialization stage. Note
down the sample ID and press ENTER.
4. Input The Exact weight of the sample and
press ENTER
5. Wait for the first beep and fire the push rod
and press ENTER.
6. Wait for the second beep and press DONE
7. Browse the result using the arrow up () and
down () keys.
8. Clean the Solution Calorimeter for the next
sample.
9. Repeat procedures for the next samples.
analytical balance
sodium chloride
ammonium chloride
Treatment of Results:
Compare the heat of solution of the three samples.
Differentiate between the endothermic and the exothermic
reaction based on the results. Discuss the effect of
changing the concentration of a solution with respect to its
heat of solution.
calcium chloride
water
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REFERENCES
http://en.wikipedia.org/wiki/Heat_of_solution
http://en.wikipedia.org/wiki/Exothermic_reaction
http://en.wikipedia.org/wiki/Endothermic
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