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Time : 3Hours
Candidates Name
Mathematics
PART I: MATHEMATICS
tan 2 x 4 tan x 9
1 tan 2 x
2. Let f : 0, 4 0, be defined by f x cos1 cos x .The number of points x 0, 4
1. The number of positive integers in the range of the function f(x) =
10 x
is
10
3. The number of integral values of k for which the equation 7cos x 5sin x 2k 1has a
solution
4. The number of integer values of m for which f x x3 mx 2 3x 11 is invertible
3x 2 9 x 17
is 5k 1 then the value of k is
3x 2 9 x 7
1 x
1
6. If x,y,z are non-zero real numbers are 1 y 1 2 y
1 z
1 z
1
1
1 1 1
0 then
x y z
1 3z
Mathematics
x x ; 2n x 2n 1
2
n
(c) f x
[2 x / ]
(d) f x x x 3 tan x / 2 , Where [.] denotes the greatest integer function, and a is a
rational number.
Mathematics
11. Let f x sgn cot x tan / 2 x , Where [x] denotes the greatest integer function less
1
12. Which of the following functions have the graph symmetrical about the origin?
x y
(a) f x given by f x f y f
.
1 xy
(b) f x given by f x f y f x 1 x 2 y 1 x 2
(c) f x given by f x y f x f y x, y R
(d)None of these.
(b)
,
4 4
(c)
,
2 2
(d) 0,
Mathematics
15. If A is an odd order sequence matrix such that A + A + 2I = 0 then which of the following
is/are true
2
x
x2
1 x
x
(d) B2 = B
(a) f = 1
(b) e = 3
(c) a + c = 1
18. If f x and g x are functions such that f x y f x.g y g x. f y , then
f g
f g
f
(a)
1
A I
2
f
f is independent of
f
(b)
(c)
Space for rough work
(d)
(d) b + d = 1
Mathematics
For each entries in Column I, darken the bubbles of all the matching entries. for example if entry (A) in
Column I matches with entries (Q), (R), (T) then darken these three bubbles in the ORS. Similarly, for the
entries (B), (C) & (D).
Marking Scheme:
+2
if only the bubble(s) corresponding to the all corresponding to the correct option(s) is(are)
darkened
0
If none of the bubbles darkened
-1
In all other cases
-2
19.
Column I
Column II
x
1 x
One-one ,onto
f : R 0 R f x x
1
x
f : R 0 R f x x
1
x
f : R 0 R f x x
1
x
f : 0, 0, f x
Mathematics
2
1 2
Column I
Column II
Adj A is
Orthogonal matrix
B is
Involutory matrix
BT is
Cofactor matrix of A
B1
-3A
PART II : PHYSICS
. Find
4. If the following combination of capacitor are connected with 4V battery then charge on
second 1F capacitor (in C) is
15. A charged particle having a positive charge q approaches a grounded metal spheres of radius
R with a constant small speed v as shown in figure. Then select the correct alternative
(a) as charge q draws nearer to the sphere, a current flows into the ground
(b) as charge q draws nearer to the sphere, a current flows out of the ground
(c) as charge q draws nearer to the sphere, magnitude of current in wire increases
(d) as charge q draws nearer to the sphere, magnitude of current in wire decreases
16. Which of the following is true?
(a) The electric field inside a closed conductor is always zero.
(b) The electric field at the surface of a conductor is perpendicular to it.
(c) The potential at the surface of a conductor is constant.
(d) The electric field lines never forms a closed loop.
17. A isolated conducting sphere
(a) Can be used as an energy storing device.
(b) The electric field inside it would be zero if it doesnt have any charge within its body.
(c)The electric field at the surface of the charge wont be continuous/
(d) Its capacitance decreases as the radius increases.
18. A small conducting sphere of radius mounted on an insulated handle and having a positive
charge q is inserted through a hole in the wall of a hollow conducting sphere of inner radius
and outer radius .The hollow sphere is supported on an insulated stand and is initially
uncharged. The small sphere is placed at the center of the hollow sphere. Neglect any effect
of the hole. Which of the following statement(/s) will be true for this system?
(a) No work will be done in carrying a charge from inner conductor to outer conductor
(b) The electric field at a point in the region between the spheres at a distance r from the
center is equal to
(c) The electric field at a point outside the sphere at a distance r from the center is equal to
(d) The potential of the inner sphere with respect to the outer sphere is given by
(A)
(B)
(C)
(D)
For each entries in Column I, darken the bubbles of all the matching entries. for example if entry (A) in
Column I matches with entries (Q), (R), (T) then darken these three bubbles in the ORS. Similarly, for the
entries (B), (C) & (D).
Marking Scheme:
+2
if only the bubble(s) corresponding to the all corresponding to the correct option(s) is(are) darkened
0
If none of the bubbles darkened
-1
In all other cases
-2
19.
Columns I
Columns II
Zero potential
C
D
20.
R
S
Column-I
Column-II
Chemistry
PART I :
= 0.5 and
0.7. Calculate the ratio of the side of the unit cell for KCl to that of NaCl. If value of ratio is
a.bcd ( where a, b, c & d are numbers. For eg. if ratio= 2.987 then c=8 ) then, find the value
of c.
3. The edge length of unit cell of LiCl having rock salt type lattice is 5014 . If Li + ions
precisely fit into the octahedral void of clased packed structure of Cl- ions, if the ionic radius
of Cl- ions is X pm. Then find the value of
value.
4. A metal crystallizes into two cubic phases, face centered cubic(fcc) and body centered
cubic(bcc), whose unit cell lengths are 3 and 6 respectively. Calculate the ratio of
densities of bcc and fcc.
Chemistry
5. 29.2% (w/w) HCl stock solution has a density of 1.25 g mL . The molecular weight of HCl
is 36.5 g mol-1. The volume(mL) of stock solution required to prepare a 200 mL solution of
0.4 M HCl is:
-1
6. 2.71 g of sulphur in 72 g naphthalene shows a freezing point lowered by 1.015 oC. Kf for
C10H8 is 6.9 K mol-1 kg. How many atoms of S are present in a molecule of sulphur?
7. A metal M of molar mass 96 g mol-1 reacts with fluorine to form a salt that can be
represented as MFx. In order to determine x, a 9.18 g of the sample of the salt is dissolved in
100 g of water and its boiling point was determined to be 374.38 K. What is the chemical
formula of the salt? Given Kb (water) = 0.512 kg mol-1. Assume complete dissociation of salt.
8. An element X of atomic mass 25.0 exists as X4 in benzene to the extent of 100%. When
10.30 g of saturated solution of X in benzene is added to 20.0 g of benzene, the depression in
freezing point of the resulting solution is 0.51 K. If Kf for benzene is 5.1 K kg mol-1, the
solubility of X(in g) in 100g of benzene will be
Chemistry
11. Which pair(s) of liquids on mixing are expected to show no net volume change and no heat
effect
(a) Acetone and ethanol
(b) Chlorobenzene and bromobenzene
(c) Chloroform and benzene
(d) N-butyl chloride and n-butyl bromide
Chemistry
12. Composition of an azeotrope
(a) Is independent of external pressure because it is a compound
(b) Alters on changing the external pressure as it is not a compound
(c) Remains unchanged during distillation at a constant external pressure
(d) Fluctuates even at constant pressure
13. Colligative properties are similar in that they all
(a) Were discovered in college laboratories
(b) Are due to solvent molecules linked together
(c) Have no harmful side effects
(d) Depend on the concentration os solute particles in solution
14. In benzene the intermolecular forces is/are:
(a) Dipole-dipole attractions
(b) Hydrogen bonding
(c) Dispersion forces
(d) and bonding
15. Which of the following(s) have non-stoichiometric defect?
(a) Frenkel defect
(b) Schottky defect
(c) Metal excess defect
(d) Electronic defect
16. Select the correct statement(s):
(a) Schottky defect is shown by CsCl
(b) Frenkel defect is shown by ZnS.
(c) Hcp and ccp structures have the same coordination number 12
(d) On increasing pressure, coordination number of CsCl decreases to that of NaCl
Chemistry
17. In Na2O structure
(a) O2- ions constitute ccp and Na+ ions occupy all the octahedral holes
(b) O2- ions constitute ccp and Na+ ions occupy all the tetrahedral holes
(c) O2- ions constitute ccp and Na+ ions occupy 50% of tetrahedral holes and 100%
octahedral holes
(d) Na+ ions constitute ccp and O2- ions occupy half of octahedral holes.
18. Which of the following has antifluorite structure?
(a) CaF2
(b) BaF2
(c) Li2O
(d) Na2O
Chemistry
For each entries in Column I, darken the bubbles of all the matching entries. for example if entry (A) in
Column I matches with entries (Q), (R), (T) then darken these three bubbles in the ORS. Similarly, for the
entries (B), (C) & (D).
Marking Scheme:
+2
if only the bubble(s) corresponding to the all corresponding to the correct option(s) is(are)
darkened
0
If none of the bubbles darkened
-1
In all other cases
-2
Chemistry
Column II
Packing efficiency
(i) /6
(ii) /8
(iii) /12
(iv) /6