Professional Documents
Culture Documents
Commission C2 - SUNAMCO
SYMBOLS, UNITS,
NOMENCLATURE AND
FUNDAMENTAL CONSTANTS
IN PHYSICS
1987 REVISION (2010 REPRINT)
Prepared by
E. Richard Cohen
and
Pierre Giacomo
(SUNAMCO 87-1)
The 1987 revision of the SUNAMCO Red Book has for nearly a quarter of a century provided
physicists with authoritative guidance on the use of symbols, units and nomenclature. As such, it
is cited as a primary reference by the IUPAC Green Book (Quantities, Units and Symbols in
Physical Chemistry, 3rd edition, E. R. Cohen et al., RSC Publishing, Cambridge, 2007) and the
SI Brochure (The International System of Units (SI), 8th edition, BIPM, S`
evres, 2006).
This electronic version has been prepared from the original TeX files and reproduces the
content of the printed version, although there are some minor differences in formatting and
layout.
In issuing this version, we recognise that there are areas of physics which have come
to prominence over the last two decades which are not covered and also that some material
has been superseded.
section 6 have been superseded by more recent recommended values from the CODATA Task
Group on Fundamental Constants.
UNION INTERNATIONALE DE
INTERNATIONAL UNION OF
PURE AND APPLIED PHYSICS
Commission SUNAMCO
SUNAMCO Commission
SYMBOLS, UNITS,
NOMENCLATURE AND
FUNDAMENTAL CONSTANTS
IN PHYSICS
1987 REVISION
Prepared by
E. Richard Cohen
Rockwell International Science Center
Thousand Oaks, California, USA
and
Pierre Giacomo
Bureau International des Poids et Mesures
S`evres, France
Document I.U.P.A.P.-25
(SUNAMCO 87-1)
UNION INTERNATIONALE DE
INTERNATIONAL UNION OF
PURE AND APPLIED PHYSICS
Commission SUNAMCO
SUNAMCO Commission
PRESIDENT (1984-1987)
D. Allan Bromley
Wright Nuclear Structure Laboratory
272 Whitney Avenue
New Haven, CT 06511, USA
PRESIDENT (1987-1990)
Larkin Kerwin
Physics Department
Universite Laval
Quebec, PQ G1K 7P4, CANADA
SECRETARY-GENERAL
Jan S. Nilsson
Institute of Theoretical Physics
Chalmers Institute of Technology
S-412 96 G
oteborg, SWEDEN
ASSOCIATE SECRETARY-GENERAL
John R. Klauder
AT&T Bell Laboratories
600 Mountain Avenue
Murray Hill, NJ 07974, USA
Reprinted from
INTRODUCTION
ii
CONTENTS
PREFACE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v
1 GENERAL RECOMMENDATIONS . . . . . . . . . . . . . . . . . . . . . . 1
1.1 Physical quantities
1
1.2 Units
4
1.3 Numbers
5
1.4 Nomenclature for intensive properties
6
1.5 Dimensional and dimensionless ratios
8
2 SYMBOLS FOR ELEMENTS, PARTICLES, STATES AND
TRANSITIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.1
2.2
2.3
2.4
2.5
Chemical elements
Nuclear particles
Fundamental particles
Spectroscopic notation
Nomenclature conventions in nuclear physics
9
9
11
11
12
15
18
19
21
iii
iv
5 RECOMMENDED MATHEMATICAL SYMBOLS . . . . . . . . . . . . 47
5.1
5.2
5.3
5.4
5.5
5.6
5.7
5.8
General symbols
Letter symbols
Complex quantities
Vector calculus
Matrix calculus
Symbolic logic
Theory of sets
Symbols for special values of periodic quantities
47
47
49
49
50
50
50
51
62
64
64
64
66
PREFACE
There are two broad classes of dictionaries: those that are proscriptive and
attempt to establish the norms of a language and those that are descriptive
and report the language as it is used. For dictionaries of a living language,
both types have their place. A manual of usage in science however
must be primarily descriptive and should reflect the standards of practice
that are current in the field and should attempt to impose a standard
only in those cases where no accepted standards exist. This revision of
the handbook has taken these precepts into account while expanding the
discussion of some topics and correcting typographical errors of the 1978
edition. There has been some reordering of the material with the hope that
the new arrangement will improve the logical flow, but, since physics is not
one-dimensional, that goal may be unachievable.
The recommended symbols in section 4, particularly those related to
physical chemistry, have been actively coordinated with the corresponding
recommendations of Commission I.1 on Symbols, Units and Terminology of
IUPAC in order to avoid any conflict between the two. The values of the
physical constants given in section 6 are drawn from the 1986 adjustment
by the CODATA Task Group on Fundamental Constants.
E. Richard Cohen
Thousand Oaks
Pierre Giacomo
S`evres
July, 1987
1 GENERAL RECOMMENDATIONS*
1.1 Physical quantities
There are two somewhat different meanings of the term physical quantity.
One refers to the abstract metrological concept (e.g., length, mass, temperature),
the other to a specific example of that concept (an attribute of a specific object
or system: diameter of a steel cylinder, mass of the proton, critical temperature
of water). Sometimes it is important to distinguish between the two and, ideally,
it might be useful to be able to do so in all instances. However little is to
be gained by attempting to make that distinction in this report. The primary
concern here is with symbols and terminology in general; section 6, however,
gives the symbols and numerical values of specific physical constants.
1.1.1 Definitions
A physical quantity** is expressed as the product of a numerical value (i.e., a
pure number) and a unit:
physical quantity = numerical value unit.
For a physical quantity symbolized by a, this relationship is represented in the
form
a = {a} [a],
where {a} stands for the numerical value of a and [a] stands for the unit of
a. Neither the name nor the symbol for a physical quantity should imply any
particular choice of unit.
When physical quantities combine by multiplication or division the usual rules
of arithmetic apply to both the numerical values and to the units. A quantity
which arises (or may be considered to arise) from dividing one physical quantity
by another with the same dimension has a unit which may be symbolized by the
number 1; such a unit often has no special name or symbol and the quantity is
expressed as a pure number.
Examples :
E = 200 J
F = 27 N/m2
f = 3 10 Hz
* For further details see International Standard ISO 31/0-1981 : General Principles
Concerning Quantities, Units and Symbols.
** French: grandeur physique; German: physikalische Gr
osse; Italian: grandezza fisica;
Russian: fizicheskaya velichina; Spanish: magnitud fsica.
2
1.1.2 Symbols
Symbols for physical quantities should be single letters of the Latin or Greek
alphabet with or without modifying signs (subscripts, superscripts, primes,
etc.). The two-letter symbols used to represent dimensionless combinations of
physical quantities are an exception to this rule (see section 4.14 Dimensionless
parameters). When such a two-letter symbol appears as a factor in a product
it should be separated from the other symbols by a dot, by a space, or by
parentheses. It is treated as a single symbol and can be raised to a positive or
negative power without using parentheses.
Abbreviations (i.e., shortened forms of names or expressions, such as p.f. for
partition function) may be used in text, but should not be used in physical
equations. Abbreviations in text should be written in ordinary roman type.
Symbols for physical quantities and symbols for numerical variables should
be printed in italic (sloping) type, while descriptive subscripts and numerical
subscripts are to be printed in roman (upright) type.
Examples :
Cg
(g = gas)
Cp
gn
(n = normal)
an n
(r = relative)
br x
Ek
(k = kinetic)
gi,k
(e = electric)
but
g1,2
Sij ,
Rijkl ,
Rijkl ,
i..l
R.jk.
and
a b.
3
Multiplication of two physical quantities may be indicated in one of the
following ways:
ab
ab
a b.
Same expressions
with a solidus
a/bcd or
a/(bcd)
(2/9) sin kx
a/b + c
a/(b c)
(a + b)/(c d)
a/b + c/d or
(a/b) + (c/d)
exp{(r r0 )/}
(G/)
4
Table 1. Prefixes for use with SI units.
101
102
103
106
109
1012
1015
1018
1021
1024
deci;
centi;
milli;
micro;
nano;
pico;
femto;
atto;
zepto;
yocto;
deci
centi
milli
micro
nano
pico
femto
atto
zepto
yocto
d
c
m
n
p
f
a
z
y
101
102
103
106
109
1012
1015
1018
1021
1024
deca;
hecto;
kilo;
mega;
giga;
tera;
peta;
exa;
zetta;
yotta;
deca
hecto
kilo
mega
giga
tera
peta
exa
zetta
yotta
da
h
k
M
G
T
P
E
Z
Y
1.2 Units
1.2.1 Symbols for units
The full name of a unit is always printed in lower case roman (upright) type.
If that name is derived from a proper name then its abbreviation is a one or
two letter symbol whose first letter is capitalized. The symbol for a unit whose
name is not derived from a proper name is printed in lower case roman type.
Examples :
metre, m
ampere, A
watt, W
weber, Wb
Remark : Although by the above rule the symbol for litre is l, in order to
avoid confusion between the letter l and the number 1, the symbol may also be
written L.
Symbols for units do not contain a full stop (period) and remain unaltered in
the plural.
Example :
7 cm and not 7 cm.
or 7 cms
1.2.2 Prefixes
The prefixes that should be used to indicate decimal multiples or submultiples
of a unit are given in table 1. Compound prefixes formed by the juxtaposition
of two or more prefixes should not be used.
Not :
Not :
Not :
ms ,
kMW ,
F ,
but :
but :
but :
ns
GW
pF
(nanosecond)
(gigawatt)
(picofarad)
When a prefix symbol is used with a unit symbol the combination should be
considered as a single new symbol that can be raised to a positive or negative
power without using brackets.
5
Examples :
cm3
mA2
s1
Remark :
cm3
s1
Nm
cm/s/s ,
J/K/mol ,
but :
but :
cm/s2
or cm s2
J/(K mol) or J K1 mol1
Since the rules of algebra may be applied to units and to physical quantities
as well as to pure numbers, it is possible to divide a physical quantity by its
unit. The result is the numerical value of the physical quantity in the specified
unit system: {a} = a/[a]. This number is the quantity that is listed in tables or
used to mark the axes of graphs. The form quantity/unit should therefore be
used in the headings of tables and as the labels on graphs for an unambiguous
indication of the meaning of the numbers to which it pertains.
Examples :
Given p = 0.1013 MPa,
Given v = 2200 m/s,
Given T = 295 K,
then
then
then
p/MPa = 0.1013
v/(m/s) = 2200
T /K = 295, 1000 K/T = 3.3898
1.3 Numbers
1.3.1 Decimal sign
In most European languages (including Russian and other languages using
the Cyrillic alphabet) the decimal sign is a comma on the line (,); this sign is
preferred by ISO (ISO 31/0-1981, p. 7) and is used in ISO publications even in
English. However, in both American and British English the decimal sign is a
dot on the line (.). The centered dot, (), which has sometimes been used in
British English, should never be used as a decimal sign in scientific writing.
6
1.3.2 Writing numbers
Numbers should normally be printed in roman (upright) type. There should
always be at least one numerical digit both before and after the decimal sign.
An integer should never be terminated by a decimal sign, and if the magnitude
of the number is less than unity the decimal sign should be preceded by a zero.
Examples :
35 or 35.0 but not 35.
To facilitate the reading of long numbers (greater than four digits either to
the right or to the left of the decimal sign) the digits may be grouped in groups
of three separated by a thin space, but no comma or point should be used except
for the decimal sign. Instead of a single final digit, the last four digits may be
grouped.
Examples :
1987
1.234 567 8
or 1.234 5678
or
2, 3 3, 4 or (137.036)(273.16)
136/273.16
136 (273.16)1
As in the case of quantities (see section 1.1.3), when the solidus is used and
there is any doubt where the numerator starts or where the denominator ends,
brackets or parentheses should be used.
1.4 Nomenclature for intensive properties
1.4.1 The adjective specific in the English name for an intensive physical
quantity should be avoided if possible and should in all cases be restricted to
the meaning divided by mass (mass of the system, if this consists of more than
one component or more than one phase). In French, the adjective massique is
used with the sense of divided by mass to express this concept.
7
Examples :
specific volume,
specific energy,
specific heat capacity,
volume massique,
energie massique,
capacite thermique massique,
volume/mass
energy/mass
heat capacity/mass
1.4.2 The adjective molar in the English name for an intensive physical
quantity should be restricted to the meaning divided by amount of substance
(the amount of substance of the system if it consists of more than one component
or more than one phase).
Examples :
molar mass,
molar volume,
molar energy,
molar heat capacity,
mass/amount of substance
volume/amount of substance
energy/amount of substance
heat capacity/amount of substance
masse volumique,
energie volumique,
mass/volume
energy/volume
current density,
surface charge density,
densite de courant,
charge surfacique,
flow/area
charge/area
but
8
1.5 Dimensional and dimensionless ratios
1.5.1 Coefficients and factors
When a quantity A is proportional to another quantity B, the relationship
is expressed by an equation of the form A = k B. The quantity k is usually
given the name coefficient or modulus if A and B have different dimensions
and factor or index if A and B have the same dimension.
Examples :
E = AH (B J )
= E
J = D n
p
L12 = k L1 L2
F = Fn
AH ,
E,
D,
k,
,
Hall coefficient
Youngs modulus
diffusion coefficient
coupling factor
friction factor
= /cV
Reynolds number : Re
mobility ratio : b
Re = vl/
b = /+
mole fraction : xB
xB = nB /j nBj
He
Ca II
Al III
ii. Roman numerals in right superscript position are used to indicate the
oxidation number.
Examples :
IV
PbII
2 Pb O4
10
Table 2. Names and symbols for the chemical elements.*
Atomic
number
Name
Symbol
Atomic
number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
hydrogen
helium
lithium
beryllium
boron
carbon
nitrogen
oxygen
fluorine
neon
sodium
magnesium
aluminum
silicon
phosphorus
sulfur
chlorine
argon
potassium
calcium
scandium
titanium
vanadium
chromium
manganese
iron
cobalt
nickel
copper
zinc
gallium
germanium
arsenic
selenium
bromine
krypton
rubidium
strontium
H
He
Li
Be
B
C
N
O
F
Ne
Na
Mg
Al
Si
P
S
Cl
Ar
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Kr
Rb
Sr
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
Name
yttrium
zirconium
niobium
molybdenum
technetium
ruthenium
rhodium
palladium
silver
cadmium
indium
tin
antimony
tellurium
iodine
xenon
cesium
barium
lanthanum
cerium
praseodymium
neodymium
promethium
samarium
europium
gadolinium
terbium
dysprosium
holmium
erbium
thulium
ytterbium
lutetium
hafnium
tantalum
tungsten
rhenium
osmium
Symbol
Y
Zr
Nb
Mo
Tc
Ru
Rh
Pd
Ag
Cd
In
Sn
Sb
Te
I
Xe
Cs
Ba
La
Ce
Pr
Nd
Pm
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
Hf
Ta
W
Re
Os
11
Table 2. Names and symbols for the chemical elements (continued).
Atomic
number
Name
Symbol
Atomic
number
77
78
79
80
81
82
83
84
85
86
87
88
89
90
iridium
platinum
gold
mercury
thallium
lead
bismuth
polonium
astatine
radon
francium
radium
actinium
thorium
Ir
Pt
Au
Hg
Tl
Pb
Bi
Po
At
Rn
Fr
Ra
Ac
Th
91
92
93
94
95
96
97
198
199
100
101
102
103
Name
Symbol
protactinium
uranium
neptunium
plutonium
americium
curium
berkelium
californium
einsteinium
fermium
mendelevium
nobelium
lawrencium
Pa
U
Np
Pu
Am
Cm
Bk
Cf
Es
Fm
Md
No
Lr
* For values of the relative atomic masses of the elements, see Pure and
Applied Chemistry 58 (1986) 1677.
e+ , e
+,
12
Table 3. Symbols for nuclear particles.
photon
neutrino
electron
muon
tauon
pion
, e , ,
e,
nucleon
neutron
proton (1 H+ )
deuteron (2 H+ )
triton (3 H+ )
helion (3 He2+ )
alpha particle (4 He2+ )
N
n
p
d
t
h
Note: The symbol has previously been used for the helion,
but should be reserved for the tauon (heavy lepton).
, W, Z
e, e , , , ,
u, d, c, s, t, b
+ , 0 , , , D+ , D0
K+ , K0 , (KL , KS ), F+
p, n, +
c
, + , 0 ,
0 ,
The names for quarks are the symbols themselves; the names up, down,
charm, strange, top (truth) and bottom (beauty) are to be considered only
as mnemonics for these symbols.
The mesons D+ , D0 and F+ and the charm baryon +
c have charm quantum
number C = +1. The B-mesons have bottomness (beauty) quantum number
B = +1.
13
number of a system should be printed in capital upright type.
2.4.1 Atomic spectroscopy
The letter symbols indicating the orbital angular momentum quantum
number are
l = 0 1 2 3 4 5 6 7 8 9 1 0 11 . . .
symbol s p d f g h i k l m n o . . .
L = 0 1 2 3 4 5 6 7 8 9 10 11 . . .
symbol S P D F G H I K L M N O . . .
A right subscript attached to the angular momentum symbol indicates the
total angular momentum quantum number j or J. A left superscript indicates
the spin multiplicity, 2s + 1 or 2S + 1.
Examples :
d 3 - electron
2
(j = 23 )
D - term
(spin multiplicity = 3)
D2 - level
J =2
(nl)k (n l )k . . .
in which k, k , . . . are the numbers of electrons with principal quantum numbers
n, n , . . . and orbital angular momentum quantum numbers l, l , . . ., respectively.
Instead of l = 0, 1, 2, 3, . . . one uses the quantum number symbols s, p, d, f, . . .,
and the parentheses are usually omitted.
Example :
the atomic electron configuration : 1s2 2s2 2p3
An atomic state is specified by giving all of its quantum numbers. In
RussellSaunders (LS) coupling an atomic term is specified by L and S and an
atomic level by L, S and J. An atomic state is specified by L, S, J and MJ or
by L, S, MS and ML .
2.4.2 Molecular spectroscopy
For linear molecules the letter symbols indicating the quantum number of the
component of electronic orbital angular momentum along the molecular axis are
= 0 1 2 ...
symbol . . .
= 0 1 2 ...
symbol . . .
A left superscript indicates the spin multiplicity. For molecules having a
symmetry center, the parity symbol g (gerade) or u (ungerade) indicating
respectively symmetric or antisymmetric behavior on inversion is attached as a
14
right subscript. A + or sign attached as a right superscript indicates the
symmetry with regard to reflection in any plane through the symmetry axis of
the molecule.
Examples :
2
3
+
g , u , , , etc.
(nlj ) (n lj ) . . . (n lj ) (n lj ) . . .
where the letter refers to the proton shell and the letter to the neutron shell.
Negative values of the superscript indicate holes in a completed shell. Instead of
l = 0, 1, 2, 3, . . . one uses the symbols s, p, d, f, . . . as in atoms (except for l = 7
which is denoted by k in atoms and by j in nuclei).
Example :
the nuclear configuration : (2d 5 )6 (2p 1 )2 (1g 9 )3
2
When the neutrons and protons are in the same shell with well-defined isospin
T , the notation (nlj ) is used where denotes the total number of nucleons.
Example :
(1f 7 )5
2
= T T
15
The designation of spectroscopic transitions is not uniform. In atomic
spectroscopy* the convention is to write the lower state first and the upper state
second; however, in molecular and polyatomic spectroscopy** the convention is
reversed and one writes the upper state first and the lower state second.
In either case the two state designations are connected by a dash or, if it
is necessary to indicate whether the transition is an absorption or an emission
process, by arrows and . If there is any chance of ambiguity, the convention
being used with regard to the ordering of the states should be clearly stated.
Examples :
2 2S 1 4 2P 3
2
atomic transition
(J , K ) (J , K )
The difference between two quantum numbers is that of the upper state minus
that of the lower state.
Example :
J = J J
The branches of the rotationvibration band are designated as:
O
P
Q
R
S
branch:
branch:
branch:
branch:
branch:
J = J J
2
1
0
+1
+2
16
The symbolic expression representing a nuclear reaction should follow the
pattern:
incoming particle
outgoing particle(s) final
initial
,
or photon
or photon(s)
nuclide
nuclide
Examples :
14
N (, p) 17O
59
Co (n, ) 60 Co
23
Na (, 3n) 20 Na
31
P (, pn) 29 Si
or magnetic monopole E0 or M0
or magnetic dipole
E1 or M1
or magnetic quadrupole E2 or M2
or magnetic octopole
E3 or M3
or magnetic 2n -pole
En or Mn
17
Examples :
A( b, c)D
A( b, c )D
A(b, c )D
A(b, c)D
A(b, c )D
A( b,c)D
18
19
usually considered to be a derived quantity, defined in terms of the ratio of two
lengths, and solid angle, a derived quantity defined in terms of the ratio of an
area to the square of a lenghth. Nevertheless, in some situations (notably in
statistical physics, in particle transport and radiative transfer and particularly
in photometry and illumination) the steradian must be treated as a base unit
in order to avoid ambiguity and to distinguish between units corresponding to
different quantities.
3.2 The International System of Units (SI)
The name Syst`eme International dUnites (International System of Units)
with the international abbreviation SI was adopted by the Conference Generale
des Poids et Mesures (CGPM) in 1960. It is a coherent system based on the
seven base units (CGPM 1960 and 1971) listed in table 4. These units are
presently defined in the following way:
1: metre; m`etre
Le m`etre est la longueur du trajet parcouru dans le vide par la lumi`ere
pendant une duree de 1/299 792 458 de seconde. (17th CGPM (1983),
Resolution 1).
The metre is the length of the path travelled by light in vacuum
during a time interval of 1/299 792 458 of a second.
2: kilogram; kilogramme
Le kilogramme est lunite de masse; il est egal a
` la masse du prototype
international du kilogramme. (1st CGPM (1889) and 3rd CGPM (1901)).
The kilogram is the unit of mass; it is equal to the mass of the
international prototype of the kilogram.
3: second; seconde
La seconde est la duree de 9 192 631 770 periodes de la radiation
correspondant a
` la transition entre les deux niveaux hyperfins de
letat fondamental de latome de cesium 133. (13th CGPM (1967),
Resolution 1).
The second is the duration of 9 192 631 770 periods of the radiation
corresponding to the transition between the two hyperfine levels of the
ground state of the cesium-133 atom.
4: ampere; amp`ere
Lamp`ere est lintensite dun courant constant qui, maintenu dans
deux conducteurs parall`eles, rectilignes, de longueur infinie, de section
circulaire negligeable, et places a
` une distance de 1 m`etre lun de lautre
dans le vide, produirait entre ces conducteurs une force egale a
` 2 10 -7
newton par m`etre de longueur. (9th CGPM (1948), Resolutions 2 and 7).
The ampere is that constant current which, if maintained in two
straight parallel conductors of infinite length, of negligible circular
cross-section, and placed 1 metre apart in vacuum, would produce
between these conductors a force equal to 2 107 newton per metre of
length.
20
Table 4. SI base units.
Base quantity
Name
Symbol
length
longueur
mass
masse
metre
m`etre
kilogram
kilogramme
time
temps
second
seconde
electric current
courant electrique
ampere
amp`ere
thermodynamic temperature
temperature thermodynamique
kelvin
kelvin
amount of substance
quantite de mati`ere
mole
mole
mol
luminous intensity
intensite lumineuse
candela
candela
cd
kg
5: kelvin; kelvin
Le kelvin, unite de temperature thermodynamique, est la fraction
1/273,16 de la temperature thermodynamique du point triple de leau.
(13th CGPM (1967), Resolution 4).
The kelvin, unit of thermodynamic temperature, is the fraction
1/273.16 of the thermodynamic temperature of the triple point of water.
The 13th CGPM (1967, Resolution 3) also decided that the unit kelvin and its
symbol K should be used to express both the thermodynamic temperature and
an interval or a difference of temperature.
In addition to the thermodynamic temperature (symbol T ) there is also the
Celsius temperature (symbol t) defined by the equation
t = T T0
where T0 = 273.15 K. Celsius temperature is expressed in degree Celsius; degre
Celsius (symbol, C). The unit degree Celsius is equal to the unit kelvin, and
a temperature interval or a difference of temperature may also be expressed in
degrees Celsius.
6: mole; mole
1 . La mole est la quantite de mati`ere dun syst`eme contenant
autant dentites elementaires quil y a datomes dans 0,012 kilogramme
de carbone 12.
2 . Lorsquon emploie la mole, les entites elementaires doivent
etre specifiees et peuvent etre des atomes, des molecules, des ions,
21
des electrons, dautres particules ou des groupements specifies de telles
particules. (14th CGPM (1971), Resolution 3).
1. The mole is the amount of substance of a system which contains
as many elementary entities as there are atoms in 0.012 kilogram of
carbon 12.
2. When the mole is used, the elementary entities must be specified
and may be atoms, molecules, ions, electrons, other particles, or specified
groups of such particles.
Note : In this definition, it is understood that the carbon 12 atoms are
unbound, at rest and in their ground state.
7: candela; candela
La candela est lintensite lumineuse, dans une direction donnee, dune
source qui emet une radiation monochromatique de frequence 540 10 12
hertz et dont lintensite energetique dans cette direction est 1/683 watt
par steradian. (16th CGPM (1979), Resolution 3).
The candela is the luminous intensity, in a given direction, of a
source that emits monochromatic radiation of frequency 540 1012 hertz
and that has a radiant intensity in that direction of (1/683) watt per
steradian.
Specific names and symbols have been given to several coherent derived SI
units; these derived units are listed in table 5.
3.3 Non-SI units of special interest in physics
Because consistency and uniformity of usage tend to enhance clarity, it is
a general rule of SI that the use of non-SI units should be discontinued.
However there are some important instances where this is either impractical or
inadvisable. The SI recognizes three categories of non-SI units to be used with
the SI.
3.3.1 Units accepted for use whose value in SI units is exactly
defined
The CIPM (1969) recognized that users of the SI will wish to employ certain
units which are important and widely used, but which do not properly fall
within the SI. The special names and symbols of those units that have been
accepted for continuing use and the corresponding units of the SI are listed in
table 6. Although the use of these units is acceptable, their combination with SI
units to form incoherent compound units should be authorized only in limited
cases.
Decimal multiples or sub-multiples of the time units listed in table 6 should
not be formed by using the prefixes given in table 1. Forming symbols for
decimal multiples or sub-multiples of units by using the symbols of the prefixes
given in table 1 is not possible with superscript symbols, such as , , and for
angle units.
22
Table 5. Derived SI units with special names.
Derived SI unit; Unite SI derivee
Name
Quantity
Grandeur
Nom
Expression
in terms of
base units
Expression
Symbole en unites
de base
Symbol
plane angle
angle plan
radian
solid angle
angle solide
steradian sr
steradian
m2 /m2
frequency
frequence
hertz
Hz
s1
force
force
newton
m kg s2
J/m
pressure
pression
pascal
Pa
m1 kg s2
N/m2 , J/m3
joule
m2 kg s2
Nm
watt
m2 kg s3
J/s
coulomb
As
volt
m2 kg s3 A1
capacitance
capacite electrique
farad
m2 kg1 s4 A2 C/V
electric resistance
resistance electrique
ohm
m2 kg s3 A2
energy, work,
quantity of heat
energie, travail,
quantite de chaleur
power, radiant flux
puissance,
flux energetique
quantity of
electricity,
electric charge
quantite delectricite,
charge electrique
electric potential,
potential difference,
electromotive force
tension electrique,
difference de potentiel,
force electromotrice
rad
Expression
in terms of
other SI units
Expression
en dautres
unites SI
m/m
W/A, J/C
V/A
23
Table 5. Derived SI units with special names (continued).
Derived SI unit; Unite SI derivee
Name
Quantity
Grandeur
Nom
Expression
in terms of
base units
Expression
Symbole en unites
de base
Symbol
Expression
in terms of
other SI units
Expression
en dautres
unites SI
siemens
m2 kg1 s3 A2
A/V, 1
weber
Wb
m2 kg s2 A1
Vs
tesla
kg s2 A1
Wb/m2
inductance
inductance
henry
m2 kg s2 A2
Wb/A
Celsius temperature
degree
Celsius
degre
Celsius
conductance
conductance
magnetic flux
flux dinduction
magnetique
temperature Celsius
luminous flux
flux lumineux
lumen
lm
cd sr *
illuminance
eclairement lumineux
lux
lx
m2 cd sr *
activity
activite
becquerel
Bq
s1
absorbed dose**
dose absorbee
gray
Gy
m2 s2
J/kg
dose equivalent**
equivalent de dose
sievert
Sv
m2 s2
J/kg
lm/m2
(lumen) from
dimensionless
Although the
they measure
24
Table 6. Commonly used non-SI units.
Unit; Unite
Quantity
Grandeur
Name
Nom
Symbol
Symbole
plane angle
angle plan
degree
degre
1 =
1
rad
=
60
10 800
1 =
rad
=
60
648 000
minute
minute
min
hour
heure
1 h = 60 min = 3600 s
day
jour
litre
litre
tonne
tonne
1 d = 24 h = 86 400 s
time*
temps
volume
volume
mass
masse
Definition
Definition
1 =
rad
180
1 min = 60 s
1 L = 1 dm3 = 103 m3
l, L
t
1 t = 1 Mg = 1000 kg
Name
Nom
(unified) atomic mass unit
unite de masse atomique
(unifiee)
electronvolt
electronvolt
Symbol
Symbole
Definition
Definition
1 u = m(12 C)/12
eV
1 eV= (e/C) J
25
3.3.2 Units accepted for use whose value expressed in SI units must
be obtained by experiment
The units listed in table 7, which are important and widely used for special
problems, are also accepted by the CIPM (1969) for continuing use with those
of the SI.
3.3.3 Units whose use may be discontinued
In view of existing practice, the CIPM (1978) considered it acceptable to
retain for the time being the units listed in table 8 for use with those of the SI,
with the exception of the units fermi, torr and calorie. These three units should
be avoided in favor of an appropriate SI unit or decimal multiple formed by
using the prefixes of table 1. All of the units listed in table 8 may be abandoned
in the future; they should not be introduced where they are not already in use
at present.
The appearance of the bar in table 8 does not imply a preference for the use of
p = 105 Pa as the thermodynamic standard state pressure. The choice between
105 Pa and 101 325 Pa (or any other value) is a matter of convenience, and is
not a direct consequence of the choice of units. However, the use of a standard
pressure as a unit under the name standard atmosphere should be avoided.
26
Name
Nom
length
longueur
angstrom
fermi
area
aire
barn
pressure
bar
bar
pression
torr
Torr
quantity of heat
quantite de chaleur
calorie
cal
curie
Ci
1 Ci = 3.71010 s1
roentgen
1 R = 2.58104 C/kg
rad
rad***, rd
1 rad = 0.01 Gy
rem
rem
1 rem = 0.01 Sv
Symbol
Symbole
A
fm *
Definition
Definition
1
A = 1010 m
1 fermi = 1015 m
1 b = 100 fm2
= 1028 m2
1 bar = 105 Pa
101325
Pa
1 Torr =
760
1 calIT = 4.1868 J **
1 cal15 = 4.1855 J **
1 calth = 4.184 J **
x0 = ct, x1 = x, x2 = y, x3 = z, x4 = ict
position vector; vecteur de position
length; longueur
breadth; largeur
height; hauteur
radius; rayon
thickness;
epaisseur
diameter; diam`
etre : 2r
element of path;
element de parcours
area; aire, superficie
volume; volume
plane angle; angle plan
solid angle; angle solide
wavelength; longueur donde
wave number; nombre donde : 1/
1
28
wave vector; vecteur donde
angular wave number; nombre donde angulaire : 2/
angular wave vector, propagation vector;
k
t
T
f,
time; temps
period, periodic time; p
eriode, duree dune periode
frequency; fr
equence : 1/T
angular frequency; pulsation : 2f
relaxation time; constante de temps : F (t) = exp(t/ )
damping coefficient; coefficient damortissement :
logarithmic decrement; d
ecrement logarithmique :
T = T /
v, u
u, v, w, c, (u, v, w)
4.2 Mechanics
mass;masse
(mass) density; masse volumique : m/V
relative density; densit
e : /
specific volume; volume massique : V /m = 1/
reduced mass; masse r
eduite : m1 m2 /(m1 + m2 )
momentum; quantit
e de mouvement : mv
angular momentum; moment cin
etique R: r p
moment of inertia; moment dinertie : (x2 + y 2 ) dm
force; force
R
impulse; impulsion :
F dt
weight; poids
moment of force; moment dune force R
angular impulse; impulsion angulaire :
M dt
torque, moment of a couple; torque, moment dun couple
pressure; pression
normal stress; contrainte normale
shear stress; contrainte tangentielle, cission
2
d
v
, mr
p
L, J
I, J
F
I
G, W, P
M
H
T
p, P
R
The moment of inertia tensor is defined by Iij = (r r ij xi xj ) dm.
With Rrespect to principal axes, this is often written as a vector,
I = (x2 + x2 ) dm, where (, , ) is a permutation of (x, y, z).
29
linear strain, relative elongation;
, e
E, (Y )
G,
ij
ij
cijkl
sklji
,
K,
,
, ()
, (f )
,
E, W
Ep , V, , U
Ek , T, K
W, A
P
q, qi
p, pi
J, S
L, (L)
fonction de Hamilton : i pi qi L
H, (H)
L dt
R
fonction caracteristique de Hamilton : 2 T dt
W, Sp
S
30
particle velocity vector and its components;
c, (cx , cy , cz )
v, (vx , vy , vz ); u, (ux , uy , uz )
p, (px , py , pz )
c0 , v 0 , hci, hvi
c, v, hci, hvi, u
c, v
l,
ij , Vij
f (c)
H
coefficient de thermodiffusion
thermal diffusion ratio; rapport de thermodiffusion
thermal diffusion factor; facteur de thermodiffusion
characteristic temperature; temp
erature caracteristique
rotational characteristic temperature ;
s
D
Dtd
kT
T
rot
vib
D
E
4.4 Thermodynamics
The index m is added to a symbol to denote a molar quantity if needed to
distinguish it from a quantity referring to the whole system. The convention is often
used that uppercase letters refer to extensive quantities and lower case letters to
specific quantities (see section 1.4).
quantity of heat; quantit
e de chaleur
work; travail
Q
W
31
thermodynamic temperature;
temperature thermodynamique
T
t,
S
U
energie libre : U T S
A, F
H
enthalpy; enthalpie : U + pV
Gibbs function; fonction de Gibbs, enthalpie libre :
H TS
G
J
Y
p ,
T ,
l
compressibility; compressibilit
e : (1/V )(V /p)T
linear expansion coefficient; dilatabilit
e lineique
cubic expansion coefficient; dilatabilit
e volumique :
(1/V )(V /T )p
heat capacity; capacit
e thermique
specific heat capacity; capacit
e thermique massique : C/m
JouleThomson coefficient; coefficient de JouleThomson
isentropic exponent; exposant isentropique :
V ,
Cp , CV
c p , cV
(V /p)(p/V )S
, ()
, (q)
q, ()
, k, K, ()
a, (D)
Q, q
I, (i)
j, J
3
When symbols for both time and Celsius temperature are required, t should be
used for time and for temperature.
32
electric potential; potentiel
electrique
potential difference; diff
erence de potentiel, tension
electromotive force; force
electromotrice
electric field (strength); champ
electrique
electric flux; flux
electrique
magnetic potential difference;
k = L12 /(L1 L2 ) 2
V,
U, V
E, E
E
Um
Fm
H
p
P
e
,
D
r , K
A
B
r
M
, (m )
m,
C
R
X
Z
G
B
Y
,
L
M, L12
4
4
In anisotropic media quantities such as permittivity, susceptibility and polarizability are second-rank tensors; component notation should be used if the tensor character
of these quantities is significant, e.g., ij .
33
electromagnetic energy density;
w, u
S
w d
Q, (Qe ), W
w
R
flux energetique, puissance rayonnante : d R
radiant flux density; flux
energetique surfacique
R : = dS
radiant intensity; intensit
e energetique : = I d
spectral concentration of radiant intensity (in terms
of frequency); intensit
eR energetique spectrique
(en frequence) : I =
I d
irradiance;
eclairement energetique : R= E dS
radiance; luminance
energetique : I = L cos
R dS
radiant exitance; exitance
energetique : = M dS
emissivity; emissivit
e : M/MB
(MB : radiant exitance of a blackbody radiator)
luminous efficacy; efficacit
e lumineuse : v /e
spectral luminous efficacy; efficacit
e lumineuse spectrale :
v, /e,
, (e ), P
I, (Ie )
I , (Ie, )
E, (Ee )
L, (Le )
M, (Me )
K
K()
I d
Km
V
V ()
Q, (Qv )
, (v )
I, (Iv )
I , (Iv, )
34
illuminance,
R illumination; eclairement lumineux :
E dS
E, (Ev )
L, (Lv )
M, (Mv )
4.7 Acoustics
acoustic pressure; pression acoustique
sound particle velocity; vitesse particulaire acoustique
velocity of sound; vitesse du son, c
elerite
velocity of longitudinal waves; c
elerite longitudinale
velocity of transverse waves; c
elerite transversale
group velocity; vitesse de groupe
sound energy flux, acoustic power;
p
u
c
cl
ct
cg
a , ()
,
LN
LW
Lp
5
(), (), and () designate spectral absorptance a ()/ (), spectral
reflectance r ()/ (), and spectral transmittance tr ()/ (), respectively.
35
h...|
|...i
commutateur de A et B : AB BA
anticommutator of A and B ;
anticommutateur de A et B : AB +R BA
i (Aj ) d
[A, B]+
Aij
hAi
A
0 i
1 0
x =
, y =
, z =
i 0
0 1
1 0
unit matrix; matrice unit
e:
0 1
Dirac (4 4) matrices; matrices (44) de Dirac : 6
0 x
0 y
0 z
x =
, y =
, z =
0
y 0
z 0
x
I 0
=
0 I
0 1
1 0
(
h/i)
a, b, ,
a , b , ,
x , y , z
1 , 2 , 3
I
x , y , z
Z
N
mN , mN (A X)
ma , ma (A X)
1
12
12 ma ( C)
mu
ma /mu
Ar , Mr
36
principal quantum number (q.n.);
n, ni
L, li
S, si
J, ji
M, mi
I, J
F
J, K
v
Q
b
,
constante de desintegration
activity; activit
e
, m
T1 , 1
2
Compton wavelength;
, l
7
8
37
mass attenuation coefficient;
m
S, Sl
Sa
R, Rl
, i
, i
, i
S
I
v
N
J
F
M, MJ
38
q.n. of component of X (X = S , F or I ) in the direction
of an external field; n.qu. de la composante de X
MX
K = | + l|
P
Te 11
G
e , x
for PM :
IA IB IC
12
j , xjk
F
T
IA , IB , IC
A, B, C
R, R0
a1 , a2 , a3
a, b, c
13
b1 , b2 , b3
a , b , c
39
lattice plane spacing; espacement entre plans r
eticulaires
Miller indices; indices de Miller
d
h 1 , h2 , h3
h, k, l
(h1 , h2 , h3 )
(h, k, l)
{h1 , h2 , h3 }
{h, k, l}
[u, v, w]
hu, v, wi
Note : When the letter symbols in the bracketed expressions are replaced
by numbers, the commas are usually omitted. A negative numerical value is
commonly indicated by a bar above the number, e.g., (110).
Bragg angle; angle de Bragg
order of reflexion; ordre de r
eflexion
short range order parameter; param`
etre dordre local
long range order parameter; param`
etre dordre a
` grande distance
Burgers vector; vecteur de Burgers
particle position vector; vecteur de position dune particule
equilibrium position vector of an ion;
s
b
r, R 14
R0
u
Qi
e
D
qD
D
,
l, le
, lph
vdr
(r)
uk (r)
NE ,
14
Lower case and capital letters are used, respectively, to distinguish between electron
and ion position vectors.
40
(spectral) density of vibrational modes;
g, N
J
ik
ik
ik
R
L
RH , AH
AE , PE
AN
ARL , SRL
Eab , ab
Sab , ab
ab
, ( )
,
A
n, nn , n
16
p, np , n+
16
nd
15
na
ni
Eg
Ed
Ea
EF , F
The symbol W is used for the quantity +, where is the electron chemical
potential which, at T = 0 K, is equal to the Fermi energy EF .
16
In general, the subscripts n and p or and + may be used to denote electrons and
holes, respectively.
41
angular wave vector, propagation vector (of particles);
q
kF
a
a
b
b
mn , mp
n , p
b
Dn , Dp
Ln , Lp
n , p
, W
TN
TC
Tc
Hc
param`etre de LandauGinzburg : L / 2
of surface superconductivity.
17
42
relative atomic mass; masse atomique relative
relative molar mass; masse molaire relative
amount of substance; quantite de mati`ere
molar mass; masse molaire
concentration; concentration (en quantite de mati`ere) : c = n/V
molar fraction; fraction molaire
mass fraction; fraction massique
volume fraction; fraction volumique
molar ratio of solution; rapport molaire dune solution
molality of solution; molalite dune solution
chemical potential; potentiel chimique 19
absolute activity; activite absolue : exp(/kT )
relative activity; activite relative
reduced activity; activite reduite : (2mkT /h2 )3/2
osmotic pressure; pression osmotique
osmotic coefficient; coefficient osmotique
stoichiometric number of substance B;
nombre stchiometrique de la substance B
affinity; affinite
extent of reaction; etat davancement dune reaction :
dB = dnB /B
equilibrium constant; constante dequilibre
charge number of an ion; nombre de charge dun ion, electrovalence
Ar
Mr
n, 18
M
c
x
w
r
m
a
z
g,
B
A
K
z
18
Ed , Ed (X)
Eea
Ei
x
z
nz
xz
20
43
neutral particle temperature; temperature des neutres
ion temperature; temperature ionique
electron temperature; temperature electronique
electron number density; densite electronique
electron plasma circular frequency; pulsation de plasma :
2
pe
= ne e2 / me
Debye length; longueur de Debye
charge of particle; charge dune particule
electron cyclotron circular frequency;
pulsation cyclotron electronique : (e/me )B
ion cyclotron circular frequency;
pulsation cyclotron ionique : (ze/mi)B
reduced mass; masse reduite : m1 m2 /(m1 + m2 )
impact parameter; param`etre dimpact
mean free path; libre parcours moyen
collision frequency; frequence de collision
mean time interval between collisions;
intervalle de temps moyen entre collisions : 1/coll
cross section; section efficace : 1/nl
(electron) ionization efficiency;
efficacite dionisation (electronique) : ( /)dN/dx
(dN : number of ion pairs formed by an ionizing electron
traveling through dx in the plasma at gas density ;
: gas density at p = 133.322 Pa, T = 273.15 K)
rate coefficient; taux de reaction
one-body rate coefficient; taux de reaction unimoleculaire :
dnA /dt = km nA
relaxation time; temps de relaxation : (e.g., = 1/km)
binary rate coefficient, two-body rate coefficient;
taux de reaction binaire (e.g., X + Y XY + h) :
dnXY /dt = kb nX nY
ternary rate coefficient, three-body rate coefficient ;
taux de reaction ternaire (e.g., X + Y + M XY + M ) :
dnXY /dt = kt nM nX nY
Townsend (electron) ionization coefficient;
coefficient de Townsend 21
Townsend (ion) ionization coefficient;
coefficient ionique de Townsend
secondary electron emission coefficient;
taux demission secondaire
drift velocity; vitesse de mouvement
Tn
Ti
Te
ne
pe
D
q
ce
ci
, mr
b
l,
coll , c
coll , c
se
k
km
kb
kt
vdr
21
The same name is also used for the quantity = /E, where E is the electric
field strength.
44
mobility; mobilite : vdr /E
positive or negative ion diffusion coefficient;
coefficient de diffusion des ions
electron diffusion coefficient;
coefficient de diffusion des electrons
ambipolar (ionelectron) diffusion coefficient;
coefficient de diffusion ambipolaire :
(D+ e + De + )/(+ + e )
characteristic diffusion length;
longueur caracteristique de diffusion
ionization frequency; frequence dionisation
ionion recombination coefficient;
coefficient de recombinaison ionion :
dn /dt = i n n+
electronion recombination coefficient;
coefficient de recombinaison electronion :
dne /dt = e ne n+
plasma pressure; pression cinetique du plasma
magnetic pressure; pression magnetique :
B 2 /2 ( : permeability)
magnetic pressure ratio; coefficient : p/pm
(pm : magnetic pressure outside the plasma)
magnetic diffusivity; diffusivite magnetique : 1/
( : electric conductivity; : permeability)
Alfven speed; vitesse dAlfven : B/()1/2
( : (mass) density; : permeability)
D+ , D
De
Da , Damb
LD ,
i
i
e
p
pm
m , m
vA
45
h, heat transfer coefficient :
heat/(time cross sectional area temperature difference)
k, mass transfer coefficient :
mass/(time cross sectional area mole fraction difference)
l, a characteristic length
v, a characteristic speed
x, mole fraction
B, magnetic flux density
D, diffusion coefficient
= 1 (/x)T,p
, cubic expansion coefficient : 1 (/T )p
, viscosity
, mean free path (par. b); thermal conductivity (par. c)
, magnetic permeability
, kinematic viscosity : /
, (mass) density
, surface tension; electric conductivity
p, pressure difference
t, a characteristic time interval
x, a characteristic difference of mole fraction
T , a characteristic temperature difference
a. Dimensionless constants of matter
Prandtl number; nombre de Prandtl : /a
Schmidt number; nombre de Schmidt : /D
Lewis number; nombre de Lewis : a/D = Sc/Pr
Pr
Sc
Le
b. Momentum transport
Reynolds number; nombre de Reynolds : vl/
Euler number; nombre dEuler : p/v 2
Froude number; nombre de Froude : v(lg)1/2
Grashof number; nombre de Grashof : l3 gT / 2
Weber number; nombre de Weber : v 2 l/
Mach number; nombre de Mach : v/c
Knudsen number; nombre de Knudsen : /l
Strouhal number; nombre de Strouhal : lf /v
Re
Eu
Fr
Gr
We
Ma
Kn
Sr
c. Transport of heat
Fourier number; nombre de Fourier : at/l2
Peclet number; nombre de Peclet: vl/a = Re Pr
Rayleigh number; nombre de Rayleigh : l3 gT /va = Gr Pr
Nusselt number; nombre de Nusselt : hl/
Stanton number; nombre de Stanton : h/vcp = Nu/Pe
Fo
Pe
Ra
Nu
St
46
d. Transport of matter in a binary mixture
Fourier number for mass transfer;
nombre de Fourier pour transfert de masse : Dt/l2 = Fo/Le
Peclet number for mass transfer;
nombre de Peclet pour transfert de masse : vl/D = P e Le
Grashof number for mass transfer;
nombre de Grashof pour transfert de masse : l3 g x/ 2
Nusselt number for mass transfer;
nombre de Nusselt pour transfert de masse : kl/D
Stanton number for mass transfer;
nombre de Stanton pour transfert de masse : k/v = Nu /Pe
e. Magnetohydrodynamics
Magnetic Reynolds number; nombre de Reynolds magnetique : vl
Alfven number; nombre dAlfven : v()1/2 /B
Hartmann number; nombre de Hartmann : Bl(/)1/2
Cowling number (second Cowling number); nombre de Cowling
(deuxi`eme nombre de Cowling) : B 2 /v 2 = Al 2
first Cowling number; premier nombre de Cowling :
B 2 l/v = Rm Co2 = Ha2 /Re
Fo*
Pe*
Gr*
Nu*
St*
Rm
Al
Ha
Co, Co2
Co1
def
= , (:=)
by definition equal to; egal par definition a
`
corresponds to; correspond a
`
=
plus; plus
+
minus; moins
48
exponential of x; exponentielle de x
exp x, ex
logarithm to the base a of x; logarithme de base a de x
loga x
natural logarithm of x; logarithme neperien de x
ln x, loge x
common logarithm of x; logarithme decimal de x
lg x, log10 x
binary logarithm of x; logarithme binaire de x
lb x, log2 x
sine of x; sinus x
sin x
cosine of x; cosinus x
cos x
tangent of x; tangente x
tan x, tg x
cotangent of x; cotangente x
cot x, ctg x
secant of x; secante x
sec x
cosecant of x; cosecant x
cosec x, csc x
For the hyperbolic functions the symbolic expressions for the corresponding
circular functions are followed by the letter: h.
Examples : sinh x, cosh x, tanh x, etc.
(The shortened forms sh x, ch x, and th x are also permitted.)
For the inverse circular functions the symbolic expressions for the corresponding
circular functions are preceded by the letters: arc.
Examples : arcsin x, arccos x, arctan x, etc.
For the inverse hyperbolic functions the symbolic expression for the corresponding
hyperbolic function should be preceded by the letters: ar.
Examples : arsinh x, arcosh x, etc. (or arsh x, arch x, etc.)
summation; somme
product; produit
finite increase of x; accroissement fini de x
variation of x; variation de x
total differential of x; differentielle totale de x
function of x; fonction de x
composite function of f and g;
fonction composee de f et g : (g f )(x) = g(f (x))
convolution of f and g; convolution de f et g :
Z
f (x t)g(t) dt
f g = (f g)(x) = (g f )(x) =
x
x
dx
f (x)
gf
f g
49
Dirac delta function; fonction delta de Dirac :
(r) = (x)(y)(z)
Kronecker delta symbol;
n symbole delta de Kronecker
a/|a| for a 6= 0,
signum a; signum a :
0
for a = 0
greatest integer a; le plus grand entier a
(x), (r)
ij
sgn a
ent a, [a]
i, j
Re z, z
Im z, z
|z|
, arg z
z , z
vector; vecteur
A, a
absolute value; valeur absolue
|A|, A
Dalembertian; Dalembertien : c /t
second order tensor; tenseur du second ordre
A
scalar product of tensors S and T ;
produit scalaire des tenseurs S et T : (i,k Sik Tki )
S:T
tensor product of tensors S and T ;
produit tensoriel des tenseurs S et T : (k Sik Tkl )
ST
50
product of tensor S and vector A;
produit du tenseur S et du vecteur A : (k Sik Ak )
S A
A,
a11
..
.
am1
aij
a1n
..
.
amn
AB
A1
E, I
AT , A
A
A
det A
Tr A
Theory of sets
Z = {. . . , 2, 1, 0, 1, 2, . . .}
{a1 , a2 , }
,
N
Z
51
the set of rational numbers;
ensemble des nombres rationnels
the set of real numbers; ensemble des nombres reels
the set of complex numbers;
ensemble des nombres complexes
set of elements of A for which p(x) is true;
ensemble des elements de A pour lequels p(x) est vrai
is included in; est contenu comme sous-ensemble dans :
BA
contains; contient : A B
is properly contained in; est strictement contenu dans
Q
R
C
{ x A | p(x) }
, ()
, ()
,
6=
,
6=
\
C
x, x(t)
x, xmax
x
, xmin
x, hxi
X, x, xrms , (xeff )
N
X
Qk Qs
v ,
xi xj ij
i,j=1
(1)
where vij is the covariance of xi and xj . In this general form, the units of
vij are the product of the units of xi and xj and the units of vks are the
* The 1986 Adjustment of the Fundamental Physical Constants, E. Richard
Cohen and Barry N. Taylor, CODATA Bulletin Number 63 (Pergamon Press,
Elmsford, NY 10523, USA, and Headinghill Hall, Oxford OX3 0BW, UK, November, 1986). CODATA is a Committee of the International Council of Scientific
Unions, 51 Blvd de Montmorency, 75016 Paris, France.
52
53
product of the units of Qk and Qs . For most cases of interest involving the
fundamental constants, the variables xi may be taken to be the fractional
change in the physical quantity from some fiducial value, and the quantities Q
can be expressed as powers of physical constants Zj according to
Qk = qk
N
Y
Zj kj ,
(2)
j=1
N
X
(3)
i,j=1
Equation (3) is the basis for the expansion of the variance matrix to include
e, h, me , NA , and F .
1
In terms of correlation coefficients defined by rij = vij (vii vjj ) 2 = vij /i j ,
2
where i is the standard deviation (i = vii ) we may write, from eq. (3),
2k =
N
X
i=1
Yki2 2i + 2
N
X
j<i
(4)
54
Table 9. 1986 recommended values of the fundamental physical constants.
The digits in parentheses are the one-standard-deviation uncertainty in the last digits of the
given value. Since the uncertainties of many of these entries are correlated, the full variance
matrix must be used in evaluating the uncertainties of quantities computed from them.
Quantity
Symbol
Value
Relative
uncertainty,
parts in 106
GENERAL CONSTANTS
Universal constants
speed of light in vacuum;
vitesse de la lumi`ere dans le vide
permeability of vacuum;
permeabilite du vide
permittivity of vacuum;
permittivite du vide : 1/ c2
gravitational constant;
constante de gravitation
Planck constant; constante de Planck
h/2
(exact)
G
h
128
0.60
0.30
0.60
0.30
mP
2.176 71(14)108 kg
64
lP
1.616 05(10)1035 m
64
tP
5.390 56(34)1044 s
64
(exact)
(exact)
Electromagnetic constants
elementary charge;
charge elementaire
magnetic flux quantum;
quantum de flux magnetique :
h/2e
Josephson frequencyvoltage quotient;
quotient frequencetension dans
leffet Josephson
quantized Hall conductance;
conductance quantifiee de Hall
quantized Hall resistance;
resistance quantifiee de Hall :
h/e2 = c/2
Bohr magneton;
magneton de Bohr : e
h/2me
nuclear magneton;
magneton nucleaire : e
h/2mp
e
e/h
0.30
0.30
0.30
2e/h
4.835 9767(14)1014 Hz V1
0.30
e2/h
0.045
RH
B
25 812.8056(12)
9.274 0154(31)1024 J T1
5.788 382 63(52)105 eV T1
1.399 624 18(42)1010 Hz T1
46.686 437(14) m1 T1
0.671 7099(57) K T1
5.050 7866(17)1027 J T1
3.152 451 66(28)108 eV T1
7.622 5914(23) MHz T1
2.542 622 81(77)102 m1 T1
3.658 246(31)104 K T1
0.045
0.34
0.089
0.30
0.30
8.5
0.34
0.089
0.30
0.30
8.5
B /h
B /hc
B /k
N
N /h
N /hc
N /k
55
ATOMIC CONSTANTS
fine-structure constant;
constante de structure fine :
ce2/2h
Rydberg constant;
constante de Rydberg :
me c2/2h
1
2
0.045
0.045
0.090
R
R c
R hc
10 973 731.534(13) m1
3.289 841 9499(39)1015 Hz
2.179 8741(13)1018 J
13.605 6981(40) eV
0.0012
0.0012
0.60
0.30
0.045
h/2me
h/me
0.089
0.089
me
9.109 3897(54)1031 kg
5.485 799 03(13)104 u
0.510 999 06(15) MeV
0.59
0.023
0.30
me /m
0.15
me /mp
0.020
me /md
0.020
me /m
0.021
e/me
0.30
M (e), Me
0.023
C
C
0.089
0.089
re
0.13
0.27
Electron
electron mass; masse de lelectron
56
electron magnetic moment;
moment magnetique de lelectron
electronmuon magnetic
moment ratio;
rapport du moment magnetique
de lelectron a
` celui du muon
electronproton magnetic
moment ratio;
rapport du moment magnetique
de lelectron a
` celui du proton
e
e /B
e /N
9.284 7701(31)1024 J T1
1.001 159 652 193(10)
1838.282 000(37)
0.34
1105
0.020
e /
206.766967(30)
0.15
e /p
658.210 6881(66)
0.010
1.883 5327(11)1028 kg
0.113 428 913(17) u
105.658 389(34) MeV
0.61
0.15
0.32
m /me
206.768 262(30)
0.15
Muon
muon mass; masse du muon
0.15
/B
/N
4.490 4514(15)1026 J T1
0.004 841 970 97(71)
8.890 5981(13)
0.33
0.15
0.15
7.2
/p
0.15
mp
1.672 6231(10)1027 kg
1.007 276 470(12) u
938.272 31(28) MeV
0.59
0.012
0.30
mp /me
1836.152 701(37)
0.020
mp /m
8.880 2444(13)
0.15
e/mp
0.30
Proton
proton mass; masse du proton
0.012
0.089
0.089
57
proton magnetic moment;
moment magnetique du proton
diamagnetic shielding correction;
facteur decran diamagnetique :
(H2 O, sph., 25 C): 1 p /p
shielded proton moment;
moment magnetique du proton
non corrige : (H2 O, sph., 25 C)
proton gyromagnetic ratio;
coefficient gyromagnetique
du proton
uncorrected; non corrige :
(H2 O, sph., 25 C)
p
p /B
p /N
H2 O
25.689(15)106
p
p /B
p /N
0.34
0.011
0.023
p
p /2
26 752.2128(81)104 s1 T1
42.577 469(13) MHz T1
0.30
0.30
p
p /2
26 751.5255(81)104 s1 T1
42.576 375(13) MHz T1
0.30
0.30
mn
1.674 9286(10)1027 kg
1.008 664 904(14) u
939.565 63(28) Mev
0.59
0.014
0.30
mn /me
1838.683 662(40)
0.022
mn /mp
0.009
0.34
0.010
0.023
Neutron
neutron mass; masse du neutron
neutronelectron mass ratio;
rapport de la masse du neutron
a
` celle de lelectron
neutronproton mass ratio;
rapport de la masse du neutron
a
` celle du proton
neutron molar mass;
masse molaire du neutron
neutron Compton wavelength;
longueur donde de Compton
du neutron : h/mn c
C,n /2
neutron magnetic moment;
moment magnetique du neutron
neutronelectron magnetic
moment ratio;
rapport du moment magnetique
du neutron a
` celui de lelectron
neutronproton magnetic
moment ratio;
rapport du moment magnetique
du neutron a
` celui du proton
0.014
C,n
C,n
0.089
0.089
n
n /B
n /N
0.41
0.24
0.24
n /e
0.24
n /p
0.24
3.343 5860(20)1027 kg
2.013 553 214(24) u
1875.613 39(57) MeV
0.59
0.012
0.30
Deuteron
deuteron mass; masse du deuteron
md
58
deuteronelectron mass ratio;
rapport de la masse du deuteron
a
` celle de lelectron
deuteronproton mass ratio;
rapport de la masse du deuteron
a
` celle du proton
deuteron molar mass;
masse molaire du deuteron
deuteron magnetic moment;
moment magnetique du deuteron
deuteronelectron magnetic
moment ratio;
rapport du moment magnetique
du deuteron a
` celui de lelectron
deuteronproton magnetic
moment ratio;
rapport du moment magnetique
du deuteron a
` celui du proton
md /me
3670.483 014(75)
0.020
md /mp
0.003
0.012
d
d /B
d /N
0.34
0.019
0.028
d /e
0.019
d /p
0.017
PHYSICO-CHEMICAL CONSTANTS
Avogadro constant;
constante dAvogadro
atomic mass constant;
constante de masse atomique :
1
12
12 m( C)
Faraday constant;
constante de Faraday
molar Planck constant;
constante molaire de Planck
molar gas constant;
constante molaire de gaz
Boltzmann constant;
constante de Boltzmann : R/NA
NA , L
0.59
mu
1.660 5402(10)1027 kg
931.494 32(28) MeV
0.59
0.30
96 485.309(29) C mol1
0.30
NA h
NA hc
8.4
k
k/h
k/hc
1.380 658(12)1023 J K1
8.617 385(73)105 eV K1
2.083 674(18)1010 Hz K1
69.503 87(59) m1 K1
8.5
8.4
8.4
8.4
Vm
22 414.10(19) cm mol1
8.4
2.686 763(23)1025 m3
8.5
S /R
1.151 693(21)
1.164 856(21)
18
18
59
RADIATION CONSTANTS
StefanBoltzmann constant;
constante de StefanBoltzmann :
( 2/60)k 4/
h3c2
first radiation constant;
premi`ere constante
de rayonnement : 2hc2
second radiation constant;
deuxi`eme constante
de rayonnement : hc/k
Wien displacement law constant;
constante de la loi du deplacement
de Wien :
max T = c2 /4.965 114 23 . . .
5.670 51(19)108 W m2 K4
34
c1
3.741 7749(22)1016 W m2
0.60
c2
8.4
8.4
* The molar entropy of an ideal monatomic gas of relative atomic weight Ar is given by
S = S + 23 R ln Ar R ln(p/p ) + 52 R ln(T /K).
60
Table 10. Maintained units and standard values.
Quantity
Symbol
Relative
uncertainty,
Value
parts in 106
electron volt: (e/C) J = {e} J
eV
standard atmosphere
standard acceleration of gravity
atm
gn
0.30
8.5
0.30
0.59
0.30
101 325 Pa
9.806 65 m s2
(exact)
(exact)
BI85
0.050
V76BI
0.30
ABI85
0.30
X-ray standards
x-unit: (Cu K1 )/1537.400
xu(Cu)
xu(Mo)
A : (W K1 )/0.209 100
0.70
13
0.45
10
0.92
61
Table 11. Expanded matrix of variances, covariances and correlation coefficients
for the 1986 recommended set of fundamental physical constants.
The elements of the variance matrix appear on and above the major diagonal
in (parts in 108 )2 ; correlation coefficients appear in italics below the diagonal.
The variances and covariances in thid table have been rounded from those given
in CODATA Bulletin No. 63.
The correlation coefficient between me and NA appears as 1 .000 in this
table because the auxiliary constants were considered to be exact in carryi
and NA appears as 1 .000 in this table because the auxiliary constants were
considered to be exact in carrying out the least-squares adjustment. When the
uncertainties of mp /me and Mp are properly taken into account, the correlation
coefficient is 0 .999 and the variances of me and NA are slightly increased.
1
1
e
h
me
NA
F
/p
20
0 .226
0 .154
0 .005
0 .005
0 .217
0 .498
e
31
921
0 .997
0 .975
0 .975
0 .902
0 .112
h
41
1812
3582
0 .989
0 .989
0 .931
0 .077
me
1
1750
3500
3497
1 .000
0 .975
0 .002
NA
F
1
1750
3500
3497
3497
0 .975
0 .002
29
/p
33
829
1688
50
67
917
0 .108
48
215
1747
1747
2
2
63
Table 12. Non-rationalized and rationalized systems.
Non-rationalized symmetrical
(Gaussian) system with three
base quantities (1.c)
Rationalized system
with four base quantities
Equations
c E = B /t
E = B/t
c H = 4j + D /t
D = 4
H = j + D/t
D=
B = 0
F = q (E + v B /c)
w = (E D + B E )/8
w=
S = c(E H )/4
B = 0
F = q(E + v B)
1
2 (E
D + B E)
S = EH
E = ( V + (1/c)A /t)
B = A
E = ( V + A/t)
B = A
D =
=
B =
=
r =
r =
D=
=
B=
=
r =
r =
r E
E + 4P
r H
H + 4M
1 + 4e
1 + 4m
E = r E
E + P
H = r H
(H + M )
1 + e
1 + m
Physical constants
2
hc
= e /
a = h
2/me e 2
hcR = e 2/2a
= e2/4 hc = ce2/2h
a = 4 h2/me e2
hcR = e2/8 a
re = e 2/me c2
B = e
h/2me c
re = e2/me
B = eh/2me
L = (q /2mc)B
= gI(e/mc)
L = (q/2m)B
= gI(e/m)
64
A.2 Systems of equations with four base quantities
The system of quantities is enlarged to four dimensions by including an
electrical quantity as a fourth base quantity. In SI and in its older relative, the
MKSA system, the fourth quantity is taken to be electric current, and in the
Syst`eme International eqs. (1) and (2) are rationalized (ke = km = 1/4). As a
result, permeability and permittivity are dimensional physical quantities. If
electrostatics and electrodynamics are to be coherent, thus avoiding the explicit
introduction of the factor c asymmetrically into the expressions for electric and
magnetic quantities, and must satisfy the condition
c2 = 1.
In SI the permeability of vacuum is defined to have the value
= 4107 N/A2 = 4107 H/m.
A.3 Relations between quantities in different systems
The basic equations between quantities in the non-rationalized symmetrical
(Gaussian) system (1c) and the corresponding equations in the rationalized
four-dimensional system are given in table 12. In order to distinguish the
physical quantities in the two systems, those in the three-dimensional system
are indicated with an asterisk ( ) when they differ from their corresponding
quantities of the rationalized four-dimensional system.+
The relationships
between the two sets of quantities are determined by setting X = aX X in the
first column and comparing the resultant equations with the corresponding ones
in the second column. These substitutions lead to:
1
(4 ) 2 =
1
(4/ ) 2 =
1
(4 ) 2 =
1
(4/ ) 2 =
4 =
V
E
=
=
E
V
D
,
D
H
,
H
A
B
=
=
B
A
e
= m
.
e
m
j
I
P
Q
= = = = ,
j
I
P
M
,
M
Symbols for Gaussian quantities may also be distinguished from those for the fourdimensional quantities by the superscript s or subscript s (for symmetric) instead of
the asterisk.
65
Table 13. CGS base units and derived units with special names.
Unit; Unite
Expression in
terms of base
units
Expression en
unites de base
Name
Symbol
Quantity
Grandeur
Nom
Symbole
length
longueur
centimetre
centim`etre
cm
mass
masse
gram
gramme
time
temps
second
seconde
force;
force
energy;
energie
viscosity;
viscosite
kinematic viscosity;
viscosite cinematique
dyne
dyn
cm g s2
erg
erg
cm2 g s2
poise
cm1 g s1
stokes
St
cm2 s1
gal
Gal
cm s2
The gal is a unit used in geophysics to express the earths gravitational field; it
should not be used as a unit of acceleration other than in this specific sense.
and their symbols, as well as the names and symbols of derived units having
special names in the CGS system are given in table 13.
The CGS electrostatic system of units (esu) forms a coherent system of units
in combination with the three-dimensional electrostatic system of quantities
of (1a). In its less common form as a four-dimensional system, the electrostatic
unit of charge (sometimes called the franklin; symbol, Fr ) is introduced and
the permittivity of vacuum is set equal to = 1 Fr2 dyn1 cm2 . Other units
may then be derived using the usual rules for constructing a coherent set of
units from a set of base units.
66
Table 14. CGS magnetic units with special names.
Unit; Unite
Name
Nom
Symbol
Symbole
Dimensiona
oersted
Oe
L 2 M 2 T1
gauss
G, (Gs)
L 2 M 2 T1
maxwell
Mx
L 2 M 2 T1
Fm
gilbert
Gi, (Gb)
L 2 M 2 T1
Quantity
Grandeur
L = length;
M = mass;
T = time.
67
Table 15. CGS units in photometry with special names.
Derived unit; Unite derivee
Quantity
Grandeur
luminance;
luminance
illuminance;
eclairement
lumineux
Name
Nom
Symbol
Symbole
Expression
Expression
stilb
sb
cm2 cd
phot
ph
cm2 cd sr
artifacts such as the metre or the second. It is, in fact, strongly recommended
that physical computations be carried out and reported in terms of such units
in order that the results should be independent (to the greatest possible extent)
of any uncertainties in the values of the physical constants.
The standard choice of units in quantum electrodynamics takes h and c as
the units of action and velocity respectively, so that the elementary charge
1
is (4 ) 2 (charge units) where the fine-structure constant is the natural
measure of the electromagnetic interaction.
For computations in atomic and molecular physics a more appropriate choice
(known as atomic units or au) takes the electron mass me to be the unit of
mass, the Bohr radius, a = h
/(me c) to be the unit of length and h
/(me c2 2 )
to be the unit of time. As a result the unit of velocity is c and the unit of
energy is Eh = me c2 2 = 2R hc, which has been given the name hartree. The
atomic units form an unrationalized, three-dimensional coherent system with
set equal to unity and the elementary charge e as the unit of charge.
Since atomic units are natural physical quantities rather than artificial
constructs, it is appropriate to write them in italic (sloping) type rather than in
the roman (upright) type normally used for units: the physical quantities are
represented as multiples of physical constants.