1

27 2015
:
: (4)

1 5
, , .
1.

p x
.
.
.

. .
5

2.

. n = 3, = 2,
. n = 4, = 4,
.
n = 2, = 0,
. n = 2, = 1,

3.

pH 10 3
25 C
. 2
. 3
.
4
. 8.
5

4.

CH2 CHCH3 1, 2, 3
,
. sp 2 , sp 2 , sp 3
. sp,
sp 2 , sp 3
3
.
sp , sp 2 , sp 2
. sp 2 , sp,
sp 3
5

A5.

( 9 F) ;
. 1s 2 2s 2 2p 5
. 1s 2 2s 1 2p 6
.
1s 2 2s 2 2p 6
. 1s 1 2s 1 2p 7 .
5

;
m = 2,
m s = +
m = 4,
m s = +
m = 0,
m s =
m = 1,
m s =
5

1 4

 2

1.
,
, ,
, , .
.

NaF p.

(C 4 H 6 )
CuC/NH 3 .

CH 3 CH 0,1 M,
CH 3 Ca 0,1 M NaC 0,1 M
.

.
.

ns 2 np 6 .

CH 3 H .
( 5)

.
( 10)
15
2.

7 , 12 , 8 , 1 .
. ,
.
( 4)
. ;
.
( 2)
. Lewis 3
.
( 4)
10

E
1.
.

2 4

 3
, , , , , , ,
, .
10
2.

2 2 SO 4 , ( )
. .
1 Na, 1,12 L
(STP).
2 2 /NaOH,
0,08 mol .
T 3 KMnO 4 0,1 M
2 SO 4 .
.
.

, .
( 3)
KMnO 4
3 .
( 12)
15
:
1:
COOH
2:
C 3 COOH
3:
NaOH

0,1 M
1M
0,1 M

K a (COOH) = 10 4
K a (C 3 COOH) = 10 5

1. mL 3 1 L 1,
p = 4;
7
2. 500 mL 1 500 mL 2,
4. p 4.
9
3. 4 Mg.
(STP).
6
4. HCOOH
MnO 4 2 SO 4 ;
( 2)
;
( 1)
3
:
= 25 C.
w = 10 14
.

3 4

 4
( )
1.

2.

3.
4.
5.
6.

. .
-
.
.
,
.
. ,
.

.
.
: (3) .
: 10.30 ..

4 4