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267
Melting
point (C)
Microhardness
HV (10 grf)
Electrical
resistivity
(cm)
217
217
227
138
17.6
15.2
12.9
17.2
13.8
12.4
11.4
30
Sn-Ag2.5/Cu.8-Sb0.5
Sn-Ag3.8/4-Cu0.5-0.7
Sn-Cu0.7
Sn 48-Bi58
HP 3852
DATA LOGGER
HP UNIX
I
DC
SOURCE
SHUNT
V
T
B. Diffusion Annealing
T7
V7
V1
T2
T1
1
V6
T5
2
V3
V4
T6
V5
V2
4
T3
T4
268
for
the
resistance
DMO-350 MICROHMETRE
Mean ()
Std. Dev.
95% Conf.
Min
Max
R ()
R (%)
Mean ()
Std. Dev.
95% Conf.
Min
Max
R ()
R (%)
SnAgCuSb
SnCu
2.98
0.21
0.15
2.57
3.17
0.30
10.99
2.93
0.20
0.14
2.64
3.19
0.25
8.87
2.85
0.12
0.09
2.71
3.09
0.24
6.16
2.88
0.09
0.06
2.71
3.01
0.20
7.19
Mean ()
Std. Dev.
95% Conf.
Min
Max
R ()
R (%)
2.83
0.31
0.22
2.51
3.53
0.15
5.57
2.81
0.17
0.12
2.65
3.26
0.13
4.85
2.79
0.13
0.09
2.71
3.14
0.11
3.91
2.78
0.26
27.8
2.47
3.20
0.10
3.69
RESULTS
SnBi
= 2 s Rm
SnAgCu
2.73
0.11
0.05
2.53
2.94
0.05
1.87
2.76
0.12
0.06
2.58
2.98
0.08
3.01
2.76
0.19
0.09
2.53
3.03
0.08
2.97
2.71
0.14
0.07
2.56
3.01
0.03
1.25
Cu ETP
2.68
0.06
0.04
2.57
2.77
1.68
Ni
9.99
0.26
0.19
9.62
10.43
6.27
Al-6061
5.57
0.20
0.14
5.18
5.81
3.50
Ag
2.48
0.15
0.11
2.20
2.66
1.56
269
SnBi
SnAgCuSb
SnCu
Phase 1 (m)
12
12
2-3
1-2
Phase 2 (m)
34
34
4-5
4-5
40
60
50
50
Plating (m)
Phase 1 (m)
2-3
12
1-2
1-2
Phase 2 (m)
4-6
34
3-4
4-5
40
60
50
50
Plating (m)
270
Fig. 3.
The resistivity of the intermetallics formed at the lead-freecopper interface can be calculated from the four-point probe
resistance measurements made on the cross-sectioned pads of
flexible connectors. Since the resistance measurement of the
microohmetre is based on the current penetration into the
material [8], a rectangular conductor, such as shown in Fig. 5
can be envisaged as a volume of the material sampled by the
microohmetre probes. The cross-section area A = a b (b = 1.5 S)
of such a conductor was derived from the resistance
measurements made on the annealed copper samples using the
known resistivity value for hard drawn copper Cu = 1.80
cm and the probe spacing S.
R = (1/A) Cu S
IV. DISCUSSION
The results of numerous studies showed that the mechanical
properties of copper-tin are strongly affected by the presence of
the intermetallics when their thickness at the interface exceeds
the critical value of 2 microns. At this thickness, the interface
between the two metals in contact becomes brittle, thus making
the interface more highly porous and more susceptible to
adverse environmental effects due to the generation of numerous
fissures in the interdiffusion layer [10- 14]. This is clearly
illustrated in Fig. 9 showing extensive cracking at the interface
between Cu3Sn and Cu6Sn5 phases.
A = Cu S / R
The results of resistance measurements made by four-point
probe (Table 1) can be used to calculate the overall resistivity
(i) of the intermetallic layers formed. The calculations were
made from the weighted averages of resistors in series using the
following expression:
R = (1/A) n xn
(3)
The evolution of the intermetallic phases at the lead-freecopper interface I schematically illustrated in Fig.4. The results
lf the SEM analysis indicated that diffusion annealing either by
thermal gradient or by electrical current for 25 days resulted in
the formation of basically Cu3Sn and C6Sn5 phases. For
practically all alloys used, the thickness of the Cu3Sn phase was
in the range 1-3 m whereas that of the C6Sn5 phase within 3-5
m.
AFTER PLATING
OXIDE
Sn
EARLY STAGES
OXIDE
Sn
Cu66Sn
Sn55
Cu
Cu6Sn5
Cu
Cu3Sn
Cu
Cu
Sn
IM
A
A
a
t
d
RCu
LATER STAGES
Ri
RSn
OXIDE
Sn
Cu6Sn5
R
Fig. 5
Cu3Sn
Cu
Fig. 4
Schematic of the intermetallic phase formation at he
lead-free - copper interface after plating and in the early and
later stages of diffusion annealing.
(2)
271
SnBi
SnAgCuSb
SnCu
Plating (m)
40.00
60.00
50.00
50.00
IM (m)
5.00
5.00
5.00
5.00
Thermal
2.83
2.81
2.79
2.78
i ( cm)
19.06
16.80
13.54
12.54
Electric
2.98
2.93
2.85
2.88
i ( cm)
37.61
30.72
21.31
24.45
CONCLUSIONS
ACKNOWLEDGEMENT
[1].
REFERENCES
Database for Solder Properties with Emphasis on New Leadfree Solders, NIST. www.boulder.nist.gov
[2].
[3].
[4].
[5].
[6].
272
[7].
[8].
[9].
[10].
[11].
[12].
[13].
[14].
[15].
[16].
[17].
[18].
[19].
273