Material Safety Data Sheet

Number:
Date:
Page:

OSHA 29 CFR 1910.1200

EN- 422-d -US

21-10-2013.
1/6

Oc ColorWave 300 Black Ink

1.

Identification of the substance/preparation and of the company/undertaking

Product name
Article number (Oc)

: Oc ColorWave 300 Black Ink

: 1060091360 / 1060089323 / 1060091356 / 29953904 / 29953908 (Ink tank 400 ml / Ink tank 200 ml /
Printhead / combipack(XL)
: 5834B005AA / 5834B001AA / 5835B001AA / 5836B004AA / 5836B008AA
: Polypropylene container with polyethylene bag inside (ink tanks)
: Inkjet printing ink. Other uses are not recommended.

Product code (Canon)

Packaging
Specific uses
Manufacturer

: Oc-Technologies B.V.
St. Urbanusweg 43, P.O. box 101, 5900 MA Venlo, the Netherlands
: sds-hq@oce.com
: Canon USA Inc.
: One Canon Park, Melville, NY, 11747, USA
: 1-800-OK-CANON
: CHEMTREC# 1-800-424-9300 (24-hour safety information)

e-mail address
Supplier
Address
Telephone no.
Emergency telephone number

2.

Hazards identification

OSHA/HCS status (USA)

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
OSHA HCS Classification
: Target organ effects
Emergency overview
Hazard statements

: Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Contains
material that may cause target organ damage, based on animal data.
: CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

Precautionary statements

: Do not handle until all safety precautions have been read and understood. Do not breathe vapor or
mist. Do not eat, drink or smoke when using this product. Use personal protective equipment as
required.
Classification according to Directive 67/548/EEC [DSD] / Directive 1999/45/EC [DPD]
Europe
Supplemental label elements
Other hazards which do not
result in classification

: Not classified.
: Safety Data Sheet available for professional user on request.
: To the best of our knowledge, with due observance of normal hygiene this product presents no health
hazard in normal use.

See Section 4 and 11 for more detailed information on health effects and symptoms.

3.

Composition/information on ingredients

Substance/mixture

: Mixture

Product/ingredient name

Identifiers

Europe
Water Soluble Organic Solvent,
Cyclic Amide
Hydroxylated alkane

Trade secret.

Water soluble organic solvent,

Polyol
Carbon black

Acrylic terpolymer
water

Classification Europe

Type

67/548/EEC

CLP 1272/2008/EC

5 - 10

Xn; R21/22

[1]

Trade secret, NJTSRN

80100451-5004

5 - 10

Xi; R36/37/38

Trade secret

5 - 10

Not classified.

Acute Tox. 4, H302

Acute Tox. 4, H312
Skin Irrit. 2, H315
Eye Irrit. 2, H319
STOT SE 3, H335 (Respiratory
tract irritation)
Not classified.

REACH #:
01-2119384822-32
EC: 215-609-9
CAS: 1333-86-4
Trade secret
EC: 231-791-2
CAS: 7732-18-5

1-5

Not classified.

Not classified.

0.1 - 2
60 - 78

Not classified.
Not classified.

Not classified.
Not classified.

Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Hazardous ingredients
United States
: Carbon black
Occupational exposure limits, if available, are listed in Section 8.

[1]

Material Safety Data Sheet

OSHA 29 CFR 1910.1200

Number:

EN- 422-d -US

Date:
Page:

21-10-2013.
2/6

Oc ColorWave 300 Black Ink

See Section 16 for the full text of the R phrases or H statements declared above.

4.

First aid measures

Description of first aid measures

Inhalation
Ingestion
Skin contact
Eye contact

: Remove to fresh air.

: Do not induce vomiting. Have conscious person drink several glasses of water or milk.
: Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or
thinners.
: Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15
minutes, keeping eyelids open. Seek immediate medical attention.

Potential acute health effects

Inhalation
Ingestion
Skin contact
Eye contact

:
:
:
:

If ink mist is inhaled, respiratory tract irritation may occur. No adverse chronic effects known.
Not classified for acute oral toxicity (OECD 401).
No known significant effects or critical hazards.
No known significant effects or critical hazards.

Over-exposure signs/symptoms
Inhalation

: No specific data.

Ingestion

: No specific data.

Skin
Eyes

: No specific data.
: No specific data.

Specific treatments

: In all cases of doubt, or when symptoms persist, seek medical attention and take along this safety data
sheet.
See Section 11 for more detailed information on health effects and symptoms.

5.

Fire-fighting measures

Extinguishing media
Suitable
Not suitable
Special exposure hazards

: Recommended: alcohol-resistant foam, CO, powders, water spray.

: Do not use water jet.
: None known.

Hazardous thermal
:
decomposition products
Special protective actions for fire- :
fighters
Special protective equipment for :
fire-fighters

6.

Decomposition products may include the following materials: carbon monoxide, carbon dioxide, smoke,
oxides of nitrogen.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No
action shall be taken involving any personal risk or without suitable training.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including
helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic
level of protection for chemical incidents.

Accidental release measures

Personal precautions

: Avoid breathing vapor or mist. Refer to protective measures listed in sections 7 and 8.

Environmental precautions

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,
soil or air).
Spill
: Wipe up small spills with disposable towels and transfer to a sealable, appropriate container for
disposal. Dispose of via a licensed waste disposal contractor.
See Section 8 for information on appropriate personal protective equipment.

7.

Handling and storage

Protective measures

: Put on appropriate personal protective equipment (see Section 8).

Advice on general occupational

hygiene
Storage

: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and
processed.
: Store in a dry and cool area. Keep container tightly closed and sealed until ready for use. Keep from
freezing.
: Not available.

Precautions (Specific uses)

Material Safety Data Sheet

OSHA 29 CFR 1910.1200

Number:

EN- 422-d -US

Date:
Page:

21-10-2013.
3/6

Oc ColorWave 300 Black Ink

8.

Exposure controls/personal protection

Occupational exposure limits

US

Ingredient name
Carbon black

Occupational exposure limits

ACGIH TLV (United States, 1/2009).
TWA: 3,5 mg/m 8 hour(s).
NIOSH REL (United States, 6/2009).
TWA: 3,5 mg/m 10 hour(s).
TWA: 0,1 mg of PAHs/cm 10 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 3,5 mg/m 8 hour(s).

Occupational exposure controls

: No special ventilation requirements. Good general ventilation should be sufficient to control worker
exposure to airborne contaminants.
Respiratory protection
: Not required during normal intended use of this product.
Hand protection
: For prolonged or repeated handling, use the following type of gloves: neoprene or nitrile gloves.
Contaminated gloves should be replaced.
Eye protection
: Safety glasses with side shields.
Skin protection
: Not required during normal intended use of this product.
Environmental exposure controls : Prevent entry into sewers, watersheds and waterways.

9.

Physical and chemical properties

Appearance
Physical state
Color
Odor

: Liquid.
: Black.
: Faint odor.

pH

: 7 to 8,5

Boiling point

: 99C (210,2F)

Flash point
Evaporation rate
Flammability
Explosion limits

:
:
:
:

Vapor pressure

: Not available.

Vapor density
Density

: Not available.
: Not available.

Relative density

: 1

Solubility

: The product is soluble in water.

Partition coefficient: n-octanol/

water
Decomposition temperature
Viscosity
Volatility

: Not available.

10.

Closed cup: >200C (>392F) [Product does not sustain combustion.]

3,78 (butyl acetate = 1)
Not determined.
Not applicable.

: Not available.
: Not available.
: 82.2% (w/w)

Stability and reactivity

Reactivity

: No specific test data related to reactivity available for this product or its ingredients.

Chemical stability

: The product is stable.

Possibility of hazardous
reactions
Conditions to avoid

: Under normal conditions of storage and use, hazardous reactions will not occur.

Incompatible materials

: None known.

Hazardous decomposition
products

: Under normal conditions of storage and use, hazardous decomposition products should not be
produced.

: None known.

Material Safety Data Sheet

OSHA 29 CFR 1910.1200

Number:

EN- 422-d -US

Date:
Page:

21-10-2013.
4/6

Oc ColorWave 300 Black Ink

11.

Toxicological information
Acute toxicity

: No adverse effects are expected under intended use.

Product/ingredient name

Result

Species

Dose

Oc TCS300/TCS500 Black ink

LD50 Oral

Rat

>2000 mg/kg

Chronic toxicity

: No known significant effects or critical hazards.

: Chronic toxicological testing of the product has not been performed.

Irritation/Corrosion Skin
Eyes

: Non irritating on rabbit (OECD 404, method B4). Not classified as a skin irritant.
: Non irritating on rabbit (OECD 405, Method B5). Not classified as an eye irritant.

Respiratory : If ink mist is inhaled, respiratory tract irritation may occur. No adverse chronic effects known.
Sensitization

Skin

Mutagenicity
Carcinogenicity

: Non-sensitizer. (OECD 406 Skin Sensitization). Not classified as a dermal sensitiser.

: Not mutagenic in Ames test.
: No known significant effects or critical hazards.

Classification
Product/ingredient name

ACGIH

Carbon black

Reproductive toxicity
Teratogenicity

A3

IARC

EPA

2B

NIOSH

NTP

OSHA

: Neither this product nor any of its components present above 0.1% are listed by IARC, NTP, or OSHA
as known carcinogens. Pure carbon black, a minor component of this product, has been listed by
IARC as a group 2B (possible carcinogen). This classification is based on rat "lung particulate
overload" studies performed with airborne particulate carbon black. Ink is not listed by IARC, NTP, or
OSHA.
: Not available.
: No known significant effects or critical hazards.

Toxicokinetics
Information on the likely
routes of exposure
Target organs

12.

: Routes of entry anticipated: Oral, Dermal.

: Contains material which may cause damage to the following organs: lungs, upper respiratory tract,
eyes.

Ecological information

Ecotoxicity
Aquatic ecotoxicity

: No experimental data available for the product.

: Not determined.

Product/ingredient name
Oc TCS300/TCS500 Black ink

Result
EC50 >1000 mg/l

Species
Daphnia

Exposure

Test

48 hours

Persistence and degradability

: Not available.

Bioaccumulative potential

: No known significant effects or critical hazards.

Mobility in soil

: Not available.

13.

Disposal considerations

Methods of disposal

RCRA classification

14.

: This product is not classified as a hazardous waste.

Do not allow to enter drains or watercourses. Dispose of according to all federal, state and local
applicable regulations.
: Not applicable. This product is not listed hazardous waste in accordance with Federal Regulation 40
CFR Part 261.

Transport information

This product is not regulated for carriage according to ADR/RID, IMDG, ICAO/IATA.
DOT Classification : Not a DOT controlled material (United States).

Material Safety Data Sheet

OSHA 29 CFR 1910.1200

Number:

EN- 422-d -US

Date:
Page:

21-10-2013.
5/6

Oc ColorWave 300 Black Ink

15.

Regulatory information

Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the
information required by the Controlled Products Regulations.
United States
OSHA HCS Classification
Hazard statements

:
:

Target organ effects

CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.

Precautionary statements

Contains

Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Contains
material that may cause target organ damage, based on animal data.
Carbon black
CAS number 1333-86-4

U.S. Federal regulations

Massachusetts

SARA 302/304: No products were found.

SARA 311/312 Hazards identification: Delayed (chronic) health hazard
Listed component
The following components are listed: CARBON BLACK

New Jersey
Pennsylvania

:
:

The following components are listed: CARBON BLACK

The following components are listed: CARBON BLACK

California Prop. 65

California Porposition 65 list contains airborne, unbound Carbon Black of respirable size. Under
intended use of this product the degree of inhalation exposure to powdered Carbon Black is negligible.
Therefore warnings under Proposition 65 are not required.

State regulations

Mexico
This safety data sheet was prepared in accordance with the Official Mexican Standard (NOM-018-STPS-2000).
Inventory Status
United States inventory (TSCA 8b) :
Canada inventory (DSL)
:
Europe inventory (EINECS/ELINCS/ :
NLP)
Swiss Inventory of Notified New
:
Substances
Japan inventory (ENCS)
:
Philippines inventory (PICCS)
:
Korea inventory (KECI)
:
Australia inventory (AICS)
:
China inventory (IECSC)
:
New Zealand Inventory of Chemicals :
(NZIoC)

16.

All components are listed or exempted.

All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are listed or exempted.
All components are notified or exempted.
All components are listed or exempted.

Other information

Revision comments

: Minor changes in several chapters.

Date of previous issue

: 08-2010

Version

: 4

Full text of classifications [CLP/

GHS]

ACUTE TOXICITY (oral) - Category 4

: Acute Tox. 4, H302
Acute Tox. 4, H312
ACUTE TOXICITY (dermal) - Category 4
Eye Irrit. 2, H319
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Skin Irrit. 2, H315
SKIN CORROSION/IRRITATION - Category 2
STOT SE 3, H335
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract
(Respiratory tract irritation) - Category 3
irritation)
: H302
Harmful if swallowed.
H312
Harmful in contact with skin.
H315
Causes skin irritation.
H319
Causes serious eye irritation.
H335 (Respiratory May cause respiratory irritation. (Respiratory tract irritation)
tract irritation)
: Xn - Harmful
Xi - Irritant
: R21/22- Harmful in contact with skin and if swallowed.
R36/37/38- Irritating to eyes, respiratory system and skin.

Full text of abbreviated H

statements

Full text of classifications [DSD/

DPD]
Full text of abbreviated R phrases

Material Safety Data Sheet

OSHA 29 CFR 1910.1200

Number:

EN- 422-d -US

Date:
Page:

21-10-2013.
6/6

Oc ColorWave 300 Black Ink

Abbreviations and acronyms

: ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DPD = Dangerous Preparations Directive [1999/45/EC]
DSD = Dangerous Substances Directive [67/548/EEC]
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
ICAO = International Civil Aviation Organization
IMDG = International Maritime Dangerous Goods
REACH = Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation [Regulation
(EC) No. 1907/2006]
RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail
PBT = Persistent, Bioaccumulative and Toxic
vPvB = Very Persistent and Very Bioaccumulative
ACGIH = American Conference of Industrial Hygeniests
STEL = Short Term Exposure Limit
TLV = Threshold Limit Value
TWA = Time Weighted Average
HCS = Hazard Communication Standard
RCRA = Resource Conservation and Recovery Act
DOT = Department Of Transportation
PEL = Permissible Exposure Limit
REL = Recommended Exposure Limit

This safety data sheet has been compiled to the best of our knowledge as a compact guide to safe handling of this product. We reserve the right
to revise safety data sheets as new information becomes available. It is the users responsibility to determine the suitability of this information for
the adoption of safety precautions as may be necessary and to contact the company to make sure that this sheet is the latest one issued. If and in
sofar as limitation of liability is permitted under the applicable laws, we do not accept liability for any inaccuracy that may occur in this information.
Copyright 2006 Oc