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Binary azeotropes
Data source color code
CRC & Lange's CRC only Lange's only other (see references)
% by spef.
weight grav
69.2
97
56
47
0.863
67.6
69.5
32
95
79
51
22
0.848
63
93
84.2
95
93
97.2
79.5
89.5
56
73
96.8
95.0
97.0
73.0
96.2
0.815
0.687
0.729
1.403
1.377
1.197
1.517
37.0
60
43.0
26.8
0.802
0.788
3.3
55.0
92
% by spef.
weight grav
81.3
56
84
0.908
0.846
87.7
74.4
78
with various other solvents
[3][5]
acetone
56.5C
No azeotrope
methyl ethyl ketone 79.6
73.5
89
0.834
pyridine
115.5
92.6
57
1.010
91.1
benzene
80.2
69.3
U 99.94 U 0.880
L 0.07 L 0.999
79.8
toluene
110.8
84.1
U 99.95 U 0.868
L 0.06 L 1.000
91.5
cyclohexane
80.7
69.8
U 99.99 U 0.780
L 0.01 L 1.00
diethyl ether
34.5
34.2
98.7
0.720
[3]
tetrahydrofuran
66
65
95
anisole
153.9
95.5
59.5
acetonitrile
82.0
76.5
83.7
0.818
chloral
97.75
95.0
93.0
[6]
hydrazine
113.5C 120.3C
68.5
ethyl nitrate
CRC 44th ed. lists azeotropes for acetic acid/water and acetone/water, Lange's 10th ed. as well as
numerous web sources indicate no azeotrope for these pairs.
% by spef.
weight grav
51
97
49
83.1
47.5
96
88.5
0.833
0.836
1.437
81
91
% by spef.
weight grav
98
98
72
27.5
70
50
91
97
61.5
45
75.0
0.882
0.905
0.908
benzene
toluene
cyclohexane
80.8
54.2
n-pentane
n-hexane
n-heptane
n-octane
36.2
30.8
68.9
50.6
98.5
59.1
125.8 63.0
with various alkyl halides
ethylene chloride
83.7
61.0
chloroform
61.1
53.5
carbon tetrachloride
76.8
55.7
ethyl bromide
38.4
35.0
n-propyl chloride
46.6
40.5
isopropyl chloride
36.4
33.4
n-propyl bromide
71.0
54.5
isopropyl bromide
59.8
48.6
isopropyl iodide
89.4
61.0
[4]
trichloroethylene
87.2
60.2
[8]
tetrachloroethylene
121.1 63.5
trichlorotrifluoroethane
47.7
39.9
(CFC 113)[4]
with various other solvents
nitromethane
101.2 64.6
acetone
56.5
55.7
acetonitrile
82.0
63.45
60.4 0.844
31
0.813
62.8
U 97.0
L 39.0
91
72
48.5
72.0
68
87.4
79.4
95.5
90.5
94
79
85.0
62
64
40.6
1.342
1.322
94
carbon disulfide
46.2
37.7
isopropanol[4]
tetrahydrofuran[9]
P = 984 mBar
88.5
64.0
9
87.9 0.796
19.0
86.0
U 50.8 U 0.979
L 97.2 L 1.261
20
65.6
60.7
69.0
94.8
139.7
84.0
65.0
1.024
b.p. of
b.p. of
% by spef.
comp. (C) mixture (C) weight grav
with various hydrocarbons
benzene
80.2
71.7
69
toluene
110.8
85.8
50
m-xylene
139.0
94.2
29.8
n-pentane
36.2
34.2
90
n-hexane
68.9
60.6
72
n-heptane
98.5
78.2
56.5
n-octane
125.8
90.5
37
with various alkyl halides
chloroform
61.2
59.2
85
carbon tetrachloride 76.8
66.7
81.5
methyl iodide
42.6
42.1
94
ethyl bromide
38.4
38.2
97
ethylene chloride 83.6
77.4
86
ethylene bromide 131.7
94.7
48.5
n-propyl chloride 46.7
45.6
92
isopropyl chloride 34.8
34.7
98.5
n-propyl bromide 71.0
64.7
73
isopropyl bromide 59.4
56.0
86
with various other solvents
carbon disulfide
46.3
42.6
83
b.p. of
b.p. of
% by spef.
comp. (C) mixture (C) weight grav
with various solvents
ethyl benzoate 212.6
186.1
53.5
diphenyl
254.9
192.0
36
mesitylene
164.6
156.0
87
naphthalene
218.1
183.9
49
toluene
110.8
110.2
93.5
m-xylene
139.0
135.6
85
o-xylene
144.4
139.6
84.0
ethylene bromide 131.7
129.8
96
nitrobenzene
210.9
185.9
41
chlorobenzene 132.0
130.1
5.6
benzyl chloride 179.3
167.0
70
benzyl alcohol 205.1
193.1
44
anisole
153.9
150.5
89.5
acetophenone
202.1
185.7
48
aniline
184.4
180.6
76
o-cresol
191.1
189.6
73
2nd Component
2nd Component
b.p. of
b.p. of
% by spef.
comp. (C) mixture (C) weight grav
254.9
243.8
45
218.1
215.2
90
b.p.
comp. 1 (C)
acetaldehyde
21.0
acetamide
222.0
acetonitrile
82.0
acetylene
aniline
86.6
184.4
carbon disulfide
46.2
chloroform
61.2
cyclohexane
81.4
diethyl ether
34.6
nitromethane
101.0
tetrahydrofuran[9]
65.6
b.p.
comp. 2 (C)
diethyl ether
34.6
[7]
n-butane
0.5
benzaldehyde
179.5
nitrobenzene
210.9
o-xylene
144.1
ethyl acetate
77.15
[8]
toluene
110.6
ethane
88.3
o-cresol
191.5
diethyl ether
34.6
1,1-dichloroethane 57.2
methyl ethyl ketone 79.6
ethyl acetate[4]
77.1
[4]
methyl acetate
57.0
methyl ethyl ketone 79.6
n-hexane
68.7
methyl ethyl ketone 79.9
ethylene dichloride 84.0
ethyl acetate
77.1
ethyl acetate
77.15
ethyl nitrate
88.7
methyl formate
31.50
[3]
methylene chloride 40
toluene
110.8
chloroform
61.2
n-hexane
69
component 2
b.p.
% wt % wt spec.
azeo. (C) comp. 1 comp. 2 grav.
20.5
76.0
24.0
0.762
7.0
16.0
84.0
178.6
6.5
93.5
202.0
24.0
76.0
142.6
11.0
89.0
74.8
23.0
77.0
81.1
25.0
75.0
94.5
40.7
59.3
191.3
8.0
92.0
34.4
1.0
99.0
0.719
46.0
94.0
6.0
45.9
84.7
15.3
1.157
46.1
97
3
40.2
73
27
79.9
17.0
83.0
0.877
60.0
72.0
28.0
1.101
73.8
71.0
29.0
1.247
75.3
78.0
22.0
1.500
74.8
57.0
43.0
1.202
72.8
46.0
54.0
74.5
64.0
36.0
28.2
44.0
56.0
40.8
30
70
96.5
55.0
45.0
72.5
34.5
65.5
63.0
46.5
53.5
toluene
110.63
pyridine
aniline
o-xylene
toluene
115.3
184.4
144.4
110.6
110.2
179.5
135.8
110.5
78.0
43
10
1.5
22.0
57
90
98.5
Ternary azeotropes
Tables of various ternary azeotropes (that is azeotropes consisting of three components). Fraction percentages are given by weight.
Data source color code
CRC & Lange's CRC only Lange's only other (see references)
b.p.
2nd comp. (C)
ethanol
78.4
n-propanol
97.2
isopropanol
82.5
allyl alcohol
97.0
benzene
80.1
b.p.
b.p.
% wt % wt % wt spec.
3rd comp. (C) azeo. (C) 1st
2nd 3rd
grav
ethyl acetate
77.1
70.3C
7.8
9.0
83.2 0.901
cyclohexane
80.8
62.1
7
17
76
18.5 74.1
7.4
benzene
80.2
64.9
U 1.3 U 12.7 U 86.0 U 0.866
L 43.1 L 52.1 L 4.8 L 0.892
4.0
92.5
3.5
chloroform
61.2
55.5
U 80.8 U 18.2 U 1.0 U 0.976
L 0.5 L 3.7 L 95.8 L 1.441
4.3
9.7
86.0
3.4
10.3 86.3
carbon tetrachloride 86.8
61.8
U 44.5 U 48.5 U 7.0 U 0.935
L <0.1 L 5.2 L 94.8 L 1.519
ethylene chloride 83.7
66.7
5
17
78
acetonitrile
82.0
72.9
1.0
55.0 44.0
12.0 37.0 51.0
toluene
110.6
74.4
U 3.1 U 15.6 U 81.3 U 0.849
L 20.7 L 54.8 L 24.5 L 0.855
methyl ethyl ketone 79.6
73.2
11.0 14.0 75.0 0.832
12.0 85.0
3.0
n-hexane
69.0
56.0
U 0.5 U 3.0 U 96.5 U 0.672
L 19.0 L 75.0 L 6.0 L 0.833
6.1
33.0 60.9
n-heptane
98.4
68.8
U 0.2 U 5.0 U 94.8 U 0.686
L 15.0 L 75.9 L 9.1 L 0.801
carbon disulfide
46.2
41.3
1.6
5.0
93.4
cyclohexane
80.8
66.6
8.5
10.0 81.5
benzene
80.2
68.5
8.6
9.0
82.4
5
11
84
carbon tetrachloride 76.8
65.4
U 84.9 U 15.0 U 0.1 U 0.979
L 1.0 L 11.0 L 88.0 L 1.436
diethyl ketone
102.2
81.2
20
20
60
n-propyl acetate
101.6
82.2
21.0 19.5 59.5
64.3
7.5
18.5 74.0
cyclohexane
80.8
66.1
7.5
21.5 71.0
66.5
7.5
18.7 73.8
8.2
19.8 72.0
benzene
80.2C
65.7C
U 2.3 U 20.2 U 77.5 U 0.855
L 85.1 L 14.4 L 0.5 L 0.966
methyl ethyl ketone 79.6
73.4
11.0 1.0
88.0 0.834
13.1 38.2 48.7
toluene
110.6
76.3
U 8.5 U 38.2 U 53.3 U 0.845
L 61.0 L 38.0 L 1.0 L 0.930
5
5
90
n-hexane
69.0
59.7
U 0.5 U 3.6 U 95.9 U 0.668
L 64.4 L 34.8 L 0.8 L 0.964
8.6
9.2
82.2
benzene
80.2
68.2
U 0.6 U 8.7 U 90.7 U 0.877
L 80.9 L 17.7 L 0.4 L 0.985
cyclohexane
80.8
66.2
8
11
81
5
11
84
carbon tetrachloride 76.8
65.2
U 71.7 U 25.6 U 2.7 U 0.777
L 0.8 L 10.1 L 89.1 L 1.464
acetonitrile
82.0
66.0
8.2
68.5 23.3
8.8
65.1 26.1
methyl ethyl ketone 79.6
68.2
U 0.6 U 71.3 U 28.1 U 0.858
L 94.7 L 0.1 L 5.2 L 0.992
3rd component
65.7
cyclohexane
81.0
63.6
methanol
64.65
52.6
acetone
56.5
60.4
chloroform
61.2
3.0
22.2 74.8
U 94.4 U 5.5 U 0.1 U 0.993
L 0.1 L 22.6 L 77.3 L 1.313
5.0
60.0 35.0
U 0.6 U 37.0 U 62.4 U 0.769
L 89.9 L 10.0 L 0.1 L 0.98
4.0
81.0 15.0
U 27.0 U 32.0 U 41.0 U 1.022
L 3.0 L 83.0 L 14.0 L 1.399
4.0
57.6 38.4
Saddle azeotrope
methyl acetate
b.p.
b.p.
3rd component
2nd comp. (C)
3rd comp. (C)
chloroform
61.2
56.5
methyl acetate 57.0
cyclohexane
81.4
carbon disulfide 46.2
57.1
cyclohexane
81.4
n-hexane
69.0
b.p.
% wt % wt % wt spec.
azeo. (C) 1st 2nd 3rd grav
57.5
23.0 30.0 47.0
53.7
17.4 5.8
76.8 0.898
51.5
16.0 43.5 40.5
37.0
50.8
17.8 48.6 33.6
45.0
14.0 27.0 59.0 0.73
Saddle azeotrope
References
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10.
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