NAME:

STUDENT ID:

Chem 142 Experiment #2: Stoichiometry I

I. Reaction of Hydrogen Peroxide and Bleach
II. Reaction of Fe2+ with 1,10-Phenanthroline

Grading: 55 pts total (45 pts for this template, 10 pts for notebook pages)
Notebook pages: Purpose/Method section complete? Are they organized and legible? Have you plotted your d

Note:
ALL sections of this report MUST be typed. With this and all future Excel-based rep
the report prints correctly (graphs, tables, and text boxes are not split across page
turn it in. If you print it and it doesn't look okay, use the tools in Excel to adjust the
then re-print the report before submitting it.

By signing below, you certify that you have not falsified data, that you have not plagiarized any part o
that all calculations and responses other than the reporting of raw data are your own independent w
declaration will result in 5 points being deducted from your report score.
Signature:

DATA, CALCULATIONS AND GRAPHS

Part I: Reaction of hydrogen peroxide and bleach
Concentration of stock solutions

Measurement

1
2
3
4

Bleach, NaOCl(aq)

3.00

Hydrogen Peroxide, H2O2(aq)

6.00

Mass of 0.500 mL Bleach, g

0.548
0.547
0.547
0.544
Average Density, g/mL

Density of Bleach, g/ml

1.10
1.10
1.09
1.09
1.09

Type your calculation of the density of bleach using the mass data from measurement #1.
density = mass/volume
0.548g bleach / 500 mL bleach = 1.10 g/mL bleach

Type your calculation of the average density of bleach using the mass data from all four measurements.
(1.10+1.10+1.09+1.09)/4 = 1.10

Type your calculation of the density of bleach using the mass data from measurement #1.
density = mass/volume
0.548g bleach / 500 mL bleach = 1.10 g/mL bleach

Type your calculation of the average density of bleach using the mass data from all four measurements.
(1.10+1.10+1.09+1.09)/4 = 1.10

Run Number
Run 1
Run 2
Run 3
Run 4
Run 5
Run 6
Run 7
Run 8
Run 9
Run 10
Run 11

mL of Bleach
4
4
4
4
4
4
4
4
4
4
4

Grams of Hydrogen Peroxide

1.028
1.504
2.089
2.551
3.017
3.555
4.049
4.581
5.02
N/A
N/A

Put your Plot of Volume (mL) of O2 vs Mass (g) of H2O2 here. Make your graph big enough to cover this instr
appropriate size for someone else to read it.

Volume of O2 Generated When Bleach and H2O2

Use the online resources if you need help figuring out how to plot a graph in Excel. (See the links on
80.0
report.)

Title the graph and label 70.0

the X and Y axis, including the correct units. Be sure to double check your u
ble
print the report.
60.0

Using the line tool on the50.0

drawing toolbar, draw the three straight lines: 1) best fit for the data where H
the data where H2O2 is in excess, and 3) a vertical
from the intersection of lines 1 and 2 down to t
H2O2line
is limiting
40.0
identify
theofequivalence/stoichometric
point. reagent
Volume
O2 (mL)
30.0

Indicate on your graph where the H2O2 is the limiting reagent and where it is in excess.
20.0
10.0
0.0
1.028

1.504

2.089

2.551

3.017

3.555

Mass of H2O2 (grams)

Grams of H2O2 solution at the Eqv Point

3.40

Moles H2O2 at the Eqv Point

2.99E-03

Moles NaOCl at the Eqv Point

3.50E-03

Stoichiometry: moles H2O2/moles NaOCl

1.170

Type your calculation for the moles of H2O2 at the equivalence point.

(3.4g H2O2 x(3g H202/100g H2O2))/34.016mm H2O2 = 2.99E-3 moles

Type your calculation for the moles NaOCl at the equivalence point.

(4mL NaOCl x 1.094 g/mL x (6g NaOCl/100gNaOCl))/100g NaOCl = 3.5E-3 moles

4.049

Type your calculation for the moles NaOCl at the equivalence point.

(4mL NaOCl x 1.094 g/mL x (6g NaOCl/100gNaOCl))/100g NaOCl = 3.5E-3 moles

Part II: Iron(II) -Phenanthroline Reaction

Concentration of stock 1,10 phenanthroline solution
Concentration of stock Fe2+ solution
Volume of stock 1,10 phenanthroline solution you obtained

Total Volume of Fe2+ added, L

0
100
200
300
400
500
600
700
800

Absorbance
0
0.001
0.039
0.091
0.148
0.16
0.162
0.16
N/A

Put your Absorbance vs mL Fe2+ here. Make your graph big enough to cover this instruction box so that it is
someone else to read it.

Volume of Fe2+ and its relation to Absorban

Use the online resources if you need help figuring out how to plot a graph in Excel. (See the links
0.18
this report.)

0.16
Title the graph and
label the X and Y axis, including the correct units (Absorbance data is unitless
your units and formatting once you print the report.
0.14

Using the line tool on the drawing toolbar, draw the three straight lines: 1) best fit for the data whe
0.12 Fe 2+ is in excess, and 3) a vertical line from the intersection of lines 1 and 2
fit for the data where
to clearly identify the
0.1 equivalence/stoichometric point.
Absorbance
Indicate
on your graph
0.08 where the iron is the limiting reagent and where it is in excess.
0.06
0.04

Fe2+ is
limiting
reagent

0.02
0
0

100

200

300

400

500

Volume of Fe2+ (microliter)

L of Fe(II) at the Equivalence Point

Moles phen at the Eqv Point

Moles Fe2+ at the Eqv Point
Stoichiometry: moles phen/moles Fe2+

1.03E-06
3.60E-06
3.50

Type your calculation of the moles of 1,10 phenanthroline that you transferred to the 50 mL volumetric flask.
1mL phen x (1L/1000mL)x(1L/3.6E-3M phen) = 3.6E-6 moles of phen

Type your calculation of the moles of 1,10 phenanthroline that you transferred to the 50 mL volumetric flask.
1mL phen x (1L/1000mL)x(1L/3.6E-3M phen) = 3.6E-6 moles of phen

Type your calculation for the moles Fe2+ at the equivalence point.

410 microliters Fe2+ x (1L / 1E6 microliters) x (2.5E-3M Fe2+/ 1L) = 1.03E-6 moles Fe2+

Type your calculation for the ratio of moles of phen to moles of Fe2+.
3.6E-6 / 1.03E-6 = 3.5

Results and Discussion

Part I
1. The expected stoichiometry is 1:1. How does your result compare (calculate the % error between your mole ratio a
within 5% of this value? (2 pts)
expected = 1, obtained = 1.1
percent error = (1.1-1)/1 x 100 = 10 %
We were not quite in the 5 % error range due to errors we may have made during the lab.
2. What is your biggest source of error in this part of the experiment? (2 pts)

The biggest error could have been due to some oxygen not being able to fully escape the tube connected to the react
our tube was set up so that when large quantities of oxygen forced its way out of the tube, some were able to escape
meant to measure all the oxygen that escaped. It is also possible that the reaction did not fully finish before we record
as we were particularly careful in making sure no more oxygen was on its way.

3. On the basis of the stoichiometry above, predict the other two products (O2 was one of the products) and write a ba
between H2O2 and NaOCl. (2 pts)
H2O2(aq) + NaOCl(aq) --> O2(g) + H2O(l) + NaCl(aq)

Part II

1. The expected stoichiometry is 3 phen:1 Fe2+. How does your result compare (calculate the % error between your m
you within 5% of this value? (2 pts)
(3.50 - 3)/3 x 100 = 16.67 %
We were not in the 5 % error range due to errors we may have made during the lab.

2. What is your biggest source of error in this part of the experiment? (2 pts)

It is possible that we did not allow for the Fe2+ solution to fully mix and react with the phen for exactly 5 minutes, this
not fully reacting and changing absorbance. We also experienced minor issues with the colorimeter not reading stable

Laboratory Waste Evaluation (1 pt)

Laboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, throw
container for disposal by the UW Environmental Health & Safety department, or released into the environment. Based o
actions during the lab, list the identity and approximate amount (mass or volume) of waste that you generated while perfo
experiment 1:
4mL bleach x 9 runs = 36mL bleach
Mass of H2O2 used throughout 9 runs = 27g H2O2

Laboratory Waste Evaluation (1 pt)

Laboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, throw
container for disposal by the UW Environmental Health & Safety department, or released into the environment. Based o
actions during the lab, list the identity and approximate amount (mass or volume) of waste that you generated while perfo
experiment 1:
4mL bleach x 9 runs = 36mL bleach
Mass of H2O2 used throughout 9 runs = 27g H2O2
experiment 1 part B:
1mL bleach
experiment 2:
1mL phen
0.8 microliters Fe2+
In bothl:
lots of deionized water

QUIZ SECTION:
LAB PARTNER:

142 AT

try I

ch
e

d and legible? Have you plotted your data as instructed?

d all future Excel-based reports, make sure that

es are not split across page breaks) before you
e tools in Excel to adjust the page breaks and

you have not plagiarized any part of this lab report, and
data are your own independent work. Failure to sign this
score.

2 pts
%m/m NaOCl
% m/m H2O2

rement #1.

from all four measurements.

2 pts

rement #1.

from all four measurements.

1 pt

mL of Oxygen
Generated
22.0
31.0
49.0
56.0
66.0
69.0
72.0
72.0
72.00
N/A
N/A

r graph big enough to cover this instruction box so that it is an

n Bleach and H2O2 React

a graph in Excel. (See the links on the postlab page for this

s. Be sure to double check your units and formatting once you

bleach is limiting reagent

nes: 1) best fit for the data where H 2O2 is limiting, 2) best fit for
rsection of lines 1 and 2 down to the x-axis in order to clearly

4 pts

here it is in excess.

3.017

3.555

4.049

4.581

5.022

of H2O2 (grams)

1 pt

moles
moles

1 pts

oles
3 pts

NaOCl = 3.5E-3 moles

4 pt

NaOCl = 3.5E-3 moles

3.60E-03

1 pt

2.50E-03

1 pt

1.00

mL

cover this instruction box so that it is an appropriate size for

elation to Absorbance

ot a graph in Excel. (See the links on the postlab page for

units (Absorbance data is unitless). Be sure to double check

phen is limiting reagent

ht lines: 1) best fit for the data where Fe 2+ is limiting, 2) best
m the intersection of lines 1 and 2 down to the x-axis in order

d where it is in excess.

400

500

600

Fe2+ (microliter)
L

1 pt

moles
moles

ed to the 50 mL volumetric flask.

1 pt

700

5 pts

ed to the 50 mL volumetric flask.

3 pts

3 pts

6 moles Fe2+
1 pt

e the % error between your mole ratio and the expected value)? Are you

ng the lab.

scape the tube connected to the reaction. It also could have been that
of the tube, some were able to escape from the "catch" graduated cylinder
on did not fully finish before we recorded data, but this is rather unlikely

was one of the products) and write a balanced equation for the reaction

e (calculate the % error between your mole ratio and the expected)? Are

e lab.

ith the phen for exactly 5 minutes, this could have resulted in the Fe2+
with the colorimeter not reading stable values.

disposed of down the sewer drain, thrown in the garbage, collected in a

released into the environment. Based on the written lab procedure and your
) of waste that you generated while performing this experiment.

disposed of down the sewer drain, thrown in the garbage, collected in a

released into the environment. Based on the written lab procedure and your
) of waste that you generated while performing this experiment.