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INTRODUCTION
Liquefied petroleum gas (LPG) is a mixture of
hydrocarbons such as propane (C3H8), propene
(C3H6), n-butane (C4H10), isobutene (methylpropane), and various proportions of other
butanes (C4H8). Traces of ethane and pentane
may also exist in the mixture [1, 2]. The
attention towards LPG is increasing day by
day due to its various applications [3]. It is
expected to use LPG not only as an efficient
alternative domestic fuel but also as a fuel in
commercial business, in industry, in
automotive engines, in transportation, farming,
power generation, and heating purposes in
Bangladesh [46]. LPG, a substitute for
petroleum, is also considered a means of
reducing the emission of COx, NOx, soot and
particulate matter [7]. There is no universal
standard for LPG composition observed in the
literature [8]. The LPG fuel composition may
vary from one source to another. Table 1
shows the variation in LPG fuel composition
obtained from various sources.
Heating value is the most important property
of any fuel, which is defined as the amount of
heat obtained from the complete combustion
of one unit-weight fuel. Because of the
different composition of propane, butane and
other lower and higher hydrocarbons in LPG
METHODOLOGY
In this work, HYSYS simulation package is
used to determine the heating value of LPG.
Aspen HYSYS process simulator is a core
element
of
AspenTechs
aspenONE
engineering applications. It has already been
proved as an efficient simulator with
reasonable accuracy. A comprehensive
thermodynamics foundation for accurate
determination of physical properties, transport
Page 51
Butene
Pentane
i-Butane
n-Butane
t-2-Butene
A [9]
B [9]
C [10]
D [10]
E [2]
F [10]
G [11]
0.72
68.62
1.47
18.00
49.00
95.40
49.00
2.70
0.02
3.12
6.37
9.80
13.40
0.30
15.40
1.80
1.40
8.00
21.00
1.50
28.10
13.73
42.33
18.80
53.64
28.00
1.20
0.20
15.00
15.60
14.30
27.75
6.72
1.00
1.00
13.50
8.60
7.71
0.78
1.00
14.20
1-Butene
c-2-Butene
0.59
0.64
i-Butene
i-Pentane
1.32
2.24
n-Pentane
Hydrogen sulfide
0.94
0.40
1.50
0.05
0.05
Moisture
Page 52
(a)
2.60E+06
2.50E+06
2.40E+06
2.30E+06
2.20E+06
2.10E+06
C3:C4=80:20
2.00E+06
C3:C4=60:40
C3:C4=40:60
1.90E+06
C3:C4=20:80
1.80E+06
0
10
2.55E+06
C3:C4=80:20
C3:C4=60:40
C3:C4=40:60
C3:C4=20:80
(b)
2.50E+06
2.45E+06
2.40E+06
2.35E+06
2.30E+06
2.25E+06
2.20E+06
2.15E+06
2.10E+06
0
10
Fig. 1: Change of Heating Value with (a) Propene and (b) Butene Content for various
Compositions of LPG.
Effect of Ethane and Pentane (Alkane)
Commercial LPG always contains small
amount of lower and higher saturated
hydrocarbon (ethane and pentane). Hence it is
important to know the effect of these
hydrocarbons on LPG heating value.
Page 53
2.60E+06
(a)
2.50E+06
2.40E+06
2.30E+06
2.20E+06
2.10E+06
C3:C4=80:20
2.00E+06
C3:C4=60:40
1.90E+06
C3:C4=40:60
1.80E+06
C3;C4=20:80
0
10
(b)
2.70E+06
2.60E+06
2.50E+06
2.40E+06
2.30E+06
2.20E+06
2.10E+06
C3:C4=80:20
2.00E+06
C3:C4=60:40
1.90E+06
C3:C4=40:60
C3:C4=20:80
1.80E+06
0
10
Fig. 2: Change of Heating Value with (a) Ethane and (b) Pentane Content for various
Compositions of LPG.
Effect of Hydrogen Sulfide and Moisture
Content
Commercial LPG always contains moisture
and sulfur compounds like hydrogen sulfide as
impurities [12, 13]. Hence, it is important to
know the effect of these impurities on LPG
heating value. Figures 3a and 3b present the
heating value against hydrogen sulfide (H2S)
and moisture content for various compositions
of LPG. From these figures, it can be seen that
Page 54
Fig. 3: Change of Heating Value with (a) H2S and (b) Moisture Content for various
Compositions of LPG.
Effect of Different Mercaptans Addition
Mercaptan (methyl or ethyl) is used with
commercial LPG to identify the leakage of
LPG from cylinder. Figure 4 compares the
effects of M-mercaptan and E-mercaptan on
heating value of LPG. It is found that with the
increasing percentage of both M-mercaptan
and E-mercaptan, the heating value of LPG
decreases. For adding 10% of M-mercaptan,
LPG loses 4.4% of its heating value while Emercaptan shows only 1.97%. This means, the
reduction in heating value of LPG using Emercaptan is almost half than that of Mmercaptan. Moreover, E-mercaptan is a noncorrosive material, and it consists of lower
sulfur content than M-mercaptan. Therefore,
E-mercaptan is the better choice to use as a
leakage identifier of LPG.
Fig. 4: Change of Heating Value with Two Mercaptan Content for LPG (C3:C4 = 70-30).
Page 55
Fig. 5: Change of Heating Value with Two Inhibitors Content for LPG (C3:C4 = 70:30).
Effect of LPG Hydrate Inhibitors Addition
Additives injection is generally required for
LPG in order to prevent corrosion and hydrate
formation in the storage and transmission
system. Methanol and mono-ethylene-glycol
(MEG) are two most common thermodynamic
hydrate inhibitors. Therefore, it is important to
know the effect of these additives on LPG
heating value. Figure 5 compares the effect of
Methanol and mono-ethylene-glycol (MEG)
on LPG (C3:C4 = 70:30) heating value. It can
be seen that with the increasing percentage of
methanol and MEG, the heating value of LPG
is decreasing. For adding 10% of methanol
and MEG separately, LPG loses 6.42 and
2.29% of its heating value respectively.
Methanol has been recognized and used as a
hydrate inhibitor for nearly as long as the
hydrate problem has been known. To prevent
hydrate formation, methanol is efficient due to
its low freezing point, high solvability and
relatively lower direct cost [13,14]. However,
methanol cannot be regenerated and reused.
Moreover, the reduction in heating value of
LPG using methanol is higher than that of
using MEG. On the other hand, MEG is
reliable and stable. It can be regenerated and
CONCLUSIONS
In this study, the effects of various
components on the heating value of LPG are
investigated by using Aspen HYSIS process
simulator. The main results obtained from this
study are as follows:
The presence of different components
such as ethane, propene, moisture and
hydrogen sulfide always decreases the
heating value, while pentane and butene
increase the heating value of LPG.
Hydrocarbon with higher numbers of
carbon than propane and butane will
always increase the heating value of LPG.
Both propene and butene would be able to
contribute in improving the fuel quality in
terms of heating value when the
composition of propane in LPG is high.
E-mercaptan is a better choice for leakage
identifier of LPG compared to Mmercaptan.
Mono-ethylene-glycol (MEG) can be used
as a hydrate inhibitor by reducing less
heating value compared to methanol.
Page 56
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