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Abstract
Ultra-fine polyimide fibers containing silver nanoparticles were prepared by electrospinning from poly(amic acid)/(trifluoroacetylacetonoto)
silver(I) (PAA/AgTFA) solution. Thermal curing of the silver(I)-containing fibers led to cycloimidization of the poly(amic acid) into polyimide
with concomitant silver(I) reduction. The polyimidesilver fibers were characterized by FT-IR, X-ray diffraction, scanning electron microscopy,
and transmission electron microscopy. The average diameters of silver nanoparticles and ultra-fine PI fibers electrospun from solutions with
different amounts of AgTFA were studied, and the crystal structure of silver nanoparticles was also presented.
2007 Elsevier B.V. All rights reserved.
Keywords: Polyimide; Silver; Nanoparticles; Electrospun fibers
1. Introduction
Silver nanoparticles are widely used due to their superior
optical [1,2], electrical, catalytic [3] and antimicrobial [4]
properties. Polymer/silver nanoparticles composites, combining
the advantages of the silver nanoparticles and the processability
of the polymers, opened a new gateway in developing
nanocomposite systems with improved performances [5].
Generally speaking, there are two approaches to prepare
polymer/silver nanocomposites. One is to disperse silver
nanoparticles into polymer matrices, being simple but difficult
to obtain well-dispersed nanoparticles due to easy aggregation
of nanoparticles. The other is in situ chemical formation of
silver nanoparticles by the reduction of silver ions which are
introduced into polymer matrices. The tailored size and size
distribution of silver particles can be achieved by choosing
some parameters such as reduction method, concentration of
precursor and temperature in this chemical process [69].
In recent years, ultra-fine polymer fibers prepared by
electrospinning of a polymer solution have been drawing
Corresponding author.
E-mail address: wdz@mail.buct.edu.cn (D. Wu).
0167-577X/$ - see front matter 2007 Elsevier B.V. All rights reserved.
doi:10.1016/j.matlet.2007.01.011
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Fig. 2. X-ray diffraction peaks of PI fiber mat electrospun from 10 wt.% PAA
solution with 7 wt.% Ag.
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Fig. 3. SEM images of PI/Ag fibers electrospun from 10 wt.% PAA solution with different amounts of AgTFA: Ag (a) 0 wt.%, (b) 1 wt.%, (c) 2 wt.% and (d) 7 wt.%.
4. Conclusion
Ultra-fine polyimide (PI) fibers containing Ag nanoparticles
were prepared by electrospinning from PAA/AgTFA solution
followed by thermal curing as well as silver reduction. The Ag
Fig. 4. TEM images of PI/Ag fibers electrospun from 10 wt.% PAA solution with different amounts of AgTFA: Ag (a) 1 wt.%, (b) 2 wt.% and (c) 7 wt.%.
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