Professional Documents
Culture Documents
THERMODYNAMICS OF MATERIALS
Time : Three hours
i)
ii)
iii)
U
T for
V
iv)
a) an ideal gas
b) a real gas.
3
dU
and
dT
( H )
for chemical reactions
T
vi)
( 2 )
vii)
( 7 )
xi)
G = 30,000 + 175 T 25 T ln T
Find the molar entropy S and molar heat capacity CP of
the metal at 500 K.
4
x)
xi)
xii)
xiii)
GB
1
O (g) = CO (g) ; G = 111, 700 87.65 T, J
2 2
ii)
( 4 )
Hf , 298 K
H2
N2
O2
( 5 )
H1400 H298
7, 905
8, 355
8, 835
ii)
9
3.
i)
ii)
c.
p =
B / BO
A / AO
= 103 atm
= 104 atm
1
O (g) = CO (g) ; G = 111, 700 87.65 T, J
2 2
C(s) + O2(g) = CO2 (g) ; G = 394, 100 0.84 T, J
8
i)
p = pO2
p = pO2
p CO / p CO2
0.826
0.990
C(s) +
4.
a.
b.
5.
i)
( 3 )
( 6 )
B.
i)
ii)
6.
i)
pV
= 1+ 5 x 104 p
RT
ii)
Calculate
a) The fugacity of hydrogen at 400 atm and 298 K.
b) The pressure at which the fugacity is twice the
furnace. Gas and air enter at 298 K. The heat loss from
the furnace is 20% of the heat input from the combustion
reactions. The gaseous products of combustion leave the
pressure.
c) The free - energy change (G) resulting from the
compression of 1 mole of hydrogen at 298 K from 1 atm
furnace at 1400 K.
What percentage of the calorific power of the fuel is
available within the furnace for heating and melting the
to 400 atm.
What is the magnitude of the contribution to C. arising
from the nonideality of hydrogen ?
9+6
furnace charge ?
Given thermodynamic data in calories / mole :
Hf , 298 K
H1400 H298
CO
CO2
H2O (g)
26, 420
94, 050
57, 800
8, 450
13, 360
10, 385
[ Turn Over ]