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5070/01
CHEMISTRY
Paper 1 Multiple Choice
May/June 2003
Additional Materials:
1 hour
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2
1
The equation for the reaction between aqueous lead(II) nitrate and aqueous potassium iodide is
shown.
Pb(NO3)2(aq)
colourless
2KI(aq)
colourless
PbI2(s)
yellow
2KNO3(aq)
colourless
chromatography
crystallisation
distillation
filtration
A gas Y, is less dense than air, very soluble in water and is an alkali.
Which method is used to collect a dry sample of the gas?
A
B
dry Y
Y
calcium
oxide
water
dry Y
D
dry Y
dry Y
Y
Y
concentrated
sulphuric acid
calcium
oxide
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3
3
damp blue
litmus paper
damp red
litmus paper
dilute
hydrochloric acid
dilute
hydrochloric acid
zinc
sodium carbonate
damp blue
litmus paper
damp red
litmus paper
aqueous sodium
hydroxide
aqueous sodium
hydroxide
ammonium chloride
Methylamine, CH3NH2 (Mr = 31), and hydrogen chloride, HCl (Mr = 36.5) are both gases which
are soluble in water.
The gases react together to form a white solid, methylammonium chloride.
In an experiment to demonstrate rates of diffusion the following apparatus is set up.
Where will the white solid form?
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4
5
A 25 cm3 sample of dilute sulphuric acid contains 0.025 moles of the acid.
What is the hydrogen ion concentration in the solution?
as an abrasive only
as a lubricant only
39
19
40
20
What can be deduced from the proton numbers and nucleon numbers of X, Y and Z?
by sharing one pair of electrons, both electrons provided by the magnesium atom
by sharing two pairs of electrons, both pairs provided by the oxygen atom
by sharing two pairs of electrons, each atom donating one pair of electrons
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5
9
calcium
chlorine
carbon
hydrogen
carbon
oxygen
hydrogen
oxygen
11 Which of the following contains the same number of electrons as an atom of neon?
A
Cl
Li C
Li+
O2
formula
mass of one
mole / g
NiS
90
FeS2
120
MoS2
160
PbS
239
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6
13 124 g of phosphorus vapour has the same volume as 71 g of chlorine gas at
the same temperature and pressure.
What is the formula of a molecule of phosphorus?
A
P8
P4
P2
size of current
time
a.c.
low
short
d.c.
high
long
a.c.
high
short
d.c.
low
long
anode (+)
chlorine
hydrogen
hydrogen
rubidium
hydrogen
chlorine
rubidium
chlorine
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16 Nitrogen dioxide, NO2, is a dark brown gas that decomposes as shown by the equilibrium
equation.
2NO2(g)
dark brown
2NO(g) + O2(g)
colourless
The diagram shows a glass flask containing a mixture of the three gases.
The mixture is pale brown.
NO2,
NO, O2
mixture
there is no change
it turns colourless
17 Two cells were set up as shown in the diagram. The arrow shows the direction of electron flow in
the external circuit.
metal X
metal Y
metal Y
metal Z
dilute
sulphuric
acid
Which set of metals would give the electron flows in the direction shown?
metal X
metal Y
metal Z
Ag
Cu
Zn
Ag
Zn
Cu
Cu
Zn
Ag
Zn
Cu
Ag
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18 The equation shows the effect of heat on copper(II) carbonate.
CuCO3(s)
CuO(s)
+ CO2(g)
A known mass of copper(II) carbonate was placed in an open crucible and heated until no more
change occurred.
The mass of the crucible and contents was weighed every minute during the heating.
Which graph shows what happens to the mass of the crucible and contents?
A
mass
mass
time
mass
time
mass
time
time
19 Substance X liberates iodine from aqueous potassium iodide and decolourises acidified aqueous
potassium manganate(VII).
How is the behaviour of X described?
A
K2SO4(aq) + 2H2O(l)
CuO(s) + H2SO4(aq) CuSO4(aq) + H2O(l)
Pb(NO3)2(aq) + H2SO4(aq) PbSO4(s) + 2HNO3(aq)
ZnCO3(s) + H2SO4(aq) ZnSO4(aq) + CO2(g) + H2O(l)
2KOH(aq) + H2SO4(aq)
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22 A black powder is burned in air.
The gas produced dissolves in water to form solution R. The pH of R is close to 7.
The gas is readily absorbed in aqueous sodium hydroxide.
What type of substance is present in solution R?
A
strong acid
strong base
weak acid
weak base
experiment
halide solution
halogen added
X
X2
Y2 displaced
Z2 displaced
Y2
no reaction
no reaction
Z2
no reaction
Y2 displaced
Br
Cl
Br
Cl
Cl
Br
Cl
Br
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10
25 In which process is a catalyst not used?
A
26 The table shows the results of two tests carried out on separate portions of a solution of salt X.
test
observation
white precipitate
What is X?
A
calcium chloride
iron(II) sulphate
lead(II) nitrate
zinc sulphate
27 Why is cryolite, Na3AlF6, used in the extraction of aluminium from aluminium oxide?
A
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28 The diagram compares the amount of carbon in two steels, P and Q.
amount of
carbon
P
Which two diagrams correctly compare the strength and brittleness of P and Q?
strength
brittleness
P
strength
Q
strength
brittleness
P
brittleness
P
strength
brittleness
P
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29 An experiment is carried out to find the order of reactivity of some metals.
Three metals are placed in solutions containing aqueous metal ions.
The results are shown.
key
metal
Mg2+
Mg
Fe
Zn
Al3+
2+
2+
Fe
Zn
= reaction
observed
= no reaction
observed
Mg
Zn
Fe
Al
Fe
Zn
Al
Mg
Mg
Al
Zn
Fe
Mg
Al
Fe
Zn
30 The carbonate of metal X is a white solid. It decomposes when heated. Carbon dioxide and a
yellow solid oxide are formed.
What is metal X?
A
copper
iron
lead
sodium
31 An 80 cm3 sample of air is trapped in a syringe. The air is slowly passed over heated iron in a
tube until there is no further decrease in volume.
iron
80 cm3 of air
heat
When cooled to the original temperature, which volume of gas remains?
A
80 cm3
64 cm3
20 cm3
16 cm3
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32 In the Haber process, nitrogen and hydrogen react to form ammonia.
What is the source of the hydrogen?
A
air
oil
limestone
sulphuric acid
33 Which reaction will not occur using cold, dilute sulphuric acid?
A
36 What is produced when ethanol is boiled with an excess of acidified potassium dichromate(VI)?
A
ethane
ethanoic acid
ethene
ethyl ethanoate
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37 When 1 volume of gas X reacts with exactly 5 volumes of oxygen it forms carbon dioxide and
water only.
What is gas X?
A
methane, CH4
ethane, C2H6
propane, C3H8
butane, C4H10
38 Which structure shows a compound that reacts with ethanol to give a sweet-smelling liquid?
A
H
C
H
H
C
H
H
C
O
D
O
C
O
compound
degree of ionisation
in water
addition of an aqueous
solution of the
compound to magnesium
high
hydrogen produced
high
no reaction
low
hydrogen produced
low
no reaction
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40 Amino acids are produced when proteins are
A
hydrolysed.
oxidised.
polymerised.
substituted.
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DATA SHEET
The Periodic Table of the Elements
Group
I
III
II
IV
VI
VII
He
Hydrogen
Helium
1
7
11
12
14
16
19
20
Li
Be
Ne
Beryllium
Boron
Carbon
Nitrogen
Oxygen
Fluorine
Neon
10
23
24
27
28
31
32
35.5
40
Na
Mg
Al
Si
Magnesium
Cl
Ar
Aluminium
Sulphur
Chlorine
Sodium
11
12
13
Silicon
14
Phosphorus
16
15
17
Argon
18
39
40
45
48
51
52
55
56
59
59
64
65
70
73
75
79
80
84
Ca
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Kr
Potassium
19
Calcium
20
Scandium
Titanium
21
22
Vanadium
23
Chromium
24
85
88
89
91
93
96
Rb
Sr
Zr
Nb
Mo
Rubidium
Strontium
37
38
Yttrium
Zirconium
39
40
Niobium
41
Manganese
25
Molybdenum
42
Iron
26
Tc
Technetium
43
Cobalt
27
Nickel
28
Copper
29
Zinc
30
Gallium
31
Germanium
32
Arsenic
33
Selenium
34
Bromine
35
Krypton
36
101
103
106
108
112
115
119
122
128
127
131
Ru
Rh
Pd
Ag
Cd
In
Sn
Sb
Te
Xe
Ruthenium
44
Rhodium
45
Palladium
46
Silver
47
Cadmium
48
Tin
Indium
50
49
Antimony
51
Tellurium
52
Xenon
Iodine
54
53
133
137
139
178
181
184
186
190
192
195
197
201
204
207
Cs
Ba
La
Hf
Ta
Re
Os
Ir
Pt
Au
Hg
Bi
Po
At
Rn
Caesium
Barium
Lanthanum
Tl
Pb
Hafnium
Tantalum
Tungsten
Rhenium
Osmium
Iridium
Platinum
Gold
Mercury
Thallium
Lead
Bismuth
Polonium
Astatine
Radon
55
56
57
226
Fr
Ra
Ac
Radium
Actinium
88
73
74
89
140
141
144
Ce
Pr
Nd
Cerium
Key
X
b
76
78
77
79
80
81
82
83
84
85
86
75
227
Francium
87
72
209
58
Neodymium
60
232
X = atomic symbol
b = proton (atomic) number
Praseodymium
59
90
Pm
Promethium
61
150
152
157
159
162
165
167
169
173
175
Sm
Eu
Gd
Tb
Dy
Ho
Er
Tm
Yb
Lu
Sama r ium
62
Europium
63
Gadolinium
64
Terbium
65
Dysprosium
66
Holmium
67
Erbium
68
Thulium
69
Ytterbium
70
Lutetium
71
238
Th
Pa
Np
Pu
Am
Cm
Bk
Cf
Es
Fm
Md
No
Lr
Thorium
Protactinium
Uranium
Neptunium
Plutonium
Americium
Curium
Berkelium
Californium
Einsteinium
Fermium
Mendelevium
Nobelium
Lawrencium
91
92
93
94
95
96
97
98
99
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
100
101
102
103
16
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Lithium