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Materials

Chemical Compatibility Guide

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The information in this brochure is intended to be for general reference purposes only and is not
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for pressure, temperature, speed and media given are maximum values determined in laboratory
conditions. In application, due to the interaction of operating parameters, maximum values may
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Chemical Compatibility Guide

Contents
Sealing materials - Elastomers.................................................................................................. 3
Application parameters of elastomers..................................................................................... 5
General field of application...................................................................................................................... 6
Chemical compatibility.............................................................................................................................. 7
Chemical Compatibility Guide for sealing materials............................................................... 8
Chemical Compatibility Guide for sealing materials and media used in
Semiconductor Manufacturing Processes............................................................................... 36
Plasma Processes +180 C / +356 F......................................................................................................... 36
Wet Processes........................................................................................................................................... 37
Thermal Processes.................................................................................................................................... 39
Gas Deposition +180 C / +356 F............................................................................................................ 40
General quality criteria and storage guidelines.................................................................... 43
General quality criteria............................................................................................................................ 43
Guidelines for the storage of polymer products based on ISO 2230.................................................... 43

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Edition August 2012

Chemical Compatibility Guide

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Edition August 2012

Chemical Compatibility Guide

Sealing materials - Elastomers


groups for sealings are the elastomers. They show good
properties like elasticity or good chemical compatibility.

Equipment manufacturers and end users expect sealing


systems to operate leak free and to maintain long service
life. Reliability is crucial to effective low maintenance cost
operations. To find the perfect sealing solution in each
individual case both material performance and seal design
are critically important. One of the main used material

The following tables provide a summary of the various


elastomer material groups. Trelleborg Sealing Solutions
can offer a large number of materials within each group.

Table 1 Elastomers
Designation

Trade Name*

Abbreviation
ISO 1629

ASTM D 1418

TSS

Acrylonitrile-Butadiene Rubber
(Nitrile Rubber)

Europrene
Krynac
Nipol N
Perbunan NT
Breon

NBR

NBR

Hydrogenated Acrylonitrile-Butadiene Rubber

Therban
Zetpol

HNBR

HNBR

Polyacrylate Rubber

Noxtite
Hytemp
Nipol AR

ACM

ACM

Chloroprene Rubber

Baypren
Neoprene

CR

CR

WC

Ethylene Propylene Diene Rubber

Dutral
Keltan
Vistalon
Buna EP

EPDM

EPDM

Silicone Rubber

Elastoseal
Rhodorsil
Silastic
Silopren

VMQ

VMQ

Fluorosilicone Rubber

Silastic

FVMQ

FVMQ

Tetrafluorethylene-Propylene Copolymer Elastomer

Aflas

FEPM

TFE/P**

WT

Butyl Rubber

Esso Butyl

IIR

IIR

WI

Styrene-Butadiene Rubber

Buna S
Europrene
Polysar S

SBR

SBR

WB

Natural Rubber

NR

WR

WR

Fluorocarbon Rubber

Dai-El
Fluorel
Tecnoflon
Viton

FKM

FKM

Perfluoro Rubber

Isolast
Kalrez

FFKM

FFKM

Polyester Urethane
Polyether Urethane

Zurcon
Adiprene
Pellethan
Vulcollan
Desmopan

AU
EU

AU
EU

WU
WU

Chlorosulphonated Polyethylene Rubber

Hypalon

CSM

CSM

WM

Polysulphide Elastomer

Thiokol

TWT

WY

Epichlorohydrin Elastomer

Hydrin

WO

* Selection of registered trade names


** Abbreviation not yet standardised

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ASTM = American Society for Testing and Materials


ISO = International Organisation for Standardisation

Chemical Compatibility Guide

Table 2 The most important types of synthetic rubber, their grouping and abbreviations
Chemical name

Abbreviation
ISO 1629

ASTM D 1418

M - Group
(saturated carbon molecules in main macro-molecule-chain)
-- Polyacrylate Rubber
-- Ethylene Acrylate Rubber
-- Chlorosulfonated Polyethylene Rubber
-- Ethylene Propylene Diene Rubber
-- Ethylene Propylene Rubber
-- Fluorocarbon Rubber
-- Perfluoro Rubber

ACM
AEM
CSM
EPDM
EPM
FKM
FFKM

ACM

O - Group
(with oxygen molecules in the main macro-molecule chain)
-- Epichlorohydrin Rubber
-- Epichlorohydrin Copolymer Rubber

CO
ECO

CO
ECO

R - Group
(unsaturated hydrogene carbon chain)
-- Chloroprene Rubber
-- Butyl Rubber
-- Nitrile Butadiene Rubber
-- Natural Rubber
-- Styrene Butadiene Rubber
-- Hydrogenated Nitrile Butadiene Rubber

CR
IIR
NBR
NR
SBR
HNBR

CR
IIR
NBR
NR
SBR
HNBR

Q - Group
(with Silicone in the main chain)
-- Fluorosilicone Rubber
-- Methyl Vinyl Silicone Rubber

FVMQ
VMQ

FVMQ
VMQ

U - Group
(with carbon, oxygen and nitrogen in the main chain)
-- Polyester Urethane
-- Polyether Urethane

AU
EU

AU
EU

CSM
EPDM
EPM
FKM
FFKM

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Chemical Compatibility Guide

Application parameters of elastomers


Elastomers as all other organic chemicals have limited
use. External influences such as various media, oxygen or
ozone as well as pressure and temperature will affect the
material properties and therefore their sealing capability.

Elastomers will amongst others swell, shrink or harden and


develop cracks or even tears.

Elastomer heat resistance / swelling in oil


Max working
temperature
(C / F)

depends on
ACN content

+325/+617
+225/+437
+200/+392
+175/+347
+150/+302
+125/+257
+100/+212
+75/+167
0/+32

20

40

60

80

120

140

160

Change of volume in IRM-OIL 903, 70h (%)

Figure 1 Change of volume in IRM-Oil 903 (old ASTM-Oil No 3)

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Edition August 2012

Chemical Compatibility Guide

Temperature range

The temperature ranges apply only


in connection with media that are
compatible with the respective
elastomers

-100/-148

-50/-58

0/+32

+50/+122 +100/+212 +150/+302 +200/+392 +250/+482 +300/+572 +350/+662


Temperature (C / F)

Operating temperature
range

Only to be achieved under particular conditions with special


materials

Figure 2 Temperature range of various elastomers

General field of application


Elastomer materials are used to cover a large number
of fields of application. The various elastomers can be
characterised as follows:
ACM (Polyacrylate Rubber)
ACM shows excellent resistance to ozone, weathering
and hot air, although it shows only a medium physical
strength, low elasticity and a relatively limited low
temperature capability. The operating temperatures range
from -20C/-4F and +150C/+302F (for a short period
of time up to +175C/+347F). Special types can be used
down to -35 C/-31 F. ACM-materials are mainly used in
automotive applications which require special resistance
to lubricants containing many additives (incl. sulphur) at
high temperatures.
CR (Chloroprene Rubber)
In general the CR materials show relatively good
resistances to ozone, weathering, chemicals and aging.

Also they show good non-flammability, good mechanical


properties and cold flexibility. The operating temperatures
range between -35 C/-31 F and +90 C/+194 F (for a
short period of time up to +120C/+248F). Special types
can be used down to -55C/-67F. CR materials are found
in sealing applications such as refrigerants, for outdoor
applications and in the glue industry.
EPDM (Ethylene Propylene Diene Rubber)
EPDM shows good heat, ozone and aging resistance. In
addition they also exhibit high levels of elasticity, good
low temperature behaviour as well as good insulating
properties. The operating temperatures of applications
for EPDM range between -45C/-49F and +150C/+302F
(for a short period of time up to +175 C/+347 F). With
sulphur cured types the range is reduced to -45C/-49F
and +130 C/+266 F (for short period of time up to
+150C/+302F). EPDM can often be found in applications
with brake fluids (based on glycol) and hot water.

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Chemical Compatibility Guide

FFKM (Perfluoro Rubber)


Perfluoroelastomers show broad chemical resistance
similar to PTFE as well as good heat resistance. They
show low swelling with almost all media. Depending on
the material the operating temperatures range between
-25C/-13F and +240C/+464F Special types can be used
up to +325C/+617F.
Applications for FFKM can be mostly found in the chemical
and process industries and in all applications with either
aggressive environments or high temperatures.
FKM (Fluorocarbon Rubber)
Depending on structure and fluorine content FKM
materials can differ with regards to their chemical
resistance and cold-flexibility. FKM is known especially for
its non-flammability, low gas permeability and excellent
resistance to ozone, weathering and aging. The operating
temperatures of the Fluorocarbon Rubber range between
-20C /-4 F and +200C /+392 F (for a short period of time
up to +230C /+446 F). Suitable formulated FKM can be
used down to -35 C /-31 F. FKM is also often used with
mineral based oils and greases at high temperatures.
FVMQ (Fluorosilicone Rubber)
FVMQ has a good heat resistance, very good low
temperature flexibility, good electrical properties and
excellent resistance to weather, ozone and UV rays.
FVMQ shows a significant better chemical resistance than
standard Silicone especially in hydrocarbons, aromatic
mineral oils, fuel and low molecular aromatic hydrocarbons
e.g. Benzene and Toluene. The temperature range is
between -50C/-58F and +175C/+347F (temporary up
to+200C/+392F).
HNBR (Hydrogenated Nitrile Butadiene Rubber)
HNBR is made via selective hydrogenation of the NBR
butadiene groups. The properties of the HNBR rubber
depend on the ACN content which ranges between
18 % and 50 % as well as on the degree of saturation.
HNBR shows good mechanical properties. The operating
temperature of HNBR ranges between -30 C/-22 F
and +140 C/+284 F (for a short period of time up to
+160C/+320F) in contact with mineral oils and greases.
Special types can be used down to -40C/-40F.
IIR (Butyl Rubber)
Butyl Rubber shows a very low gas and moisture
permeability. In addition IIR also exhibits a good resistance
to a large number of organic and inorganic chemicals,
ozone, weathering and aging. The electrical insulating
properties of IIR are excellent. Its temperature range is
between -40C/-40F and +110C/+230F and for a short
period of time up to +120C/+248F.
NBR (Nitrile Butadiene Rubber)
The properties of the Nitrile Rubber depend mainly on
the ACN content which ranges between 18 % and 50 %.
In general they show good mechanical properties. The

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Edition August 2012

operating temperatures range between -30 C/-22 F


and +100 C/+212 F (for a short period of time up to
+120 C/+248 F). Suitable formulated NBR can be used
down to -60 C/-76 F. NBR is mostly used with mineral
based oils and greases.
Polyurethane (Zurcon Polyurethane)
Polyurethanes are an exceptionally complex material
group. They are individually designed and fit various
applications needs. Therefore it is not possible to unify
the materials properties.
Zurcon polyurethane materials from Trelleborg Sealing
Solutions are customized to appropriate applications
and stand out due to their excellent elastic properties
and optimum abrasion resistance. Outstanding tensile
strength, low compression set and good resistance to O2
and O3 are further significant characteristics. Depending
on the individual Zurcon polyurethane type the
application temperature range from below -50 C/-58 F
up to +110C/+230F, temporary even higher, is feasible.
VMQ (Silicone Rubber)
VMQ shows excellent heat resistance, cold flexibility,
dielectric properties and especially good resistance to
weather, ozone an UV rays. Specific VMQ formulations
are resistant to aliphatic engine and gear oils, water
up to +100 C/+212 F and high-molecular chlorinated
hydrocarbons. The temperature range is between
-50 C/-58 F and +175 C/+347 F (temporary up to
+230C/+446F).

Chemical compatibility
It is important to recognise that when using this guide, the
ratings shown are based on published data and immersion
tests. These tests are conducted under laboratory
conditions predominantly at room temperature and may
not represent adequately the conditions in the field.
Relative short term laboratory tests may not pick up all
the additives and impurities which may exist in long term
service applications.
Care must be taken to ensure that all aspects of the
application are considered carefully before a material is
selected. For example at elevated temperatures some
aggressive fluids can cause a much more marked effect on
an elastomer than at room temperature.
Physical properties as well as fluid compatibility need to be
considered. Compression set, hardness, abrasion resistance
and thermal expansion can influence the suitability of a
material for a particular application.
It is recommended that users conduct their own tests to
confirm the suitability of the selected material for each
application.
Our experienced technical staff can be consulted for
further information on specific applications.

Chemical Compatibility Guide

Chemical Compatibility Guide for sealing materials


Rating system
A Very good suitability
Elastomer shows little or no effect from exposure.
Little effect on performance and physical properties.
Very good resistance.
B Good suitability
Some effects from exposure with some loss of physical
properties. Some chemical swelling.

C Limited suitability
Significant swell and loss of physical properties after
exposure. Additional tests should be done.
U The elastomer is unsuitable for application in this
media.
- Insufficient information available for service in this
media.

HNBR

NBR

VMQ

FVMQ

FKM
Resifluor 500

FKM

FFKM (Isolast)

EPDM

CR

Acetaldehyde

AU

Chemical

ACM

B/C

Acetamide

Acetic Acid

Acetic Acid Chloride

Acetic Acid Vapors

Acetic acid, 96-99,5% (Glacial)

Acetic Anhydride

Acetone

Acetophenone

Acetylacetone

Acetylchloride

Acetylene Gas

Acetylene Tetrabromide

Acrolein

Acrylonitrile

Adipic Acid

Adipic Aciddiethylester

Aero Lubriplate

Aero safe 2300

Aero safe 2300 W

Aero Shell 1 AC Grease

Aero Shell 17 Grease

Aero Shell 7 A Grease

Aero Shell 750

Aero Shell Fluid 4

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Edition August 2012

ACM

AU

CR

EPDM

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

FFKM (Isolast)

Chemical Compatibility Guide

Aerozene 50 (50%Hydrazine,
50% UDMH)

B
(J9505)

Air

Chemical

Alcohol (Methanol)

Alkyl Arylsulphonic Acid

Alkyl Benzene

Allyl Alcohol (2-Propene-1-ol)

Allyl Chloride (3-Chloro-1-Propene)

Allyl Ketone

Aluminium Acetat

Aluminium Bromide

Aluminium Fluoride

Aluminium Nitrate

Aluminium Phosphate

Aluminium Sulfate

Aluminium-Potassiumsulfate Solution

Aluminum Chloride Solution

Aluminum Hydroxide Solution

Aluminum Sulphate Solution

Ambrex 33 (Mobile)

Ambrex 830 (Mobile)

Amines, primary (such as Methyl,


Ethyl, Propyl, Allyl)

Aminoacetic Acid

Ammonia (gas)

A
(J9503)

Ammonia (gas, hot)

A
(J9503)

Ammonia (liquid)

Ammonia Solution

Ammonia, anhydrous

A
(J9503)

Ammonia, aqueous Solution

Ammonia-Lithium

Ammonium Acetate

Ammonium Carbonate

Ammonium Carbonate Solution

Ammonium Chloride

Ammonium Chloride Solution

Ammonium Fluoride

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FKM

Ammonium Hydroxide Solution

Ammonium Nitrate Solution

Ammonium Nitrite

Ammonium Phosphate, Monobasic,


Dibasic, Tribasic

Ammonium Sulfate Solution

Ammonium Sulfide

Ammonium Thiocyanate

Amyl Acetate

Amyl Alcohol

VMQ

FFKM (Isolast)

NBR

EPDM

HNBR

CR

FVMQ

AU

Ammonium Hydroxide

FKM
Resifluor 500

Chemical

ACM

Chemical Compatibility Guide

Amyl Borate

Amyl Chloride

Amyl Naphtalene

Anderol L-774

Aniline Chlorohydrate

Aniline Liquid

Animal Fats

Anisole

Antimony Chloride

Antimony Chloride, dry

Aqua Regia
(Nitric Acid/Hydrochloric Acid)

Argon Gas

Aromatic Fuels (up to 50% Aromatic)

Aromatic Hydrocarbons
(100% Aromatic)

Arsenic Acid

Arsenic Acid, Solution

Asphalt, Emulsion

ASTM Test Fuel A

ASTM Test Fuel B

ASTM Test Fuel C

ASTM-Oil IRM 902

ASTM-Oil IRM 903

ASTM-Oil No.1

ATM-Brake Fluid (Glycolbased)

Automatic-Transmission Fluid

Automotive Gasoline

10

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Chemical Compatibility Guide

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Barium Carbonate

Barium Chloride Solution

Barium Hydroxide Solution

Barium Nitrate Solution

Barium Sulfate

Barium Sulfide Solution

Battery Acid (Sulfuric Acid diluted)

Chemical

Beef Tallow

Beer

Beet Sugar Sap

Benzaldehyde

Benzenesulfonic Acid

Benzine (Gasoline)

Benzine 50/Benzene 30/Ethanol 20

Benzine 50/Benzene 50

Benzine 60/Benzene 40

Benzine 70/Benzene 30

Benzine 80/Benzene 20

Benzoic Acid, Solution

Benzol (Benzene)

Benzophenone

Benzyl Alcohol

Benzyl Chloride

Biphenyl

Bitumen

Black Liquor

Blast Furnace Gas

Bleach Solution

Bleaching Powder Solution

Boiler Feed Water

Bone Oil

Borax (Sodiumborate)

Borax Solutions

Boric Acid

Brake Fluids (based on glycol ether)

Brake Fluids (based on mineral oil)

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11

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Chemical Compatibility Guide

Bromine

Bromine Solution in Water

Bromine Vapour

Bromobenzene

Bromochlorotrifluoroethan

Bunker Oil

Butadiene

Butandiol

Butane

1-Butanethiol

Butanole

Butantriol

Butene

Buthylphenol

Butter

Buttermilk

Butyl Acetate

B/C

B/C

Butyl Alcohol

Butyl Amine

A
(J9503)

Butyl Carbitol

Butyl Cellosolve

Butyl Diglycol

Butyl Phthalate

Butyl Pyrocatechol

Butyl Stearate

Butylbenzoate

Butylene

Butylether

Butyraldehyd

Butyric Acid

Butyric Acid Butyl Ester

12

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Chemical Compatibility Guide

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Calcium Acetate

Calcium Bisulfate

Calcium Bisulfide Solution

Calcium Carbonate

Calcium Carbonate Slurry

Calcium Chloride

Calcium Chloride, brine

Calcium Cyanide

Calcium Hydroxide Solution

Calcium Hypochlorite Solution

Calcium Nitrate

Calcium Oxide

Calcium Phosphate Slurry

Calcium Silikate

Calcium Sulfate

Calcium Sulfide

Calcium Sulfite

Calcium Thiosulfate

Caliche Solution (Sodium Nitrate)

Campher

Campher Oil

Cane Sugar Sap

Carbitol

Carbolic Acid (Penole)

Carbolineum

Carbon Dioxide, dry

Carbon Dioxide, wet

Carbon Disulfide

Carbon Monoxide

Carbonic Acid

Carboxylic Acids

Casein

Castor Oil

Cellosolve (2-Etho-yethanol)

Celluloseacetat

Chile Salpetre (Sodium Nitrate)

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13

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Chemical Compatibility Guide

Chinawood Oil

Chloracetic Acid

Chloracetic Acid Ethylester

Chloric Acid

Chloride of Lime

Chlorine Dioxide

Chlorine gas, anhydrous

Chlorine Water

Chlorine, liquid

Chloroacetaldehyde

Chloroacetone

Chloroamine

Chlorobenzene

Chlorobromomethane

Chlorobutadiene

Chloroform

Chloromethyl Ether

Chloronaphthalene

(o)-Chlorophenol

Chlorosulfonic Acid

Chlorothene

Chlorotoluene

Chrome Alum

Chromic Acid

Chromo sulfuric Acid

Cider

CIP fluids, acidic*

CIP fluids, alkaline

Citric Acid

Citrous Oils

Coal Tar

Cobalt Chlorite

Coca-Cola

Cocoa Butter

Coconut Grease

Coconut Oil

Coconut, Fatty Acid

Cod-liver Oil

Coffee

Chemical

* organic/inorganic acids, please contact our specialists

14

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FKM

Coke Oven Gas

Copper Acetate Solution

Copper Ammonium Acetate

Copper Chloride, Solution

Copper Cyanide

Copper Fluoride

Copper Nitrate

Copper Sulfate (Blue Vitriol) Solution

VMQ

FFKM (Isolast)

NBR

EPDM

HNBR

CR

FVMQ

AU

Coffee Extract

FKM
Resifluor 500

Chemical

ACM

Chemical Compatibility Guide

Corn Oil

Cotton Oil

Cottonseed Oil

Cresol

Crontonaldehyde

Crude Oil

Cumene

Cuprous Ammonia Acetate Solution

U
-

Cyclohexane

Cyclohexanole

Cyclohexanone

Cyclohexylamine

A
(J9503)

(p)-Cymene

Chemical

VMQ

B
B

NBR

B
B

HNBR

B
B

FVMQ

A
A

FKM
Resifluor 500

A
A

FKM

A
A

FFKM (Isolast)

A
A

EPDM

B
B

CR

AU

U
U

ACM

Cyanic Acid
Cyanic Acid Solution

DDT Solutions (Kerosene Solvent)

DDT Solutions (Toluene Solvent)

Decalin (Decahydronaphtalene)

Decane

Dextrin

Dextrose

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15

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

Di-Isobutylene

Di-Isooctyl Sebacate

Di-Isopropyl Benzene

Di-Isopropyl Ketone

VMQ

CR

NBR

AU

Di-Isobutyl Ketone

HNBR

Chemical

ACM

Chemical Compatibility Guide

Diacetone

Diacetone Alcohol

1,2-Diaminoethane

A
(J9503)

Diamylamine

A
(J9503)

Diazinone

Dibenzyl Sebacate

Dibenzylether

Dibromodifluoromethane

Dibromomethylbenzene

Dibutyl Ether

Dibutyl Phthalate

Dibutyl Sebacate

Dibutylamine

A
(J9503)

Dichloro Acetic Acid

Dichloro Acetic Acid Methylester

Dichloro-iso-propylene ether

Dichlorobutane

Dichlorobutylene

Dichloroethane

Dichloroethylene

Dichloromethane

Dichloropentane

3,1-Dichloropropene

Dicholorobenzene

Dicyclohexylamine

A
(J9503)

Diesel Fuel

Diesel Oil

Diethanolamine

Diethyl Amin

A
(J9503)

Diethyl Aniline

16

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B/C

Diethyl Maleate

Diethyl Sebacate

Diethyl Sulfate

Diethylene Glycol

Diethylene Triamine

Diglycolic Acid

Dihexyl Phthalic Acid Ester

Dihydroxy Tartaric Acid (Tartaric Acid)

1,4-Dihydroxybenzene

A/B

A
(J9503)

A
(J9503)

AU

Chemical

ACM

VMQ

NBR

FKM

HNBR

FFKM (Isolast)

FVMQ

EPDM

FKM
Resifluor 500

CR

Chemical Compatibility Guide

Diethyl Benzene

Diethyl Carbonate

Diethyl Ether

Diethyl Formaldehyde

Diethyl Hydrazine

Dimethyl Amine

Dimethyl Aniline

Dimethyl Ether

Dimethyl Formamide

A/B

A/B

Dimethyl Hydrazine

Dimethyl Ketone

Dimethyl Phenol

Dimethyl Phthalate

Dimethylbutane

Dinitro Toluene

Dinitrogene Oxid

Dioctyl Amine

A
(J9503)

Dioctyl Phthalate

Dioctyl Sebacate

Dioxane

Dioxolane

Dipentene

Diphenyl

Diphenyl Ether

Diphenyle Oxide

Dipropylene Glycol

Dithionite

Divinyl Benzene

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17

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

DMT (Dimethyl Terephthalate)

DNCB (Dinitrochlorobenzene)

Dodecanol

Domestic Fuel Oils

Dowtherm A

Dowtherm E

Duodecanol (Laurylalcohol)

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

Chemical Compatibility Guide

Epichlorhydrin

Essential Oils

Ethane

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

A
(J9503)

Ethanol Amine

Ether

Ethyl Acetate

B/C

Ethyl Alcohol, Ethanol

Ethyl Benzene

Ethyl Bromide

Ethyl Cellulose

Ethyl Hexanole

Ethyl Oxalate

Ethyl Pentachlorobenzene

Ethyl Pyridine

Ethyl Sulfate (Diethyl Sulfate)

Ethylacrylate

Ethylchloride

Ethylchloroacetate

Ethylene

Ethylene Bromide

Ethylene Chloride

Ethylene Chlorohydrin

18

(J9503)

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Edition August 2012

CR

EPDM

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

A
(J9503)

Ethylene Dibromide

Ethylene Dichloride

Ethylene Glycol

Ethylene Glycol Ethylether (Cellosolve)

Ethylene Oxide

A
(J9503)

Ethylene Silicate

Ethylene Trichloride

VMQ

AU

Ethylene Diamine

ACM

Chemical

ACM

FFKM (Isolast)

Chemical Compatibility Guide

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

Fats (animal/vegetable)

Fatty Acids

Ferric Chloride Solution

Ferric Nitrates

Chemical

Ferric Sulfate (Ferric Vitrinol)

Ferric Sulfate Solution

Fir Oil

Fish Oil

Fluorine

Fluorobenzene

Fluorosilicic Acid

Formaldehyde (Formalin-Solution)

Formaldehyde (Methanal)

Formamide

A
(J9503)

Formic Acid

Freon 11

Freon 112

Freon 113

Freon 114

Freon 114 B2

Freon 115

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19

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Chemical Compatibility Guide

Freon 12

Freon 13

Freon 13 B1

Freon 134 a

Freon 14

Freon 142 b

Freon 152 a

Freon 21

Freon 218

Freon 22

Freon 31

Freon 32

Freon 502

Freon BF

Freon C316

Freon C318

Freon MF

Freon PCA

Freon T-P35

Freon TA

Freon TC

Freon TF

Freon TMC

Freon TWD602

Fruit Juices

Fumaric Acid

Furan

Furfural (Furfurylaldehyde)

Furfurylalcohol

Chemical

20

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Edition August 2012

Chemical Compatibility Guide

VMQ

Gas Oil

Gasoline/Alcohol Mix

Gasoline, 100 Octane

Gasoline, 130 Octane

Gasoline, aromatic

Gasoline, Ethyl and Regular

Gasoline, Refined

Gasoline, Sour

Gasoline, with Mercaptan

Gelatin

Generator Gas

Glaubers Salt

Glucose solution

Glucose, aqueos

Glycerin (Glycerol)

Glycerol

Glycerol Chlorohydrin

Glycerol Triacetate (Triacetin)

Glycerol Trinitrate (Nitroglycerin)

Glycine

Glycolic Acid

Chemical

VMQ

NBR

NBR

HNBR

HNBR

FVMQ

FVMQ

FKM
Resifluor 500

FKM
Resifluor 500

FKM

FKM

FFKM (Isolast)

FFKM (Isolast)

EPDM

EPDM

CR

CR

AU

AU

Gallic Acid

ACM

Chemical

ACM

HEF-3

Helium Gas

Heptane

Hexachloro Acetone

Hexachloro Butadiene

Hexachloro Cyclohexane (Lindane)

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21

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

Hexafluorosilicic Acid

A/B

Hexaldehyd

Hexalin (Cyclohexanol)

Hexamine

Hexanal (Capronaldehyde)

Hexane

Hexanetriol

Hexene

Hexyl Alcohol

VMQ

CR

NBR

AU

1-Hexadecanol

Chemical

HNBR

ACM

Chemical Compatibility Guide

Hydrazine

A
(J9503)

Hydrazine Hydrate

A
(J9503)

Hydrobromic Acid

Hydrochlorique Acid (Muriatic Acid)


37%

Hydrocyanic Acid

Hydrofluoric Acid (cold)

Hydrofluoric Acid (hot)

Hydrogen Chloride Gas

Hydrogen Fluoride

A/B

A/B

Hydrogen Peroxide, concentrated

A-C

Hydrogen Sulfide

Hydrogen, Gas

Hydrogene Bromide, unhydrous

Hydrogensulfite Leach

Hydroquinone

Hydroxy Acetic Acid

Hydroxylamine

Hydroxylamine Sulfate

Hypochlorous Acid

22

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Chemical Compatibility Guide

VMQ

Iodine

Iodine tincture

Iodoform

Iso-Butane

Iso-Butyl Alcohol

Iso-Butyl Methyl Ketone

Iso-Butylene

Iso-Butyraldehyde

Iso-Cyanate

Iso-Dodecane

Iso-Octane

Iso-Pentane

Iso-Propyl-Acetate

Iso-Propyl-Alcohol

Iso-Propyl-Benzene

Iso-Propyl-Chloride

Iso-Propyl-Ether

A/B

Chemical

VMQ

NBR

NBR

HNBR

HNBR

FVMQ

FVMQ

FKM
Resifluor 500

FKM
Resifluor 500

FKM

FKM

FFKM (Isolast)

FFKM (Isolast)

EPDM

EPDM

CR

CR

AU

AU

Ink

ACM

Chemical

ACM

Jet Fuel JP3

Jet Fuel JP4

Jet Fuel JP5

Jet Fuel JP6

JP3 (Fuel)

JP4 (Fuel)

JP5 (Fuel)

JP6 (Fuel)

JPX (Fuel)

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Edition August 2012

23

Chemical Compatibility Guide

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Kerosene

Ketchup

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Lactams

Lactic Acid

Lanolin

Latex

Laughing Gas (N2O)

Lavender Oil

Lead Acetate Salt Solution

Lead Arsenate

Lead Nitrate

Lead Nitrate Solution

Lead Sulfate

Lemon Juice

Ligroin

Lindol

Linoleic Acid

Linseed Oil

Liqueurs

Lithium Bromide Brine

Lithium Chloride

Lithium Hydroxide

A/B

24

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Edition August 2012

Chemical Compatibility Guide

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Machinery Oil (mineral)

Maganese Chloride (Solution)

Magnesium Acetate Solution

Magnesium Chloride Solution

Magnesium Hydroxide (Solution)

Magnesium Silicate (Talcum)

Magnesium Sulfate (Epson Salts)

Maleic Acid

Maleic Anhydride

Malic Acid

Margarine

Mayonaise

Menthol

Mercaptans

Mercuric Chloride Solution

Mercury

Mercury Nitrate

Mesityl Oxide

Methacrylic Acid

Methanal

Methane

Methanol

Methoxy Benzene

Methoxy Butanol

Methyl Acetate

B/C

Methyl Acetoacetate

Methyl Acrylate

Methyl Alcohol

Methyl Amine

A
(J9503)

Methyl Aniline

Methyl Bromide

Methyl Butyl Ketone

Methyl Carbonate

Methyl Cellosolve

Methyl Cellulose

Methyl Chloride

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Edition August 2012

25

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Chemical Compatibility Guide

Methyl Cyclopentane

Methyl Ethyl Ketone

Methyl Formate

Methyl Glycol

Methyl Glycol Acetate (Ethyleneglycol)

Methyl Iso-Butyl Ketone

Methyl Iso-Propyl Ketone

Methyl Methacrylate

Methyl Methacrylic Acid Ester

Methyl Oleate

Methyl Phenyl Ether (Anisole)

Methyl Pyrrolidone

Methyl Salicylate

Methylene Chloride

2-Methylpentane

3-Methylpentane

Milk

Milk of Lime

Mineral Oil

A/B

A/B

Mineral Spirits

Molasses

Monobromobenzene

Monochloroacetic Acid

Monochloroacetic Acid Ethyl Ester

Monochlorobenzene

Monoethanol Amine

A
(J9503)

Mononitrochlorobenzene

Morpholine

Muriatic Acid (HCl) (Hydrochloric Acid)

Muriatic Acid (HCl), diluted

26

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Edition August 2012

Chemical Compatibility Guide

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Naphtha

Naphthalene

Naphthenic Acid

Naphtolen ZD

Natural Gas

Neats Foot Oil

Neon Gas

Nickel Acetate

Nickel Chloride

Nickel Nitrate

Nickel Sulfate

Nitrating Acids

Nitric Acid, concentrated

Nitric Acid, fuming

Nitro Benzene

Nitro Glycerin

Nitro Glycol

Nitro Methane

Nitro Propane

Nitro Toluene

Nitrogen Gas

Nitrogen Tetroxide

Nonanol

Nut Oil

Chemical
Octadecane
Octal
Octane
Octanol (Octylalcohol)

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Edition August 2012

VMQ

NBR

FFKM (Isolast)

HNBR

EPDM

FVMQ

CR

FKM
Resifluor 500

AU

FKM

ACM

27

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Olefin, crude

Oleic Acid

Oleic Alcohol

Oleum (Sulfuric Acid, 0 to 50%)

Olive Oil
Ortho Dichloro Benzene
Oxalic Acid

Ozone

A/B

B/C

Chemical

VMQ

NBR

HNBR

FVMQ

Oil of Turpentine

FKM
Resifluor 500

Octylcresol

FKM

FFKM (Isolast)

EPDM

CR

AU

Octylalcohol

ACM

EPDM

CR

AU

Chemical

ACM

FFKM (Isolast)

Chemical Compatibility Guide

Palm Kernel Oil

Palm Oil

Palmitic Acid

Para Dichloro Benzene

Paraffin

Paraffin Oil

Peanut Oil

Pectin

Penta Chloro Diphenyl

Penta Chloro Phenol

Pentane

Pentanol

Perchloric Acid

Perchloro Ethylene

Petroleum

Petroleum Ether

Phenol

Phenyl Benzene

Phenyl Ether

28

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Edition August 2012

Chemical

ACM

AU

CR

EPDM

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

FFKM (Isolast)

Chemical Compatibility Guide

Phenyl Hydrazine

A
(J9503)

Phosphine

Phosphoric Acid

Phosphoric Acid 45%

Phosphorous Trichloride

Photographic Developing Bath

Phthalic Acid

Phthalic Anhydride

Picoline, alpha

Picric Acid, Aqueous Solution

Pine Oil

Pineapple Juice

Pinene

Piperidine

Polyvinyl Acetates

Potassium Acetate

Potassium Aluminium Sulfat

Potassium Bicarbonite

Potassium Bisulfate

Potassium Borate

Potassium Bromate

Potassium Bromide

Potassium Carbonate

Potassium Chlorate

Potassium Chloride

Potassium Chromate

Potassium Cyanide

Potassium Dichromate

Potassium Hydroxide (Solution 50%)

Potassium Hydroxide, Potassium Lye

Potassium Hypochlorite (Javelle water)

Potassium Iodide

Potassium Nitrate

Potassium Perchlorate

Potassium Perfluoroacetate

Potassium Permanganate

Potassium Persulfate

Potassium Phosphate

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29

VMQ

Potassium Sulfite

Propane

Propanol

2-Propanone (Acetone)

2-Propene-1-ol

Propinyl Alcohol

Propion Aldehyde

Propionic Acid

Propyl Acetate

Propyl Acetone

Propyl Amine

A
(J9503)

Propyl Nitrate

Propylene

Propylene Dichloride

Propylene Glycol

Propylene Oxide

A
(J9503)

Pyridine

Pyrrole

Chemical

VMQ

NBR

NBR

HNBR

HNBR

FVMQ

FVMQ

FKM
Resifluor 500

FKM
Resifluor 500

FKM

FKM

FFKM (Isolast)

FFKM (Isolast)

EPDM

EPDM

CR

CR

AU

AU

Potassium Sulfate

ACM

Chemical

ACM

Chemical Compatibility Guide

Rapeseed Oil

Roast Gas (dry)

Rosin (Colophony)

30

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Edition August 2012

Chemical Compatibility Guide

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Salicylic Acid

Sea Water

Sewage

Silcone grease

Silicic Acid

Silicon Dioxide

Silicone Oil

Silver Cyanide Solution

Silver Nitrate

Silver Salts

Skydrol 500

Skydrol 7000

Soap Solution

Soda (Sodium Carbonate)

Sodium Acetate

Sodium Benzoate

Sodium Bicarbonate Solution

Sodium Bisulfate Solution

Sodium Bisulfite Solution

Sodium Borate (Borax)

Sodium Carbonate (Soda Ash)

Sodium Carbonate Solution

Sodium Chlorate

Sodium Chloride (Common Salt)

Sodium Chloride Solution

Sodium Chlorite

Sodium Cyanide Solution

Chemical

Sodium Dichromate

Sodium Fluoride

Sodium Hydroxide

Sodium Hydroxide, Caustic Soda

Sodium Hypochlorite Solution

Sodium Nitrate

Sodium Nitrite

Sodium Peroxide Solution

Sodium Phosphate

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31

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Chemical Compatibility Guide

Sodium Silicate Solution

Sodium Sulfate Solution


(Glaubers Salt)

Sodium Sulfhydrate Solution

Sodium Sulfide

Sodium Sulfite Solution

Sodium Tetraborate Solution

Chemical

Sodium Thiosulfate (Antichlor)

Soy Bean Oil

Sperm Oil

Spermacetin

Spirits

Stannic Chloride Solution

Starch

Stearic Acid

Stoddard Solvent

Styrene

Succinic Acid

Sucrose Sap

Sugar Solutions

Sulfur

Sulfur Chloride

Sulfur Dioxide (SO2)

Sulfur Dioxide Liquid (anhydrous)

Sulfur Dioxide, gaseous

Sulfur Hexafluoride (SF6)

Sulfuric Acid (0 to 50%)

A/B

A/B

Sulfuric Acid, diluted

Sulfurous Acid

32

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Chemical Compatibility Guide

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Talcum

Tallow

Tannins

Tar

Tartaric Acid

Tetrachloroethane

Tetrachloromethane

Tetrachloroethylene

Tetrahydrofuran

Thionyl Chloride

Thiophene

Titanium Tetrachloride

Toluene (Toluol)

Transformer Oil

Tri-Iso-Propyl Benzene

Triacetin (Glycerine Triacetate)

Triaryl Phosphate

Tributoxy Ethyl Phosphate

Tributyl Marcaptane

Tributyl Phosphate

Trichloro Benzene

Trichloro Ethane

B/C

Trichloro Ethyl Phosphate

Trichloro Ethylene

B/C

Trichloroacetic Acid

A
J8325)

Tricresyl Phosphate

Triethanolamine

Triethyl Borane

Triethyl Glycol

Triethylaluminium

Trifluoro Ethane

Trinitrotoluene (TNT)

Trioctyl Phosphate

Trisodium Phosphate Solution

Turpentine

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33

Chemical Compatibility Guide

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Urea

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Vaseline

Vaseline Oil

Vegetable Juices

Vegetable Oils

Vinegar

Vinyl Acetate

Vinyl Chloride, liquid

Vinylidene Chloride

Chemical

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Waste Gas (cont. Carbon Dioxide)

Waste Gas (cont. Carbon Monoxide)

Waste Gas (cont. Hydrogen Chloride)

Waste Gas (cont. Hydrogen Fluoride)

Waste Gas (cont. Nitrous Fumes)

Waste Gas (cont. Sulfur Dioxide)

Waste Gas (cont. Sulfuric Acid)

Water steam < +150 C / +302 F

Water steam > +150 C / +302 F

Water to +80 C / +176 F

Water to +135 C / +275 F

34

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Edition August 2012

Chemical

ACM

AU

CR

Xenon

Xylene (Xylol)

Xylidines (aromatic Amines)

Chemical

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Yeast

VMQ

VMQ

Wood Spirit

NBR

NBR

HNBR

Wine + Whiskey

HNBR

FVMQ

FVMQ

Wax Alcohols

FKM
Resifluor 500

Water vapour > +140 C / +284 F

FKM
Resifluor 500

FKM

FKM

FFKM (Isolast)

FFKM (Isolast)

EPDM

Water vapour < +140 C / +284 F

EPDM

CR

AU

Chemical

ACM

ACM

Chemical Compatibility Guide

ACM

AU

CR

EPDM

FFKM (Isolast)

FKM

FKM
Resifluor 500

FVMQ

HNBR

NBR

VMQ

Zeolites

Zinc Acetate

Zinc Chloride Solutions

Zinc Sulfate

Chemical

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Edition August 2012

35

Chemical Compatibility Guide

Chemical Compatibility Guide for sealing materials and media used in


Semiconductor Manufacturing Processes
Rating system
A Very good suitability
Elastomer shows little or no effect from exposure.
Little effect on performance and physical properties.
Very good resistance.
B Good suitability
Some effects from exposure with some loss of physical
properties. Some chemical swelling.

C Limited suitability
Significant swell and loss of physical properties after
exposure. Additional tests should be done.
U The elastomer is unsuitable for application in this
media.
- Insufficient information available for service in this
media.

Plasma Processes +180 C / +356 F


FFKM

FKM

Isolast FabTM Range

ResifluorTM 800

J9610

J9650

J9670

J9675

VCT1S

Ammonium Fluoride

Argon

Boron Trichloride

Carbon Tetrachloride

Chlorine

Dichlorodifluoromethane (F-12)

Fluoroform (F-23)

Freon 152 a

Helium

Hexafluoroethane (F-116)

Hydrogen

Hydrogen Bromide

Hydrogen Chloride

Nitrogen Trifluoride

Oxygen

Perfluoropropane

Silicon Tetrachloride

Silicon Tetrafluoride

Sulphur Hexafluoride

Tetrafluoromethane (F-14)

Trifluoromethane (F-23)

Tungsten Hexafluoride

Chemical

36

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Chemical Compatibility Guide

Wet Processes

Chemical

FFKM

FKM

Isolast FabTM Range

ResifluorTM 800

J9610

J9650

J9670

J9675

VCT1S

Acetic Acid (30%)

Acetic Acid, glacial

Acetone

Acetophenone, 4-Hydroxy

ACT 690C

ACT 935

ACT 970

ACT CMI

ACT K-101

ACT K-117

ACT NE-14

ALEG 310

Amino Diglycol

Aminoethoxyethanol

Ammonia

Ammonium Fluoride

Ammonium Hydroxide, conc.

Aqua Regia

Boron Tribromide

Buffered Oxide Etchants (BOE)

Butyl Acetate

Butyl diglycol

Cellosolve

Chromic Acid

Citric Acid

CKl-888

Copper Sulfate (Blue Vitriol) Solution

Cyclohexane

Deionized Water (UPDI)

Dichlorofluoroethane (F-114b)

Dichlorotrifluoroethane (F-123)

Dimethylacetamide

EKC 265

EKC 4000PCT

EKC 830

Ethanolamine

Ethoxyethyl Acetate (EGMEEA)

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37

Chemical Compatibility Guide

FFKM

TM

FKM
ResifluorTM 800

Isolast Fab

Range

J9610

J9650

J9670

J9675

VCT1S

Ethyl Acetate

Ethyl Lactate

Gamma-Butyrolcatone

Hexymethyldisilizane (HMDS)

Hydrochloric Acid

Hydrofluoric Acid

Hydrogen Peroxide

Hydroxyethylpyrrolidone

Hydroxylamine

Isopropyl Alcohol (IPA)

Methanol

Methoxy Propyl Acetate

Methoxydipropanol

Methoxyethanol (DGMMA)

Methoxypropanol

Methyl (n-) Pyrrolidone (nMP)

Methyl Ethyl Ketone (MEK)

Methyl Isobutyl Ketone (MIBK)

MICROPUR

Monoethanolamine (MEA)

N-Cyclohexylpyrrolidone

Nitric Acid

Ozonated Deionized Water

Pentamethyldiethylenetriamine (PMDETA)

Phosphoric Acid

Phosphorus Oxychloride

Piranha

Potassium Hydroxide

PRS-1000

PRS-3000

QZ 3501 Polyimide Developer

RER 500

RER 652

REZI 28

SC-1 (Standard Clean-1)

SC-2 (Standard Clean-2)

Sodium Hydroxide

Stoddard Solvent

Sulfuric Acid

Tetramethyl Ammonium Hydroxide

Chemical

38

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Chemical Compatibility Guide

FFKM

TM

FKM
ResifluorTM 800

Isolast Fab

Range

J9610

J9650

J9670

J9675

VCT1S

Tetramethylcyclotetrasiloxane (TMCTS)

TMAH 25%

TOK 105 Stripper

TOK 106 Stripper

Toluene

Trichloroethylene (TCE)

Trichlorofluoromethane (F-11)

Trichlorophenylsilane

Trichlorosilane

Trichlorotrifluoroethane

Trimethyl Borate (TMB)

Trimethyl Phosphite (TMP)

Xylene (Xylol)

Chemical

Thermal Processes
FFKM

FKM

Isolast FabTM Range

ResifluorTM 800

Chemical

J9610

J9650

J9670

J9675

VCT1S

Ammonia

Dichlorosilane

Hydrogen Chloride

Nitrogen

Oxygen

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Edition August 2012

39

Chemical Compatibility Guide

Gas Deposition +180 C / +356 F


FFKM

FKM

Isolast FabTM Range

ResifluorTM 800

Chemical

J9610

J9650

J9670

J9675

VCT1S

Ammonia

Ammonium Fluoride

Ammonium Persulfate

Antimony Trioxide

Argon

Arsenic Trioxide

Arsine

Boron Tribromide

Boron Trichloride

Boron Trioxide

Bromide Anhydrous

Bromide Pentafluoride

Bromide Trifluoride

Bromotrifluoroethylene

Carbon Dioxide

Chlorine Trifluoride

Chlorodifluoromethane (F-22)

Chloropentafluoroethane (F-115)

Chlorotrifluoromethane (F-13)

Diborane

Dichlorodifluoromethane (F-12)

Dichlorofluoromethane (F-21)

Dichlorosilane

Dichlorotetrafluoroethane (F-114)

Dimethyl Amine (DMA)

Dimethyl Ether

Disilane

Ethylene

Fluorine

Fluoroform (F-23)

Freon 114 (Dichlorotetrafluoroethane)

Freon 115 (Chloropentafluoroethane)

Freon 116 (Hexafluoroethane)

Freon 12 (Dichlorodifluoromethane)

Freon 124 (Chlorotetrafluoroethane)

Freon 125 (Pentafluoroethane)

Freon 13 (Chlorotrifluoromethane)

40

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Edition August 2012

Chemical Compatibility Guide

FFKM

TM

FKM
ResifluorTM 800

Isolast Fab

Range

J9610

J9650

J9670

J9675

VCT1S

Freon 134a (Tetrafluoroethane)

Freon 13b1 (Bromotrifluoromethane)

Freon 142b (Difluorochloroethane)

Freon 21 (Dichlorofluoromethane)

Freon 22 (Chlorofluoromethane)

Freon 23 (Fluoroform)

Germane (Germanium Tetrahydride)

Helium

Hexafluoroethane (F116)

Hydrogen

Hydrogen Bromide

Hydrogen Chloride

Hydrogen Fluoride

Hydrogen Iodide

Hydrogen Selenide

Hydrogen Sulfide

Iodine Pentafluoride

Isobutane

Methane

Methane Thiol

Methyl Bromide

Methyl Chloride

Monoethanolamine

Nitrogen

Nitrogen Trifluoride

Nitrous oxide

Oxygen

Ozone

Perfluoropropane

Phosgene

Phosphine

Potassium Hydroxide

Silane

Silicone Tetrabromide

Silicone Tetrachloride

Silicone Tetrafluoride

Sodium Hydroxide

Sulfur Hexafluoride

Sulfur Tetrafluoride

TEOS

Chemical

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Edition August 2012

41

Chemical Compatibility Guide

FFKM

TM

FKM
ResifluorTM 800

Isolast Fab

Range

J9610

J9650

J9670

J9675

VCT1S

Tetrafluoromethane (F-14)

Titanium Tetrachloride

Trichloroethane

Trichloromethane

Trifluoromethane (F-23)

Trimethyl Amine

Trimethyl Borate

Trimethyl Phosphite

Tungsten Hexafluoride

Vinyl Chloride

Vinyl Fluoride

Xenon

Chemical

42

Latest information available at www.tss.trelleborg.com


Edition August 2012

Chemical Compatibility Guide

General quality criteria and storage guidelines


General quality criteria
The cost-effective use of seals and bearings is highly
influenced by the quality criteria applied in production.
Seals and bearings from Trelleborg Sealing Solutions
are continuously monitored according to strict quality
standards from material acquisition through to delivery.
Certification of our production plants in accordance with
international standards QS 9000/ISO 9000 meets the
specific requirements for quality control and management
of purchasing, production and marketing functions.
Our quality policy is consistently controlled by strict
procedures and guidelines which are implemented within
all strategic areas of the company.
All testing of materials and products is performed in
accordance with accepted test standards and specifications,
e.g. random sample testing in accordance with
ISO 2859-1:2004-01 AQL 1,0 general inspection level II,
normal inspection.
Inspection specifications correspond to standards
applicable to individual product groups (e.g. for O-Rings:
ISO 3601).
Our sealing materials are produced free of chlorofluorinated hydrocarbons and carcinogenic elements.

 uidelines for the storage of


G
polymer products based on
ISO 2230
Many polymer products and components are stored for
long periods of time before being put into service, so it
is important they are stored in conditions that minimize
unwanted changes in properties. Such changes may result
from degradation, in which case they may include excessive
hardening, softening, cracking, crazing and other surface
effects. Other changes may be caused by deformation,
contamination or mechanical damage.
Packaging
Unless otherwise specified in the appropriate product
specification, rubber products should be enclosed in
individual sealed envelopes. The packaging should be
carried out in an atmosphere in which the relative humidity
is less than 70 %, or if polyurethanes are being packed,
less than 65 %. Where there is serious risk of ingress of
moisture (e.g. rubber-metal-bonded parts), aluminum
foil/paper/polyethylene laminate or other similar means
of protection should be used to ensure protection from
ingress of moisture.
Temperature
The storage temperature should be below 25 C /77 F and
the products should be stored away from direct sources of
heat such as boilers, radiators and direct sunlight. If the

Latest information available at www.tss.trelleborg.com


Edition August 2012

storage temperature is below 15 C /59 F, care should be


exercised during handling of stored products, as they may
have stiffened and have become susceptible to distortion
if not handled carefully.
Humidity
The relative humidity should be such that, given in the
variations of temperature in storage, condensation
does not occur. In all cases, the relative humidity of the
atmosphere in storage should be less than 70 %, or if
polyurethanes are being stored, less than 65 %.
Light
Rubber should be protected from light sources, in particular
direct sunlight or intense light having a high ultra-violet
content. It is advisable that any windows of storage rooms
be covered with a red or orange coating or screen.
Radiation
Precautions should be taken to protect stored products
from all sources of ionizing radiation likely to cause
damage to the products.
Ozone
Ozone has a particularly harmful effect on rubber. Storage
rooms should not contain any equipment that is capable
of generating ozone, such as mercury vapor lamps or highvoltage electrical equipment giving rise to electric sparks
or electrical discharges. Combustion gases and organic
vapors should also be excluded, as they may give rise to
ozone via photo-chemical processes. When equipment
such as a fork-lift truck is used to handle large rubber
products, care needs to be taken to ensure this equipment
is not a source of pollution that may affect the rubber.
Combustion gases should be considered separately. While
they are responsible for generating ground-level ozone,
they may also contain unburned fuel which, by condensing
on rubber products, can cause additional deterioration.
Deformation
Rubber should be stored free from tension, compressive
stresses or other causes of deformation. Where products
are packaged in a strain-free condition, they should be
stored in their original packaging. In case of doubt, the
manufacturer's advice should be sought. It is advisable
that rings of large internal diameter are formed into three
equal loops so as to avoid creasing or twisting. It is not
possible to achieve this condition by forming just two
loops.
Contact with liquids and semi-liquid materials
Rubber should not be allowed to come into contact with
liquid or semi-liquid materials (for example, petrol, greases,
acids, disinfectants, cleaning fluids) or their vapors at any
time during storage, unless these materials are by design
an integral part of the product or the manufacturer's
packaging. When rubber products are received coated
with their operational media, they should be stored in this
condition.

43

Chemical Compatibility Guide

Contact with metals

Extension storage period

Certain metals and their alloys (in particular, copper and


manganese) are known to have harmful effects on some
rubbers. Rubber should not be stored in contact with such
metals except when bonded to them. They should be
protected by wrapping in, or by separation with, a suitable
material, e.g. paper or polyethylene.

This is the period for which a rubber product, appropriately


packaged, may be stored after the initial storage period,
before further inspection and re-testing is necessary.

Contact with dusting powder


Dusting powders should only be used for the packaging of
rubber items in order to prevent adhesion. In such cases,
the minimum quantity of powder to prevent adhesion
should be used. Any powder used should be free from
any constituent that would have a harmful effect on the
rubber or the subsequent application of the rubber.

Assembly
These are products or components containing more than
one element, one or more of which is made of rubber.
Generally it is not recommended to store elastomeric
products in an assembled condition. If it is necessary to do
so, the units should be checked more often. The inspection
interval depends on the design and geometry of the
components.
Inspection before extension storage

Contact between products made from rubbers of different


compositions should be avoided. This includes products of
the same type but differing in color.

Before any items are to be stored for an extension period,


representative samples of each type should be selected for
inspection at the end of the appropriate initial storage
period. Inspection should be in accordance with the
relevant product specification.

Rubber-to-metal bonded products

Visual inspection

The metal part of rubber-to-metal bonded products should


not come into contact with the rubber of other products.
Preservative used on the metal should be of a type that
it will not adversely affect the rubber or the bond to
such an extent that it does not comply with the product
specification.

Inspect each of the items for the following:


1. Permanent distortions, such as creases or flats.
2. Mechanical damage, such as cuts, tears, abraded
areas or delaminated plies.
3. Surface cracking when viewed under a microscope
at x10 magnification.
4. Changes in surface condition, such as hardening,
softening or tackiness.

Contact between different products

Storage life
This is the maximum period of time that a rubber product,
appropriately packaged, may be stored. After this time the
product is regarded as unserviceable for the purposes for
which it was originally manufactured. The storage life of a
rubber product is influenced by its shape and size as well
as its composition. Thick products usually undergo slower
changes through degradation than thinner ones.
Initial storage period
This is the maximum period, starting from the time of
manufacture, for which a rubber product, appropriately
packaged, may be stored under specified conditions before
a sample needs to be inspected or re-tested.

Assessment at the end of the initial period


If, following the visual inspection procedure the items are
not satisfactory, they should not be stored for an extended
period. If the items are satisfactory and are stored for an
extended period a record should be kept of the date initial
storage began as well as the date the extended storage
period began. Items stored for an extended period should
be inspected and tested at, or before, the expiry of the
extension storage period before they are put into service or
stored for a further extended period.

Table 3 Initial and extension storage periods for unassembled components


Material group

Initial storage period

AU, EU, NR, SBR

5 years

Extension storage period


2 years

ACM, AEM, CR, ECO, HNBR, IIR, NBR

7 years

3 years

CSM, EPDM, FKM, VMQ, FVMQ

10 years

5 years

FFKM e.g. Isolast

20 years

5 years

Zurcon

10 years

5 years

PTFE

unlimited

Note 1: If the storage temperature is over or under 25 C/77 F this will influence the storage time. Storage at 10 C/50 F higher will
reduce the storage time by about 50 %. Storage at 10 C/50 F lower will increase the storage time by around 100 %.
Note 2: In application areas such as aerospace the storage periods can differ from this specification. These specific storage conditions
have to be agreed between the supplier and the buyer.

44

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Edition August 2012

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Europe

Telephone

Americas

Telephone

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Telephone

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+34 (0) 91 71057 30

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+41 (0) 21 631 41 11

MIDDLE EAST REGIONAL

+41 (0) 21 631 41 11

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+91 (0) 80 2245 5157

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(BELARUS, ROMANIA, TURKEY, UKRAINE)

(SLOVAKIA)

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www.tss.trelleborg.com

99GBL2BROAE0812

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MACEDONIA, SERBIA AND MONTENEGRO, SLOVENIA)

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