1.1 PROPYLENE AMMOXIDATION Acrylonitrile is produced in commercial quantities almost exclusively by the vapor-phase catalytic propylene ammoxidation process developed by Sohio (Castelli, 2010).
The commercial process uses a fluid-bed reactor in which propylene,
ammonia, and air contact a solid catalyst at 4005108C and 49196 kPa (0.52.0 kg/cm2) gauge. It is a single-pass process with about 98% conversion of propylene, and uses about 1.1 kg propylene per kg of acrylonitrile produced. Useful by-products from the process are HCN (about 0.1 kg per kg of acrylonitrile), which is used primarily in the manufacture of methyl methacrylate, and acetonitrile (about 0.03 kg per kg of acrylonitrile), a common industrial solvent (Castelli, 2010). In the commercial operation the hot reactor effluent is quenched with water in a counter current absorber and any unreacted ammonia is neutralized with sulfuric acid. The resulting ammonium sulfate can be recovered and used as a fertilizer. The absorber off-gas containing primarily N2, CO, CO2, and unreacted hydrocarbon is either vented directly or first passed through an incinerator to combust the hydrocarbons and CO. The acrylonitrile-containing solution from the absorber is passed to a recovery column that produces a crude acrylonitrile stream overhead that also contains HCN (Davis et al., 2000). The column bottoms are passed to a second recovery column to remove water and produce a crude acetonitrile mixture. The crude acetonitrile is either incinerated or further treated to produce solvent quality acetonitrile. Acrylic fiber quality (99.2% minimum) acrylonitrile is
obtained by fractionation of the crude acrylonitrile mixture to remove
HCN, water, light ends, and high boiling impurities (Castelli, 2010).
Disposal of the process impurities has become an increasingly
important aspect of the overall process, with significant attention being given
to
developing
cost-effective
and
environmentally
acceptable
methods for treatment of the process waste streams. These catalysts are multi component mixed
metal
oxides
mostly
based on
bismuth
molybdenum oxide. Other types of catalysts that have been used
commercially are based on ironantimony oxide, uraniumantimony oxide, and telluriummolybdenum oxide (Davis et al., 2000) .
1.3 PROPANE CYANIZATION WITH NITRIC OXIDE
1.4 ADVANTAGES AND DISADVANTAGES OF PRODUCTION PROCESS
Table 1.4.1: Advantages and disadvantages of production process of propylene
Ammoxidation (Michael, 2010).
PRODUCTION PROCESS OF PROPYLENE AMMOXIDATION
Advantages Disadvantages Higher recovery efficiency of acrylonitrile Additional energy consumption due to low pH Lower polymer production in the quench section Opportunity to re-use waste water streams
Table 1.4.1: Advantages and disadvantages of production process of propane cyanization
with nitric oxide.
1.5 REASON OF CHOOSING THE PROCESS
The first reason of choosing this process in production of acrylonitrile is because it is very simple that could be easily carry out with best understanding. This is because it has a clear flow process in a row of seven. Besides that, the convincing of choosing this process flow diagram is because it has not very high temperature condition to proceed this production of Acrylonitrile. Which is 410c 500c where by others process flow could leads up to 1000C (Michael, 2010). Moreover, in this process production of Acrylonitrile has a maximum beneficial of the products. Where this process production produces a use by product which is HCN. Besids that bypoduct, it also have CO, N2, and CO2 in off gas produce in Absorber chamber. This gases are useful in incinerator in combust the hydrocarbons and CO. The column bottoms are passed to a second recovery column to remove water and produce a crude acetonitrile mixture. The crude acetonitrile is either incinerated or further treated to produce solvent quality acetonitrile. Where there to have the maximum of production of acrylonitrile (Michael, 2010). The propylene-based process developed by ammoxidation was able to displace almost all other commercial production technologies because of its substantial advantage in overall production cost, primarily due to lower raw material costs. Raw material costs, less by-product credits, account for 60% of the total acrylonitrile production for a world scale plant. The process has remained economically advantaged over other process technologies because higher acrylonitrile yields, resulting from the introduction of improved commercial catalyst (Michael, 2010).
1.5 PROCESS FLOW DIAGRAM OF PROPYLENE AMMOXIDATION
Fig 1.5.1 Production of propylene ammoxidation (Michael, 2010).
Fuel Property Estimation and Combustion Process Characterization: Conventional Fuels, Biomass, Biocarbon, Waste Fuels, Refuse Derived Fuel, and Other Alternative Fuels