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a,*
Department of Energy and Environmental Science, Ch. Devi Lal University, Sirsa, Haryana, India
b
District Science Specialist, Hisar, Haryana, India
c
District Food and Supplies Ocer, Sirsa, Haryana, India
Received 22 February 2007; received in revised form 8 March 2007; accepted 19 March 2007
Available online 9 May 2007
Abstract
The aim of this study was the assessment of reduction of chemical oxygen demand (COD) and biological oxygen demand (BOD) of
wastewater from coee processing plant using activated carbon made up of Avacado Peels. The complete study was done in batch mode
to investigate the eect of operating parameters. The results of the COD and BOD concentration reduction with avocado peel carbon
(APC) and commercial activated carbon (CAC) were compared and optimum operating conditions were determined for maximum
reduction. Adsorption isotherm was also studied besides the calculation of optimum treatment parameters for maximum reduction of
COD and BOD concentration from euent of the coee processing plant. The maximum percentage reduction of COD and BOD concentration under optimum operating conditions using APC was 98.20% and 99.18% respectively and with CAC this reduction was
99.02% and 99.35% respectively. As the adsorption capacity of APC is comparable with that of CAC for reduction of COD and
BOD concentration, it could be a lucrative technique for treatment of domestic wastewater generated in decentralized sectors.
2007 Elsevier Ltd. All rights reserved.
Keywords: Adsorption; Avacado; BOD; COD; Coee processing wastewater/euent
1. Introduction
Ethiopia had been the origin of coee because rst coee
plant was initially found and cultivated by Oromo people
in the Kafa province of Ethiopia from which it got its name
(ITC, 2002). Ethiopia is worlds third largest coee exporter after Burundi and El Salvador (ITC, 2002). Jimma zone
is one of the areas in Ethiopia where coee processing
plants are cultivated in large numbers.
In this zone, wet coee processing method has been
adopted. Wet coee processing procedure requires mechanical removal of pulp with the help of water as a result of
which it produces considerable amount of wastewater
*
1854
1855
Characteristics of
euent
WHO permissible
limits
pH
Electrical conductance (mho/
cm)
Temperature (C)
Turbidity (Nephalometer
Turbidity Unit)
Total solids (mg/l)
Total suspended solids (mg/l)
Total dissolved solids (mg/l)
Chemical oxygen demand
(mg/l)
Biochemical oxygen demand
(mg/l)
MPN (coliform cells/100 ml)
4.5
3.1 104
6.8 8.5
1 103
25
430
20
510
2050
700
1350
22,000
650
200
450
300
12,000
100
1 109
1.5 107
1856
95
100
90
90
85
80
% reduction
110
% reduction
100
80
75
70
60
% COD by CAC
% COD by APC
70
% BOD by CAC
% BOD by APC
50
65
% COD by CAC
% BOD by CAC
% COD by APC
% BOD by APC
40
60
0
20
40
60
80
100
30
120
10
11
12
5.5
log x/m
where, x/m (mg/g) was the amount of COD and BOD removed (x) per unit mass of adsorbent (m), Ce (mg/l) was
residual COD and BOD concentration of aqueous solution, k and 1/n were Freundlich constants and measure
of adsorption capacity and adsorption intensity
respectively.
The Freundlich isotherm corresponding to the experimental measurements for APC and CAC were plotted on
log scales as shown in Figs. 3 and 4 respectively. Values
of regression coecient (r2) had been calculated from the
linear t and based on the t, the respective values of the
slope 1/n and intercept on y-axis taken as k were also calculated. Values of 1/n, k and regression coecient r2 for
APC were 0.2401, 4.7786 and 0.8636 corresponding to
y = -0.2401x + 4.7786
2
R = 0.8636
4.5
4
3.5
COD by APC
3
2.5
log Ce
Freundlich adsorption isotherm for BOD concentration reduction by ApC
log x/m
5
4.5
4
3.5
3
2.5
2
1.5
1
0.5
0
y = -0.2497x + 4.5886
2
R = 0.8645
BOD by APC
Linear (BOD by APC)
log Ce
Fig. 3. Freundlich plot for COD and BOD reduction using APC
adsorbent. Initial COD and BOD concentrations: 22,000/12,000 mg/l,
treatment time: 70 min, pH: 7, agitation speed: 600 rpm and adsorbent
particle size: 60.75 mm.
1857
90
3.5
COD by CAC
Linear (COD by CAC)
3
2.5
2
log Ce
% reduction
log x /m
4.5
70
50
log x /m
4.5
y = - 0.2698x + 4.7302
2
R = 0. 8599
% COD by CAC
% BOD by CAC
% COD by APC
% BOD by APC
3.5
30
2.5
2
1.5
BOD by CAC
Linear (BOD by CAC)
log Ce
pH
10
12
14
Fig. 5. Eect of pH on % COD and BOD reduction using APC and CAC
adsorbents. Initial COD and BOD concentrations: 22,000/12,000 mg/l,
treatment time: 70 min, adsorbent dose 4 g/100 ml, agitation speed:
600 rpm and particle size of adsorbent: 60.75 mm.
Fig. 4. Freundlich plot for COD and BOD reduction using CAC
adsorbent. Initial COD and BOD concentrations: 22,000/12,000 mg/l,
treatment time: 70 min, pH: 7, agitation speed: 600 rpm and particle size
of adsorbent: 60.75 mm.
100
3.3. pH
The eect of pH on the adsorption capacity of CAC and
APC and hence COD concentration and BOD concentration reduction from wastewater was shown in Fig. 5. The
optimum pH for maximum adsorption of organic impurities and COD concentration and BOD concentration
reduction from wastewater of coee processing plant by
CAC and APC was 7.
3.4. Initial COD concentration and BOD concentration
The eect of initial COD and BOD concentration of the
wastewater solution on the percent COD and BOD reduction by CAC and APC was shown in Fig. 6. The percent
COD concentration and BOD concentration reduction
with APC and CAC was found to increase with increase
in the initial COD concentration and BOD concentration
and after reaching to saturation levels, it started decreasing. The rate of adsorption increased because of the
increasing driving force. But at 24,000 mg/l of initial
90
80
% reduction
70
60
50
40
30
2000
7000
12000
% COD by CAC
% BOD by CAC
% COD by APC
% BOD by APC
17000
22000
27000
32000
COD concentration and 12,000 mg/l of initial BOD concentration, the curves reached their saturation points. It
was because of saturation of adsorbent sites and hence
the ratios of the initial number of adsorbate molecules to
the available adsorption sites of the adsorbent diminished
accordingly.
3.5. Agitation speed
To investigate the eect of agitation speed on % COD
and BOD reduction with APC and CAC, the agitation
speed was kept from 100 rpm to 1000 rpm. Fig. 7 showed
1858
110
Table 2
Eect of adsorbent particle size on % COD and BOD reduction by APC
and CAC
100
Adsorbent
particle size
APC
% COD
reduction
% BOD
reduction
% COD
reduction
% BOD
reduction
A (60.75 mm)
B (60.55 mm)
C (60.35 mm)
D (60.25 mm)
50.34
67.89
89.25
98.20
58.22
73.76
91.45
99.18
57.89
72.54
93.56
99.02
63.78
79.89
94.05
99.35
% reduction
90
80
CAC
70
60
50
50
250
% COD by CAC
% BOD by CAC
% COD by APC
% BOD by APC
450
650
850
Table 3
Residual COD and BOD concentration after treatment with APC and
CAC under batch mode operation
Adsorbents
Residual COD
concentration
Residual BOD
concentration
APC
CAC
296
215.6
98.4
78.0
1050
that there was a good trend for the percent COD and BOD
concentration reduction with the agitation speed for CAC
and APC. Maximum COD concentration and BOD concentration reduction were observed around 600 rpm for
both the adsorbents. But at higher agitation speeds, the
loosely attached molecules might re-enter into the adsorbate, hence lowering the % COD concentration and %
BOD concentration reduction. Therefore, we kept the agitation speed at 600 rpm to see the eect of percent COD
and BOD concentration reduction by both the adsorbents.
3.6. Adsorbent particle size
For observing the eect of adsorbent particle size on %
COD concentration and % BOD concentration reduction
of wastewater, they have been segregated in four categories
starting with A as A (60.75 mm), B (60.55 mm), C
(60.35 mm) and D (60.25 mm). From the study, it was
found that adsorbent particle size had signicant inuence
on percent reduction of COD and BOD concentration with
APC and CAC. The percent COD and BOD concentration
reduction for both the adsorbents were maximum for particle size of category D and the minimum reductions in
COD and BOD was obtained corresponding to particles
of category A for both the adsorbents as shown in Table
2. The values for maximum % COD concentration and %
BOD concentration reduction with APC and CAC were
98.20% and 99.18% and 99.02% and 99.35% respectively
corresponding to category D. It was observed that smaller
particles showed better adsorption than the larger ones
because surface area is directly related with adsorption
capacity. This could be explained on the basis of net surface area as smaller particles in a given quantity of powder
The optimum operating conditions were; treatment time: 70 min, adsorbent dose: 4 g/100 ml of euent, pH: 7, Initial COD and BOD concentrations: 24,000/12,000, agitation speed: 600 rpm and adsorbent particle
size: 60.25 mm.
would have larger surface area than the case when bigger
particles are taken.
3.7. Optimum operating conditions for maximum COD and
BOD reduction
We tried to obtain conditions for the maximum reduction of COD and BOD concentration for both the adsorbents. The optimum operating conditions for getting
maximum COD/BOD concentration reduction from coee
processing euent with APC and CAC were same and
these conditions were; treatment time: 70 min, adsorbent
dose: 4 g/l00 ml, pH: 7, initial COD/BOD concentration:
22,000/12,000 mg/l, agitation speed: 600 rpm and adsorbent particle size: 60.25 mm. It could be inferred from
the experimental results presented in this paper that residual concentrations of COD and BOD after treatment with
APC under optimum operating conditions were 396 mg/l
and 98.4 mg/l respectively and were well within the permissible limits of WHO standards as shown in Table 3. These
results could be utilized for working out the design parameters of an adsorption based industrial wastewater treatment system. Moreover, if APC was added in secondary
treatment tank for the euent treatment, there would be
a good saving of energy, which otherwise could hence been
consumed in aeration process.
4. Conclusion
Present study showed that APC is eective for reduction
of COD and BOD concentration from euent of coee
processing plant. Adsorption of COD and BOD was found
1859
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