Industrial & Engineering Chemistry Research - Modeling the High-Pressure AmmoniaWater System with WATAM and the PengRobinson

Equation of State for Kalina Cycle Studies (ACS Pu...

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Modeling the High-Pressure AmmoniaWater System with WATAM and

the PengRobinson Equation of State for Kalina Cycle Studies

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Enick,Robert
Robert
Enick,
M.

M.

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Robert M. Enick
Glenn P. Donahey , and Mike Holsinger
Department of Chemical and Petroleum Engineering, 1249 Benedum Engineering Hall, University of
Pittsburgh, Pittsburgh, Pennsylvania 15261
Ind. Eng. Chem. Res., 1998, 37 (5), pp 16441650
DOI: 10.1021/ie970638s
Publication Date (Web): March 19, 1998
Copyright 1998 American Chemical Society

Section:

Unit Operations and

Processes

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Abstract
The Kalina power cycle uses an ammoniawater mixture as the working fluid in the 283866 K

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History

temperature range and at pressures up to 22 MPa. Modeling of these cycles, typically

accomplished with a process simulator, requires accurate descriptions of the phase behavior
of this binary. Therefore 58 previously published Pxy isotherms in the 203618 K temperature
range were used to evaluate the predictive capabilities of the PengRobinson (PR) equation of

http://pubs.acs.org/doi/pdf/10.1021/ie970638s[27/03/2015 05:21:45 ]

Published In Issue: May 04, 1998

Received for review September 10, 1997
Revised manuscript received December 30,
1997

Industrial & Engineering Chemistry Research - Modeling the High-Pressure AmmoniaWater System with WATAM and the PengRobinson Equation of State for Kalina Cycle Studies (ACS Pu...

state (EOS) and WATAM. WATAM provided a much better correlation of saturated liquid

Accepted January 5, 1998

densities than the PR EOS. Although both models adequately correlated liquid phase
compositions, WATAM provided a better fit of the near-critical vapor phase data. The Peng
Robinson EOS consistently overestimated the mixture critical pressures. Several correlations,
based on different objective functions, for the temperature-dependent binary interaction
parameter were developed. Slight improvements in the predictive capabilities of the PR EOS
were realized using the Panagiotopolous and Reid composition-dependent mixing rule, which
required two temperature-dependent parameters. Temperature-dependent correlations for
each parameter were regressed from PTxy data. Guidelines for using the PR EOS in a
process simulator to model Kalina cycles were developed.

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Abstract | Full Text HTML | PDF | PDF w/ Links

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http://pubs.acs.org/doi/pdf/10.1021/ie970638s[27/03/2015 05:21:45 ]

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