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VINYL BROMIDE
FIRE
REACTIVE
OTHER
DEGREE OF HAZARD
0 = Minimum Hazard
1 = Slight Hazard
2 = Moderate Hazard
3 = Serious Hazard
4 = Severe Hazard
COLOR CODING
HEALTH = BLUE
FIRE = RED
REACTIVITY = YELLOW
OTHER = WHITE
OTHER CODES
OX = Oxidizer
ACID = Acid
ALK = Alkali
COR = Corrosive
W = Use No Water
RCRA Number
EPA Class
Halogenated Hydrocarbon
DOT Proper Shipping Name
None
Not Applicable
593-60-2
DOT Emergency Guide Code
Flammable Gas
60
Molecular Formula
UN 1085
CH2=CHBr
Synonyms
Bromoethene; bromoethylene.
PEL:
Not
Established
REL:
Reduce to
Lowest Level
STEL:
Not
Established
Possible
Human
Carcinogen
TLV:
5 ppm
22 mg/m3
Not
Determined
Suspected
Human
Carcinogen
60F (15.6C)
Vapor Pressure (mm Hg)
107.0
Melting Point
-219F (-104C)
3.7
Solubility
Colorless gas (or liquid below 60F) with a characteristic, pungent, but pleasant odor.
Not Established
LEL: 9%
NFPA Classification
UEL: 15%
Autoignition Temperature
986F (530C)
Extinguishing Media
Stop flow of gas. Use dry chemical, carbon dioxide, water spray, or regular foam.
Special Fire Fighting Procedures
Poisonous gases are produced in fire. Wear self-contained breathing apparatus (SCBA) and full protective
gear. Move containers from fire if it can be done without risk. Keep cooling sides of fire-exposed containers with water long after fire is out.
Unusual Fire and Explosion Hazards
Dangerous fire and explosion hazard. Containers may explode in fire. Stay away from the ends of tanks.
Vapors are heavier than air and can travel for great distances to an ignition source to flashback and cause
fire or explosion.
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Under normal conditions of handling and storage, vinyl bromide is considered stable in closed containers.
Avoid heat, flame, other sources of ignition, and contact with incompatible materials and chemicals.
Stability
Stable
Unstable
Conditions to Avoid
Hazardous
Polymerization
May Occur
Poisonous gases and acrid fumes are produced in fire, including carbon dioxide, carbon monoxide, and
toxic fumes of bromine.
Absorption (skin/eye)?
Ingestion?
X (liquid)
Health Hazards
INHALATION: Causes depression of the central nervous system (CNS) with symptoms of headache, vertigo, nausea, and drowsiness. High concentrations may cause loss of consciousness.
There may be decreased mental status and confusion. Possible liver and kidney damage.
SKIN & EYES: Irritation with possible redness and pain to the skin and eyes. Eye contact may result in
mild to moderate irritation and possible inflammation. The compressed gas can lead to
tissue damage (frostbite) on contact with the skin or eyes.
INGESTION:
Carcinogenicity
NTP Listed?
Suspected Human
Confirmed Animal
No
OSHA Regulated?
Target Organs?
No
Group 2A
None reported. However, liver, kidney, heart, and respiratory problems may be aggravated by exposure.
Emergency and First-aid Procedures
Eye contact: Do not allow victim to keep eyes tightly shut. Do NOT rub eyes. Flush immediately with
warm (tepid) water for 15 minutes (minimum); seek medical attention. Skin contact: Remove all contaminated clothing, including shoes. Immediately wash area with flooding amounts of warm (tepid) water for
15 minutes (minimum). Do NOT rub or use dry-blown heat on frostbitten tissue. Seek medical attention
immediately. For inhalation: Remove the person from exposure. Provide respiratory assistance and CPR.
Transfer to medical facility. If swallowed: Not a likely exposure route since vinyl bromide exists as a gas
at room temperature and pressure.
Remove all ignition sources, wear SCBA respiratory protection. Restrict those not involved in cleanup
from entering area. Stop flow of gas if it can be done without risk. Provide explosion-proof ventilation.
Absorb liquids with vermiculite and deposit in sealed containers.
Preferred Waste Disposal Method
No citation.
Precautions to be Taken in Handling and Storage
Store cylinders in cool, well-ventilated location. Keep away from sources of heat and sunlight.
Other Precautions and Warnings
Cylinders must always be stored upright and properly secured (around the body of the cylinder, never the
neck). Never drag or roll cylinders. Metal containers should be bonded and grounded.
No OSHA PEL established. For best protection, use a supplied-air respirator or a self-contained breathing
apparatus (SCBA) with full facepiece operated in positive pressure mode.
Ventilation
Eye Protection
Work/Hygiene Practices
Always wash hands thoroughly after using chemical; never bring food, drink, or smoking materials into
vicinity of chemicals.
1996 by CRC Press, Inc.
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VINYL BROMIDE
CH2=CHBr
CAS: 593-60-2
H
C
Br
Skin:
Irritation with potential for redness, pain, inflammation, and tissue damage (frostbite).
Eye:
As a gas, vinyl bromide is moderately toxic by inhalation. While absorption through the skin has not been
known to occur, skin contact can cause localized damage to tissues. Ingestion is rare but possible (liquid
threat only). Vinyl bromide is considered a suspected
human carcinogen and a confirmed animal carcinogen.
Mutation data have also been reported. Physiologically, it is an anesthetic and narcotic. The primary
human response to vinyl bromide is depression of the
central nervous system (CNS).
Inhalation causes some irritation of the eyes, nose,
and lungs. Symptoms of exposure and CNS depression include drowsiness, slurred speech, lack of coordination, and possible loss of consciousness.
Skin contact may cause localized burning at site of
contact as a result of frostbite damage. Eye contact
can result in severe irritation to the cornea, with redness and swelling. Damage can be serious if not immediately flushed from eye surface. Liver and kidney
damage have been reported in test animals.
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Personnel should avoid direct contact with vinyl bromide. The exact nature of it human toxicity has not
been clearly established. It is very possible that it is a
human cancer agent. Occupational poisoning occurs
most commonly by inhalation. If a less toxic material
or compound cannot be substituted for vinyl bromide,
then engineering controls are the most effective
method of reducing exposures. The best protection is
to enclose operations and/or provide local explosionproof exhaust ventilation at the site of vinyl bromide
release. While not always operationally feasible, isolating operations can also reduce exposure. Using respiratory protection is less effective than the controls
mentioned above, but is still advisable whenever
working with or around vinyl bromide. Caution
should be exercised when selecting respiratory protection since it is not known if exposure to vinyl bromide
will cause cancer in humans. The ACGIH has established a TLV of 5 ppm over an eight-hour period.
This level is extremely low and difficult to accurately
monitor. For exposures to high concentrations, or
when the concentration is unknown, use a supplied-air
respirator with full facepiece and mask operated in
positive pressure mode or a self-contained breathing
apparatus (SCBA) with full facepiece operated in pressure demand. If a full facepiece is not available, then
chemical goggles should be worn to protect the eyes.
A face shield should also be considered. To prevent
hand and skin exposures, impervious thermal gloves
should be worn.
Administrative controls should also be in place to
minimize the potential for human exposures. These
may include written procedures or policies which
specify the methods and techniques that will be practiced whenever personnel are to work with vinyl bromide.
All personnel should receive training on the use,
hazards, protective measures, emergency actions, and
other precautions per 29 CFR 1910.1200 (Hazard
Communication), prior to the first assignment in an
area where vinyl bromide is used or stored.
If symptoms develop or overexposure is suspected, the following recommended medical tests
should be considered:
Eye wash stations should be provided in the immediate work area for emergency use. If there is
a possibility of skin exposure to vinyl bromide,
emergency shower facilities should be provided.
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Some substances increase in concentration, or bioaccumulate, in living organisms as they breathe contaminated air, drink contaminated water, or eat contaminated food. These chemicals can become concentrated in the tissues and internal organs of animals
as well as humans.
The concentration of vinyl bromide found in fish
tissues is expected to be about the same as the average
concentration of vinyl bromide in the water from
which the fish was taken.
Proper training of all transporters will reduce the likelihood of a mishap or accident resulting in a leak or
spill of vinyl bromide into the environment. Labels on
all containers, trucks, and rail cars must meet DOT
requirements and accurately reflect their contents to
enable emergency responders to react properly and
quickly to any disaster thereby reducing the potential
risk to the environment and to personnel.
Storage of vinyl bromide should be segregated
from other chemicals and materials to minimize the
risk of cross-contamination. Cylinders must always be
stored upright and properly secured (always around
the cylinder body, never around its neck). Cylinders
must never be dragged or rolled during handling.
They must be kept away from heat and direct sunlight.
If a spill or leak to the environment has occurred,
fire department, emergency response and/or hazardous
materials spill personnel should be notified immediately. Cleanup should be attempted only by those
trained in proper spill containment procedures using
non-sparking tools. Contaminated soils should be removed for incineration and replaced with clean soil. If
vinyl bromide should contact the water table, aquifer,
or navigable waterway, time is of the essence. It may
be insoluble and remediation may be successful. The
local and/or state emergency response authorities must
be notified. A comprehensive emergency response or
disaster preparedness/recovery plan should be in place
prior to any operations involving the use, transportation, storage, or disposal of vinyl bromide.
If vinyl bromide is spilled or leaked, the following
specific steps are recommended:
6 Water Solubility
Vinyl bromide may be insoluble to slightly soluble in
the aquatic environment. Concentrations between 1
and 100 milligrams may mix with a liter of water.
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REFERENCES
Ahlbom, A. 1993. Biostatistics for Epidemiologists. New York: CRC
Press/Lewis Publishers.
American Conference of Governmental Industrial Hygienists. 1988.
Documentation of the Threshold Limit Values and Biological Exposure Indices, 5th Edition (with updates). Cincinnati: ACGIH