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DOI 10.1007/s10948-014-2725-7
ORIGINAL PAPER
Received: 7 June 2014 / Accepted: 18 August 2014 / Published online: 3 September 2014
Springer Science+Business Media New York 2014
2 Experiment
1 Introduction
Ba1x Kx BiO3 (BKBO) is a very interesting superconductor
with transition temperature (Tc ) about 30 K because it has
three-dimensional ABO3 perovskite structure and no transition metal elements. [1] The atoms at the A site (such as
H. Zhang X. Lin G. Li () F. Liao J. Lin ()
Beijing National Laboratory for Molecular Sciences,
State Key Laboratory of Rare Earth Materials Chemistry
and Applications, College of Chemistry and Molecular
Engineering, Peking University Beijing 100871,
Peoples Republic of China
e-mail: liguobao@pku.edu.cn
e-mail: jhlin@pku.edu.cn
Y. Zheng S. Li
Beijing National Day School, Beijing 100039,
Peoples Republic of China
460
samples were obtained also from JEM2100F with an accelerating voltage of 200 KV. Magnetic susceptibility was
measured in the temperature range between 5 and 50 K
by SQUID magnetometer (Quantum Design MPMS) in an
applied magnetic field of 100 Oe. Resistance of selected
sample was measured between 2 and 50 K by physical
property measurement system (PPMS).
Fig. 2 SAED patterns along different directions (ae) and the Rietveld plot of X-ray diffraction data (f) of BBP11
461
b = 8.5110 (3) A,
a = 6.0285 (3) A,
c = 6.06523 (3) A
b = 8.5293 (3) A,
a = 6.0417 (3) A,
c = 6.06867 (3) A
Space Group
Ba1
Ba2
Pb/Bib
Pb/Bib
O1
O2
O3
O4
O5
O6
R factorc
Imma
0.0000, 0.2500, 0.5028 (3)
Imma
0.0000, 0.2500, 0.5017 (3)
BBP10
Phase B
b = 6.0526 (3) A
a = 6.0367 (3) A,
= 59.76 (2)
c = 6.0560 (3) A,
= 60.16 (2) , = 60.13 (2)
P1
0.2503 (3), 0.2479 (3), 0.2670 (3)
0.7496 (3), 0.7458 (3), 0.7682 (3)
0.0000, 0.0000, 0.0000
0.4995 (3), 0.5018 (3), 0.4986 (3)
0.3505 (3), 0.1532 (3), 0.6732 (3)
0.8041 (3), 0.7332 (3), 0.2402 (3)
0.7675 (3), 0.2560 (3), 0.2326 (3)
0.2522 (3), 0.8125 (3), 0.6864 (3)
0.1922 (3), 0.7578 (3), 0.2513 (3)
0.6807 (3), 0.2545 (3), 0.7639 (3)
a The
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Fig. 4 SAED patterns along different direction indexes in orthorhombic (a1, a2, a3, a4, and a5) and triclinic (b1, b2, b3, b4, and b5) lattice, and
the Rietveld plot of X-ray diffraction data (c) for BBP9
Similarly,
BBP9 may also be tetragonal [10] (I4/mcm,
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Fig. 6 The temperature-dependent magnetic susceptibilities and shielding volume fraction of BBP8 (a), BBP9 (b), BBP10 (c), and the temperature
dependent resistance of BBP9 (d)
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Fig. 7 The Rietveld plot of X-ray diffraction data (a), the temperature-dependent magnetic susceptibilities (b), the EDS of two kinds of particles
(c, d) of BBP1K
3.2.1 BBP1K
The Rietveld refinement of the X-ray diffraction data of
BBP1K indicates that there are three phases in BBP1K
as shown in Fig. 7a. They all crystallize in space group
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these samples exhibiting superconductivity with Tc decreasing from 25 K for BBP2k to 15 K for BBP6K, which is
shown in Fig. 8.
3.2.3 BBP7K to BBP9K
Fig. 8 The Rietveld plot of X-ray diffraction data (a) of BBP3K, the EDS of BBP3K (b), the temperature dependent magnetic susceptibilities of
BBP2K (c), BBP3K (d), BBP4k with zero-field cooling and 100 Oe field cooling (e), BBP5K (f), BBP6k (g)
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Fig. 9 The Rietveld plot of X-ray diffraction data (a) of BBP7K, the EDS of BBP7K (b), the temperature-dependent magnetic susceptibilities of
BBP7K (c), BBP7K-500 (treated again at 500 C for 4 h) (d), BBP8k (f), BBP9K (g), and the temperature dependent resistance of BBP7k-500 (e)
Fig. 10 The volume of unit cell (a) of the phases in the samples and transition temperature Tc (b) found in the samples
confirmed by magnetic measurement to show superconductivity as shown in Fig. 9d. The temperature-dependence
resistant of BBP7K-500 confirmed that BBP7K-500 was
superconductor with Tc at 11 K.
4 Summary
The series of BaBi1y Pby O3 (0 . y . 1) has
been synthesized by solid-state reaction. X-ray and
selected area electron diffraction data confirm that
BaBi1y Pby O3 (0 . y . 0.88) crystallizes in space
group P1 and BaBi1y Pby O3 (0.93 . y . 1) crystallizes in space group Imma. The samples with the nominal formula BaBi1y Pby O3 (y = 0.70, 0.80, 0.90) shows
superconductivity with transition temperature (Tc ) around
11 K. When BaBi1y Pby O3 (0 . y . 0.80) was treated
with KOH and KF at 450 C, the corresponding samples with the nominal formula Ba1x Kz Bi1y Pby O3 were
obtained. The corresponding reaction is found to be topotactic because the topological structure of BaBi1y Pby O3 and
Ba1x Kz Bi1y Pby O3 is the same.
The sample Ba1x Kz BiO3 (BBP1K) consists of three
phases, which may all crystallize in space group P1. Two
of them do not contain K, and the third phase contains K which may be contributor of the superconductivity
with Tc around 30 K found in this sample. The samples Ba1x Kz Bi1y Pby O3 (y = 0.1, 0.2, 0.3, 0.4, and 0.5,
noted as BBP2K, BBP3k, BBP4K, BBP5K, and BBP6K,
respectively) consist of two-phase crystallizing in space
group P1. The EDS data show that there is no K in the
samples, which mean that the samples can be noted as
Ba1x Bi1y Pby O3. The decrease of the volume of unit cell
shown in Fig. 10 agrees well with this suggestion. Superconductivity with Tc around 20 K is found for these samples, which means that new superconductors may appear,
because as we know, there is no report on such materials. More work is needed to confirm this observation. The
samples Ba1x Kz Bi1y Pby O3 (y = 0.6, 0.7, and 0.8, noted
as BBP7K, BBP8k, and BBP9K, respectively) consist of
one-phase crystallizing in space group P1. No K is found
in these samples by EDS data. Superconductivity with Tc
about 11 K was confirmed for BBP7K.
Acknowledgments This work is supported by the National Key
Basic Research Project of China (2010 CB833103) and the National
Natural Science Foundation of China (Grant 21271014).
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