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a r t i c l e i n f o abstract
Article history: Fires and especially pool fires are among the most frequent accidents in process facilities. Flame
Received 17 June 2011 impingement and thermal radiation are the main hazardous characteristics of pool fires. Pool fires have
Received in revised form been the subject of numerous modeling and experimental studies covering a variety of areas such as
4 November 2011
fire and flame structure, emissive power, temperature distribution and fire characteristics. The effects
Accepted 14 November 2011
Available online 27 December 2011
of environmental parameters such as wind velocity, humidity and water/ice droplets in the air have not
been studied extensively. Further, the effect of surrounding surface reflectivity has not been studied.
Keywords: This issue is very important for cold regions like the Arctic, where outdoor surfaces are covered with
Absorption snow and ice for several months of the year. Furthermore, there is no comprehensive fire consequence
Arctic
modeling tool that includes pool fire development, environmental characteristics effects and thermal
Pool fire
radiation. This study proposes a new comprehensive model for steady state and fully developed pool
Surface reflectivity
fires. This new model takes into account the effects of environmental variables such as temperature, the
presence of droplets and surface reflectivity on thermal radiation and subsequently on the fire
consequence assessment.
& 2011 Elsevier Ltd. All rights reserved.
0379-7112/$ - see front matter & 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.firesaf.2011.11.003
2 G. Keshavarz et al. / Fire Safety Journal 48 (2012) 1–10
direct-downward spray is not the optimum direction and the 2.1. Fay model
efficiency of extinction increases as spray direction goes toward
horizontal [19]. Chen et al. [20] studied the effect of the initial fuel This model is a two zone pool fire model that describes
temperature on the burning rate and burning states of pool fires. flame properties, combustion and plume zones. The combustion
Their experimental study shows that the duration of steady zone begins from the base of the fire and goes up to the end
burning decreases as the initial temperature of the fuel increases. of the visible flame. In this zone the evaporated fuel vapor reacts
Furthermore, if the initial fuel temperature reaches the boiling with air in stoichiometric proportions and forms combustion
temperature, there would not be a steady burning period. products. When fuel evaporates from the pool surface, it enters
Ravigururajan [21] has proposed a method to calculate the effect a circulation region. Fuel vapor flows radially toward the edges
of water/ice droplets on thermal radiation attenuation. of the pool fire and then moves upward and inward towards
Despite numerous works investigating pool fires, the effect of the flame tilt in the center line. A portion of fuel vapor moves
environmental variables has not been comprehensively studied. downward towards the liquid surface and hence the circulation
In most of the studies only a single environmental parameter has is completed. This fuel circulation provides fuel vapor for the flame
been considered. The combination of these environmental variables surface. Fuel vapor and air diffuse, respectively, outward and inward
will affect the consequences of any pool fire, especially in the Arctic and intersect each other on the flame surface, where reaction occurs
region, as these parameters coexist and affect the behavior and and heat is released. The released heat results in a temperature
thermal radiation of a pool fire. In this study a new model is increase and density reduction, and subsequently the upward
developed that takes into account environmental parameters, diffusion and bulk movement of products. The low density and high
including temperature, wind, the presence of droplets and surface temperature products enter the plume zone. The plume zone is
reflectivity. The Fay model [11] was used as the base for the model. above the combustion zone and rises until temperature significantly
This model has the advantage of a continuous temperature distribu- decreases and produced gases dilute.
tion. Furthermore, it also includes the effect of water/ice droplets Temperature and fuel concentration distribution are functions of
and surface reflectivity. Therefore, the proposed model accounts for the mixing process. If mixing is diffusion driven and laminar, oxygen
all environmental variables related to the Arctic. and fuel vapor diffuse and reaction occurs. For this case, the flame
surface is thin and the temperature is almost equal to the adiabatic
flame temperature. Since the phenomenon is laminar, the changes
2. Pool fire modeling of temperature and combustion products concentration are sudden,
where both temperature and combustion products’ concentration
The flame of pool fires is typically nonuniform in temperature increase rapidly in a thin layer. In contrast to laminar and diffusive
and species concentration distribution in terms of three-dimen- flames, the rapid mixing ensures the temperature change is smooth
sional calculations; therefore, modeling of pool fires is challen- due to turbulence. Hence the flame surface temperature is lower
ging. Pool fire models are generally classified into two groups; the and flame surface thickness is greater compared to the laminar
simplest model assumes thermal radiation controls fuel evapora- regime. Details and equations can be found in Fay’s work [11].
tion. These models do not account for combustion and air As Fig. 1 illustrates, the Fay model is a simple, quick and direct
entrainment in their calculations; rather, they calculate radiation approach for pool fire modeling. This model requires fuel proper-
based on flame temperature, size and shape. Orloff [15] presented ties like heating value and heat of evaporation, stoichiometric
such a model to calculate the radiation of pool fires. In contrast to ratios, pool size, wind and the environment’s temperature.
simple models, fundamental models prescribe the fire behavior Although this model has been verified and calibrated against
based on air entrainment, mixing, combustion, flow and plume the results of field tests and has acceptable accuracy, there are
rising. Fay [11] has recently proposed such a model for a wide some limitations that, if overcome, will result in a better and
variety of pool sizes and wind velocities. more comprehensive model.
G. Keshavarz et al. / Fire Safety Journal 48 (2012) 1–10 3
written as
Fuel type and pool size
qz ¼ C p T z o_rAc ð5Þ
the absorption coefficient of air and subsequently reduce the This equation can be substituted in Eq. (16) to obtain the final
intensity of radiation. Temperature, wavelength, size and mass form of the thermal radiation equation:
per volume of the droplets are the main parameters that affect the 0 1 0 1
absorption coefficient [23,24]. As the emission from water/ice Z Aob !! ! !
1 n :di n : di r
droplets is much smaller than the energy that they absorb [25], q00 ¼ eðdi,TÞ@ 3 A þrf eðdir ,TÞ@ A dA ð24Þ
4 0 di dir 3
thermal radiation from the droplets has not been taken into
calculations. So far a model has been developed that is capable of including
The absorption coefficient and reflection index of ice and the environmental parameters effects on the behavior of pool
water/ice droplets for a variety of temperatures and wavelengths fires. Fig. 2 presents the sequence of steps for the proposed model.
have been provided in Refs. [24,26–28]. The absorption coeffi- The main environmental parameters for the Arctic region are
cients of ice and water/ice droplets vary significantly with snow/ice covered surfaces and droplets. In the next section we
wavelength. On the other hand, wavelength also determines will see how these two parameters can affect the thermal
radiation energy: radiation intensity from a pool fire. The quantitative comparison
between the proposed method and the Fay model is explained
2hc2 1 2hc2 hc through a pool fire modeling case study. Here, we use a pool fire
el ¼ exp ð17Þ
l5 exp ðhcÞ=ðlkU TÞ 1 l5 lkU T of gasoline with 1.4 m diameter to illustrate these models. The
assumption is that there is no wind.
where h, c and kU are Planck’s constant (6.62 10 34 J s), the
speed of light (3 108 m/s) and Boltzmann’s constant
(1.38 10 23 J/K), respectively. A differentiation of this equation 3. Results and discussion
(17) determines which wavelengths contribute more to energy
transfer: 3.1. Results
hc 1 2897
lmax ¼ , lmax ðmmÞ ¼ ð18Þ The Fay model was revised and extended to include the effect
5kU T T
of environmental parameters like surface reflectivity and the
In the present model, the interval of thermal radiation wave- presence of water/ice particles. As mentioned by Fay [11], his
length, 10 8–10 3 m, is divided into Nw wave bands and attenua- model is discontinuous at Z¼Lc. An example of this discontinuity
tion is calculated for each band. The widths of these bands are not has been shown in Fig. 3 for the purpose of illustration. The main
equal and reduce as wavelength becomes closer to lmax. For each reason for this discontinuity is that vertical energy transport due
wavelength band, one needs to calculate the absorption coeffi- to mass movement has not been considered in the combustion
cient of air. Assuming that mass per volume of droplets in the air zone and subsequently this zone has a constant temperature. The
is md and that droplets have a Gaussian distribution with mean initial temperature of the plume zone depends on the coefficients;
and variance values m and s2, respectively, for any wave band like particularly Zp Fig. 3 shows temperature in the plume zone for
the jth with average wavelength lj, the corresponding absorption three different Zp. The major issue of using the Fay model is that
G. Keshavarz et al. / Fire Safety Journal 48 (2012) 1–10 5
950
Fuel type and pool size Fay model
900 New model
850
Mass burning rate
800
Temperature (K)
Fuel Froude number 750
700
Wind velocity effect
650
600
Modified temperature of the combustion zone
550
500
Temperature, mass flux and velocity of the plume zone
450
0 0.5 1 1.5 2 2.5 3 3.5
Height (m)
Surface reflectivity and droplets effect
Fig. 4. Temperature distribution for different models: Fay model (1) and new
model (2).
Thermal radiation to receiver
55
(1)
Fig. 2. Solution steps of the proposed model. Thermal Radiation (KW/Square meter) 50 (2)
45
1000
40
(1)
900 (2) 35
(3)
30
800
25
Temperature (K)
20
700
15
600 10
5
500 1.5 2 2.5 3 3.5 4 4.5 5
Radial Distance (m)
400
Fig. 5. Comparison of thermal radiation predicted by Fay model (1) and the
proposed model (2) at height 1.0 m.
300
0 0.5 1 1.5 2 2.5 3 3.5
Height (m)
Furthermore, the radiation equation that has been used in the
Fig. 3. Temperature distribution for the Fay model; very small Zp (1), small Zp Fay model uses an average temperature and ultimately under-
(2) and medium Zp (3). Temperature is discontinuous at the intersection of zones. predicts the radiation flux. Thermal radiation fluxes for both
models have been compared in Fig. 5. The difference is higher
near the pool fire and as the radial distance increases this
there is no specific value or method to obtain Zp and, as Fig. 3 difference is reduced.
shows, temperature highly depends on this parameter. Another major limitation in the Fay model is not considering
To avoid these issues of discontinuity in the temperature and radiation from the plume zone as it cannot account for radiation
not having the exact value of Zp, the temperature profile in the where the temperature profile is not constant. Neglecting the
combustion zone has been modified (Fig. 4). Hence the value of Zp plume zone might be reasonable when the height of the combus-
is calculated based on continuity of mass and energy at the tion zone is large or when the target is near the ground. However,
intersection of the combustion zone and the plume zone. The for the cases where the target is high, radiation from the plume
new distribution of temperature is the result of considering heat zone cannot be neglected. The thermal radiation flux of the plume
transfer between different heights in the combustion zone. zone that has been calculated by the proposed model is shown in
As temperature is continuous, the initial temperature of the Fig. 6. This figure clearly illustrates that the plume zone
plume zone is set equal to the temperature at the end of contributes more at higher heights, although the total radiation
combustion zone. from this zone might be small compared to that of the combus-
In Fig. 4 the integrals of temperature curves for both models, tion zone. Fig. 7 demonstrates the percentage of plume zone
the Fay model and the present model, are the same and the total contribution compared to total radiation flux that a target
released energy is the same for both cases. However in the receives. This figure shows that plume zone contribution for
present model, the temperature is low near the pool surface and higher heights is more important compared to lower heights.
it increases with height as the released energy rate increases and Therefore, neglecting radiation from the plume zone results in
energy is transferred upward due to hot gases movement. severe underestimating of radiation flux at large heights.
6 G. Keshavarz et al. / Fire Safety Journal 48 (2012) 1–10
3 5
Height (m)
2.5 0.5 4
1.5
2
3
2
2.5
2
1.5
3
1
1
0.5
0
1 .5
0.5 0 2 4 6 8 10 12
2
16
or far away from the pool fire. The reason for this small
4
contribution is that at short distances the reflection has a very
3.5 large angle and the second part of Eq. (16) becomes negligible.
Finally the difference reduces as radial distance increases.
14
Height (m)
3
12 We expect that the contribution of reflection reduces as the
18
16
2.5 height increases. The reason for this behavior is that both the
12 reflection angle and distance increase with height. However, this
2
14 is not always the case and near the surface at approximate height
12
1.5 of 0.4–0.7 m, as shown in Fig. 9, the reflection contribution
12 increases slightly. This behavior is due to radiation from the top
1
of the combustion zone, from the bottom of the plume zone and
0.5 reflected thermal radiation. Except for the slight growth in the
10
reflected thermal radiation, the reflection contribution reduces as
2 3 4 5 6 7 8
height increases. A comparison between Fig. 10a and b shows that
Radial Distance (m)
the thermal radiation distribution changes significantly with
Fig. 7. Precentage of plume zone contribution in the total radiation flux. reflection.
The proposed model was further extended to include the effect
of water/ice droplets. The introduction of droplets into air reduces
the transparency of air, increases the extinction coefficient of air
Fig. 7 also illustrates that as the radial distance increases, the and subsequently results in higher attenuation of thermal radia-
influence of the plume zone decreases and the combustion zone tion flux. The attenuation depends on parameters such as pool fire
dominates the thermal radiation flux. At large radial distances, temperature and wavelength, and droplet kind, size, distribution
even for large heights, the radiation from the plume zone and mass concentration in air. Here the effect of droplet size,
becomes negligible compared to the combustion zone. In this distribution, mass concentration and droplet kind (water or ice)
case, the radiation angle and the distance to the target become has been examined.
almost the same for both the plume and combustion zones. Fig. 11 presents the thermal radiation flux for several cases. In
this figure, variance is considered zero (all droplets have the same
3.2. Surface reflectivity size in each case). The mass concentration for Cases 2–4 is the
same. As shown in Fig. 11, large droplets have a negligible effect
The plume zone’s share of thermal radiation is small compared on thermal radiation (comparing Cases 1 and 2). However, as the
to that of the combustion zone and neglecting it results in droplet size reduces the attenuation increases, and for small
underestimation of thermal hazards. Therefore, plume zone droplets the attenuation of radiation is rapid (Case 4).
radiation has been considered in all subsequent sections. After Fig. 12 demonstrates the effect of droplets’ size distribution on
correcting the temperature distribution and including the plume thermal radiation. As the variance increases, thermal radiation
zone in thermal radiation, we may investigate the effect of surface reduces more due to the presence of smaller particles in air. It
reflectivity on thermal radiation. The Fay model does not account must be noted that as the mean size of droplets reduces, variance
for this parameter or we can say that the surface reflectivity is becomes more important.
0 for this model. For a snow and ice covered surface, the surface The relationship between the attenuation coefficient and the
reflectivity may be as high as 0.93. mean size of droplets is observed to be an inverse relationship.
In Fig. 8, the difference in thermal radiation flux predicted Eq. (21) indicates a direct relation between mass concentration
by the Fay model and the proposed model is shown and and the attenuation coefficient. Fig. 13 shows that as mass
illustrates that as surface reflectivity increases, the Fay model concentration increases, thermal radiation decreases.
G. Keshavarz et al. / Fire Safety Journal 48 (2012) 1–10 7
5 0.
5
0.5
4.5 1
1
4
3.5
1
Height (m) 3 2
1
2.5
2
2 2
4
1
1.5
1
10
4
12
0.5
2
2 3 4 5 6 7 8 9 10 11 12
Radial DIstance (m)
Fig. 9. Reflection contribution in the thermal radiation when surface reflects the radiation (reflectivity index is 0.9).
5 5
5
5
2
2
4.5 4.5
5
4 4 10
10
3.5 3.5
Height (m)
Height (m)
5
3 3
2
2.5 2.5
10
10
5
2 2
1.5 1.5
5
1 1
2
50
50
100
100
10
10
0.5 0.5
5
2 3 4 5 6 7 8 9 10 11 12 2 3 4 5 6 7 8 9 10 11 12
Radial Distance (m) Radial Distance (m)
Fig. 10. Thermal radiation flux when (a) surface reflectivity index is 0.0 and (b) surface reflectivity is 0.9.
60 35
(1) (1)
Thermal Radiation (KW/Square meter)
(2) (2)
Thermal Radiation (KW/Square meter)
30 (3)
50 (3)
(4) (4)
25
40
20
30
15
20 10
5
10
0
0 2 2.5 3 3.5 4 4.5 5
2 2.5 3 3.5 4 4.5 5 Radial Distance (m)
Radial Distance (m)
Fig. 12. Effect of droplet diameter distribution on thermal radiation extinction; for
Fig. 11. Attenuation of thermal radiation flux for different droplets sizes: no all cases the mean diameter is 5m and distribution is Gaussian: s2 ¼ 0.0 (1) (all
droplet in air (1), very large droplets (D ¼ 400m) (2), large droplets (D ¼100m) droplets have the same diameter), s2 ¼1.0 (2), s2 ¼ 2.0 (3) and s2 ¼ 5.0 (4).
(3) and medium droplets (D ¼ 20m) (4).
Fig. 14 shows the impact of water droplets on thermal radia- increases gradually with the radial distance until reaching a peak
tion. Case 1 refers to the presence of water droplets in air while in and then decreases. Over long distances the difference reduces
Case 2 there are no water droplets. At each height, the difference since the thermal radiation of both cases decreases significantly.
8 G. Keshavarz et al. / Fire Safety Journal 48 (2012) 1–10
60 4
-4
(1)
Thermal Radiation (KW/Square meter)
(2)
50 (3) 3.5
(4) -6
(5) 3
40 -6
2.5
Height (m)
-4
-6
30
2
20
1.5
-2 -4
10 0 -6
1
0 0.5
2 2.5 3 3.5 4 4.5 5 8 6 4 2 0 -2 -4 -6
Radial Distance (m) 2 2.5 3 3.5 4 4.5 5
Radial Distance (m)
Fig. 13. Effect of droplet mass concentration on the attenuation of thermal
radiation: md ¼5 g/m3 (1), md ¼ 10 g/m3 (2), md ¼ 20 g/m3 (3), md ¼40 g/m3
Fig. 15. Difference in received thermal radiation (Case 1–Case 2), md ¼10 g/m3,
(4) and md ¼ 80 g/m3 (5).
D¼ 50m and ref. ¼0.9 for Case 1.
4 -5
-5 -5.5 45
.5
-4
-4 (1)
5 -5.5
3.5 -5. -6
40 (2)
-7
30
5
-7
Height (m)
2.5
-5.
-7.5
25
5
-6.
.5
-7
-7
-6
2 20
-8
15
-7.
1.5
-8
10
1
-6.5
-7.5
5
-8
-7
-6
0.5 0
2 2.5 3 3.5 4 4.5 5 2 2.5 3 3.5 4 4.5 5
Radial Distance (m) Radial Distance (m)
Fig. 14. Difference in received thermal radiation (Case 1–Case 2), md ¼ 10 g/m3, Fig. 16. Effect of different type of droplets on the thermal radiation extinction:
D ¼50m. For this case the surface reflexivity has not been considered. water droplets (1) and ice droplets (2).
-4
3.5 dA in this integral is equal to
-2
-6
1.5 -2
0 cosðyÞcosðjÞdA ¼ di2 cosðyÞcosðjÞdy dj ¼ 4di2
2 0 ðp=2Þ ðp=2Þ
1 -4
ðA:5Þ
4
-6
6
-2
8
2
Appendix B
extended to account for surface reflectivity and the presence of
water/ice particles in air. As a result, the proposed model is For a Gaussian distribution, the Probability Density Function
effective in a region like the Arctic, where surface reflectivity and (PFD) can be shown to be
!
the presence of droplets are the main environmental parameters. 1 ðxmÞ2
The proposed model was expanded to account for radiation f ðxÞ ¼ pffiffiffiffiffiffiffiffiffiffiffiffi exp ðB:1Þ
2ps2 2ps2
from the plume zone. Although the thermal radiation from this
zone is small compared to the combustion zone, the plume zone where m presents the mean value and s2 determines the width of
still has an important role, especially for large heights. The model distribution. ‘‘s2 equals 0’’ mathematically means that all the
also includes thermal radiation reflection from the surrounding droplets have the same diameter m. Then we have
surfaces. The model evaluates the presence of water/ice droplets
4prd 3
in air. All these modifications/extensions are important for fire md ¼ rd V d ¼ N m ðB:2Þ
3
risk assessment in cold regions.
The results show that thermal radiation increases significantly where Vd is the occupied volume by droplets and N is the number
near the surface due to reflection. However, droplets will have the of droplets per unit volume. Finally
opposite effect. For the Arctic region, where surface and droplets 3md
act simultaneously, thermal radiation is expected to be higher at Ad ¼ Npm2 ¼ ðB:3Þ
4rd m
short distances and less for large distances. However, these
distances are related to the diameter and height of the pool fire,
fuel type, surface reflectivity index, droplet size and distribution
and the mass concentration of droplets. Results show that there References
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