Professional Documents
Culture Documents
FULL TEST
Time : - 3 Hours
1.
Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Point Pen. Use
of pencil is strictly prohibited.
2.
Answers are to be given on Response Sheet provided at the end of this paper. You can tear this Response
Sheet along the cut marks provided. Fill in the particulars carefully in the Response Sheet provided.
3.
4.
The Test Booklet consists of 180 questions. The maximum marks are 720.
5.
6.
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9.
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11. Once you have evaluated the test, you should assess it thoroughly.
SECTION 1 - PHYSICS
1.
(c)
S
r r3
S2 r 3
r
(b)
r r3
S
(d)
r r3
S
2.
3.
(a) 7
(b) 6
(c) 12
(d) 2
A sample of ideal monoatomic gas is taken round
the cycle ABCA as shown in the figure. The work
done during the cycle is
7.
8.
9.
B (4P,3V)
P
C (P,3V)
t
A
(P,V)
10.
4.
(a) 3 PV
(b) zero
(c) 9 PV
(d) 6 PV
The escape velocity for a body projected
vertically upwards from the surface of earth is
11 km/s. If the body is projected at an angle of 45
with the vertical, the escape velocity will be
(a) 22 km/s
(b) 11 km/s
(c)
5.
6.
11
2
km/s
11.
(d) 11 2 km/s
u2
g
(c)
2u 2
g
(b)
u2
4g
(d)
u2
2g
(a)
T1 - T2
T1
(b)
T2 - T1
T2
(c)
T1 - T2
T2
(d)
T1
T2
10 mF
20 W
20 V
12.
(a) < 2 mJ
(b) 2 mJ
(c) > 2 mJ
(d) None of these
In which of the following Bohrs orbit n in a
hydrogen atom emits the photons of lowest
frequency ?
3
(a) n = 4 to n = 3
(b) n = 2 to n = 1
(c) n = 4 to n = 2
(d) n = 3 to n = 1
13. A wheel having moment of inertia 2 kg-m2 about
its vertical axis, rotates at the rate of 60 rpm
about this axis, The torque which can stop the
wheels rotation in one minute would be
(a)
p
N-m
18
(b)
2p
N-m
15
p
p
N-m
N-m
(d)
15
12
Photoelectric effect shows
(a) wave like behaviour of light
(b) paritcle like behaviour of light
(c) both wave like and particle like behaviour
(d) Neither wave like nor particle like behaviour
of light
The K.E. of one mole of an ideal gas is E = (3/2)
RT. Then Cp will be
(a) 0.5 R
(b) 0.1 R
(c) 1.5 R
(d) 2.5 R
A triangular block of mass M with angles 30,
60 and 90 rest with its 30 90 side on a
horizontal table. A cubical block of mass m rests
on 60 30 side. The acceleration which M must
have relative to the table to keep m stationary
relative to the triangular block is (assuming
frictionless contact)
(c)
14.
15.
16.
(a) g
(b)
(c) 4/10 A
(d) 7/10 A.
19. The force between the two short electric dipoles,
separated by a distance r, varies as
(a) r2
(b) r3
4
(c) r
(d) r4
20. If R is universal gas constant, the amount of
heat needed to raise the temperature of 2 moles
of an ideal monoatomic gas from 273 K to 373 K,
when no work is done, is
(a) 100 R
(b) 150 R
(c) 300 R
(d) 500 R
21. A block B of mass 4 kg is placed on a rough
horizontal plane. A time dependent horizontal
force f = kt acts on the block, k = 2 N/s2. The
frictional force between the block and the plane
at t = 2 sec is ( = 0.2)
(a) 4N
(b) 8 N
(c) 12 N
(d) zero
22. In a transformer, number of turns in the primary
coil are 140 and that in the secondary coil are
280. If current in primary coil is 4 A, then that in
the secondary coil is
(a) 4 A
(b) 2 A
(c) 6 A
(d) 10 A
23. A closed spherical surface of radius R encloses
an electric dipole. The net electric flux through
the surface is
R
g/ 2
(d) g / 5
g/ 3
17. The condition for obtaining secondary maxima
in the diffraction pattern due to single slit is
(c)
(a)
a sin q = nl
l
2
nl
(c) a sin q = ( 2n - 1) l (d) a sin q =
2
18. Seven resistances, each of value 20 W, are connected to a 2 V battery as shown in the figure.
The ammeter reading will be
2V
A
(a) 1/10 A
(b) 3/10 A
(a) zero
(c)
q
e0
+q
(b) 2q.4pR2
(d)
2q
e0
27.
28.
29.
30.
31.
32.
33.
34.
35.
mvM
M+m
(a)
momentum =
(b)
kinetic energy =
(c)
momentum =
(d)
kinetic energy =
m V2
2
36.
mV (M + m)
M
m2 v2
2 (M + m)
4
(c) 1.256 10 V
(d) 6.28 10 5 V
The average kinetic energy of a molecule of a
perfect gas is
(a) (2/3) K T
(b) 1.5 K T
(c) 2.5 K T
(d) None of these
A ray of monochromatic light suffers minimum
deviation of 38, while passing through a prism
of refracting angle 60. Refractive index of the
prism material is
(a) 2.4
(b) 0.8
(c) 1.3
(d) 1.5
In a circuit, containing a resistance R and a
capacitance C, if the frequency f of impressed ac
increases, the impedance Z of circuit will
37.
(a) decrease
(b) increase
(c) remain constant
(d) first decrease and then increase
Two bodies of masses 10 kg and 100 kg are
separated by a distance of 2m ( G = 6.67 1011
Nm2 kg2). The gravitational potential at the mid
point on the line joining the two is
(a) 7.3 107 J/kg
(b) 7.3 109 J/kg
9
(c) 7.3 10 J/kg
(d) 7.3 106 J/kg
For a given material, the Youngs modulus is 2.4
times that of rigidity modulus, the Poissions ratio
is
(a) 0.2
(b) 0.4
(c) 1.2
(d) 2.4
A particle executes S.H.M. having time period T,
then the time period with which the potential
energy changes is
(a) T
(b) 2 T
(c) T/2
(d)
A bar magnet of magnetic moment M is placed
in the magnetic field B . The torque acting on
the magnet is
(a)
MB
(b)
MB
1
MB
(d) M + B
2
Figure shows a capillary rise H. If the air is blown
through the horizontal tube in the direction as
shown, then rise in capillary tube will be
(c)
38.
39.
(a) = H
(b) > H
(c) < H
(d) zero
If red light and violet light rays are of focal
lengths f R and f V respectively, then which
one of the following is true ?
(a)
lR l V
(b)
mR > mV
(c)
mR = mV
(d)
mR < mV
5
40. A soap bubble has radius r and volume V. If the
excess pressure inside the bubble is P. Then PV
is proportional to
(a) r
41.
42.
43.
44.
45.
(b)
(a)
r2
(c) r 3
(d) r 4
The materials suitable for making electromagnets
should have
(a) high retentivity and low coercivity
(b) low retentivity and low coercivity
(c) high retentivity and high coercivity
(d) low retentivity and high coercivity
The photo electric work function for a metal
surface is 4.125 eV. The cut-off wavelength for
this surface is
(a) 4125 A
(b) 3000 A
(c) 6000 A
(d) 2062 A
In a n-p-n transistor
(a) holes move from emitter to base
(b) negative charge moves from emitter to base
(c) holes move from base to collector
(d) negative charge moves from collector to
base
Ground waves are polarised
(a) Parallel to the earth's surface
(b) normal to the earth's surface
(c) at an angle 45 from earth's surface
(d) in any direction.
The logic behind NOR gate is that it gives
(a) high output when both inputs are low
(b) high output when both inputs are high
(c) low output when both inputs are low
(d) None of these
SECTION 2 - CHEMISTRY
46. Huckel's rule states that a monocyclic
conjugated compound will be aromatic if it
contains
(a) (4n + 2p) electrons
(b) (4p + 2n) electrons
(c) 4p electrons
(d) (4n + 2)p electrons
47. Which of the following is optically inactive?
H
H 3C
Cl
Cl
H3C
CH3
Cl
Cl
CH3
(b)
Cl
Cl
(c)
H 3C
H 3C
H
48. EAN of cobalt is 36 in [Co(NH3)2O2(en)Cl].
Thus, O2 is
(a) dioxide
(b) superoxide ion
(c) peroxide ion
(d) oxide
49. Chromyl chloride oxidises toluene to
benzaldehyde, this reaction is known as
(a) Rosenmund reaction
(b) Wurtz reaction
(c) Etard reaction
(d) Fittig reaction
50. If 0.1 M of a weak acid is taken, and its percentage
of degree of ionization is 1.34%, then its
ionization constant will be :
(a) 0.8 105
(b) 1.79 105
5
(c) 0.182 10
(d) none of the above
51. An organic compound X (molecular formula
C6H7O2N) has six carbon atoms in a ring system,
two double bonds and a nitr o group as
substituent, X is
(a) Homocyclic but not aromatic
(b) Aromatic but not homocyclic
(c) Homocyclic and aromatic
(d) Heterocyclic and aromatic
52. In which of the following regions hydrogen and
helium are found
(a) Stratosphere
(b) Mesosphere
(c) Exosphere
(d) Troposphere
53. Milk of magnesia is
(a) Mg (OH) 2
(b) Ca(OH) 2
(c) CaCO3
(d) MgCO3
54. Which of the following has highest knocking
property ?
(a) Aromatic hydrocarbons
(b) Olefins
(c) Branched chain paraffins
(d) Straight chain paraffins
55. Among the following compounds (I - III), the
ease of their reaction with electrophiles is,
OCH3
(a)
NO2
(b) [ Co ( H 2 O ) 2 ( NH 3 ) 2 Cl 2 ] +
56.
57.
58.
59.
60.
61.
II
III
63.
64.
65.
66.
67.
68.
62.
69.
(c) Dq = Dw + pDv
7
(d) For reversible isothermal expansion of 1 mole
of an ideal gas from volume V1 to V2, work
done is equal to RT ln (V2/V1)
70. The correct order of the decreasing ionic radii
among the following isoelectronic species are :
(a) Ca 2+ > K + > S2 > Cl1
(b)
(c)
71.
72.
73.
74.
75.
76.
l
?
2
(a) 0, 90
(b) 90, 0
(c) 30, 90
(d) 90, 30
77. Equivalent conductance of an electrolyte
containing NaF at infinite dilution is 90.1
Ohm1cm2. If NaF is replaced by KF what is the
value of equivalent conductance?
(a) 90.1 Ohm1cm2
(b) 111.2 Ohm1cm2
(c) 0
(d) 222.4 Ohm1cm2
78. The enthalpy of combustion of C6H6 is 3250 kJ,
when 0.39 gm of C6H6 is burnt in excess of
oxygen in an open vessel, the amount of heat
evolved is
and
(a) 8.32 kJ
(b) 12.36 kJ
(c) 16.25 kJ
(d) 20.74 kJ
79. In which of the following is there a consistent
decrease in atomic radius as the atomic number
increases?
(a) halogens
(b) representative elements
(c) transition elements
(d) lanthanides
80. The basicity of aniline is less than that of
cyclohexylamine. This is due to
(a) + R effect of NH2 group
(b) I effect of NH2 group
(c) R effect of NH2 group
(d) hyperconjugation effect
81.
E =
RT
In K eq
nF
1
H 2 O; K 2
H 2 + O 2
2
The equilibrium constant for the oxidation of
NH3 by oxygen to give NO is
(a)
K 2 K32
K1
(b)
K 22 K3
K1
(b)
K1 K 2
K3
(d)
K 2 K33
K1
87.
1
1
H2(g) + O2(g) OH(g) ;
2
2
DH = 42.09 kJ mol1
H2(g) 2H(g) ; DH = 435.89 kJ mol1
O2(g) 2O(g) ; DH = 495.05 kJ mol1
Calculate the O H bond energy for the
hydroxyl radical.
(a) 223.18 kJ mol1
(b) 423.38 kJ mol1
1
(c) 513.28 kJ mol
(d) 113.38 kJ mol1
88. Elements X, Y and Z have atomic numbers 19, 37
and 55 respectively. Which of the following
statements is true about them ?
(a) Their ionization potential would increase
with increasing atomic number
(b) Y would have an ionisation potential
between those of X and Z
(c) Z would have the highest ionization
potential
(d) Y would have the highest ionization
potential.
89. MnO42 (1 mole) in neutral aqueous medium
disproportionates to
(a) 2/3 mole of MnO4 and 1/3 mole of MnO2
(b) 1/3 mole of MnO4 and 2/3 mole of MnO2
(c) 1/3 mole of Mn2O7 and 1/3 mole of MnO2
(d) 2/3 mole of Mn2O7 and 1/3 mole of MnO2
90. Formation of a solution from two components
can be considered as
(i) pure solvent separated solvent
molecules, DH1
(ii) pure solute separated solute molecules,
DH2
(iii) separated solvent and solute molecules
solution, DH3
Solution so formed will be ideal if
(a) DH so ln = DH1 + DH 2 - DH 3
(b) DH so ln = DH1 - DH 2 - DH 3
(c) DH so ln = DH 3 - DH1 - DH 2
(d) DH so ln = DH1 + DH 2 + DH 3
SECTION 3 - BOTANY
91.
9
(a)
(b)
(c)
(d)
102.
103.
104.
105.
106.
(a) Manganese
(b) Calcium
(c) Magnesium
(d) Potassium
107. Movement of ions or molecules in a direction
opposite to that of prevailing electrochemical
gradient is known as
(a) diffusion
(b) active transport
(c) pinocytosis
(d) brownian movement
108. Which one is the correct summary equation of
photosynthesis?
109.
110.
111.
112.
113.
10
A
C
B
118.
D
Substrate
Product
119.
Progress of Reaction
114.
115.
116.
117.
120.
121.
122.
123.
124.
125.
11
126.
127.
128.
129.
130.
12
Foreign DNA
A
Vector
DNA
(plasmid)
141.
join foreign
DNA to plasmid
142.
E.coli
Cells
Divide
143.
(a) A Exonuclease, B Endonuclease,
C DNA ligase, D Transformation
(b) A Exonuclease, B Exonuclease,
C DNA ligase, D Transformation
(c) A Exonuclease, B Endonuclease,
C Hydrolase, D Transduction
(d) A Restriction endonuclease,
B Restriction endonuclease, C DNA
ligase, D transformation
144.
SECTION 4 - ZOOLOGY
136. Slime moulds in the division myxomycota (true
slime moulds) have
(a) pseudoplasmodia.
(b) spores th at develop into free living
amoeboid cells.
(c) spores that develop into flagellated
gametes.
(d) feeding stages consisting of solitary
individual cells.
137. Which of the following substances would cause
coagulation of blood at th e site of its
introduction?
(a) Prothrombin
(b) Fibrinogen
(c) Thromboplastin (d) Heparin
138. Leech is
(a) carnivorous
(b) sanguivorous
(c) ectoparasite
(d) Both (b) and (c)
139. RBCs in human are
(a) biconcave and nucleated
(b) biconvex and nucleated
(c) biconcave and enucleated
(d) biconvex and enucleated
140. Lymph differs from blood in possessing
145.
B
D- chain
C
E
Bond/Bridge
E- chain
13
(of L-Chain ); C - Variable region
(of L-Chain); D - Light polypeptide chain
(L-Chain); E - Heavy polypeptide chain
(H-Chain); F - Disulfide (bond)
(c) A- Antigen binding site; B - Variable region
(of L-Ch ain); C - Constan t region
(of L-Chain); D - Heavy polypeptide chain
(L-Chain); E - Light polypeptide chain
(H-Chain); F - Hydrogen (bond)
(d) A - Antigen binding site; B - Variable region
(of L-Ch ain); C - Constan t region
(of L-Chain); D - Light polypeptide chain
(L-Chain); E - Heavy polypeptide chain
(H-Chain); F - Hydrogen (bond)
146. The copper ions of IUDs
(a) Suppress the motility and fertilization
capacity of sperms
(b) Make the uterus unsuitable for implantation
(c) Increase phagocytosis of sperms
(d) Make cervix hostile to sperms
147. The transfer of zygote or early embryo (up to 8
blastomere) into fallopian tube is
(a) IVF and ET
(b) ZIFT
(c) GIFT
(d) IUT
148. The embryonic membrane involved in the
formation of placenta in human is
(a) yolk sac
(b) allantois
(c) amnion
(d) chorion
149. Identical twins are produced when
(a) One fertilized egg divides and two
blastomeres separate
(b) One sperm fertilizes two eggs
(c) One egg is fertilized with two sperms
(d) Two eggs are fertilized
150. Which of the following induces parturition ?
(a) Vasopressin
(b) Oxytocin
(c) Growth hormone
(d) Thyroid stimulating hormone
151. Jaundice is a disorder of
(a) Excretory system
(b) Skin and eyes
(c) Digestive system
(d) Circulatory system
152. Child death may occur in the marriage between
(a) Rh+ man and Rh + woman
(b) Rh+ man and Rh woman
(c) Rh man and Rh woman
(d) Rh man and Rh + woman
14
162. The change of the light-coloured variety of
peppered moth (Biston betularia) to its darker
variety (Biston carbonaria) is due to
(a) mutation
(b) regeneration
(c) genetic isolation (d) temporal isolation
163. A person with the sex chromosomes XXY suffers
from
(a) Downs syndrome
(b) Klinefelters syndrome
(c) Turners syndrome
(d) Gynandromorphism
164. There is no life on moon due to the absence of
(a) O2
(b) water
(c) light
(d) temperature
165. The density of a population in a given habitat
during a given period, fluctuates due to changes
in four basic process. On this basis fill up A and
B boxes in the given diagram with correct options
166.
167.
168.
169.
170.
171.
172.
173.
174.
175.
176.
177.
15
178. Increased asthmatics attacks in certain seasons
are related to
(a) eating fruits preserved in tin containers
(b) inhalation of seasonal pollen
(c) low temperature
(d) hot and humid environment.
179. For transformation, micro-particles coated with
DNA to be bombarded with gene gun are made
up of :
(a) Silver or Platinum
(b) Platinum or Zinc
(c) Silicon or Platinum
(d) Gold or Tungsten
180. Which one of the following statements is correct
16
(b)
(d)
21
(a)
22
(b)
41
(b)
42
(b)
61
(d)
81
(b)
101
(c)
121
(b )
141
(c)
1 61
(d )
62
(b)
82
(a)
102
(d )
122
(a)
142
(d )
1 62
(a)
(a)
23
(a)
43
(b)
63
(c)
83
(a)
103
(c)
123
(d )
143
(d )
1 63
(b )
(b)
24
(b)
44
(b)
64
(b)
84
(d)
104
(a)
124
(c)
144
(b )
1 64
(b )
(d)
25
(a)
45
(a)
65
(d)
85
(d)
105
(b )
125
(d )
145
(a)
1 65
(a)
(a)
26
(d)
46
(d)
66
(b)
86
(d)
106
(c)
126
(a)
146
(a)
1 66
(b )
(c)
27
(b)
47
(c)
67
(b)
87
(b)
107
(b )
127
(d )
147
(a)
1 67
(b )
(d)
28
(d)
48
(c)
68
(d)
88
(b)
108
(d )
128
(d )
148
(d )
1 68
(c)
(a)
29
(d)
49
(c)
69
(c)
89
(a)
109
(d )
129
(a)
149
(a)
1 69
(a)
10
(a)
30
(d)
50
(c)
70
(c)
90
(d)
110
(b )
130
(d )
150
(b )
1 70
(d )
11
(c)
31
(b)
51
(a)
71
(b)
91
(a)
111
(a)
131
(b )
151
(c)
1 71
(d)
12
(a)
32
(d)
52
(c)
72
(a)
92
(a)
112
(c)
132
(a)
152
(b )
1 72
(b )
13
(d)
33
(a)
53
(a)
73
(b)
93
(c)
113
(b )
133
(c)
153
(c)
1 73
(d)
14
(b )
34
(c)
54
(d)
74
(c)
94
(b)
114
(b )
134
(d )
154
(c)
1 74
(b )
15
(d)
35
(a)
55
(d)
75
(b )
95
(a)
115
(a)
135
(d )
155
(d )
1 75
(d )
16
(c)
36
(c)
56
(c)
76
(c)
96
(b)
116
(a)
136
(c)
156
(a)
1 76
(c)
17
(b)
37
(a)
57
(c)
77
(a)
97
(a)
117
(b )
137
(c)
157
(d )
1 77
(d)
18
(c)
38
(b)
58
(a)
78
(c)
98
(b)
118
(b )
138
(d )
158
(d )
1 78
(b )
19
(d)
39
(d)
59
(a)
79
(b)
99
(b)
119
(d )
139
(c)
159
(c)
1 79
(d )
20
(c)
40
(b)
60
(d)
80
(a)
100
(b)
120
(a)
140
(a)
160
(b )
1 80
(d)
SECTION 1 -PHYSICS
1.
2.
3.
r r3
ML-3 L3
=
=T
S
MT - 2
(d) The no. of significant figures in 3400 is 2.
(a) The work done = area of P V graph
u2
2
=
r=
g
2g
(b)
6.
1
3P 2V = 3PV
2
2g R e
is
u
2
7.
17
9.
11.
T1 - T2
T1
But Cv =
1
1
CV 2 + CV 2 = CV2
2
2
13.
(Q f = 60rpm \ w = 2pf = 2p
60
60
p
N-m
15
(b) Photoelectric effect is accounted by particle
like bahaviour of light (i.e. by quantum
theory of light)
fE =
24. (b)
t=
14.
15. (d)
3
5
R + R = R = 2.5 R
2
2
16. (c)
30
q + q
=0
e0
1
1
mv e 2 = 1000 (11.2 103 ) 2
2
2
10
= 6.4 10 J (approx.)
E=
3
Cv = dE / dT = R
2
Cp =
2 3 R (373 - 273)
= 300 R
2
E
1
3
En = - 1 E 2 - E1 = E1 1 - = E
2
1
n
4 4
1 1 5
E 3 - E 2 = E1 - =
E1
4 9 36
So, the gap between two successive
orbitals decreases. Naturally radiations due
to transition between these levels will also
go on decreasing. So, transition from n = 4
to n = 3 will have lowest frequency.
(d) t Dt = L0
{Q since Lf = 0}
t Dt = Iw
or t 60 = 2 2 60p/60
nfRdT
2
\ dQ =
26.
2p
path difference
l
p 2p
=
0.8
2
l
l = 0.8 m 4 = 3.2 m
velocity = l v = 3.2 120 = 384 m/s
(d) Since maximum part of the power of
modulated wave is contained with the
carrier wave which does not transmit any
desired information, hence to avoid
wastage of power to suppress carrier
balanced modulator is used.
27. (b)
Vr.m.s =
Vmax
2
120
2
= 84.8V
18
28.
(d)
T1 = 2p
37.
mv
(m + M)
1
m 2 v2
K.E. = (m + M) V 2 =
2
2(m + M)
29.
36.
is MB sin q
38.
39.
l
g
30.
FV FR
1.21l
= 1.1T1
g
2
(0.4 104 ) 2 p
(0.5)
60
=
2
= 0.628 10 4V
32.
33.
d +A
sin m
2
(d) m =
A
sin
2
98
sin
sin 49
2
= 1.5
=
=
sin 30
sin 30
(a) The impedance of circuit is
2
34.
PV =
41.
42.
Y
- 1 = 0.2
2h
4T 4 3
16 T 2
p.r =
p.r
r 3
3
PV r 2
(b) Electro magnet should be amenable to
magnetisation & demagnetization
\ retentivity should be low & coercivity
should be low
(b) Since work function for a metal surface is
hc
l0
where l0 is threshold wavelength or cut-off
wavelength for a metal surface.
here W = 4.125, eV = 4.125 1.6 1019 Joule
Z = ( R ) + (1/ 2pfc )
Which will decrease with the increase of
frequency f of impressed ac.
(c)
4T
r
W=
6.67 10-11 10
6.67 10-11 100
Vg =
1
1
35.
so l 0 =
43.
6.6 10 -34 3 10 8
4.125 1.6 10 -19
(b)
n
= 3000 A
C
n
B
19
shown. Current is flowing from base to
emitter so, electrons are flowing from emitter
to base.
Hence option (b) is the answer.
44. (b) Ground waves have the property of being
polarized normal to the earth's surface.
45. (a) In case of NOR logic circuit, when input
is 0, the output is 1 that is when both the
inputs are low, the output is high.
46.
47.
SECTION 2 -CHEMISTRY
(d) Huckels rule states that for aromaticity
there must be (4n + 2) p electron present in
compound where n is an integer
(c) It has centre of symmetry, so optically
inactive.
CH3
49.
55.
56.
CHO
CrO 2Cl2
(c)
Benzaldehyde
57.
CH3 COO- + H +
CH3COOH
K=
0
0.1 0.0134
0
0.1 0.0134
[CH3COO ] [H ]
[CH 3COOH]
NO2
NO 2
51.
(a)
52.
53.
58.
= 0.182 10-5
67200 0.334
=4
100 56
(c) K2HgI4 + KOH is called Nesslers reagent.
It is used for the detection of NH4+ in group
analysis and in quantitative determination
of ammonia solution. It gives a yellow or
brown precipitate with concentrations as
low as 1 ppm of NH3.
(a) Both lattice energy and hydrolysis energy
decreases moving down the group due to
gradual increase in size of M++ ion. So
former tends to increase the solubility while
latter tends to decrease it. But lattice energy
has dominating role here. And therefore,
solubility increases down the group.
Initial
0.1
At equilibrium 0.1(1 0.0134)
in CCl4
Toluene
50.
54.
59.
or
60.
20
61.
(d)
E 0cell = E0
+ E0
1.10 = E 0
+ 0.34
Zn / Zn 2+
Zn / Zn 2+
E0
Zn / Zn 2+
E0cell
Cu 2+ / Ca
or
\
= 0.76 V
+ E0 +
Ag / Ag
second cell
0.46 = -0.34 + E 0
Ag + / Ag
Ag + / Ag
= 0.80 V
Zn / Zn 2+
62.
63.
+ E0
Ag + / Ag
= 0.76 + 0.80
= 1.56 V
(b) It is optically active when two Cl atoms are
in cis position.
(c)
U H2
U N2
TH 2 28
TN 2 2
65.
71
63
73.
Thus, (a)
(b) No. of equivalents of caustic sdoda = 20
103 0.5 = 102
\ No. of equivalents of acid = 102
Also,
74.
[A - ]
[HA]
= 7.87
(b) In froth floatation process, ore particles
float because their surface is hydrophobic
i.e., not easily wetted by oil.
(b) Initial concentration = 10 mol L1
\ Conc. after 20 min (two half lives) = 2.5 mol L1
57
vicdihalide
SnO 2 + 2OH -
SnO 32 - + H 2O
3+
Lu3+ < Eu3+ < La 3+ < Y39
1
= 9.15 + log
12
67.
72.
\ TN 2 > TH 2
pH = pKa + log
66.
gem-dihalide
TH2
0.0693 min1
rate = k [reactant]
= 0.0693 2.5 mol L1 min1
1
7
=
TN 2 2
TN2 = 2TH 2
64.
0.693
0.693
=
10 min
t1 / 2
68.
= E0
Cu / Cu 2+
E0
Now, k =
first cell
75.
0.45
x = 10 -2 x = 2
90
21
76.
77.
78
80.
81.
(c)
(a)
(c)
(a)
(b)
2d sin q = nl
2l sin q = l
1
\ sin q =
2
q = 30
l
2 sin q = l
2
\ sin q = 1
\ q = 90
Thus, 30 and 90 as in (c).
Because at infinite dilution the equivalent
conductance of strong electrolytes
furnishing same number of ions is same.
15
C6 H 6 + O2
6CO2 + 3H 2O
2
1 mole 3250 kJ
0.39
0.39
mole 3250
= 16.25 kJ
78
78
The reason for the lesser basicity of aniline
as compared to that of cyclohexylamine is
+R effect of NH2 group (i.e., electron
releasing resonance effect of NH2 group).
Nernst equation is
2.303 RT
[C]c [d]d
log
Ecell =
nF
[A]a [B]b
For general cell reaction
cC + dD
aA + bB
When Ecell drops to zero the concentration
of ions will be equilibrium concentrations.
2.303RT
E ocell =
log K c
nF
[Since at equilibrium Ecell = 0]
0.0591
Eocell =
log K c at 298K.
n
(a) Mac Arthur process involves extraction of
gold from sulphide ore with the help of
KCN.
(a) The boron atom in boric acid, H3BO3 is
electron deficient i.e., boric acid is a Lewis
acid with one p-orbital vacant. There is no
d-orbital of suitable energy in boron atom.
So, it can accommodate only one additional
electron pair in its outermost shell.
(d) Given,
2NH 3 ; K1
N 2 + 3H 2
....(i)
2NO; K 2
N 2 + O 2
....(ii)
or
83.
84.
[NH3 ]2
[NO]2 [H2O]3
[NH3 ]2 [O2 ]5 / 2
, K2 =
[N 2 ] [H 2 ]3
[NO]2
[N 2 ] [O 2 ]
[H 2O]3
or
K
=
3
[H 2 ] [O 2 ]
[H 2 ]3 [O 2 ]3 / 2
[H 2O]
Now operate,
K 2 . K 33
K1
[H 2 O]3
[N ] [H2 ]3
[NO]2
. 2
3
3
/
2
[N 2 ] [O2 ] [H 2 ] [O2 ]
[NH3 ]2
[NO]2 [H 2 O]3
[NH 3 ]2 [O 2 ]5 / 2
\ K=
E ocell
82.
1
H 2 O; K 3
O2
....(iii)
2
We have to calculate
4NH 3 + 5O2
4NO + 6H 2O; K = ?
5
2NH 3 + O2
2NO + 3H 2 O
2
H2 +
=K
K 2 . K 33
K1
85.
86.
(d)
C6 H 5COOH
C6 H6 + Na 2CO3 + H 2O
Zn dust (Y)
87.
C6 H 5 OH C6 H 6 + ZnO
(b) We have to calculate the enthalpy of the
reaction OH (g) O(g) + H(g)
From the given reactions, this can be
obtained as follows.
1
2
1
+ [H2(g) 2H(g)] ; DH =
2
1
+ [O2(g) 0 2O(g)]; DH =
2
Add
1
435.89 kJ mol1
2
1
495.05 kJ mol1
2
22
88.
89.
(a)
3MnO4 2 + 2H 2O
MnO 2 + 2MnO 4 + 4OH
or
MnO 2
4 +
2
H2O
3
1
2
4
MnO 2 + MnO 4 + OH
3
3
3
SECTION 3 -BOTANY
92.
93.
94.
96.
97.
98.
23
114. (b) The atmospheric nitrogen is fixed in the soil
in the form of nitrate. Nitrate and ammonium
can be taken up by plants or used by other
soil organisms. Any nitrate or ammonium
that is not used for growth is added to the
pool of inorganic nitrogen in the soil.
116. (a) In 1953 Wilkins obtained very fine X-ray
crystallographic pictures of DNA from
which Watson and Crick developed the
double helix model of DNA.
117. (b) Genetic mapping help in studying the
architecture of the chromosomes and of
entire genome.
118. (b) During transcription, from the DNA
template complementary mRNA is formed
and thymine is replaced by uracil.
119. (d) Humus is the organic material in soil is the
dark brown or black colouration. In soil
science, humus refers to any organic matter
which has reached a point of stability, where
it will break down no further and might, if
conditions do not change, remain
essentially as it is for centuries, if not
millennia. In agriculture, humus is
sometimes also used to describe mature
compost, or natural compost extracted from
a forest or other spontaneous source for
use to amend soil. It is also used to describe
a topsoil horizon that contains organic
matter (humus type, humus form, humus
profile).
120. (a) DDT was subsequen tly banned for
agricultural use worldwide under the
Stockholm Convention, but its limited use
in disease vector control continues to these
days in certain parts of the world and
remains controversial. Along with the
passage of the Endangered Species Act,
the US ban on DDT is cited by scientists as
a major factor in the comeback of the bald
eagle in the contiguous US.
121. (b) Ozone layer is present in the stratosphere
in the atmosphere of the earth. It protects
the earth from UV rays (less than 300 nm).
Hole in the ozone layer means thinning of
ozone layer that allows harmful UV rays
to reach earth which cause skin diseases.
122. (a) Selection is picking up only those plants
for reproduction which have desired
qualities. Hybridization is crossing of two
or more types of plants for bringing their
traits together in the progeny. Introduction
123. (d)
124. (c)
126. (a)
127. (d)
128. (d)
130. (d)
131. (b)
132. (a)
134. (d)
24
136. (c)
137. (c)
140. (a)
141. (c)
144. (b)
148. (d)
152. (b)
153. (c)
SECTION 4 -ZOOLOGY
Slime moulds in the division of myxomycota
have spores that develop into flagellated
gametes.
Fibrinogen, prothrombin, thromboplastin
are respectively clotting factors I, II and III.
Thromboplastin released from injured
platelets or injured tissue. This converts
prothrombin into thrombin in the presence
of calcium ions. The thrombin converts
fibrinogen into fibrin and the latter forms
the clot.
Lymph differs from blood in that it contains
less protein and no red blood cells. Lymph
contains white blood cells.
Pseudocoelomate is any i n v e r t e b r a t e
animal whose body cavity is a pseudocoel,
a cavity between the gut and the outer body
wall derived from a persistent blastocoel,
rather than a true coelom. Pseudocoelomate
animals include the Rotifera and Nematoda.
Amniocentesis is the most widely used
method for prenatal detection of many
genetic disorders. It is also a technique used
for determining the sex of the foetus.
Chorionic villi found in the maternal blood
is involved in the formation of placenta in
man.
Rh factor was discovered by Kar l
Landsteiner. A child of Rh+ man will be
Rh+ whether the mother is Rh+ or Rh. If
the mother is Rh+ then there will be no
problem but if mother is Rh so when the
blood of Rh+ child (in womb) mixes with
the blood of Rh mother then some
antibodies in mothers blood are formed
against Rh+ factor which coagulate the
womb blood causing death. If birth takes
place then there is a possibility of child
death in early years. This in known as
erythroblastosis foetalis. In most cases
the Ist pregnancy may succeed but after
that it fails.
Continued consumption of fat rich
diet causes hypercholesterolemia.
Hypercholesterolemia is the presence of
high levels of cholesterol in the blood.
High cholesterol raises risk for heart
disease, heart attack, and stroke. Kidney
stones are solid mass made up of tiny
crystals. There are different types of
154. (c)
155. (d)
156. (a)
158. (d)
160. (b)
161. (d)
162. (a)
25
163. (b)
164. (b)
166. (b)
167. (b)
168. (c)
169. (a)
eg. thyroxine
Peptides
eg. insulin
Steroids
eg. aldosterone
The maximum volume of air a person can
breath in after a forced expiration or the
maximum volume of air a person can
breathe out after a forced inspiration is
called vital capacity (VC). This includes
tidal volume, inspiratory reserve volume
and expiratory reserve volume.
(TV + IRV + ERV). VC varies from 3400 ml
4800 mL, depending upon age, sex and
height of the individual.
The inner layer of the posterior two-thirds
of the eyeball consists of a light sensitive
layer, called retina that possesses two
types of photoreceptors called the rods
and the cone cells. Retina reduces the
internal reflection so any damage to it
171. (d)
173. (d)
175. (d)
176. (c)
177. (d)
178. (b)
179. (d)
180. (d)