Professional Documents
Culture Documents
GAP.8.0.1.1
June 2, 2003
fires
building explosions
vapor cloud explosions
vessel explosions
Of course, any risk may possess the potential for one or more of these incident types.
This GAP Guideline describes a method used by GAP Services for estimating the loss potential in oil
and chemical properties that can be used in establishing PMLs. A method for estimating the
catastrophic loss potential from a vapor cloud explosion is also given.
This GAP Guideline should be used for property loss prevention purposes only and should not be
used for designing or siting blast resistant buildings or for specifying personnel protection.
The amount of material which might be spilled and the nature of the failure which would cause this
spill.
The physical properties of the material and the operating conditions of the process, such as
temperature and pressure.
Global Asset Protection Services and its affiliated organizations provide loss prevention surveys and other risk management, business continuity and facility asset
management services. Unless otherwise stated in writing, our personnel, publications, services, and surveys do not address life safety or third party liability issues. The
provision of any service is not meant to imply that every possible hazard has been identified at a facility or that no other hazards exist. Global Asset Protection Services and its
affiliated organizations do not assume, and shall have no liability for the control, correction, continuation or modification of any existing conditions or operations. We
specifically disclaim any warranty or representation that compliance with any advice or recommendation in any document or other communication will make a facility or
operation safe or healthful, or put it in compliance with any law, rule or regulation. If there are any questions concerning any recommendations, or if you have alternative
solutions, please contact us.
GAP.8.0.1.1
June 2, 2003
All of the foregoing factors should be considered, and it should be kept in mind that the loss estimated
must be based on reasonably adverse conditions. The estimate should consider the effect of the
impairment of one form of active protection, such as water spray, foam, or drainage. Obviously,
passive protection features, such as spacing, fireproofing, and diking are not subject to impairment
simultaneous with a loss.
Generally speaking, where good drainage (more than one direction) or diversionary diking is utilized
to prevent the spread of flammables, and the spacing is in accordance with GAP.2.5.2 the loss
estimate should be based on major damage to the production units within the drainage/diking zone.
Some damage would be expected to surrounding units from radiation. Missile damage from exploding
vessels is generally not to be considered as a PML incident.
As with analysis of a postulated fire incident, internal building explosions cannot be rigorously
analyzed. The release of flammable liquids or gases into a building, with subsequent ignition and
explosion, will result in destruction of the building. Possible damage to nearby buildings should be
considered. Subsequent fires from broken piping would also be a factor. Automatic sprinkler
protection would most likely be rendered inoperative from an internal building explosion. The degree
of damage anticipated from a building fire with one or more sprinkler systems out-of- service
(reasonably adverse conditions) and an internal building explosion with subsequent damage to the
sprinkler system would be similar.
GAP Guidelines
2
GAP.8.0.1.1
June 2, 2003
have shown a need to include hot flammable liquid spills and a method of establishing the
catastrophic loss potential of a vapor cloud explosion. The initial incident is assumed to be the spilling
of a large quantity of flammable materials. It is highly probable that a large spill will become ignited.
The reasonably adverse condition assumed is that the ignition of the cloud will propagate to an
unconfined vapor cloud explosion. Thus, it is not necessary to assume that any fire protection
facilities will be impaired prior to the ignition. These facilities may be damaged and impaired,
however, due to the explosion.
Assumptions
GAP Services uses a reasonably simple vapor cloud explosion potential model. A number of papers
have been written in recent years that define the vapor cloud explosion phenomenon to a finer degree
than is used in this calculation method. These papers provide methods of analyzing losses after they
occur by considering variables such as spill rate, wind velocity, direction, other atmospheric
conditions, reactivity of the spilled material, amount of obstructions and partial confinement within the
cloud.
In predicting the loss potential, these variables are generally unknown and a conservative and
practical approach must be chosen which will reduce these variables to little or no consequence.
Therefore, the following assumptions are made in this calculation method:
The spill is instantaneous and leak rate is not considered. The one exception to this is a spill from
a pipeline fed by large capacity remote storage facilities.
The spilled material is instantaneously vaporized and a cloud is immediately formed based on the
thermodynamic conditions of the flammable liquid or gas prior to release. For example, spills of
liquefied gases are assumed to fully vaporize instantaneously with no autorefrigeration of the liquid
pool.
The cloud formed is cylindrically shaped with a vertical axis as the cloud height. Wind distortion
and distortion due to the presence of buildings or structures are not considered.
The cloud composition is assumed to be of uniform composition with the vapor-air mixture being at
the midpoint of the explosive range.
A heat of combustion of 2000 Btu/lb (4648 kJ/kg) for TNT is used to convert the heat of
combustion of the material to an equivalent weight of TNT.
It is recognized that explosion of a confined vapor-air mixture in a building will result in greater
explosive efficiency than the unconfined explosion of the same volume of vapor-air mixture. However,
in most cases, the volume occupied by the open-air cloud from most credible spills will be much
greater than the volume of most buildings. Therefore, a spill which originates inside of a building
should be assumed to form the same size and shape cloud as if the spill occurred in the open.
GAP Guidelines
3
GAP.8.0.1.1
June 2, 2003
Flammable gases existing under a pressure of 500 psig (34.5 bar) or higher.
Flammable or combustible liquids existing above the atmospheric boiling point and maintained as
a liquid because of the application of pressure. Materials which have a viscosity greater than
1 106 centipoises or a melting point above 212F (100C) are not considered to be liquids within
the scope of this calculation method. Liquids in the process at temperatures above their
autoignition temperatures should not be considered as having a vapor cloud potential since they
will ignite upon contact with air.
CALCULATION METHOD
Throughout these calculations, units from both the English system and the SI (International System of
Units) are used in the same equation. This is due to the availability of data from the sources indicated
in the references.
The size of a spill is based on the contents of the largest process vessel or train of process
vessels connected together and not readily isolated. Shut-off valves which are actuated both
automatically and manually from a remote location may be considered in reducing the size of the
estimated spill. Automatic dump or flare systems, if safely arranged, may be considered in
reducing the size of the spill. Shut-off valves and dump and flare systems may only be considered
in limiting the spill from vessels connected to the largest process vessel. The minimum spill
source to be used is the largest process vessel. The largest spill does not always present the
largest vapor cloud potential, smaller spills of light products can create a larger vapor cloud.
The existence of ignition sources may not be used in reducing the cloud size. The total amount
which might be spilled must be used in estimating the cloud size. Loss experience has shown that
large clouds may be formed without ignition by nearby ignition sources.
Gases or liquids used as fuels are not considered, based on loss experience.
The failure of a major storage tank is not considered, based on loss experience.
The failure of a major pipeline is not considered.
The size of a spill should be based on the contents vessels or train of vessels connected together
and having the largest vapor cloud potential. The existence of shut-off valves should not be
considered.
GAP Guidelines
4
GAP.8.0.1.1
June 2, 2003
The existence of ignition sources may not be used in reducing the cloud size. The total amount
which might be spilled must be used in estimating the cloud size. Loss experience has shown that
large clouds may be formed without ignition by nearby ignition sources.
(1)
where:
WG = weight of gas discharged
n = number of moles of gas
M = molecular weight of gas calculated from atomic weights
According to the Gay-Lussac perfect gases law:
n=
PV
RT
(2)
where:
P=
V=
R=
T=
Therefore:
WG =
MPV
RT
(3)
MP ( psia ) V (ft 3 )
10.73 (T ( o F ) + 460)
(3E)
MP (bar ) V (m 3 )
0.08314 (T ( o C + 273))
GAP Guidelines
5
(3S)
GAP.8.0.1.1
June 2, 2003
If the material exists in the system as a liquid, the weight of the liquid may be calculated as follows:
WL = VL
(4)
where:
WL =
VL =
(4E)
( g mL ) VL (m 3 )
1000
(4S)
W L C pm (T1 T 2 )
(5)
H v
where:
Wv =
WL =
Cpm =
geometric mean of specific heats over the range T1 to T2. The geometric mean of
the specific heats over the range T1 to T2 may be calculated from:
Cpm = (C1 x C2 x x Cpn)!/n
where:
C1, C2, C3, .Cpn are values of Cp taken at equal intervals between T1 and T2
(Gallant)
T1 =
temperature of the liquid in the process or boiling point of the liquid at process
pressure, whichever is less (Gallant)
T2 =
Hv =
GAP Guidelines
6
GAP.8.0.1.1
June 2, 2003
English units:
WV (lb ) =
WV (lb ) =
WL (lb ) C pm
cal
Hv
( )
C (T1 T2 ) o C
(cal g )
( )
(5E)
o
o
5 WL (lb )C pm cal g C (T1T2 ) F
9
Hv cal g
(5E')
WL (kg )C pm ( kJ g o K ) (T1 T2 ) ( oC )
(5S)
( )
SI Units:
WV (kg ) =
v ( kJ kg )
(l kJ kg o K =0.2389cal g o C )
W H c
H ce
(6)
where:
We =
Weight of TNT which will produce an explosive force equivalent to the force
produced by explosion of the vapor cloud.
Hce =
W=
Hc =
Heat of combustion of vapor (Perry,2 NFPA Handbook3) Use the values for gaseous
products of CO2 and H2O. Other heats of combustion may be calculated from
available heat of formation data.
f=
Explosive yield factor. Published information indicates that the explosive yield factor
f, for spillage explosions of rocket propellants and liquid oxygen, initiated at no time
delay, is about 0.1. Analysis of actual chemical plant vapor cloud explosions
indicates f values in the range of 0.01 to 0.05. In establishing probable maximum
loss estimates (PMLs) and catastrophic loss estimates, a f value of 0.02 should be
used.
GAP Guidelines
7
GAP.8.0.1.1
June 2, 2003
English Units:
W ( lb ) c
We (ton ) =
(Btu lb )
(6E)
4 10 6
SI Units:
W e (kg ) =
W (kg ) H c
(kJ kg )
4648
W e ( ton) =
W (kg )H c
(kJ kg )
4,216,573
(6S)
The equivalent weight of TNT is expressed in tons as explosion damage tables are given in tons
(1 ton = 2000 lb).
1
3
(7)
d =d 1(W e )
(8)
where:
d=
d1 =
W1 =
We =
This relationship has been reduced to a graph (Figure 1) which may be used to determine the
overpressure circle diameters. In Figure 1, a conversion has been made from kilotons TNT to tons
TNT. No metricated graph is available.
For establishing the PML, the maximum overpressure to be used is 5 psi (0.35 bar). Current theory
suggests that overpressures up to 15 psi (1 bar) should be establishing catastrophic loss potential
estimates.
Determination Of Damage
Tables 1A, 1B, 1C, 1D and 2 are to be used in determining the extent of damage from explosion of a
vapor cloud. These tables are based on overpressure damage only and do not consider the
possibility of major damage from ensuing fire. If there is a possibility of an ensuing fire of long
duration because of large volumes of flammable liquid holdup in processes, the ensuing fire must be
considered. Within the 5 psi (0.35 bar) circle blast damage will probably result in total destruction of
most processing units. Damage within this area should be considered as 100%.
GAP Guidelines
8
GAP.8.0.1.1
June 2, 2003
GAP Guidelines
9
GAP.8.0.1.1
June 2, 2003
TABLE 1A
Summary of Blast Damage To Structures
Overpressures
(psi)
0.5
1.0
1.5
3.5
Controlhouses
Steel Roof
Precast
Decking and
Concrete Roof
No Frame
and Steel
Frame
Steel Frame
bet. Vessels
Crude Units
Atmos./Vacuum Towers
Fractionator Towers
Rectangular
Octagonal
Rectangular Mounted on
Conc. Frame Conc. Frame Conc. Frame
Conc.
Pedestal
NOTE:
Atmospheric
Vacuum
Towers
NOTE:
Vacuum
Towers only
Conc.
brackets fail
causing
frame
collapse
4.5
Anchor bolts
yielding
5.0
5.5
Conc. frame
cracking
Conc. frame
collapse
7.0
7.5
8.0
8.5
10.0
Conc. frame
cracking
Vessel
anchor
bolts fail
causing
frame
collapse
Conc. frame
cracking
Conc. frame
collapse
Vessel &
foundation
overturn
Steel frame
collapse
12.0
16.0
Source:
Minimize Damage to Refineries From Nuclear Attack, National And Other Disasters, The Office Of Oil & Gas, U.S.
Dept. Of The Interior; February 1970
GAP Guidelines
10
GAP.8.0.1.1
June 2, 2003
TABLE 1B
Summary Of Blast Damage To Structures
Overpressures
(psi)
00.5
01.0
01.5
03.5
04.5
05.0
05.5
07.0
NOTE:
Reactor &
Fractionator
supported by
same frame
Anchor bolts
yielding
Leeward
columns buckle
East or West
blast
Overturns
Easterly blast
Leeward cols.
buckle. East
blast
Leeward cols.
buckle. West
blast
07.5
08.0
08.5
Overturns
Westerly blast
Source:
Overturns
Anchor bolts fail
Concrete frame
cracking
Conc. frame
cracking
10.0
12.0
16.0
Fractionator Tower
Mounted on
Conc. Pedestal
Steel frame
overturns
Conc. frame
collapse
Conc. frame
collapse
Minimize Damage to Refineries From Nuclear Attack, National And Other Disasters, The Office Of Oil & Gas, U.S.
Dept. Of The Interior; February 1970
GAP Guidelines
11
GAP.8.0.1.1
June 2, 2003
TABLE 1C
Summary Of Blast Damage To Structures
Overpressure
(psi)
Vapor
Recovery Unit
Mounted on
Pedestal
and Large
Footing
Rectangular
Steel
Frame
Atmospheric
Maintenance
Building
Corrugated
Asbestos
Siding fails
Moves
slightly
from
original
position
Guyed
Corrugated
Asbestos
Louvers fail
Moves
slightly
from
original
position
02.0
03.0
Steel frame
deformation
03.5
Steel
frame
overturns
Blast
diagonally<
oriented.
Tower
collapses
04.0
Steel
frame
overturns.
Blast
squarely
oriented
05.0
06.0
Steel frame
collapse.
06.5
07.0
07.5
09.0
09.5
Flares
Tower
Supported
Vacuum
00.3
01.5
Water
Cooling
Tower
Stacks
collapse
Steel frame
collapse
Stacks
collapse
Steel frame
collapse
Brick walls
collapse.
Severe
frame
deformation.
Steel frame
collapses
Vessel
overturns
10.0
10.5
11.0
Collapse
above
middle
collar
Complete
collapse
15.0
20.0
Source:
Minimize Damage to Refineries From Nuclear Attack, National And Other Disasters, The Office Of Oil & Gas, U.S.
Dept. Of The Interior; February 1970
GAP Guidelines
12
GAP.8.0.1.1
June 2, 2003
TABLE 1D
Summary Of Blast Damage To Structures
Overpressure
(psi)
Pipe Bands
Steel Frame
Concrete
Frame
Boiler Stack
F.C.C. Unit
00.3
01.5
Tile walls
fail
Steel frame
deformation
04.0
05.0
06.0
06.5
07.0
Bulk
Terminal
Roof of
Admin.
Bldg.
collapses.
Cone roofs
of tanks
collapse
Cone Roof
Storage Tanks
Floating Roof
Empty
tank
uplift
Empty
tank
uplift
Concrete
frame
cracking
Concrete
frame
collapse
Steel frame
collapse
Stack and
foundation
overturn
Tanks uplift
(0.5 to 0.9)
filled)
Steel frame
deformation
Support
deformation
(full)
support
Support
deformation
(empty)
Overturns
(full)
Overturns
(empty)
07.5
09.0
09.5
Steel frame
collapse
10.0
10.5
11.0
15.0
20.0
Source:
Spherical
02.0
Bulk
Terminal
03.0
03.5
TEL
Building
Roof
collapse
Minimize Damage to Refineries From Nuclear Attack, National And Other Disasters, The Office Of Oil & Gas, U.S. Dept.
Of The Interior; February 1970
GAP Guidelines
13
GAP.8.0.1.1
June 2, 2003
TABLE 2
Blast Overpressure Effects On Vulnerable Refinery Parts
E Q U IP M E N T
0 .5
1 .0
1 .5
C O N T R O L H O U S E
S T E E L R O O F
A
C O N T R O L H O U S E
C O N C R E T E R O O F
A
E P
C O O L IN G
T O W E R
T A N K : C O N E R O O F
IN S T R U M E N T
C U B IC L E
2 .0
2 .5
3 .0
3 .5
4 .0
4 .5
F
D
7 .5
8 .0
8 .5
9 .0
>
9 .5 1 0 .0 1 2 .0 1 4 .0 1 6 .0 1 8 .0 2 0 .0 2 0 .0
L M
I
G
P
I
F
V
IP
P IP E S U P P O R T S
D
U
T
I
S O
P
U T IL IT IE S : G A S
M E T E R
U T IL IT IE S : E L E C T R IC T R A N S F O R M E R
R E A C T O R
C R A C K IN G
Q
H
L
T
L
H
E L E C T R IC M O T O R
B L O W E R
F R A C T IO N A T IO N
C O L U M N
T
R
P R E S S U R E V E S S E L :
H O R IZ O N T A L
T
T
P I
I
U T IL IT IE S : G A S
R E G U L A T O R
E X T R A C T IO N
C O L U M N
S T E A M
7 .0
T A N K F L O A T IN G
R O O F
6 .0 6 .5
R E A C T O R
C H E M IC A L
R E G E N E R A T O R
5 .5
F IR E D H E A T E R
F IL T E R
5 .0
M Q
I
V
I
T U R B IN E
V
S
T
I
H E A T E X C H A N G E R
T A N K : S P H E R E
P R E S S U R E V E S S E L :
V E R T IC A L
I
P U M P
T
V
Code
A.
B.
C.
D.
E.
F.
G.
H.
I.
J.
K.
L.
M.
N.
O.
P.
Q.
R.
S.
T.
U.
V.
GAP Guidelines
14
GAP.8.0.1.1
June 2, 2003
Outside of the 5 psi (0.35 bar) circle (but within the 3 psi (0.21 bar) circle) blast damage should be
considered to be a minimum of 70%. There is also a definite chance of broken piping leading to
ensuing fire. Sprinkler and waterspray systems will be damaged if not of proper explosion resistant
design which should include the following:
Outside of the 3 psi (0.21 bar) circle (but within the 1 psi (0.07 bar) circle), the blast damage will be a
minimum of 40%. There is less chance of broken piping and ensuing fire in modern plants, but the
possibility should be considered.
D h
Vc =
c
4
(9)
where:
Vc =
Dc =
h=
If the cloud is assumed to be at the midpoint of the flammable range and at atmospheric conditions:
M Patm Vc
W
=
u
R Tatm
(10)
where:
W=
Patm =
Tatm =
R=
u=
fraction of the cloud represented by vapor when the entire cloud is at the midpoint of
the flammable range. u is calculated from an average of the lower flammable limit
(LFL) and the upper flammable limit (UFL):
u=
LFL(%vol ) + UFL(%vol )
2 100%
By substituting equation 10 in equation 9 and solving for Dc, the approximate size of the resulting
vapor cloud may be calculated as follows (assuming that the vapor is heavier than air at its
atmospheric boiling point):
GAP Guidelines
15
(11)
GAP.8.0.1.1
June 2, 2003
Dc
4 R T atm
Patm
W
Muh
(12)
For gases that are lighter than air at their atmospheric boiling point, the size of the vapor cloud has no
meaning within the scope of this guide and should not be calculated.
English Units:
Dc (ft ) = 22.19
W ( lb )
M h (ft )
(12E)
W ( kg )
M h( m )
(12S)
SI Units:
Dc (m ) = 5 .544
Many cases have shown that a leak at low pressure will form a drifting vapor cloud about 10 ft
(3.05 m) high or deep.
Equations 12E and 12S can be reduced to:
English Units:
Dc (ft ) = 7.017
W ( lb )
M
(13E)
W ( kg )
M
(13S)
SI Units:
Dc (m ) = 3.174
If there is a reason to believe that a different cloud height is likely, a different height value can be
used. For example, discharge at a high point or a high pressure, directed upwards, may result in a
deeper cloud.
A sample calculation of a vapor cloud explosion loss estimate is shown in GAP.8.0.1.1.A.
VESSEL EXPLOSIONS
Background
Explosion of a vessel in a process unit can cause extensive damage to the process unit and
surrounding buildings, structures, and equipment. The intensity of the explosion is dependent upon
the size and ultimate failure pressure of the vessel. The driving force for the explosion is not
important. The cause of the overpressure can be runaway chemical reaction, overheating, or plugged
or inadequate vent facilities.
The process conditions or fire conditions which lead to the vessel failure are considered to be the
initial incident. The fact that a major process vessel ruptures explosively at its failure point is
considered to be a reasonably adverse condition. Thus, it is not necessary to assume that any fire
GAP Guidelines
16
GAP.8.0.1.1
June 2, 2003
protection facilities will be impaired prior to ignition. Damage and impairment, however, may occur
due to the explosion.
Calculation Method
The TNT equivalent of the potential energy of a gas above ambient temperature and stored at
pressure can be calculated by the textbook formula for isothermal expansion:
E = n R T ln
1
P2
(14)
where:
E = energy of isothermal expansion
n = number of moles of gas
R = gas constant
T = gas temperature
P1 = initial pressure
P2 = final pressure after expansion
The number of moles of gas contained in a given vessel can be determined using the Ideal Gas
Law:
PV = RT
(15)
P1
P2
(16)
where:
E = energy of isothermal expansion
P1 = maximum pressure of vessel at failure
V = volume of gas in vessel
P2 = final pressure after expansion
The energy released in a vessel explosion may now be estimated. This energy release is normally
expressed as a TNT equivalent. Thus, based on the heat of combustion for TNT of 2000 Btu/lb
(4648 kJ/kg), the following equation may be used to calculate a TNT equivalent for a vessel
explosion:
GAP Guidelines
17
GAP.8.0.1.1
June 2, 2003
We =
PV P
E
= 1 ln 1
ce
ce P2
(17)
where:
We =
Weight of TNT which will produce an explosive force equivalent to the force
produced by explosion of the vessel.
Hce =
A simplified form of equation 17 can be used since the expansion of the gas is into the open air
(P2 = Patm):
We =
P1V
P
E
=
ln 1
ce
ce P atm
(18)
English Units:
E (Btu ) = 0.185P1 ( psia ) V (ft 3 ) ln
P1 ( psia )
14.7
P1 ( psia )
14.7
(17E)
(18E)
SI Units:
E (bar ) = 1 10 5 P1 (bar ) V (m 3 ) ln
W e (kg ) =
P1 (bar )
1.013
(17S)
1 10 5 P1 (bar ) V (m 3 ) P1 (bar )
ln
1.013
4,648,000
P1 (bar )
1.013
(19S)
The maximum pressure of the vessel at failure P1 should be, in most cases, the maximum failure
pressure of the vessel for a runaway reaction where vent facilities are plugged or overtaxed. The
pressure at which the vessel will fail is often approximately four times the maximum working pressure
of the vessel. However, if lower or higher design safety factors were used and can be documented,
the actual multiplier should be used.
It is conceded that vessels also fail for reasons other than simple overpressure. Mechanical failure
due to overheating or corrosion/erosion thinning can result in failure at pressures at or below the
normal working pressure of the vessel. However, the use of the maximum yield pressure of the vessel
will give a conservative result.
The value of We obtained is then used with the graph in Figure 1 to determine the diameter of the
overpressure circles. As with the vapor cloud calculation, the maximum overpressure assumed is
GAP Guidelines
18
GAP.8.0.1.1
June 2, 2003
5 psi (0.35 bar). Determination of damage from explosion and ensuing fire should be done utilizing
the minimum damage amounts outlined for vapor cloud explosions.
A sample calculation is shown in GAP.8.0.1.1.B.
GAP Guidelines Referenced
GAP.2.5.2
REFERENCES
1.
R. W. Gallant, Physical Properties Of Hydrocarbons, Volumes 1 & 2, Gulf Publishing Company, Houston, TX.
2.
R. H. Perry, D. Green, Perrys Chemical Engineers Handbook, 6th edition, McGraw-Hill Book Company, New York, NY.
3.
NFPA Handbook, 16th edition, Section 5, Chapter H, National Fire Protection Association, Quincy, MA.
GAP Guidelines
19