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Dr. C. Samanta
Dr. R. K. Voolapalli
Manager
(R&D) BPCL
Chief Manager
(R&D) BPCL
Scientist
IIP, Dehradun
Director
IIP, Dehradun
DME
Propane
n-Butane
Methane
Methanol
Diesel
6,900
11,100
10,930
12,000
4,800
10,000
4,620
5,440
6,230
5,040
3,790
8,400
14,200
21,800
28,300
8,600
n.a
n.a
3.4~ 17
2.1~9.4
1.9~8.4
5~15
5.5~36
0.6~6.5
Cetane number
55~ 60
10
40~55
Viscosity
(Kg/m3 at 25C)
0.12~ 0.15
0.2
0.2
0.7
2~4
Liquid density
(Kg/m3 at 25C)
0.67
0.49
0.57
0.42
0.79
0.84
Boiling pt (C)
-25
-42
-0.5
-162
65
180~370
Fig 2: DME can be produced from multiple feedstock through direct and indirect syn-gas conversion routes
Synthesis of DME
Two processes have been claimed so far
for the production of DME known as
2 CO + 4 H2
(ii) 2 CH3OH
2 CH3OH
! CH3OCH3 + H2 O
H0 = -182.2 kJ/mol
G0 = -4.5 kJ/mol,
H0 = -23.5 kJ/mol
G0 = -62.5 kJ/mol,
H0 = -205.7 kJ/mol
In case the water gas shift reaction (4) supported by the catalyst
(iv) CO + H2O
! CO2 + H2
G0 = -28.6kJ/mol,
H0 = -41.2 kJ/mol
! CH3OCH3 + CO2
CH3OH + H2O
G0 = -91.10 kJ/mol,
H0 = -246.6 kJ/mol
H0 = -50.1 kJ/mol
Methanol Synthesis
Operating conditions
Catalyst: CuO (60-70%)-ZnO (20-30%)-Al2O3
(5-15%) or Cr2O3 (5-15%)
Temperature: 220-300 0C
Pressure: 50-100 Atm ( 5-10MPa)
Composition of the feed : 59-74 H2, 15-27%
CO, 8% CO2, 3 % CH4,
Conversion of CO to methanol per pass is
normally : 16-40%
H2 : CO ratio : 2.17
The selectivity to methanol: ~99.8%.
Under normal commercial operating conditions,
CuO/ZnO/Al2O3 methanol catalysts have quite long
lifetimes, up to 2-5 years.
Fig 4: Scopus search data on publications with key words in topics Direct DME Synthesis, vs Years.
Fig 5: Schematic overview of direct DME synthesis from syngas (source JFE)
Summary
DME is emerging as an alternative renewable fuel
and has potential to replace crude oil derived fuels
viz. diesel and LPG. Since DME can be produced
from a variety of locally available feedstock DME
production is not dependent upon the price of crude
oil which will help in offering its competitive price
with that of diesel. China, Japan, European Union
and North America are aggressively promoting DME
as a cleaner fuel for transportation.
The recent EPAs approval of biogas-based DME is
a significant milestone for DME industry which is
going to greatly promote the use of DME as an
environmentally friendly renewable fuel in the years
to come. Leading automobile industry giants such
as Renault and Volvo have developed DME based
fuel engine for buses.
In India, LPG is used for cooking in more than
33 million homes, and the demand is increasing with
imports rising rapidly. In Australia, over half a million
vehicles use LPG - all of which could be powered
using DME. In both cases, DME can immediately
be used as a blend with LPG without the need to
change infrastructure. While renewables are still
being developed, DME has huge potential to help
both India and Australia to move from a high carbon
society to a low one.
One of the major hurdles for DME to be used a
commercial transportation fuel is however, cost
involved in investment and setup of distribution
infrastructure. Development of efficient small-scale
DME plant based on direct DME synthesis would
drastically reduce DME production cost. In addition,
due to its lower viscosity and lubricity than diesel
DME needs purpose built fuel injection systems.
Requirements for modifications to the fuel
distribution infrastructure and vehicle engine parts
to accommodate the use of DME will influence the
market introduction from bus and truck fleets to
passenger diesel cars.