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QUALITY
:: Furan Analysis ::
HGE120025
HGE120018
HGE120023
HGE120021
| Slide 1
:: Furan Analysis ::
>>Overview
| Slide 2
>>Overview
1. Transformer is an important component in the electricity network.
2. Transformer insulation consists of the following & the performance of the
transformer itself depends on the integrity of these materials eg. mineral oil,
paper insulation or cellulosic materials i.e pressboard or woods
3. Life of transformer is determined by the life of its paper insulation.
4. Age of the paper insulation is determined by the mechanical strength of the
paper and is measured in terms of its Degree of Polymerisation (DP).
5. Estimating DP from the oil furan concentration in particular is a non-intrusive
method as it need not take the transformer out of service as it is not possible to
take paper samples during running operation.
6. Therefore, the DP value is determined on the basis of cellulose decomposition
products i. e. furans. These are partly oil-soluble and give some indication of
the rates of decomposition of the solid insulation.
| Slide 3
:: Furan Analysis ::
>>Introduction (Komal)
| Slide 4
>>Introduction
1. Main objective of furan testing is to determine whether the paper in a given
transformer has been or is being damaged by:
Heat
Oxygen
Moisture
2. Furanic compounds found in transformers are solely formed by the degradation
of the cellulosic insulation.
3. The causes of paper to degrade from original state could be due to:
Mechanical stresses i.e internal mechanical vibration & design
weaknesses reduces the paper insulation mechanical tension
Electrical stresses i.e high loading, overheating, arching & partial
discharges causes paper insulation to loose its polymerisation integrity
Environmental i.e high humidity & moisture content in air around the
transformer contributes to cellulose paper insulation deterioration
Type & quality of paper
Type & quality of oil
Operating condition i.e high loading or operation at maximum loading
affects the paper insulation mechanical and chemical strength.
| Slide 5
>>Introduction
Moisture
Content
Acid
Number
Furans
Oil
Analysis
Dissolved
Gas
Analysis
Dielectric
Strength
Power
Factor
| Slide 6
>>Introduction
Furan derivatives are a measure of the degradation
of cellulose paper. When the paper ages, its degree
of polymerization reduces, so its mechanical strength
decreases.
The degree of polymerization can only be determined
directly by taking a sample of paper, a very complex
operation and almost never performed in practice.
However, the degree of polymerization of the paper
can be directly related to the concentration of furan
derivatives in the oil.
| Slide 7
>>Introduction
Furan derivate are formed as a direct result of the
breakdown of the polymeric structure of cellulose
paper.
The content of furan derivatives is relatively easy to
measure in the oil, using HPLC and is thus a way of
measuring the aging of the paper.
| Slide 8
:: Furan Analysis ::
>>Types & Properties
| Slide 9
| Slide 10
Ball-Stick Model
Skeletal Formula
| Slide 11
2-Furaldehyde or 2FAL
2-Acetylfuran or 2ACF
5-Methyl-2-Furaldehyde or 5M2F
2-Furfurol or 2FOL
5-Hydroxymethyl-2-Furaldehyde or 5HM2F
| Slide 12
:: Furan Analysis ::
>>Procedure
| Slide 13
>>Procedure (Sampling)
Proper Transformer Sampling (ASTM D923)
The ability of insulating oil analysis to provide an
early sign of a problem condition is dependent on the
quality of the oil sample that is sent to the lab.
| Slide 14
>>Procedure (Sampling)
Proper Transformer Sampling (ASTM D923)
Fluids with specific gravity greater then 1.0 should be
sampled from the top because free water will float.
For fluids with a specific gravity less than 1.0, such as
mineral-based transformer oils, synthetic fluids and
silicone oils, the sample should be taken from the
bottom since water will tend to drop to the bottom in
these fluids.
| Slide 15
>>Procedure (Sampling)
| Slide 16
>>Procedure (Sampling)
Proper Transformer Sampling (ASTM D923)
The ideal situation for collecting a sample from an
electrical apparatus is 95F (35C) or higher, zero
percent humidity and no wind.
Cold conditions, or conditions when relative humidity is
in excess of 70 percent, should be avoided, as this will
increase moisture in the sample.
Collecting a sample during windy conditions is also not
recommended because dust and debris enter the clean
sample easily and disrupt accurate particle counts.
| Slide 17
>>Procedure (Sampling)
| Slide 18
>>Procedure (Sampling)
| Slide 19
>>Procedure (Analysis)
High-Performance Liquid Chromatography (HPLC) is
a reliable method to perform furan analysis on
transformer oil. The standards are IEC 61198 and
ASTM D5837.
Using the High Performance Liquid Chromatography
(HPLC) test method, it is prerequisite that the sample
is soluble in a solvent as the measured substances
cannot be transferred into the gaseous phase without
decomposition (by contrast to a gas
chromatography).
| Slide 20
>>Procedure
| Slide 21
>>Procedure (Analysis)
| Slide 22
>>Procedure
The five compounds mentioned above are separated
on an appropriate column and each is detected by
use an ultraviolet detector that is adjusted
automatically to the appropriate wavelength for each
of the five components.
| Slide 23
>>Procedure (Analysis)
IEC 61198: Method for the determination of 2-furfural
and related compounds in mineral insulating oils.
ASTM D5837: Standard test method for furanic
compounds in electrical insulating liquids by HighPerformance Liquid Chromatography (HPLC).
10g of oil are solved in 10 ml of pentane for the
measurement. This mixture is drawn through a silica
gel column by negative pressure where the polar
cellulose elements (furan derivates) accumulate.
| Slide 24
>>Procedure (Analysis)
After that 20 ml of pentane are flushed through the
column to remove all remaining oil components. After
drying of the silica gel column in a vacuum, the
adsorbed furan derivates are extracted by 10ml of
acentonitrile into a volumentric flask.
After flushing of the chromatograph column the
extracted mixture is injected into the sample loop out of
the volumetric flask and the measurement is started.
The sample is pumped through a column. Depending
on the kind of the furan derivates there is an interaction
between the derivates and the stationary phase of the
column.
| Slide 25
>>Procedure (Analysis)
If there is a strong interaction, the substance remains
relatively long in the column (long retention time). If
there is a weak interaction, the respective substance
passes the column quicker (short retention time).
A UV/VIS detector at the end of the column can at the
same time measure the intensity and the kind of the
furan derivates.
| Slide 26
>>Procedure
Calibration solutions are made up for each of the
components to be analyzed and there are used to
standardize the instrument responses.
From the data on the standard solutions, the
extraction efficiencies for each component can be
calculated and corrections can be made accordingly.
The results are usually reported in terms of parts per
billion (ppb).
0 100 ppb = Acceptable; 101- 1000 ppb = Marginal;
Greater than 1000ppb = Unacceptable
| Slide 27
:: Furan Analysis ::
>>Case Studies
| Slide 28
>>Direct Evaluation
| Slide 29
| Slide 30
>>Furan Analysis
| Slide 31
| Slide 32
DP Value
Significance
0-0.1
1200-700
Healthy transformer
0.1-1.0
700-450
Moderate deterioration
1-10
450-250
Extensive deterioration
>10
<250
DP RANGE
<200
200-250
REMARK
Test indicates extensive paper degradation exceeding the critical point. Strongly
recommend that the transformer be taken out of service immediately and visually
inspected.
The paper is near or at the critical condition. Recommend that the transformer be taken
out of service as soon as possible and thoroughly inspected. Paper samples can be
taken for direct DP testing.
260-350
The paper is approaching the critical condition. Suggest inspection be scheduled and/or
re-sample within 1 year to reassess condition.
360-450
The paper is starting to approach the critical condition. Suggest a re-sample in 1-2 years
time.
460-600
Significant paper deterioration but still well away from the critical point.
610-900
>900
| Slide 33
INSULATION FAILURE
The Progression Towards Insulation Failure
| Slide 34
TRANSFORMER DETAILS
Primary Voltage: 11 kV
Impedence: 4.1%
Conservator: No
| Slide 35
| Slide 36
| Slide 37
Dyn11
Impedance: 5.41%
Conservator: Yes
9.90
218
3.08
2.0 (max)
7.87
| Slide 38
| Slide 39
| Slide 40
RESIDUAL SLUDGE
BY PRODUCTS OF OIL OXIDATION
| Slide 41
>>Conclusion
The use of furanic compounds can greatly aid in the
assessment of the condition of the solid paper insulation which
is useful in analysis of incipient fault condition and causes of
failures.
Some of the furanic compounds have sufficient stability in
transformer that they may provide useful information about the
long term aging of the cellulosic insulation.
Furan analysis enables test to be carried out without affecting
the operation of the transformer
| Slide 42