Professional Documents
Culture Documents
Contents
Introduction
11
Product description
13
15
Overview of applications
16
17
23
Lead stabilization
23
Calcium/zinc stabilization
26
Tin stabilization
27
Basic Formulations
28
30
32
33
35
Introduction
As a rule, thermoplastics are usually processed in a melt.
Many plastics are not chemically stable enough at the
necessary processing temperatures. The results are
oxidation, cross-linking, chain scission, etc. The thermal
sensitivity of PVC is well known. Hydrogen chloride already
begins to split off above 120 C and is associated with
dramatic losses in the optical, mechanical, and rheological
characteristics of the polymer. The rapid discoloration
(charring) and the formation of corrosive fragmentation
products (HCl) are the main problems in this context.
Thermostabilizers make it possible to eliminate or reduce
substantially the splitting off of hydrogen chloride. In
addition to the thermal stress, the plastic melt is also
subject to strong mechanical stress (shear and friction)
during processing. Depending on the processing method,
80 % of the heat energy is brought into the polymer via
friction and only about 20 % through direct heating.
Additives that have a favorable effect on the flow behavior
of the polymer melt are therefore indispensable for troublefree processing. They are called lubricants or waxes.
Volatility
In everyday plastics processing, the volatility of lubricants plays an important role. The
formation of vapors and condenses on machines and equipment parts not only impairs production, but also working conditions for the personnel. In extrusion processes the effect is
seen in the form of deposits on the nozzles. In calendering films, with their large open melt
surfaces, formation of vapors is especially critical. In injection molding too, deposits on the
tools are undesirable. Low-molecular fatty acid esters are viewed as particularly critical in
this context.
Figure 1:
Morphological structure of PVC
Secondary particle
(particles)
Globules
(microparticles)
Nodules
(submicroparticles)
100 m
1 m
10 nm
Plasticization
Shear dependent
viscosity control
Reduction of friction
Viscosity reduction
Release effect
Slip effect
Figure 2:
Mode of action of lubricants
Lubricants with long hydrocarbon remnants protect the globules and prevent degradation
into nodules. However, viscosity is lower when there are fewer nodules. Experience has
shown that ester lubricants with long (C26-C32) non-polar remnants, such as montanic acid
esters, display a wide processing range and are less susceptible to variations in shear
speeds (fig. 4). In practice the use of montan waxes is said to provide a wider processing
window (shear dependent viscosity control).
Montanic acid esters in particular are typical examples of such ester waxes. They delay
slightly the gelation of the PVC mass, but thanks to their polar groups, they are anchored to
the globules adequately enough that no plateout occurs. This provides optimal prevention
of adhesion to the hot machine parts. In addition, there is almost no effect upon melt
strength and Vicat softening temperature.
Influence on intrinsic viscosity and melt strength of PVC
Intrinsic viscosity is understood as the drop in viscosity of a melt with increasing shear.
For example, lubricants that increase the intrinsic viscosity of PVC are especially useful
in extrusion processes, in which there are areas of different shear speed. In especially
shear-intensive zones in the extruder, a less viscous melt exerts less resistance, thus
lessening the danger of local thermal overload (i. e., charring). In zones of reduced shear,
the melt is thicker, and it is easier to introduce heat energy. In addition, the melt displays
higher firmness where there is low shear, e. g., in the shaping area (nozzle) or when
drawing a calender film.
External
Fatty acid ester
Fatty acid amide (Licowax C)
Figure 3:
Classification of various lubricants
by their effect in tin-stabilized PVC
Figure 4:
Viscosity in relation to modulus
of shear deformation
Model
Melt
Spring
Elasticity
Damper
Viscosity
Figure 5:
Spring-damper model
of viscoelastic behavior
Put simply the plastic melt has a memory: if the material is compressed for only a short time
(e. g., in a very short nozzle), it tends to relax and resume its original form immediately after
leaving the pressure zone. If the kneading mass does not run optimally through the roll gap
and displays waves and deformation, these waves will also appear again as flow lines on the
other side of the gap. This behavior can also be quantified via the die swell, which, for example
in injection molding, represents an undesirable effect (fig. 6).
Basically there are two ways to influence viscoelastic behavior.
First: Improve the flowability of the melt by adding internal lubricants or by selecting a
suitable type of PVC. However, the former have the disadvantage of lowering melt strength.
Second: Control swelling behavior through suitable additives. While PMMA copolymers
(processing aids, high-molecular release agents) have a great influence on swelling,
lubricants with release properties have practically no such effect.
50
45
40
Figure 6:
35
30
additives
25
20
+ 0.5
phr*
Licowax E
+ 0.5
phr
Licolub WE 4
100.0 parts
1.5 phr
0.5 phr
+ 0.5
phr
Fatty acid
complex ester
+ 0.5
phr
High-molecular
release agent
+ 1.0
phr
High-molecular
release agent
10
11
12
Outlook
Lubricants are present in formulations in only small quantities, but they have a decisive effect
on the rheology and, in part, on the characteristics of the PVC.
Unfortunately, there is no ideal lubricant. Instead, based on the customers requirements
profile and the equipment conditions, an optimal formulation must be developed, which,
as a rule, cannot be finalized until a production test is done. An important parameter in the
selection of the components of the formulation is price, which also applies to the lubricant.
However, price means the effective price, i. e. the price/performance ratio. The following
information will show that high-quality lubricants based on montan wax can have a positive
influence on many characteristics, help avoid problems, and thus have an optimal price/
performance ratio.
Product description
Based on their chemical structure, Licowax, Licolub and Licocene can be divided into
5 groups:
Montan waxes
The montan wax esters Licowax E, Licowax OP, Licolub WE 4, Licolub WM 31 and
Licolub WE 40 are secondary products of the oxidative refinement of raw montan wax.
The montanic acids contained in raw montan wax are unbranched, even-numbered
monocarboxilic acids with chain lengths in the range of C26-C32. These long-chain montanic
acids result in low volatility for these products.
Licowax E, Licolub WE 4, and Licolub WE 40 are esters of montanic acids with ethylene
glycol and glycerol, in which the latter are complex esters. Licowax OP differs from these
products in that the montanic acids are only partially esterified with butanediol and that
the rest is saponified with calcium hydroxide. Licowax OP thus contains not only montanic
acid esters but also calcium montanate, and it thus displays additional effects (binds acid).
Licolub WM 31 is an ester based on montanic acids and long chain, aliphatic acids.
Due to its polar centers and the long, non-polar hydrocarbon chains, the montanic acid
esters combine internal and primarily external lubrication effects in PVC:
Maintenance of transparency
Intrinsic viscosity
Low volatility
Melt strength
13
Polyethylene waxes
The low molecular weight PE waxes from Clariant are waxes polymerized using the Ziegler
and the Metallocene process, with especially high thermostability. They thus differ from
decomposition waxes, which are usually produced through thermal decomposition of
polyethylenes.
Licowax PE 520 is a medium-molecular, branched polyethylene wax with low density
and is marked by high resistance to oxidation and thus high color and viscosity stability.
Licowax PE 520 and Licowax PE 190 have a strong external lubricating effect in PVC.
Licowax PE 190 is a high-molecular, linear PE wax with high density and is used preferably
in the production of transparent PVC articles.
Licocene PE 4201 is a medium-molecular, low branched metallocene polyethylene wax with
even stronger external lubricating effect in PVC than Licowax PE 520 and Licowax PE 190.
Licowax PED 191 is a high-molecular, oxidated, and thus polar PE waxes, which is used
primarily in tin-stabilized rigid PVC due to its strong nonstick effect and high transparency
for sheet extrusion and the production of blow molded parts. In addition it promotes
gelation in lead-stabilized or calcium / zinc-stabilized PVC.
Licolub H 12, a polar PE wax based on Licowax PE 520, also has a strong antisticking
effect. Important areas of applications are pipe and profile extrusion and extrusion blow
molding, especially when the final product does not require high transparency.
Polypropylene wax
Licocene PP 6102 is a isotactic metallocene polypropylene wax and has a strong external
lubricating effect in PVC. It is suitable for regulation of gelation behavior of Pb-stabilized
and Ca/Zn-stabilized PVC mixtures and provides a more moderate buildup of pressure in the
extruder in comparison to Licowax PE 520.
Hydrocarbon wax
Licolub H 4 is a modified hydrocarbon wax with an external lubricating effect, which is used
primarily in extrusion (Pb-/Sn-stabilized) and in injection molding of opaque PVC products.
Amide wax
Licowax C is an amide wax of type N,N-bis-stearyl ethylenediamine with particularly good
thermostability. It provides PVC film with slip (rigid sheets) and anti-blocking characteristics
(flexible films) as well as good release properties in injection molding applications (flexible
PVC). During processing it acts predominantly as an internal lubricant to improve flow.
Test methods
Drop point
Acid value
Density (23 C)
Viscosity
14
[C]
[mg KOH/g]
[g/cm 3]
[mPas]
ISO 2176
ISO 2114
ISO 1183
DIN 53018
Chemical characteristics
Licowax E
Montan wax-based
ester wax
Licowax OP
Acid value
[mg KOH/g]
Density
23 C [g/cm 3]
Viscosity
[mPas]
~ 81
~18
~ 1.02
~30
~ 99
~ 12
~ 1.02
~ 300
~ 75
~ 12
~ 1.00
~ 26
~ 80
~ 26
~ 1.01
~ 76
~ 20
1.02
Color
pale yellowish
yellowish
Ca 2+
Licolub WM 31
Licolub WE 4
Montan wax-based
ester wax
Licolub WE 40
Complex ester of
montanic acids
yellowish
~ 60
yellowish
~ 150
yellowish
almost white
Licowax C
Amide wax
~ 142
~ 6
~ 1.00
Licolub H 12
~ 104
~ 17
~ 0.95
~ 300
almost white
~ 123
~ 17
~ 0.98
~ 1,800
almost white
Licowax PE 190
~ 135
~ 0.96
~ 25,000
Licowax PE 520
~ 120
~ 0.93
~ 650
Licolub H 4
~ 110
~ 0.92
~ 13
white
white
white
white
white
~ 145
~ 0.90
~ 60
~ 127
~ 0.97
~ 60
a = at 100 C, b = at 120 C, c = at 150 C, d = at 140 C, e = at 170 C, f = softening point according to DIN 51920, ASTM D 3104
15
Overview of applications
Overview of the main uses for Licolub and Licowax in various types of PVC processing
Product
Calendering
Extrusion
Licowax C
Licowax E
Licowax OP
Licowax PE 190
Licowax PE 520
Licocene PE 4201
Licowax PED 191
Licocene PP 6102
Licolub H 4
Licolub H 12
Licolub WE 4
Licolub WE 40
Licolub WM 31
16
Injection
molding
Foam
applications
Flexible
applications
Extruder
Homogenization
Viscosity reduction
Phase compatibilizing
Dispersion
Calender
Anti-blocking effect
(Viscosity)
Printability
Figure 7:
Calender film production as
processing steps
Transparency
Thermostability
With the waxes from Clariant, Licowax and Licolub, you can get the job done. The montanic
acid esters in particular provide a high degree of processing safety and result in good
product characteristics:
n
n
n
Licolub WE 4
Licolub WE 40*
Licolub WM 31*
n
n
n
Licowax OP
Licowax E
Licowax C
From a technical point of view, these are the highest-quality additives for the production of
PVC calender films (fig. 8).
Advantages
Effects
Improved flow
Release effect
Demolding properties
High melt strength
Dimensional stability
Figure 8:
Advantages and effects
of the montan waxes in PVC
Less condensation
Transparency
No plateout
17
18
The release effect of various lubricants is usually determined on the two-roll mill by measuring
the time it takes for the melt to stick to the roll. The longer the tack-free time, the better the
release effect. The following test (fig. 9) shows that high-molecular release agents have a
corresponding effect, but only at much higher dosages and without an additional lubricating
effect.
In assessing lubricants, however, one must always consider the entire formulation. It is
known that various additives can influence each other. Thus, as a rule, higher amounts of
release agents have to be used in formulations with impact modifiers. There can be two
different causes for this situation. For one thing, the addition of MBS impact modifiers
(methacrylic styrene-butadiene copolymers) can increase tackiness. For another, it is also
possible that the lubricants will dissolve preferably in the MBS phase and thus no longer be
available to reduce tackiness on the surface of the PVC.
Licolub WE 4 displays a better release effect, in formulations both with and without MBS,
i. e. a longer tack-free time than the fatty acid complex ester and Licowax E (fig. 10). The
latter in turn offers advantages regarding rapid gelation and high transparency (see below)
in comparison to the other lubricants.
30
25
Figure 9:
20
Influence of release-effective
15
lubricants in comparison to
high-molecular release agents
10
5
0
Licowax E
0.5 phr
Licolub WE 4
0.5 phr
High-molecular
release agents
0.5 phr
High-molecular
release agents
1.0 phr
19
Without MBS
40
35
Figure 10:
Comparison of the effect of fatty
montan wax on tack-free time for
formulations with and without MBS
30
Tack-free time [min]
25
20
15
10
5
0
Licowax E
Licolub WE 4
Fatty acid
complex ester
100.0 parts
1.5 phr
0.3 phr
0.3 phr
With MBS
40
35
30
25
20
15
10
5
0
Licowax E
Licolub WE 4
20
Fatty acid
complex ester
100.0 parts
8.0 phr
1.0 phr
1.5 phr
0.5 phr
0.5 phr
With the help of a measuring rolling mill, it is possible to quantify not only the tack-free time
but also the adhesive force. In addition, it is possible to track the tackiness of a formulation
relative to time, which can produce interesting results (fig. 11).
Here the advantage of Licolub WE 4 compared to fatty acid complex ester is obvious too.
After longer processing time, the FACE deviates from Licolub WE 4, i. e., the adhesive force
of WE 4 remains at the desired level throughout the duration of processing.
When using mixtures of fatty acid complex esters and fatty acid esters (FACE/FAE) it is
common to use 0.5 -1.0 phr high-molecular-weight, release agent, too in order to improve
tack-free time. By replacing FACE/FAE with Licolub WE 4 this release agent can be
significantly reduced (fig. 12), wich leads to cost minimization.
60
50
Fatty acid complex ester
40
Figure 11:
30
Licolub WE 4
20
Differentiation of lubricants
on a measuring rolling mill
10
0
0
200
400
600
800
1,000
1,200
1,400
Time [sec]
Formulation: S-PVC, k-value 60
parts
Octyltin stabilizer
Glycerol dioleate
100.0
1.2 phr
0.5 phr
6.0 phr
0.5 phr
0.3 phr
without high-molecular-weight
release agent
40
35
34
32
Figure 12:
Release effect of Licolub WE 4 in
30
25
23
19
20
mixture
15
10
5
0
Mixture of
FACE/FAE
Licolub WE 4
Mixture of
FACE/FAE
Licolub WE 4
100.0
1.5 phr
8.0 phr
1.0 phr
0.6 phr
0.5 phr
21
In comparison to Licowax E, Licolub WE 4 has a better release effect under slight loss of
transparency (fig. 13), although Licolub WE 4 is still better than the fatty acid complex ester.
Licowax OP is used primarily for film formulations that contain acetate copolymers, since
the calcium montanate it contains has a co-stabilizing effect. Here too the advantages of the
montan waxes compared to fatty acid complex ester mixtures are seen (fig. 14). Licowax OP
clearly offers longer tack-free time than the corresponding fatty acid ester containing
calcium, and the gelation time is shorter. For results with Licolub WM 31 please regard our
flyer Licolub WM 31.
If slip effects are needed for rigid PVC films, then amide waxes are used, i. e., Licowax C
(dosage 0.1 - 0.3 phr). However, in case these films are to be further processed (e. g., printed,
metalized, etc.), the strong migration tendency of this type of wax to the film surface
should be taken into consideration and the dosage adjusted accordingly. Upon request,
our Marketing / Technical Service Department of the Business Line Waxes will be happy
to provide you with model formulations for a wide variety of film applications.
90
Figure 13:
Influence of various montan waxes
vs. fatty acid complex ester on
Transparency [%]
89
88
87
86
85
84
sheets)
83
Licowax E
Formulation: M-PVC, k-value 57
MBS impact modifier
PMMA processing aid
Octyltin stabilizer
Licolub WE 4
100.0 parts
8.0 phr
1.2 phr
1.6 phr
Licolub WE 40
ESBO*
Glycerol dioleate
Test product
FACE
1.0 phr
0.3 phr
0.6 phr
Figure 14:
Release effect and gelation
behavior of fatty acid esters
containing calcium (Ca-FAE/FACE)
in comparison to Licowax OP
18
16
129
14
124
12
10
8
119
6
4
114
2
0
109
Ca-FAE/FACE
22
Licowax OP
100.0 parts
1.5 phr
8.0 phr
1.0 phr
0.6 phr
0.5 phr
134
20
Lead stabilization
Licocene PE 4201
n Licolub H 12
Licolub H 4
n Licowax PED 191
n Licowax PE 520
n
n
n
Licolub WM 31
Licowax E
Licowax OP
Due to the relatively strong lubricating effect of lead stabilizers, the addition of a certain
amount of external lubricants is usually sufficient in these systems.
The lead salts are combined with neutral and / or dibasic lead stearate and calcium stearate.
The lead salts provide acceptable flowability, and stearic acid (which reacts on the surface
of the lead oxides) and hydrocarbon waxes can be added in order to delay gelation. These
provide also good slippage along the walls in the extruder head and nozzle. However, if the
dosage is too high, there is a danger that deposits will form on the nozzles.
Licowax PE 520 (PE wax) and even more Licocene PE 4201 are used to regulate gelation
behavior, i. e., they delay gelation and improve the surface, especially the gloss of
Pb-stabilized PVC compounds. The amounts added range from 0.05 to 0.2 phr.
23
24
The hydrocarbon wax Licolub H 4 also acts as an external lubricant. Licolub H 4 and
Licocene PE 4201 are used predominantly in the production of pipes. Dosage: 0.2-0.6 phr.
Oxidized PE waxes, such as Licolub H 12, increase energy input in the extruder and thus
provide optimal, early gelation. Its positive influence on gelation can be strengthened
through the use of high-molecular, oxidized PE waxes, i. e. Licowax PED 191 (fig. 15). As
a result of the even faster gelation, the better homogeneity of the melt leads to improved
physical characteristics and higher surface gloss. Dosage: 0.1-0.4 phr.
For high-quality profiles, e. g., profiles for windows, combination with the partially saponified
montan wax ester Licowax OP or the montan wax ester Licowax E and Licolub WM 31
(0.3-0.5 phr wax) is recommended. The profiles then have a smooth surface even at high
pigment and filler contents, without impairing weldability or thermostability.
60
55
Figure 15:
Energy input of oxidized PE waxes
50
45
40
Licolub H 12
Formulation: S
-PVC, k-value 60
parts
PMMAprocessing aid
CaCO3
Lead stabilizer mixture
Hydrostearic acid
Distearyl phthalate
Lubricant combination
Test product
100.00
2.00
5.00
4.75
0.20
0.60
0.35
0.20
phr
phr
phr
phr
phr
phr
phr
Cylinder temperature:
175/185/190 C
Tool temperature:
185/185/190/200 C
25
Licocene PE 4201
Licocene PP 6102
n
n
Licolub H 4
Licolub H 12
Licowax PE 520
Licolub WE 40
In Ca/Zn-stabilized systems, depending on the chain length of the Ca/Zn compound, the
stabilizer has hardly any self-lubricating effect. Therefore somewhat higher quantities of
lubricants and processing aid are needed. To reduce friction fatty acid esters are used,
or, in profile applications, the use of montanic acid esters is recommended.
In these compounds too the non-polar and thus incompatible waxes Licowax PE 520,
Licolub H 4, Licocene PE 4201 and Licocene PP 6102 act as external lubricants, which
regulate gelation behavior. In comparison to Licowax PE 520, the Licocene waxes causes
a later and lower build-up of pressure in the extruder as well as stronger nozzle lubrication.
The polar and thus partially compatible lubricants Licolub H 12 (oxidized PE wax) and
Licolub WE 40 (montanic acid complex ester) fulfill the same functions already described
for the lead-stabilized compounds. As a rule, the additive quantities are from 0.2-0.4 phr.
An example of how oxidized PE wax increases energy input is shown in figure 16.
Figure 16:
Increase in energy input through
70
65
60
55
50
Without
+ 0.1 phr
Licolub H 12
Formulation: S
-PVC, k-value 68
100.0
parts
PMMAimpact modifier
6.0 phr
5.0 phr
CaCO3
3.0 phr
TiO2
Ca/Zn-stabi. compound
without lubricant
3.0 phr
Hydroxystearic acid
0.3 phr
Licolub WE 40
0.3 phr
Licowax PE 520
0.3 phr
26
+ 0.2 phr
Licolub H 12
Cylinder temperature:
175/185/190 C
Tool temperature:
185/185/190/200 C
Tin stabilization
n
Licocene PE 4201
Licowax PE 520
Licolub H 4
Licolub H 12
Licowax PED 191
n
n
Licolub WE 4
Licolub WM 31
PVC compounds produced with tin stabilizers tend to stick to hot metal parts on the
processing equipment. Therefore the use of external and internal lubricants is indispensable.
Calcium stearate is normally used in large quantities, acts as a co-stabilizer, and supports
gelation. The build-up of pressure in the extruder and the lubricating effect are controlled
by non-polar hydrocarbon and PE waxes (Licolub H 4, Licowax PE 520 and Licocene PE 4201).
For higher requirements concerning anti-sticking, oxidized PE waxes (Licolub H 12, Licocene
PE 4201 and Licowax PED 191) are preferred. Furthermore, the use of montan waxes (Licolub
WE 4 and Licolub WM 31), e. g., in the production of high-quality profiles, offers a large
number of technical (and economical) advantages, which have already been described in
detail in the preceding sections.
27
Basic Formulations
Pipes /profiles
Ca/Zn pipe formulation
S-PVC, k-value 65-68
Ca/Zn stabilizer compound
Phosphite (e. g. TNPP)
PMMA impact modifier
Distearyl phthalate
Hydroxystearic acid
Licolub H 4 / Licocene PE 4201
Licowax PE 520
Parts
100.0
0.4
0.8
1.0
1.2
0.2
1.0
5.0
S-PVC, k-value 65-68
Sn stabilizer (containing sulfur)
Calcium stearate
MBS impact modifier
Licolub H 4 / Licocene PE 4201
Licolub H 12
TiO2
CaCO3
Parts
100.0
3.4
0.4
2.0
0.2
0.3
0.2
7.0
4.0
S-PVC, k-value 67
Sn stabilizer (containing sulfur)
MBS impact modifier
PMMA processing aid
Calcium stearate
Licolub H 4 / Licocene PE 4201
Licolub H 12
TiO2
Parts
100.0
1.2
5.0
0.5
1.2
1.0
0.2
10.0
28
Parts
100.0
1.5
1.0
1.0
0.5
0.6
0.4
0.1
8.0
3.0
Sn shrink-wrapping film
Parts
100.0
2.0
8.0
1.0
1.0
0.6
0.5
0.1
S-PVC, k-value 60
Sn stabilizer (containing sulfur)
MBS impact modifier
PMMA processing aid
Glycerol dioleate
Licolub H 12
Parts
100.0
1.5
5.0
1.5
0.8
0.3
S-PVC, k-value 58
Sn stabilizer (containing sulfur)
Impact modifier
PMMA processing aid
Epoxidized soya bean oil
Licolub WE 4 / Licolub WM 31
Licowax PED 191
Parts
100.0
1.7
10.0
1.5
1.2
0.3
0.2
29
Requirements:
Improvement
in lubrication between the surface of the metal
and the expandable melt (containing a foaming agent)
Prevention of plateout
Lead stabilization
n
Licocene PE 4201
n
n
Licolub H 4
Licolub H 12
n
n
Licowax E
Licolub WM 31
Pb sheet, free-foamed
S-PVC, k-value 60
Tribasic lead sulfate
Dibasic lead stearate
PMMA processing aid
Calcium stearate
Distearyl phthalate
Licolub H 4 / Licocene PE 4201
Licowax E / Licolub WM 31
Licolub H 12
Foaming agent (e. g., azodicarbonamide)
TiO2
CaCO3
Parts
100.0
2.2
0.7
5.0
0.3
0.2
0.1
0.2
0.2
1.0
4.0
2.0
30
Parts
100.0
4.0
0.4
6.0
0.8
0.6
0.4
0.5
2.0
5.0
3.0
Calcium/zinc stabilization
n
Licocene PE 4201
Licolub H 4
Licowax OP
Parts
100.0
3.0
0.4
7.0
0.8
0.1
0.4
0.2
0.2
1.0
4.0
2.0
Tin stabilization
n
n
n
Licowax E
Licolub WM 31
Sn sheet, free-foamed
S-PVC, k-value 60
Sn stabilizer (containing sulfur)
PMMA processing aid
Calcium stearate
Epoxidized soya bean oil
Distearyl phthalate
Licowax E / Licolub WM 31
Licowax PED 191
Foaming agent (e. g., azodicarbonamide, hydrogen carbonate)
TiO2
CaCO3
Parts
100.0
1.5
7.0
0.8
0.5
0.5
0.3
0.6
1.0
4.0
2.0
31
Licowax E
Licowax OP
Licolub WM 31
n
n
n
n
Lead stabilization
S-PVC, k-value 60
Tribasic lead sulfate
Dibasic lead stearate
Neutral lead stearate
Calcium stearate
Glycerol monostearate
Licowax E / Licolub WM 31
Parts
100.0
2.5
0.6
0.1
0.4
0.5
0.5
Tin stabilization
S-PVC, k-value 60
Sn stabilizer (containing sulfur)
Impact modifier
PMMA processing aid
Glycerol monostearate
Licowax E / Licolub WM 31
32
Parts
100.0
2.0
2.0
1.0
1.0
0.5
Licowax E
Licolub WM 31
These profiles are usually produced on linear, horizontal extrusion equipment. The k-values
preferred lie between 65 and 70, with S-PVC and also E-PVC being used, depending on the
application. For the most part, phthalate plasticizers are used. The stabilization system
utilized depends on the application. Usually lead stabilizers are used; or for transparent
applications tin (or formerly barium/cadmium/zinc). For cost reasons one often incorporates
natural or precipitated calcium carbonate as fillers in dosages of up to 80 phr (coating
mixtures). The resulting impairment of processing characteristics is not inconsiderable.
Therefore in this area too, montanic acid esters, i. e., Licowax E, Licolub WM 31, have
proven quite useful especially for small cross-sections.
Pb cable sheathing formulation
S-PVC, k-value 70
Phthalate plasticizer
Tribasic lead sulfate
Calcium stearate
Licowax E / Licolub WM 31
CaCO3
Parts
100.0
60.0
6.0
0.4
0.5
30.0
Licolub WE 4
Licolub WM 31
Licowax C
Glass-clear flexible PVC films are usually produced using a suspension PVC (but M-PVC
is also used) with k-values between 65 and 75. Depending on the requirements, however,
k-values of 55 to 80 are applied. For pigmented films E-PVC is preferred (higher filler capacity,
better antistatic behavior). The phthalate plasticizer content is between 20 and 100 phr.
For processing flexible PVC on the calender or in extrusion blow molding, external lubricants
are needed in order to prevent sticking to the hot machine parts. Here the montanic acid
ester Licolub WE 4 or Licolub WM 31 displays optimal performance with regard to antisticking effect, processing window, and final product characteristics (dosage: 0.3-0.5 phr).
There is less need for internal lubricants, primarily for semi-rigid settings.
33
Parts
100.0
2.0
8-11.0
2.5
1.0
6.0
0.2
0.2
Parts
100.0
2.0
8-11.0
2.5
1.0
6.0
0.2
0.3
Parts
> 55.0
1.0
40.0
10.0
1.0
References
n
n
n
34
Product
Delivery form
Packaging
Product
PE bag
Pallet
20kg
1000kg
PE bag
PE bag
Pallet
Pallet
Bigbag
15kg
20kg
750kg
1000kg
1000kg
Licolub H4
Fine grain
PE bag
Pallet
25kg
750kg
Licowax PE 520
Granules
Fine grain
Powder
Licowax PE 190
Powder
Granules
Licolub H 12
Powder, fine grain PE bag
Pallet
Bigbag
Licowax PED 191 Flakes
Powder
20kg
1000kg
450kg3
Delivery form
Packaging
Licowax C
Powder
Micropowder
PE bag
25kg
Pallet
1000kg
Bigbag
500kg
Paper bag 25kg
Pallet
300kg
Licowax E
Flakes, powder
Powder fine
PE bag
20kg
Pallet
1000kg
Bigbag
450kg1
Bigbag
500kg2
Paper bag 25kg
Pallet
600kg
Licowax OP
Flakes, powder
PE bag
Pallet
Bigbag
Bigbag
20kg
1000kg
450kg1
500kg2
Licolub WE 4
Flakes, powder
PE bag
Pallet
Bigbag
Bigbag
20kg
1000kg
450kg1
500kg2
Licolub WE 40
Powder
PE bag
Pallet
Bigbag
20kg
1000kg
500kg
Licolub WM 31
Flakes, powder
PE bag
Pallet
Bigbag
Pallet
20kg
1000kg
450kg
900kg
1 = Flakes
2 = Powder
3 = Fine grain
Safety information
For each Clariant product there is a material safety data sheet available with comprehensive information regarding safety.
35
www.additives.clariant.com
Headquarters:
Clariant International Ltd
Business Unit Additives
Marketing and Operations Waxes
Rothausstrasse 61
4132 Muttenz
Switzerland
Phone: +41- 61-4 69 -7912
Fax: +41- 61-4 69 -7550
Global Marketing and Technical Center:
Clariant Produkte (Deutschland) GmbH
Business Unit Additives
Marketing and Operations Waxes
Technical Marketing Waxes
Ludwig-Hermann-Str. 100
86368 Gersthofen
Germany
Phone: +49-8 21-4 79-2693
Fax: +49-8 21-4 79-2968
DA 8293 E_10/2010
* For sales to customers located within the United States and Canada the following applies in addition:
DA 8293 E_02/04
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express or
implied, as to the informations accuracy, adequacy, sufficiency or freedom from defect and assumes
no liability in connection with any use of this information. Any user of this product is responsible for
determining the suitability of Clariants products for its particular application. * Nothing included in
this information waives any of Clariants General Terms and Conditions of Sale, which control unless it
agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due
to possible changes in our products and applicable national and international regulations and laws,
the status of our products could change. Material Safety Data Sheets providing safety precautions,
that should be observed when handling or storing Clariant products, are available upon request and
are provided in compliance with applicable law. You should obtain and review the applicable Material
Safety Data Sheet information before handling any of these products. For additional information, please
contact Clariant.