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Nitride
I. INTRODUCTION
The basic principle with which GaN produces power is by
pyroelectricity. Pyroelectricity is the ability of certain
materials to generate a temporary voltage when they are
heated or cooled .The change in temperature modifies the
positions of the atoms slightly within the crystal structure,
such that the polarization of the material changes. This
polarization change gives rise to a voltage across the crystal.
If the temperature stays constant at its new value, the
pyroelectric voltage gradually disappears due to leakage
current.All pyroelectric materials are also piezoelectric, the
two properties being closely related. Some piezoelectric
materials have a crystal symmetry that does not allow
pyroelectricity.
Some pyroelectric materials are gallium
nitride (GaN), caesium nitrate (CsNO3), polyvinyl fluorides,
derivatives of phenylpyrazine, and cobalt phthalocyanine.
Pyroelectricity can be visualized as one side of a triangle,
where each corner represents energy states in the
crystal: kinetic, electrical and thermal energy. The side
between electrical and thermal corners represents the
pyroelectric effect and produces no kinetic energy. The side
between kinetic and electrical corners represents
the piezoelectric effect and produces no heat.Although
artificial pyroelectric materials have been engineered, the
effect was first discovered in minerals such as tourmaline. The
pyroelectric effect is also present in both bone and tendon.
II. GALLIUM NITRIDE-A PYROELECTRIC MATERIAL
Gallium
nitride (GaN)
is
a
binary III/V direct
bandgap semiconductor commonly used in bright lightemitting diodes since the 1990s. The compound is a very hard
material that has a Wurtzite crystal structure. Its wide band gap of
3.4 eV affords it special properties for applications in optoelectronic,
C.Structure of GaN:
In the figure shown below :
Yellow represents gallium
White represents Nitride ions
Crystal
+-+-+-
Charges cancel
each other, so
no current flow
+-+-+-
Crystal
+++++
Current Meter
deflects in +
direction
Force
+++
+
----
. Changes the
direction of
current flow, and the
crystal gets
shorter and fatter.
VI. CONCLUSION
Since GaN
has more advantages than piezoelectric
materials(SiO2) and spring mechanism,it can be installed in
the pavement blocks such as busy street, the area which is
exposed to temperature variations.The obtained power can be
stored and it can be supplied to the sonsumers.
Current
Meter
deflects
in direction
REFERENCES
[1] Piezoelectricity: Evolution and Future of a Technology
Carol Zwick Rosen, Basavaraj V. Hiremath, Robert Everest
Newnham
[2]Wikipedia
[3] An introduction to the theory of piezoelectricity
By Jiashi Yang
[4] The Group 13 Metals Aluminium, Gallium, Indium and
Thallium: Chemical ...
By Simon Aldridge, Tony Downs, Anthony J. Downs
Resona
nce
frequen
cy [Hz]
Ris
e
tim
e
10
90
%,
Curre
nt
into
1 k
[A]
Power
density
[W/cm3
/g]
1
M
loa
d
[ms
]
5 x 33
mm2
318
250
63
74
9 x 33
mm2
291
179
88
96
11 x 33
mm2
328
178
128
130
5 x 25.4
mm2
605
100
164
196
7 x 25.4
mm2
488
122
100
80
9 x 25.4
mm2
555
83
200
192
11 x
25.4
mm2
569
70
287
308