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making them a viable option for applications were energy and power
are more important than efficiency.
Cell Operation
In general, DMFCs use a methanol solution (around 1M or about
3% in mass) to carry the reactant into the cell. This type of
electrochemical cells typically operates at temperatures that range
between 50oC and 120oC. On high temperatures, these cells have to be
operated in a pressurized environment. Although their operation is
more efficient at high temperature in pressurized environment, DMFCs
operated under these conditions end up causing so many losses in the
complete system. Therefore, operating these cells in atmosphericpressure conditions is preferred.
When operating DMFCs, a phenomenon by which methanol
diffuses through the membrane without reaction, occurs due to the
methanol cross over. This phenomenon causes a significant decrease in
efficiency because crossed-over methanol, after reaching the airside
(the cathode), immediately reacts with air. This is debated to result in a
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reduction in the cell's voltage. Other problems that might arise when
operating DMFCs include the management of carbon dioxide that is
created at the anode. The ability to maintain the solution water is
another problem that is expected when operating DMFCs. Finally, it is
noted that the only waste products with these types of fuel cells are
carbon dioxide and water. Figure 1 presents a typical schematic of a
methanol fuel cell.
Equation
Reaction
Anode
+ C O2
++ 6 e
CH 3 OH + H 2 O 6 H
Oxidation
3 H 2 O
++6 e
3
O +6 H
2 2
Cathode
Overall reaction
Reduction
3
CH 3 OH + O2 2 H 2 O+C O2
2
redox reaction
Equation
Reaction
+C O2
5 H 2 O+6 e
CH 3 OH +6 OH
Anode
oxidation
6 OH
3
O + 3 H 2 O+6 e
2 2
Cathode
Overall reaction
reduction
3
CH 3 OH + O2 2 H 2 O+C O2
2
redox reaction
Literature Review
Several studies have been conducted to examine the efficiency
of direct methanol fuel cells. Antonucci et al. (1999) investigated direct
methanol fuel cell based on a composite Nafion-silica electrolyte for
high temperature operation. In their study, operation of a liquid-fed
DMFC working at 145C was demonstrated by using a composite
membrane made of Nafion ionomer and silica. Several advantages
have been attained through using the enhanced humidification
conditions of the membrane-electrode (M&E) assembly. For instance,
this enhanced humidification assembly allowed for taking advantage of
the high operation temperature with consequent speeding up of the
methanol oxidation kinetics. It is reported by Antonucci et al. (1999)
that a peak power density of 240 mW/cm 2 for an oxygen-fed cell was
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intermediates.
Peak power densities of 250 and 150 mW cm2 in oxygen and
air, respectively, were obtained.
Hamnett (1997) investigated the mechanism and electrocatalysis
in the direct methanol fuel cell. In his study, a unified treatment of the
mechanism of electrocatalysis of methanol oxidation on platinum and
platinum-containing alloys was studied. Several alloys were examined
to evaluate their effect. As reported by Hamnett (1997) the effect of
various alloys is shown to be interpretable within this overall model,
and methods for the systematic improvement of the rate of electrooxidation of methanol are described. According to Hamnett (1997),
some recent results for model direct methanol fuel cells showed that
critical performance parameters for commercial exploitation are now
achievable with modern catalytic formulations and cell designs.
Xiao et al. (2013) examined the performance of a direct
methanol
fuel
cell
using
flexible
proton-conducting
glass-based
Future Trends
The focus of recent research is on investigating the performance
of direct methanol fuel cells while varying the various components
composing the cells. To achieve this objective, the underlying
processes of the entire system must be well understood and
established.
Research
efforts
shall
be
distributed
between
10
References
-
Nafion-silica
electrolyte
for
high
temperature
11