Professional Documents
Culture Documents
Dr. P. Barrade
Laboratoire dElectronique Industrielle
EPFL - STI ISE - LEI
ELD 136, Station 11
Ch-1015 Lausanne / Switzerland
Phone : +41 (0)21 693 2651
Fax : +41 (0)21 693 2600
Philippe.Barrade@epfl.ch
Seminar on Supercapacitors
Dr. P. Barrade
Summary
Generalities on Supercapacitors
Principle, technology and construction
Electric-based model
Conclusion
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Energy storage devices
Capacitors
Dielectric (Film-Foil, Metallized film)
Oxide electrolytic (Al, ta)
Electrostatic
Electrostatic
Electrochemical capacitor
Pseudocapacitor
Double layer capacitor (ECDL)
Faradaic
Electrostatic
Battery
Pb
NiCa
NiMH
Li+
Faradaic
Fuel cell
H2, Methanol (reforming)
Flywheel
Superconducting Magnetic Energy Storage (SMES)
Energy conversion
Mechanical
Magnetic
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Energy storage devices
Ragone diagram : Energy Density versus Power Density
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Energy storage devices
Energy density
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Principle, Technology and Construction
Conventional capacitor
ELCD capacitor
Electrolyte
Dielectric
C = r A/d
W = 1/2 CU2
Electrodes
Current Collectors
A:
D:
er:
U:
R:
1-3V
+ + + + + + + + + + + - + + + + + + + + + + + + + + + -
+
+
+
+
+
+
+
Separator
+ + + + + + + + + + + + + + + - + + + + + + + + + + + -
+
+
+
+
+
+
+
discharged
charged
2 - 10
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Principle, Technology and Construction
Materials :
Electrolyte :
Acqueous : high ionic conductance, high power density (1V, 1.2S*cm) KOH, H2SO4
Organic : high voltage, high energy density (2.5-3V, 50mS*cm) (Ex : 40mS*cm)
Electrode
Carbon: activated carbon
Separator
Organic: polymer (ex : 25m microporous polyolefin), paper
Inorganic: glas fibers, ceramics
Current collector
Metal foil (Al, Ti, Fe)
Courtesy from Montena Component SA
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Principle, Technology and Construction
Construction
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Main properties
Life time : ageing mechanisms
Type of aging
Electrical solicitations
Environmental (temperature, corrosive atmosphere)
Mechanical (vibrations, shocks)
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Main properties
Cell behaviour under crushing conditions:
Strong resistance for axial crushing
Weak resistance for transverse crushing
Temperature / fire
Opening of cells in 6 min (600C without fire)
Opening of cells in 4 min in case of direct fire exposure
Flammable gaz emission in case of opening celle if T>500C
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Supercapacitors today:
Maximum voltage : 2.7V
1 Million charge/discharge cycles
~0.01Euro/F
From few farads to few thousand farads
From the single component to the modules
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Modelling supercapacitors :
The main parameters of a supercapacitor (from the power electronicians point
of view) :
The energy that can be stored :
Capacitance : from 1F to 3000F (and more !)
Maximum voltage : typically 2.5V -> 2.7V (and more ?)
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Modelling supercapacitors :
The main parameters of a supercapacitor :
an ideal capacitor
Defined by the surface of electrodes, width on ions
a series resistor
Defined by the quality of carbon deposition on the aluminium current collectors
Defined by the electrical conductivity of the carbon
Defined by the ionic mobility of the electrolyte
a leakage resistor
Overcharge beyond the decomposition limit of the electrolyte
Impurities redox reaction
Redox reaction of functional groups on the edge of carbon particles
Electronic conductance through the separator
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Modelling supercapacitors :
Capacitance and series resistance (ESR)
Example of the BCAP0010 (Montena Component SA)
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Modelling supercapacitors :
Additional parameters (specificity of supercapacitors)
Non-constant capacitance and relaxation phenomena
Voltage dependant capacitance
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Modelling supercapacitors :
Additional parameters (specificity of supercapacitors)
Voltage dependant capacitance (due to the width of the double layer)
C = Co + Ku
!
Cu
How to consider?
Current capacitance
Q = Cu i c =
Ci
Energetic capacitance
dQ
du
i c = Co + 2Ku
dt
!#"#$ dt
P = i c u = Co + Ku u
du
1"
4 %
W c = $ Co + Ku ' u 2
dt
2#
3
!#"#$&
Cw
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Modelling supercapacitors :
Additional parameters (specificity of supercapacitors)
Voltage dependant capacitance. Example of the BCAP0008 (Montena
Component SA) : C=1800F, Co=1800F and K=150F/V, U=2.5V
C
1800F
5625J
Co+K*u
2175F
6796J
+20.8%
Ci
2550F
7968J
+41.6%
Cv
2300F
7187J
+27.7%
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Modelling supercapacitors :
Additional parameters (specificity of supercapacitors)
Relaxation phenomena
Due to porosity of electrodes (misopores, mesopores, macropores)
During a fast charge (discharge), ions will first enter (leave) into macropores,
then in mesopores
Diffusion of ions in misopores is characterized by long constant times
During ageing process, relaxation phenomena is re-inforced by impurities
affecting the dimension of the pores
After a fast charge (discharge), non homogeneous repartition of loads on the
electrodes
Diffusion of the loads to reach a homogenous distribution (depends on size of
the pores and size of the ions)
Voltage decrease (after charge)
Voltage increase (after discharge)
Seminar on Supercapacitors
Dr. P. Barrade
Generalities on Supercapacitors
Modelling supercapacitors :
Additional parameters (specificity of supercapacitors)
Seminar on Supercapacitors
Dr. P. Barrade
The two last parameters define the maximum voltage and current that a
supercapacitors tank can provide
10
Seminar on Supercapacitors
Dr. P. Barrade
The needed energy can be obtained thanks to the link equation between the
energy Wc and the power Pc :
Wc =
Pc dt
Seminar on Supercapacitors
Dr. P. Barrade
11
Seminar on Supercapacitors
Dr. P. Barrade
Wc =
1
CUc 2
2
It is not possible to use the total amount of energy stored into a supercapacitor : a
residual voltage has to be taken into account to consider that the component is
discharged
Seminar on Supercapacitors
Dr. P. Barrade
1
CUM 2
2
Voltage discharge ratio: the minimum voltage during the discharge has to be
limited for efficiency reasons
d = 100
Um
UM
d2
1002
2W
u 2
d
CUM 2 1
1002
12
Seminar on Supercapacitors
Dr. P. Barrade
Energy requirements
Using a 2600F/2.7V/0.4m supercapacitor
Example: 220kJ to store
Ns =
2W
u 2
d
CUM 2 1
1002
2600F, 2.5V
d=50%
d=60%
d=70%
Total stored
energy
N=31
W=293.8kJ
N=37
W=350.6kJ
N=46
W=438kJ
Seminar on Supercapacitors
Dr. P. Barrade
13
Seminar on Supercapacitors
Dr. P. Barrade
%
"
&
'
uc = U M 4 1
Tch =
Rs C ln
di
100
100
100
df
di
t 3
R
sC 5
e
Seminar on Supercapacitors
Dr. P. Barrade
1
UM
Rs
uc
=)
Pr =
1
UM 2 1
Rs
di
100
Pr dt =)
0
1
Wr = CUM 2 1
2
di
100
1
1
CUM 2
df (200
2
100
df )
2t
e Rs C
1
2t
C
e Rs C A
B
@1
di (200
di )
1
Cucf 2
2
1
Cuci 2 =)
2
Wc =
1
CUM 2
2
"
df
100
di
100
2 #
14
Seminar on Supercapacitors
Dr. P. Barrade
Wc
Wc + Wr
=)
1
(df + di )
200
Seminar on Supercapacitors
Dr. P. Barrade
Charge
Icc>0 and df>di
Main equation
di
1
+ Icc t
100 C
uc = U M
U M df di
Icc 100
Tch = C
uc = U M
Charge/discharge time
Tch = C
di
1
+ Icd t
100 C
U M df di
Icd 100
Energy lost
Wr = Rs CIcc UM
df di
100
Energy stored/provided
Wc =
1
CUM 2
2
Wr = Rs CIcd UM
"
df
100
di
100
df di
100
2 #
15
Seminar on Supercapacitors
Dr. P. Barrade
Discharge
Icd<0 and df<di
Efficiency
=
Wc
Wc + Wr
=
1 + 2Rs
1
Icc 100
U M df + di
Wc + Wr
Wc
= 1 + 2Rs
Icd 100
U M df + di
Tch
Tch + 2Rs C
df di
df + di
= 1 + 2Rs C
1 df di
Tch df + di
Seminar on Supercapacitors
Dr. P. Barrade
Discharge
Time for loading energy has to be kept up to 10s for a 90% energy efficiency (Ic<320A or
P<700W)
Time for unloading energy has to be kept up to 10s for a 90% energy efficiency
(Ic<320A or P<400W)
Taking into account the necessity of 90% of energy efficiency, the current or the power
for charging/discharging have to be limited: the power density is only 806W/kg (instead
of 4300W/kg)
16
Seminar on Supercapacitors
Dr. P. Barrade
For this special application, the power availability is the main sizing criterion
Seminar on Supercapacitors
Dr. P. Barrade
Available energy :220kJ (61Wh) if the voltage is kept over 60.36% of the maximum
Total stored energy : 341kJ (95Wh)
17
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
Thermal conductivity
Generaly given by manufacturer, but deduced from experimental protocol that gives quite
vague datas
Thermal capacitance
Generaly not given by manufacturer
A way to obtain this data is to consider that supercapacitors are made of 60% of
aluminium, 25% of carbon, and 15% of water (from a thermal point of view)
Status at LEI: a complete evaluation will be made next summer
18
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
Thermal aspects
Example: Stand-by mode, 15mn warming under sunning conditions (1000w/m2)
19
Seminar on Supercapacitors
Dr. P. Barrade
Thermal aspects
Example: stand-by mode, inrush air speed is 0.5m/s
Seminar on Supercapacitors
Dr. P. Barrade
Thermal aspects
Example: power provided per cell is 110W, losses per cell are 11.3W (90.6%), during
2400s (40mn), inrush air speed is 0.5m/s
20
Seminar on Supercapacitors
Dr. P. Barrade
Thermal aspects
Example: power provided per cell is 110W, losses per cell are 11.3W (90.6%), during
2400s (40mn), inrush air speed is 0.5m/s
Horizontal gradiant temperature
For this application, forced cooling is needed, even if temperature is not stabilised
Seminar on Supercapacitors
Dr. P. Barrade
Thermal aspects
Example: power provided per cell is 110W, losses per cell are 11.3W (90.6%), during
2400s (40mn), inrush air speed is 0.5m/s
Horizontal gradiant temperature
For this application, forced cooling is needed, even if temperature is not stabilised
21
Seminar on Supercapacitors
Dr. P. Barrade
Limitation:
Example of a hybrid elevator
Supercapacitive tank plugged on the DC bus
L
Grid
u1, u2, u3 AC
i1, i2, i3
Ud
Il
It
DC
Uc
DC
Ls
Is DC
Ia
Us
DC
Supercapacitive
accumulator
Shaft
Ib
mw1
S
mw2
Braking resistors
me
mp
mc
Seminar on Supercapacitors
Dr. P. Barrade
Limitation:
Example of a hybrid elevator
Shaft length: 18m, 5 floors
Cabin mass: 800kg
Up to 8 passengers
Accumulator capacity: 20Wh
22
Seminar on Supercapacitors
Dr. P. Barrade
Limitation:
Example of a hybrid elevator
Tests on strategies for energy management
Rule Based vs. Dynamic Programming
75
50
25
Rules
0
0
20
40
60
80
Energy [kJ]
75
50
25
DP
0
0
20
40
Mission
60
80
Seminar on Supercapacitors
Dr. P. Barrade
23
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
Uc1
C2
Uc2
24
Seminar on Supercapacitors
Dr. P. Barrade
C2=80% of C1
No sharing
C2=80% of C1
Sharing
Uf (V)
4.5
Uc1f (V)
2.5
2.5
Uc2f (V)
2.5
2.5
2.5
E (J)
6250
4500
5625
Seminar on Supercapacitors
Dr. P. Barrade
25
Seminar on Supercapacitors
Dr. P. Barrade
T1
C1
i'2
i1
C1
Np1
i2
C2
Np2
T'3
T2
i3
C3
D'3
L1
il1
T2
C2
L2
i2
D2
i3
C3
Nf
Df
D2
D'2
il2
T1
D1
T'2
D1
Np3
association of buck-boost
dc-dc converters
T3
D3
Seminar on Supercapacitors
Dr. P. Barrade
Voltage Equalization
Voltage sharing solution, using dissipative
elements offer also a high efficiency.
High performances obtained thanks to an
efficient control and management of voltage
equalization processes
Supercapacitor manufacturers are able to
propose ready-to-use solutions, directly
integrated into a modular supercapacitive
tank
Cell balancing
Module to module balancing
Integration of protection against short-circuits
Voltage monitoring for external control
Up to 1kV!!!!!
26
Seminar on Supercapacitors
Dr. P. Barrade
1
CUc 2
2
Ic = C
dUc
dt
A power interface between the Scaps bank and its load has to be defined :
Example : interface between a Scaps bank and a DC bus
DC bus
Which topology ?
Scaps
bank
Power
Converter
Seminar on Supercapacitors
Dr. P. Barrade
Buck converter
DC bus
DC bus
Scaps
bank
Scaps
bank
Buck
Converter
Boost
Converter
27
Seminar on Supercapacitors
Dr. P. Barrade
Huge number
of series connected
Scaps :
Large number of
active components
Safety problems
High cost
Reduced number
of series connected
Scaps :
reduced number of
active components
Low cost
easier symetrizing
process
High efficiency
Low efficiency
Seminar on Supercapacitors
Dr. P. Barrade
DC bus
Scaps
Scaps
bank
bank
28
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
29
Seminar on Supercapacitors
Dr. P. Barrade
90
80
70
60
Energie (J)
Vitesse (km/h)
100
50
40
4
3
30
20
10
0
x 10
100
200
300
400
500
t (s)
600
700
800
900
1000
-1
100
200
300
400
500
t (s)
600
700
800
900
1000
Seminar on Supercapacitors
Dr. P. Barrade
DEPART
STATION 1
STATION 2
STATION n
Bus
Supercondensateurs
ARRIVEE
30
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
31
Seminar on Supercapacitors
Dr. P. Barrade
DEPART
STATION 1
s1
s2
STATION 2
Supercondensateurs
intermdiaires
STATION n
s1
s2
Bus
Supercondensateurs
Supercondensateurs
intermdiaires
ARRIVEE
Seminar on Supercapacitors
Dr. P. Barrade
32
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
a)
Efficiency increase
Reversible front-end
b)
Efficiency increase
Local accumulator
c)
33
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
u1, u2, u3 AC
i1, i2, i3
Ud
Il
It
DC
Uc
Ls
Is DC
Ia
Us
DC
Supercapacitive
accumulator
Shaft
DC
Ib
mw1
S
mw2
Braking resistors
me
mp
mc
Objectives
Increase of the global efficiency
Limitation of power fluctuations on the grid
34
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
Power [kW]
Elevator
Rules
DP
2
0
0
20
40
60
80
6
Rules
4
2
0
0
Power [kW]
300
Elevator
Energy [kJ]
Power [kW]
20
40
60
80
200
100
6
DP
4
2
0
0
20
40
Mission
60
80
0
0
20
40
Mission
60
80
35
Seminar on Supercapacitors
Dr. P. Barrade
75
50
25
Rules
0
0
20
40
60
20
40
Mission
60
80
Energy [kJ]
75
50
25
DP
0
0
80
Seminar on Supercapacitors
Dr. P. Barrade
36
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
technology of
supercapacitors
They are power
compatible
Life time / number of
cycles compatibles
It has to be checked if
they are energy
compatible!
37
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
Altitude (m)
1600
1500
1400
1300
1200
1100
1000
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
Time (s)
Power profile
Instantaneous
Mean
Power (kW)
500
0
-500
-1000
-1500
-2000
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
Time (s)
38
Seminar on Supercapacitors
Dr. P. Barrade
600
500
400
300
200
100
0
0
100
200
300
400
500
600
Seminar on Supercapacitors
Dr. P. Barrade
39
Seminar on Supercapacitors
Dr. P. Barrade
Inverter
DC
AC
OUT
DC
DC
dc/dc interface
Seminar on Supercapacitors
Dr. P. Barrade
200
200
Uout (V)
Uin (V)
400
-200
-400
0.2
0.25
0.3
0.35
0.4
0.45
0.5
-200
20
-400
0.05
Icap (A)
15
0.1
0.25
0.3
0.35
0.4
0.45
0.2
0.25
Icap (A)
Uout (V)
0.25
10
0.5
400
-10
200
-20
-30
-200
-400
0.2
0.2
20
0
0.2
0.15
t (s)
10
0.25
0.3
0.35
0.4
t (s)
Network failure
0.45
0.5
-40
0.05
0.1
0.15
t (s)
Reconfiguration
40
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
41
Seminar on Supercapacitors
Dr. P. Barrade
Operational requirements
Doors Operation independent from AC electrical system
Emergency opening even after transversal break of the fuselage
Local energy storage
High reliability
Extremely high availability
Minimum burden to the A/C Electrical System (max. 130VA, no peak loads)
Minimum radiated and conducted distortion
Maximum radiated and conducted susceptibility
Robustness for primary power interrupts and transients
Seminar on Supercapacitors
Dr. P. Barrade
Therefore
42
Seminar on Supercapacitors
Dr. P. Barrade
Seminar on Supercapacitors
Dr. P. Barrade
Conclusion
For most of applications, supercapacitors are used to smooth power fluctuations on a
main energy source
Reduced energy density
High power density
Long lifetime
Supercapacitive tank can be sized in a 2 steps process:
Energy requirements: this defines mainly the number of components
Power requirements: in order to match the required power availability
Supercapacitors technology seems to be now mature enough for large scale
applications
Price
Performances
However: needs in strong developments in power electronics, competition with
other technologies (flywheel)
43