Professional Documents
Culture Documents
Uses
Copper
Zinc
Lead
- Car batteries
- Plumbing (flashing) and in solder
- In crystal glass and as glaze for pottery
Brass
Solder
elements
found
Iron 74%
Chromium 18%
Nickel 8%
Copper 65%
Zinc 35%
Lead 67%
Tin 33%
Properties
Resists corrosion
High strength
Shiny surface
Resists corrosion
Ductile
Malleable
Shiny, polishes well
Antibacterial
Uses
Sinks, cutlery
equipment
Machinery parts
Doorknobs,
ornaments
Musical instruments
Screws
Electrical wires
Pipes
How use
relates to
property
Stainless steels
resistance to
corrosion, shiny
surface and strength
makes it suitable for
kitchenware and sinks
as it is both
aesthetically pleasing
and does not rust
easily. Stainless steel
parts are also used in
industry for its
corrosion resistance
and strength.
Solder is most
commonly used
for electrical
wires/connectors
or pipes, as its
low melting point
means it can be
melted to join
metal surfaces
so the base
surfaces do not
melt.
Low melting
point
Galinstan
68.5% Ga, 21.5% In,
10% Sn
Nitinol- 1959
Nickel titanium
alloy
The first metal to be extracted from an ore was copper in about 6000 B.C.
This copper was used to make domestic utensils and possible some types of
ornaments. Working copper, however, was difficult as the melting point
needed was too great for wood fires to achieve. Furthermore, the finished
products of copper were fairly soft as pure copper is an extremely soft metal.
Therefore, copper tools did not replace the stone ones currently in use.
BRONZE AGE(3000BC) As time progressed, it was discovered that heating
copper and tin ores with charcoal produced a much harder metal alloy
Bronze. Bronze has a much lower melting point than copper and so could be
melted, moulded and worked much more easily in wood fires. Around 2000
B.C., bronze had become prominent and used for tools and weapons
throughout the European and Asian continents. This led to a technological
difference between societies with bronze and those without it, nations that
first developed methods of mining and using Bronze as weapons were able to
conquer less developed nations.
IRON AGE (1000BC) It was not until 1200 B.C. that humans developed a
method of generating higher temperatures enough to extract iron from iron
oxide and also the ability to forge iron into tools and weapons. The
technology for extracting, processing and moulding rapidly spread out
throughout Europe and Asia. Iron is a much harder metal than bronze, and
therefore most weapons and tools were made of iron instead.
Anthropologists and historians end the Iron Age at 1 C.E and like to call the
era to present the Modern Age. Throughout the Modern Age, the
technologies for producing iron and steel rapidly improved, and quantities
being used increased markedly (Especially after the Industrial Revolution of
the eighteenth century).
Future developments- A team of international research scientists at Monash
University in Melbourne led by Professor Nick Birbilis have developed a new
alloy by adding small amount of arsenic to magnesium to reduce corrosion
rates. Magnesium is an extremely light structural metal with many potential
industrial uses, but is not commonly used due to its poor corrosion
resistance. The research team has discovered that the addition of arsenic
poisons the corrosion reaction before it completes. This discovery could
lead to widespread use in aerospace, automotive and electronics, and will
help develop the next generation of magnesium products, which must be
more stainless.
5. Explain why energy is required to extract a metal from its ore.
Ores are naturally occurring mixtures that contains metals and other minerals
or compounds. Almost all extraction of metals requires a chemical reaction
called reduction, which removes the oxygen from metal compounds. This
needs a large amount of energy to break and rearrange the strong chemical
bonds in the compound.
6. Outline why there are more metals available for people to use
now than there were 200 years ago.
The availability of metals for commercial and industrial use depends upon
one or both of the following factors:
Metals differ in their reactivity with other chemicals and this influences their
uses
1. Describe observable changes when metals react with dilute acid,
water and oxygen
Metals vary in their reactions with certain substances. Some are very reactive
whereas others are extremely unreactive to the same substance.
Reaction with Oxygen:
All metals except silver, platinum and gold react with oxygen to form oxides:
- Li, Na, K, Ca, Ba react rapidly at room temperature.
- Mg, Al, Fe, Zn react slowly at room temperature but burn vigorously if
heated in air or pure oxygen.
- Sn, Pb, Cu react slowly and then only if heated.
All the oxides formed are ionic compounds.
Those metals which burn in air or oxygen form crystalline white solids that
have none of the physical properties of the original metal (lustre, strength
etc.)
When metals slowly react at room temperature, they lose their shiny lustrous
appearance. Some, such as Al, become coated with a dull layer of tightly
adhering oxide, which prevents further reaction. However, others like iron,
form a powdery surface layer of oxide which does not impede further
reaction.
For example when magnesium is heated in air, large amounts of heat and
light energy are given off in the exothermic reaction. The initial shiny silver
metal turns into a white powdery substance known as Magnesium oxide.
2Mg(s) + O2(g)
2MgO(s)
2NaOH(s) + H2(g)
MgCl2(aq) + H2(g)
Remember:
OILRIG
2. describe and justify the criteria used to place metals into an order
of activity based on their ease of reaction with oxygen, water and
dilute acids
Metals vary in their reactivity.
Reactive metals will react with oxygen, whereas those that are inactive will
not, placing them lower on the activity series.
A highly reactive metal with react with cold water, whereas metals that dont
react with cold water may react with hot water and are lower on the activity
series
. Metals that dont react with water, need to be tested in dilute acid to test
their reactivity.
Thus metals that react vigorously are deemed to be more reactive than those
that react less vigorously or only with concentrated acids.
The reason for this procedure is that metals that react with oxygen will react
more vigorously with water and then acids. Thus by determining where each
metal will react, we can make up an activity series which is a list of metals
based on their order of reactivity.
The activity series of the common metals goes as follows:
K, Na, Li, Ba, Ca, Mg, Al, Zn, Fe, Sn, Pb, Cu, Ag, Pt, Au
Acids are substances which in solution produce hydrogen ions, H+. It is the
hydrogen ions which react with the metals. These ions result in the transfer of
electrons between the substances involved.
Metals reacting with acids are redox reactions. Another name for these
reactions is electron-transfer reactions. We have already seen that
magnesium metal reacts with oxygen gas to form white solid magnesium
oxide:
2Mg(s) + O2( g) 2MgO(s)
Mg loses two electrons to become Mg2+ (in ionic MgO) so Mg is oxidised to
Mg2+. Oxygen gains two electrons to become oxide O2, so oxygen is reduced
to
oxide. This is therefore a redox reaction.
The reaction of a metal with dilute acid to form hydrogen gas is an example
of a redox reaction. As discussed above zinc reacts with hydrochloric acid, the
net ionic equation being:
Zn(s) + 2H+(aq) Zn2+
(aq)
+ H2( g)
As we go from left to right across the activity series, metal ions become
easier to reduce to metal atoms. Due to the fact that metal ions are present
in ores, it can be said that the further to the right in the activity series a
metal is, the more easily it can be extracted from its ores.
7. Construct half-equations to represent the electron transfer
reactions occurring when metals react with dilute hydrochloric and
dilute sulphuric acids
2Al
(s)
+ 6HCl
(aq)
Oxidation: Al
Mg
(s)
+ H2SO4 (aq)
MgSO4
Oxidation: Mg (s)
(aq)
H2 (g)
+ H2 (g)
H2 (g)
The electrons are kept moving around the nucleus by electrostatic forces
between the positively charged nucleus and negatively charged electrons.
Electrons orbit the nucleus in energy levels/shells that have a set size and
energy.
The energy of the orbit is related to its size. The lowest energy is found in
the smallest orbit.
Radiation is absorbed or emitted when an electron moves from one orbit
to another.
Date
~330
BC
1789
Comment
Jns Jakob
Berzelius
1828
Johann Dbereiner
1829
Alexandre-Emile
Bguyer de
Chancourtois
1862
John
Newlands
1864
Lothar Meyer
1869
Mendeleev is still
considered to be the
father of the Periodic
table.
Meyer is also recognised
for identifying periodic
behaviour which allowed
for the development of
groups and periods.
Dmitri Mendeleev
1869
William Ramsay
1898
Henry Moseley
1914
Glenn Seaborg
1940
Reactivity
For metals, the reactivity of elements increases down the group and
decreases as it goes across the period. After group 4, reactivity decreases
down the group and increases across the period.
For
efficient resource use, industrial chemical reactions must use
measured amounts of each reactant
1. Define the mole as the number of atoms in exactly 12g of carbon12 (Avogadros number)
A mole is defined as the amount of a substance that contains the same
number of particles(atoms, ions, molecules) as there are atoms in exactly 12
g of Carbon 12. Chemists have determined that the number of atoms in 12
g of carbon 12 is
'
6.022 1023 .
23
n=
m
M
n=
number of particles
NA
A mole of silver (atomic weight 108) is 6.02 1023 atoms of silver or 108
grams of silver. A mole of sucrose (molecular weight 342) is 6.02 10 23
molecules of sucrose or 342 grams of sucrose.
The accepted abbreviation for mole is mol.
3. The empirical formula of a compound is the formula that tells us the ratio
in which the atoms are present in the compound.
The molecular formula of a compound is the formula that tells us how
many of each type of atom are present in a molecule of the compound.
4. Process information from secondary sources to interpret balanced chemical
equations in terms of mole ratios.
Because the existence of formulae and atomic weights, and hence the ability
to write chemical equations, are essential for the concept of moles, it can be
concluded that the work of Gay-Lussac and Avogadro was critically important
in developing the mole concept.
The relative abundance and ease of extraction of metals influences their
value and breadth of use in the community.
1. Define the terms mineral and ore with reference to economic and
non-economic deposits of natural resources. Give one example of an
economic deposit and one example of a non-economic deposit.
Minerals are defined as pure crystalline compounds or elements that occurs
in the earths crust. Ores are defined as naturally occurring deposits found in
the earths crust that contain a mixture of minerals from which a metal can
be economically extracted. To be classified as an economic deposit, the ore
must contain a high percentage of the required mineral and can be easily
extracted (e.g Copper in chalcopyrite and aluminium). Non economic deposits
are ones that do not contain minerals which are economically viable to
extract and produce. (e.g alumino-silicates in mica)
2. Describe the relationship between the commercial prices of
common metals, their actual abundances and relative costs of
production. Use iron, copper, aluminium, tin and gold as your
examples.
Aluminum has high crustal abundance at 8.1x105 ppb by mass, but was
previously so difficult and expensive to extract it had very limited use.
Now with a commercially viable method of extraction it is US$1837/tonne
Iron has always been relatively cheaper due to its abundance at 5.0x10 5
ppb/mass and its low production cost as it can be extracted on a large
scale and with low cost. US$400/tonne
Copper and tin are less abundant at 5.0x102 and 30 ppb/mass
respectively and are therefore more expensive. Copper is US$3782/tonne
and tin is US$6880/tonne
Gold is the most expensive of metals due to its extremely low abundance
at only 0.05 ppb/mass , and though it has become easier to produce its
demand is still very high. US$10 200 000/tonne
This means that once current sources of ores are exhausted, they cannot be
renewed within a current lifetime, making them non-renewable.
Collect the used products from homes, shopping centers, factories etc.
Transport the collected material to a central processing plant
Separate the aluminium from the impurities such as dirt, labels etc.
Re-smelt the metal into ingots
Roll ingots into sheets of aluminium
Transport these sheets to product manufacturers.
Aluminium is the third most abundant metal in the Earths crust, but
is more expensive to extract it from its ore than iron. To extract it, a large
Energy (MJ)
required per tonne
Extraction
65 000
Recycling
800
The yield of a metal from a particular mineral or ore is the mass of metal
that can be obtained from a particular mass of the mineral/ore.
Measurement of the yield from a particular ore body is extremely
important in the mining and minerals industry because it determines
whether extraction of the metal from that ore is profitable or not.