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1. Fundamentals of concrete.
1) Concrete Components (Cement, Water, Fine Aggregate and Coarse Aggregate )
6) Normal, air-entraining
7)
5. Chemical Composition.
Type of Portland
cement
Chemical composition, %
SiO2
A l2O3
F e2O3
18.7-22.0 4.7-6.3
1.6-4.4
CaO
MgO
S O3
N a2O
1.8-4.6
0.11-1.20
3.0
0.61
2.1-4.0
0.05-1.12
2.7
0.51
2.5-4.6
0.14-1.20
3.5
0.56
1.7-2.5
0.29-0.42
2.2
0.36
1.8-3.6
0.24-0.76
2.3
0.48
Normal
I
(min-max)
(mean)
Moderate sulfate resistance
II
(min-max)
(mean)
High early strength
III
(min-max)
(mean)
Low heat of hydration
IV
(min-max)
(mean)
High sulfate resistance
V
(min-max)
(mean)
20.5
5.4
20.0-23.2 3.4-5.5
21.2
4.6
18.6-22.2 2.8-6.3
20.6
4.9
21.5-22.8 3.5-5.3
22.2
4.6
20.3-23.4 2.4-5.5
21.9
3.9
2.6
2.4-4.8
3.5
1.3-4.9
2.8
3.7-5.9
5.0
3.2-6.1
4.2
60.6-66.3 0.7-4.2
63.9
2.1
60.2-65.9 0.6-4.8
63.8
2.1
60.6-65.9 0.6-4.6
63.4
2.2
62.0-63.4 1.0-3.8
62.5
1.9
61.8-66.3 0.6-4.6
63.8
2.2
White (min-max)
22.0-24.4
2.2-5.0
0.2-0.6
22.7
4.1
0.3
(mean)
63.9-68.7 0.3-1.4
66.7
0.9
2.3-3.1
0.09-0.38
2.7
0.18
The approximate percentage of each compound can be calculated from a chemical oxide
analysis (ASTM C 114 or AASHTO T 105). The equations suggested by Bogue for calculating
the percentage of major compounds are given below.
C3S %=4.07 (CaO)-7.6 ( SiO2)-6.72 (A l2O3) -1.43 (F e2O3) -2.85 (S O3)
C2S %=2.87 (SiO2)-0.754 ( 3 CaO* SiO2)
C3A %=2.65 (A l2O3)-1.69 (Fe2O3)
C4AF %=3.04 (Fe2O3)
Type of Portland
cement
C2S
C3A
C4AF
40-63
9-31
6-14
5-13
300-421
54
18
10
369
37-68
6-32
2-8
7-15
318-480
55
19
11
377
III (min-max)
46-71
4-27
0-13
4-14
390-644
(mean)
Low heat of
55
17
548
IV (min-max)
21.5-22.8
27-36
3-4
11-18
319-362
(mean)
High sulfate
42
32
15
340
V (min-max)
43-70
11-31
0-5
10-19
275-430
(mean)
White
54
22
13
373
(min-max)
51-72
9-25
5-13
1-2
384-564
(mean)
63
18
10
482
Normal
I (min-max)
(mean)
Moderate sulfate
resistance
II (min-max)
(mean)
High early
strength
hydration
resistance
Portland Cement
(AASHTO T 129)
b.
c.
d.
e.
f.
Bulk density of cement varies between 830 kg/m3 and 1650 kg/m3
g.