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1
When 124g of copper(II) carbonate is heated, black colour of the residue and colourless gas
produced.
[Given that the relative atomic mass of Cu,64;O,16;C,12:
Volume of 1 mol of gas = 24 dm3 at room condition]
i.
ii.
iii.
iv.
iv.
v.
vi.
vii.
Zinc
carbonate
Diagram 2
2.
Limewater
Diagram 2 shows set-up of the apparatus for an experiment when 6.5 g of zinc carbonate powder is
heated strongly. A residue of Solid X which is yellow in colour when hot and white in colour when
cooled and the colourless gas Y are produced.
(a)
State the type of reaction for the preparation of zinc (II) carbonate in a laboratory.
Precipitation/double decomposition
[ 1mark]
(b)
(i)
Name gas Y.
(ii)
[2 marks]
(c)
Name solid X.
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[1 mark]
(d)
(e)
Calculate :
(i)
[1 mark]
(ii)
(iii)
[2 marks]
(f) Calculate the number of ion in 1.0 mole of the chloride metal formed when Solid X is reacted
with hydrochloric acid.
[Avogadros constant = 6.02 X 1023 mol-1]
[2 mark]
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QUESTION 2
Burette
(a) (i)
(b) Name the analysis technique used and the type of reaction involved in
this experiment.
[ 2 marks ]
(c) The average volume of hydrochloric acid used in this experiment is 12.50 cm3.
Calculate the molarity of hydrochloric acid used.
[ 3 marks ]
(d) You are given copper(II) nitrate solution.
(i)
Describe how you would test for the presence of cation and anion in the solution.
[ 6 marks ]
4|BENGKEL AMBANG SPM 2009PAPER 2
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QUESTION 3
Hydrogen
gas
Chlorine gas
1.0 mol dm -3 of
Sodium chloride solution
Carbon
electrode X
Carbon
electrode Y
Electrode X
Electrode Y
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QUESTION 4
Diagram 9
Diagram 9 shows the apparatus set-up for electrochemical cell.
(a) What is the role of Part X in the electrochemical cell ?
To produce electricity
[ 1 mark]
(b) State the energy change that occurs in Part X and Part Y.
(i)
Part X:
(ii)
Part Y :
[ 2 marks]
(ii)
(d) (i)
[ 2 marks ]
(iii)
(e) (i)
(ii)
In Diagram 9 , label the anode of Part Y by writting the word anode. [1 mark]
Write the half-equation of the reaction that occurs at the anode in Part Y.
[ 1 mark]
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QUESTION 5
Compound J
White
precipitate Q
Dissolved in
excess sodium
hydroxide
solution
Dissolved in
water
Reaction I
Colourless J
solution
+ NaOH (aq)
Reaction II
+ H2SO4 (aq)
White
precipitate R
Diagram 4
Diagram 4 shows a series of process done by a student to identify a compound J.
(a)
With refer to reaction I, white precipitate Q is formed which is soluble in excess sodium hydroxide
solution. Name all the ions which are probably presence in solution J.
(b)
(c )
Write down the ionic equation for the reaction forming the white precipitate, R.
(d)
(i)
Name two cations which produced white precipitate that will not dissolve
in excess sodium hydroxide solution.
(ii)
[3 marks]
7|BENGKEL AMBANG SPM 2009PAPER 2
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QUESTION 6
Table 1 shows the observations from some test carried out on salt Y.
Test
Ujian
I: Heating of solid salt Y and test with moist
blue litmus paper
Observation
Pemerhatian
A metal oxide is formed and acidified
brown gas released.
Table 1
i.
Identify an anion that is present in Test I and describe a chemical test to verify the anion .
[4
marks]
ii.
Identify cation that are present in Test II and describe a chemical test to verify the cations.
[4 marks]
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QUESTION 7:
Compound J
Oxide M
[Brown when hot,
yellow when cooled]
Heat
Gas L
[Colourless]
+ dilute nitric
acid
White
precipitate Q
Dissolved in
excess sodium
hydroxide
solution
Reaction I
Colourless J
solution
+ NH3 (aq)
Reaction II
White
precipitate R
+ Na2SO4 (aq)
Diagram 2
Diagram 2 shows a series of process done by a student to identify a compound J.
(a)
(b)
With refer to reaction I, white precipitate Q is formed which is soluble in excess sodium
hydroxide solution.
Name all the ions which are probably presence in solution J.
......................................................................................................................................
[ 1 mark]
Referring to reaction I and II,
name the cation presence in solution J.
...................................................................................................................................
[1 mark]
(c )
Write the ionic equation for the reaction forming the white precipitate, R.
[2 marks]
(d)
[1 mark]
(e)
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...................................................................................................................................
[4 marks]
QUESTION 8
Carbon
Carbon
Bromine water
(b)
(c)
(d)
(ii)
(iii)
[1 mark]
(e)
(f)
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[1 mark]
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.
[1 mark]
QUESTION 9
Butane
Process I
But-1-ene
Process II
Butan-1-ol
Process IV
Process III
Compound Q
Butanoic acid
Diagram 4
Diagram 4 shows a flow chart for a series of changes of organic compounds from one homologous
series to another homologous series.
(a)
[2 marks]
(b)
(ii)
(c)
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(ii)
(iii)
[2 marks]
(d)
[1 mark]
(e)
(i)
(ii)
(c)
Draw the graph of total volume of gas collected against time. [4 marks]
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QUESTION 9
A student carried out the electrolysis of dilute silver nitrate solution by using carbon
electrodes. Table 5.1 below shows the result of the experiment.
Experiment Description
Observation
Table 5.1
(a)
(i)
[1 mark ]
(ii)
[1 mark ]
(iii)
In the Table 5.2 below, give all the formula of the ions in the electrolysis
process of dilute silver nitrate solution which moved to the anode and cathode.
[2 marks]
Anode
Cathode
Table 5.2
(b)
(i)
:
[1 mark ]
(ii)
State how would you verify the gas released at the anode.
..
[2 marks]
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(c)
[3 marks]
QUESTION 10
Process I
Propene, C3H6
Process II
Alcohol P
DIAGRAM 6
6.
Diagram 6 shows the conversion of propene, C3H6 to carbon dioxide gas and water.
(a)
ii.
iii.
[ 3 marks ]
(b)
In Process II, Alcohol P burns in excess oxygen to form carbon dioxide and water.
(i)
(ii)
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(c )
[ 2 marks ]
(d)
[ 2 marks ]
QUESTION 11
2. The research and development of chemistry has led to the production of useful manufactured
substances to improve our quality of life. Table 2 shows some examples of these substances.
Types of substance
Examples
Polymer
Polyvinyl chloride
Composite
Reinforced concrete
Glass
Ceramic
Cement
Table 2
(a)
(i)
...............................................................................................................................
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...............................................................................................................................
[1 mark]
(ii) Polyvinyl chloride is often used in the making of water pipes. State one
advantage of this type of pipe compared to iron pipe.
........................................................................................................
.......................
[1 mark]
(iii) Draw a structural formula of polyvinyl chloride.
[1 mark]
(b)
.......................
[1 mark]
(c)
(ii)
(iii)
Explain why glass containers are more suitable for storing preserved food than
metal containers.
...............................................................................................................................
[1 mark]
List the chemical composition of soda lime glass.
...............................................................................................................................
[2 marks]
Soda lime glass cannot withstand high temperature. Name another type of glass
that is more heat-resistant.
...............................................................................................................................
[1 mark]
(d)
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........................................................................................................................................
[1 mark]
QUESTION 12
(a)
What is an alloy?
[1 mark]
(b)
Pure metal X
(i)
Pure metal Y
[2 marks]
(ii)
[2 marks]
(c )
Diagram 3 shows the flow chart for the industrial manufacture of sulphuric acid.
Sulphur
Sulphur dioxide
Heat
V2O5, 1 atm
450 0C 500 0C
Sulphuric acid
Concentrated
H2SO4,
Oleum
Diagram 3
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(ii)
(iii)
Write the chemical equation when oleum reacts with water to form sulphuric
acid.
[2 marks]
(d)
There are four types of glasses that are used in our daily lives.
(i)
(ii)
Type of glass
Borosilicate glass
Uses
Cookware
Laboratory glassware
.............................................
Decorative lamp
Prism
Bottle
Mirrors
Table 2
[2 marks]
(iii)
.
[1 mark]
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QUESTION 13
Process
C
State 3
Process
A
Process
B
Process
D
State 4
State 1
State 2
The experiment in diagram above shows the change of matter from one state to another state.
(a) Name the process:
(i)
Process A : ..
(ii)
Process B : ..
(iii)
Process C:
(iv)
Process D : ..
(b)
State 1
(c)
(d)
State 2
Compare the water particles in solid and liquid forms in terms of:
(i)
(ii)
Energy content
(iii)
Movement of particles
State whether energy is absorbed or released when ice melts.
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State 3
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QUESTION 14
Diagram 2 shows the symbols of atom for element U, V, W and X.
23
11
24
12
35
17
40
18
12
6
DIAGRAM 2
(a) Write the electron arrangement of atom W.
.........................................................................................................................
[1 mark]
(b) (i)
Element U, V ,W and X are placed in the same period in the Periodic Table.
State the period for the elements.
Period: ...................................
[2 marks]
(ii)
(ii) Arrange the elements in decreasing order in state of the atomic size.
.................................................................................................................
[1 mark]
(iv)
(c)
(ii)
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(d)
(ii)
(ii)
[2 marks]
(e)
[2 marks]
QUESTION 15
Table 1 shows the atomic structure of six elements. A,B,C,D,E and F are not the actual symbols of the
elements.
Element
Proton
Neutron
Electrons
A
B
C
D
E
F
6
6
8
11
18
20
6
8
10
12
22
20
6
6
8
10
18
18
Table 1
Use information from Table 1 to answer the following questions.
(a) State three types of subatomic particles in an atoms
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[1 mark]
(b) (i)
[ 1 mark]
(ii)
(c) (i)
[ 1 mark]
(ii)
Explain why element in 1(iii) does not react with other elements.
.
.................................................................................................
................................................................................................
[ 1 mark]
(d)
[ 1 mark]
(e)
Write the ionic equation for the compound formed between element C and D.
[ 2 mark]
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ESSAY
QUESTION 1
(a) Salts can be classified into soluble and insoluble salt.
(i)
[ 1 mark ]
(ii)
Name the chemical needed to prepare salt in (a) and name the reaction.
[ 3 marks]
Blue solution of Y
+ NaOH
solution
Blue Precipitate
Diagram 8
Based on Diagram 8, identify the
(i)
(ii)
(iii)
Black powder of X
Blue solution of Y
Cation and anion of Y solution
[ 4 marks]
(c )
An experiment is carried out to construct an ionic equation for an insoluble salts, lead(II)
chromate (VI).
A fixed volume of 5.0 cm 3 of 1.0 mol dm -3 lead(II) nitrate, Pb(NO3)2 solution is
placed into each of the eight test tube of the same size.
Different volume of 1.0 mol dm -3 potassium chromate (VI), K2CrO4 solution is
added to each test tube.
The height of the yellow precipitate, lead(II) chromate(VI) formed into each test
tube is measured, recorded and plotted in graph 8.
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Graph 8
Based on graph 8:
(i)
Calculate
(ii)
Based on the answer in (c )(i), construct an ionic equation for the formation of
lead(II) chromate(VI)
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[ 2 marks]
QUESTION 2
(a)
(i)
(ii)
(b) A student intends to electroplate the iron spoon that is easily to rust with a silver metal to make
it look more attractive and more resistant to corrosion. Design a laboratory experiment to
electroplate the iron spoon.
Your answer should consist of the following:
Chemicals required
Procedures of the experiment
Diagram showing the set up of apparatus
Half equations at anode and cathode
[2 marks]
Substance
Volume
/ cm3
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Concentration
/ mol dm-3
Heat of
neutralization, H
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(kJ/mol)
Hydrochloric acid
sodium hydroxide
II
25.0
25.0
Ethanoic acid
25.0
sodium hydroxide
25.0
2.0
-57
2.0
2.0
-55
2.0
Table 7
For experiment I,
(i)
(b)
Based on the data provided in Table 7, explain why heat of neutralization for
Experiment II is lower than in Experiment I.
[2 marks]
(d)
Precaution step
[10 marks]
QUESTION 4
A student carried out an experiment to determine the value of heat of neutralization. Diagram 3 shows the
set-up apparatus used in the experiment.
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Diagram 3
The following data obtained:
Initial temperature of hydrochloric acid, 1
= 30 0C
Highest temperature of the mixture of product, 2 = 43.5 0C
In this experiment, 50 cm 3 of 2.0 mol dm -3 of sodium hydroxide solution is added to 50 cm3 of 2.0 mol dm3
of hydrochloric acid.
Given that the specific heat of capacity of the solution is 4.2 J g -1 0C-1 and the density of the solution is 1.0 g
cm-3 .
Based on the informations given above:
(a) Calculate:
(i)
(ii)
QUESTION 5:
Diagram below shows changes of a carbon compound involving a series of reactions.
+ H2
Propane
Heat
acidified
Potassium
dichromate(VI)
Alumina
Propene
Heat
Alcohol Y
Propanoic acid
Carbon 60.00%
Hydrogen 13.33%
Oxygen 26.67%
Relative molecular mass = 60
Relative atomic mass of H = 1 , O= 16 and C = 12
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[7 marks]
[4 marks]
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(c ) (i) The information below is regarding alkene Y.
Carbon 85.7%
Hydrogen 14.3%
Relative molecular mass = 42
Relative atomic mass of H = 1 ,and C = 12
(e) Table below shows the results of a test to differentiate between propene and propane.
Procedure
Bromine water is added to propene
Bromine water is added to propane
Observation
Brown colour is decolourized
Brown colour remains
[4 marks]
QUESTION 6:
(a)
Diagram 1
Qualitative analysis can be used to determine the presence of cations and anions in solutions.
Describe chemical test that can be used to verify the ions in each solution.
[10 marks]
(b)
A pupil carried out an experiment to investigate the chemical changes that occur to copper (II)
chloride as a result of reaction P.
The result of the experiment is shown in Diagram 2
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Diagram 2
(i) The chemical equation for reaction P is as follows:
PbCl2 + Na2CO3
2NaCl + PbCO3
Excess sodium carbonate is added to 50 cm3 of mol dm-3 lead(II) chloride. Given that the
relative molecular mass of PbCO3= 267.
Calculate the mass of lead(II) carbonate precipitate formed.
[2 marks]
(ii) Name solid X and state its colour.
[2 marks]
[2 marks]
QUESTION 7
(a)
(a)
(i)
[ 3 marks]
(ii)
[ 2 marks]
(iii)
[3 marks]
(ii)
State the alloy suitable for building bodies of planes and give reasons for your answer.
[3 marks]
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Diagram showing the set-up of apparatus
List of apparatus
Procedures of the experiment
[10 marks
QUESTION 8
A group of pupils carried out three experiments to investigate the factors affecting the rate of a reaction.
Table 3 shows information about the reactants and the temperature used in each experiment.
Experiment
Temperature /0C
Reactants
Excess calcium carbonate chips and
30 cm3 of 0.5 mol dm-3 hydrochloric acid
Excess calcium carbonate chips and
30 cm3 of 0.5 mol dm-3 hydrochloric acid
Excess calcium carbonate chips and
30 cm3 of 0.5 mol dm-3 hydrochloric acid
I
II
III
30
40
40
Table 3
(i) Sketch a graph to shows the result for the experiments. [ 2 marks ]
(ii)
(iii) The chemical equation below shows the reaction between calcium carbonate and
hydrochloric acid.
CaCO3 + 2HCI
Given that the relative atomic mass of C=12, O=16, Ca=40 and the molar volume of any
gas in 24 dm3 mol-1 at room temperature and pressure.
Calculate the maximum volume of carbon dioxide gas produced in Experiment II.
[4 mark]
QUESTION 9
A student carried out three experiments to investigate the effects of the factor influencing the rate of
reaction. Table I shows the result of the experiments.
Eksperiment
I
3
Set-up of
apparatus
50 cm sulphuric
acid 1.0 mol dm -3
acid
6.5g
Zinc strip
II
III
50 cm
sulphuric acid
1.0 mol dm -3
acid
50 cm 3 sulphuric acid
1.0 mol dm -3
6.5g
Zinc strip
6.5g
Zinc strip
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Temperature/0C
30
40
60
100
40
30
Table 1
(i)
Write the chemical equation for the reaction between magnesium and hydrochloric acid.
Calculate the maximum volume of hydrogen gas produced.
[Relative atomic mass: Mg, 65; molar gas volume; 24 dm3 mol-1 at room condition]
[6 marks]
(ii)
Calculate the average rate of reaction for the Experiment I, II, and III in cm3 s-1.
[3 marks]
(iii)
State a factor that effect the rate of reaction for the experiment above
And explain based on collision theory.
[6 marks]
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