Professional Documents
Culture Documents
Authors
Faizzi Lokman
Robert OMalley
Masashi Date-Shappard
Group 31
Student Number
43115095
41185786
42932914
Page i
15C
5Mpa
11.16m
33.33m
Propylene Carbonate
50mm HiFlow Hyd (plastic)
The flash drum removing light components from the methanol product stream was best
operated under a temperature of 35oC and pressure of 1.6 MPa. Under these conditions
99.95% of the light components were removed and 93% of the methanol is recovered with
7% of the methanol in the vapour phase with the light components.
To obtain 99% pure methanol a distillation column was designed under the following
conditions:
Operating Parameters
Actual number of stages
13
Actual reflux ratio
0.859
Net heat duty of column (gW)
94.69
Condenser duty (gW)
-71.64
Reboiler duty (gW)
166.3
Minimum required steam flow in reboiler 76.91
(ton/s)
Distillate to feed ratio for methanol
0.99
Location of feed stage
9
With the separation units operating under these specifications the plant can obtain a product
purity of methanol at 99%mol and a combustion exhaust gas carbon dioxide concentration of
2%mol.
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Page ii
Table of Contents
1.0 Introduction ....................................................................................................................................... 1
2.0 Methodology ..................................................................................................................................... 1
2.1 Mass Balance ................................................................................................................................ 1
2.1.1 Block Flow Diagram .............................................................................................................. 2
2.2 Absorber Design ........................................................................................................................... 3
2.2.1 Solvent Selection.................................................................................................................... 3
2.2.2 Minimum Required Liquid to Gas Ratio ............................................................................... 4
2.2.3 Design Diagram of Absorption Column ................................................................................ 4
2.2.4 Process Flow Diagram of the Absorber and Stripping System .............................................. 4
2.2.5 Random Packing Material Selection ...................................................................................... 5
2.2.6 Calculation of Tower Diameter.............................................................................................. 5
2.2.7 Estimation of Mass Transfer Coefficients, Height of Transfer Units for Liquid and Gas
Phases and Height of Overall Gas Transfer Units .......................................................................... 6
2.2.8 Calculation of Tower Height.................................................................................................. 6
2.2.9 Final Absorber Specifications ................................................................................................ 6
2.3 Distillation Design ........................................................................................................................ 7
2.3.1 Flash Separation Unit Design ................................................................................................ 7
2.3.2 Distillation Column Design ................................................................................................... 8
2.2.3 Selection of Property Method .............................................................................................. 10
3.0 Discussion and Analysis ................................................................................................................. 10
3.1 Absorber Design ......................................................................................................................... 10
3.1.1 Physical Solvent over Chemical Solvent ............................................................................. 10
3.1.2 Lowest CO2 Concentration .................................................................................................. 10
3.1.3 Amine Consideration ........................................................................................................... 11
3.1.4 Maximum Temperature Change across Column for Isothermal System ............................. 11
3.1.5 Validity of the Assumption of Insolubility of non-CO2 Components. ................................ 11
3.2 Distillation Design ...................................................................................................................... 12
3.2.1 Flash Drum........................................................................................................................... 12
3.2.3 Distillation Column .............................................................................................................. 12
4.0 Conclusions and Recommendations ............................................................................................... 13
4.1 Absorber...................................................................................................................................... 13
4.2 Distillation Process ..................................................................................................................... 13
References ............................................................................................................................................. 14
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Page iii
Group 31
Page iv
2.0 Methodology
2.1 Mass Balance
As part of the initial calculations performed for this project, methodical mass balances were
performed on every unit in the methanol plant up to the methanol synthesis reactor. A diagram of the
overall methanol plant, marked with a red line, indicating the end point of mass balance calculations
is available in Appendix A.
Data provided by the project brief and assumptions made in order to solve the mass balances are
shown below:
Table 1 Key data and assumptions regarding mass balances
Data Provided
Methane feed rate of 2000 kmol/s
20% of methane feed used for combustion
Steam Feed rate is 3 times molar rate of methane
for reaction
Reaction 1,2 (reforming reactions) go to 70%
completion
Reaction 3 (combustion reaction) goes to 90%
completion
10% of Carbon monoxide produced in R1 is used
in R2
Temperatures at different stages of the process
Group 31
Assumptions made
Flow rate of air for combustion 5% more than
required
Relative humidity of air is 70%
Ambient air temperature is 30 degrees Celsius
Methane feed is 100% methane
Steam feed is pure water
No reactions occurring other than those specified.
Only water condenses out of the syn gas stream
Page 1
Figure 1: Block flow diagram for the reforming section of the methanol plant
An example mass balance calculation for the combustion reaction is shown below.
Combustion Reaction
The combustion reaction, shown below, uses 25% of feed methane and it is also an assumed that there
is 5% excess air than required for complete combustion.
Equation 1
An equation for the required flow rate of oxygen is derived.
Equation 2
Where the numbered subscripts denote the stream number in Figure 1 of Section 2.1.1.
The total flow rate of air is calculated based on the oxygen to nitrogen ratio of 21:79 along with the
water carried with it at 70% relative humidity at 300C, 1 atm. Which means partial pressure of water
in air equals 70% of vapour pressure of water at 300C, 1 atm, which is then turned into a mole fraction
of the airflow. The air flow is added to the combustion methane stream 7 to get stream 8. To calculate
the components of stream 9 the combustion reaction mentioned earlier is used to convert 90% of the
methane to its products, with the equation for each component listed below.
Equation 3
Equation 4
Equation 5
Equation 6
Equation 7
Condensing
As the temperature and pressure were specified in stream 12 the vapour pressure of water was used to
calculate the amount of water that was left in gas stream in which the remainder of water from stream
10 was removed in stream 11 due to the streams being in equilibrium.
Table 5 containing stream variable values are available in Appendix A.
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Page 2
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Page 3
0.12
0.1
0.08
0.06
Equilibrium line
0.04
Operating Line
0.02
Lmin
0
0
0.02
0.04
0.06
0.08
0.1
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Page 4
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Page 5
Noy, the number of overall gas transfer units, was calculated to be 4.301.
With a Hoy value of 7.749m and a Noy value of 4.301, the height of packing required was calculated
to be approximately 33.33m as it is Hoy multiplied by Noy. This gives the column a height to
diameter ratio of 3.28, which is greater than the rule of thumb ratio of 2-3:1, but it is still an
acceptable value (Kotta, 2014)
2.2.9 Final Absorber Specifications
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Page 6
Temperature
Pressure
Diameter
Height
Selected Solvent
Selected Random Packing Material
15C
5Mpa
11.16m
33.33m
Propylene Carbonate
50mm HiFlow Hyd (plastic)
The gas released to the atmosphere after passing through the absorber meets the 2% carbon dioxide
mole fraction specification, and the total adjusted flow of the exiting gas is 33.88 kmol/s.
Figure 4 ASPEN PLUS model of the flash separation unit and distillation column system
The design steps used to determine the operating conditions for the flash separation unit and the
distillation column will now be explained in detail.
2.3.1 Flash Separation Unit Design
The purpose of the flash separation unit or flash drum was to separate the light gases (carbon dioxide,
carbon monoxide, hydrogen, and methane) from methanol and water, which are the less volatile
components.
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Page 7
Operating Conditions
Flash Drum Temperature (oC)
Flash Drum Pressure (MPa)
35
1.6
Outlet Conditions
Fraction Vapour (Total)
0.791
Mole Fraction
Component
Vapour
Liquid
Carbon Dioxide
0.99982
1.84E-04
Carbon Monoxide
0.98951
0.0105
Hydrogen
0.99992
8.35E-05
Methane
0.99889
1.11E-03
Methanol
0.0685
0.93149
Water
0.0175
0.98253
The operating temperature of 35 oC was specified in the project brief Appendix (The University of
Queensland, 2014), but the operating pressure was not. In order to find the optimal operating pressure
for the flash drum, a sensitivity analysis was performed to quantify how the amount of methanol being
lost in the light gas vapour stream changed as the operating pressure was varied.
The graph of the sensitivity analysis is provided in Figure 7 of Appendix D:
As it can be seen in Figure 7 in the Appendix D, the amount of methanol lost in the vapour stream is
very high at low operating pressures, but falls as the pressure increases. Initially, the rate of change is
great, but beings to decrease with increasing pressure. If the pressure is too high, more light gases
leave in the liquid stream, compromising its purity, but conversely, low pressure results in more
methanol loss. Therefore an optimal operating pressure of 1.6 MPa, which balances these two factors,
was selected. At this pressure, only 6.85% of the methanol entering the flash drum is lost to the
vapour stream and the amount of light gases leaving with the liquid is 1% or less for each component.
Another sensitivity analysis performed on the flash drum operating conditions was the temperature at
which the separation process was taking place. The effect on operating temperature was observed by
plotting the methanol loss rate into the vapour product stream of the flash drum to determine if the
original temperature of 35 oC is acceptable. The graph of the resulting sensitivity analysis is shown in
Figure 8 the Appendix D:
The data curve in Figure 8 of Appendix D shows that at the operating temperature of 35 oC, the
methanol loss is only 6.85%, so this operating pressure was deemed to be acceptable.
2.3.2 Distillation Column Design
The process used to design the distillation column was of a much greater complexity and it required
the use of two column blocks in ASPEN PLUS, as shown in Figure 4 of Section 2.3. Initially, the
block DSTWU was used to calculate the number and configuration of stages as well as a minimum
reflux ratio and operating pressures for the condenser and reboiler. DSTWU was only used for initial
Group 31
Page 8
Operating Parameters
Actual number of stages (-)
13
Actual reflux ratio (-)
0.859
Methanol Recovery (-)
0.98
Methanol product purity (%)
99.0 Specification Achievable
Net heat duty of column (gW)
94.69
Condenser duty (gW)
-71.64
Reboiler duty (gW)
166.3
Minimum required steam flow in reboiler 76.91
(ton/s)
Distillate to feed ratio for methanol
0.99
Location of feed stage (-)
9
At these operating conditions, the flow rate of methanol product is 2214 kmol/s.
The minimum steam flow required in the reboiler to provide the heat duty was calculated by using the
heat of vaporisation of steam at 30 PSIG obtained from the NIST thermo-physical property databanks
and the required reboiler duty. This calculation was performed under the assumption that all the
energy lost by the steam is gained by the reboiler. In reality, this would not be the case due to
efficiencies and losses, so the actual amount is greater. Working steps used for this calculation are
provided in the report Appendix E.
It is recommended that the type of plate used for this tray column should be sieve trays. This
recommendation was made because the operating pressure of the column is approximately one bar,
which means that sieve trays are suitable as long as excessive weeping is not occurring in the column
(GBH Enterprises, N.D). In addition to this, sieve trays are one of the cheapest plate types available
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Page 9
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Page 10
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Page 11
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Page 12
4.1 Absorber
The carbon dioxide mole fraction was able to be reduced to the specified amount of 2% by passing it
through a random packed absorber and contacting it with propylene carbonate, the solvent. The
operating temperature and pressure for the column was 15 oC and 5Mpa, respectively, and at these
conditions, the actual scaled flow rate of solvent was calculated to be 44.97 kmol/s.
Group 31
Page 13
References
Anderson, S. & Newell, R., January 2003, Prospects for Carbon Capture and Storage Technologies.
Billet, R. & Schultes, M., Predication of Mass Transfer Columns wit Dumped and Arranged
Packings Volume 77, Institute of Chemical Engineers
Burr, B. & Lyddon, L., 2010, A Comparison of Physical Solvents For Acid Gas Removal, Bryan
Research & Engineering, Inc
Cameron, I. 2014, Gas Liquid Absorption, lecture notes for CHEE3004: Unit Operations course at
The University of Queensland, distributed on 26/08/14.
Coulson, J.M., Sinott, R.K. & Richardson, J.F., 1999, Coulson & Richardson's Chemical
Engineering, Volume 6, Oxford, Butterworth-Heinemann.
Ebenezer, S 2005, Removal Of Carbon Dioxide From Natural Gas For LNG Production, Norwegian
University of Science and Tec hnology, Trondheim available at
http://www.google.com/patents/US2926751#forward-citations (viewed on 20/05/14)
Fang, M.& Zhu, D. 2012. Chemical Absorption. Handbook of Climate Change Mitigation. W.-Y.
Chen, J. Seiner, T. Suzuki and M. Lackner, Springer, US, pp. 1441-1514.
GBH Enterprises, Selection of Internals for Distillation Columns, [Online], available on
https://www.academia.edu/3641162/Selection_of_Internals_for_Distillation_Columns (viewed
19/09/14)
Higman, C. 2006, Chapter 13: Gas Treating, Elsevier
Intalox Packing Tower Systems, 2010, Plastic Random Packing, Koch-Glitsch
Keskes. E. et al, 2008, A Ohysical Absorption Process For the Capture of CO2 From CO2-Rich
Natural Gas Streams Chemical Engineering Department, Imperial College London
Kohl, A. & Miller, F., 1960, Organic carbonate process for carbon dioxide, United States Patent.
Kothandaraman, A., June 2010, Carbon Dioxide Capture by Chemical Absorption: A Solvent
Comparison Study, Massachusetts Institute of Technology.
Kotta, L. 2014, CHEE3004 Project 1 Final Thoughts, supplementary information provided for
CHEE3004: Unit Operations course at The University of Queensland, distributed on 13/09/14.
Kotta, L. 2014, Multistage binary distillation, lecture notes for CHEE3004: Unit Operations course
at The University of Queensland, distributed on 19/08/14.
Kotta, L. 2014, Project 1: The design of a gas-liquid absorber and distillation system, provided for
The University of Queensland CHEE3004 project.
Manning, M. 2013, ' Driven By China, Global Methanol Demand Rises 23 Percent in Two Years,
Unprecedented Demand Growth Expected for 2012 to 2022, Says New IHS Study', IHS Press release,
Houston, 11 March.
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Page 14
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Page 15
Appendices
Appendix A: System Diagram, Stream table and Physical properties
Figure 5 Flow chart of the entire methanol production plant, marked with end of mass balances
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Page 16
Stream
1
200
Total flow
0
(kmol/s)
Temperatur 30
e (C)
1.6
Pressure
(MPa)
200
Methane
0
(kmol/s)
1
Methane
mole
fraction
0
Water
(kmol/s)
0
Water mole
fraction
0
Carbon
monoxide
(kmol/s)
0
Carbon
monoxide
mole faction
0
Carbon
dioxide
(kmol/s)
0
Carbon
dioxide mole
fraction
0
Hydrogen
(kmol/s)
0
Hydrogen
mol fraction
0
Oxygen
(kmol/s)
Oxygen mole 0
fraction
0
Nitrogen
(kmol/s)
0
Nitrogen
mole
fraction
Group 31
10
11
12
13
14
480
0
160
0
640
0
640
0
8640
40
0
4516
4516
8640
358
4
5056
5056
4516
210
30
145
450
855
30
255
960
855
35
35
100
150
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
1.6
7.5
0.1
160
0
160
0
160
0
480
40
0
400
40
480
480
480
40
0.25
0.25
0.05
6
0.08
9
0.009
0.05
6
0.09
5
0.09
5
0.009
480
0
480
0
480
0
3680
116
836
3602
358
4
18
18
836
0.75
0.75
0.42
6
0.02
6
0.185
0.41
7
0.00
4
0.00
4
0.185
1120
1042
1042
1042
0.13
0.12
0.12
0.12
360
78
78
78
360
0.079
7
0.00
9
0.00
9
0.00
9
0.079
7
3360
3438
3438
3438
0.38
9
0.39
8
0.39
8
0.39
8
840
120
120
0.18
6
0.027
0.027
3160
3160
3160
0.7
0.7
0.7
Page 17
Mole Fraction
(-)
0.01087
Molar Flow
(kmol/s)
0.4
Carbon Dioxide
0.0978
3.6
Nitrogen
0.8587
31.6
Oxygen
0.0326
.2
Group 31
Kinematic Viscosity
(m2/s)
Density
(kg/m3)
3.21E-07
36.98
1.09E-07
154.1
3.10E-07
58.94
3.06E-07
69.15
Page 18
Total
Temp (deg C)
Pressure (Mpa)
Gas flow in (rescaled) kmol/s
Total
CO2
Other
Solvent
Water
Propylene Carbonate
Propylene Glycol
Solvent
Water
Propylene Carbonate
Propylene Glycol
Group 31
3680
15 CH4
5 CO2
N2
36.8 O2
3.6
33.2
288
125.1
6.4
30.2
288
3.91E-03
0.076
0.016192053
mw kg/kmol
16.04
44.01
28
32
Xmax out
Temperature
298
3.13E-03
0.056
0.013
308
184.8
10.6
45.6
308
2.65E-03
0.046
0.011
kinematic
Dynamic Visc
mass fraction mol fraction density kg/m3 total density
viscosity (m2/s) total viscosity (m2/s)
40
0.174
0.0109
36.98
0.4019
4.02E-07
3.21E-07
3.49E-09
360
4.305
0.0978
154.1
15.0770
1.51E-05
1.09E-07
1.06E-08
3160
24.04
0.8587
58.94
50.6141
5.06E-05
3.10E-07
2.66E-07
120
1.043
0.0326
69.15
2.2548
2.25E-06
3.06E-07
9.97E-09
29.57
1
68.3478 avg
2.90E-07
318
243
12.4
52.6
318
2.01E-03
0.039
9.30E-03
Solvent
Water
Propylene Carbonate
Propylene Glycol
Solvent
Water
Propylene Carbonate
Propylene Glycol
288
25.02
1.28
6.04
288
732.4
37.47
176.8
Lmin (kmol/s)
Temperature
298
913.4
50.9
223.1
308
1082.0
62.1
267.0
318
48.6
2.48
10.52
318
1422.7
72.6
308.0
Page 19
Best Temperature
Best Solvent
Propylene carbonate
288K
Non solute fraction
L actual (kmol/s)
X out actual
Out
CO2 Absorbed
44.97
0.0637
0.98
0.678
Change in CO2
2.922
CO2 in outlet gas
0.678
Lmin/G Ratio
1.018
Hoy Calculations
0.0978
0.020
0.082
Y*out
Log Mean
Noy
K4
0.350
xin*
xout
xout*
log mean x
Nox
Kxa
Packing Parameters
0.0156
0.0637
0.0764
-0.0141
4.5060
7.49E-02
packing surface
area
a
m^3/m^3
E
118.4
0.925
2.561E-06
characteristic
Ch
0.881
rohG
68.35
characteristic
CL
1.553
rohL
1205
characteristic
Cv
0.369
1088
4627
1.013
35.69
81.14
Packing Factor Fp
52
4627
1.28
GdotY
henry's constant
mass flow
m
36.8
44.97
height of gas tu
Hg
3.832
13.410
height of liquid tu
HL
specific liquid hold up hL
diffusity of Co2 in liquidDL
liquid velocity
uL
aPh
liquid froude number NfrL
reynold number liq
NreL
3.74E+00
0.101
2.20E-09
0.0473
29.6
0.027
933.35
V
L
FLV
pressure drop
A
Adjusted diffusivity
Dg
viscosity of gas mewG
1.713
9.81
3.41E+04
0.000
0.196
1.60E-05
density of gas
Group 31
0.000
0.018
4.301
rohG
dp
K
Height of TransferHoy
Units
4.28E-07
2.90E-07
68.35
3.80E-03
0.9967
7.749
Visc ^0.1
py(px-py)^-1
Diameter
Height
Height to
Diameter Ratio
2.22E-01
1.28721E-05
10.16
33.33
3.280
Page 20
Total
Temp (deg C)
=SUM(E2:E5)
15
CH4
Pressure (Mpa)
CO2
44.01
360
=G3*D3
=E3/$B$1
kmol/s
=B1/100
=E3/100
=B5-B6
N2
O2
28
3160
120
=G4*D4
=G5*D5
=SUM(F2:F5)
=E4/$B$1
58.943
=E5/$B$1
69.148
=SUM(G2:G5)
32
154.12
Solvent
Water
288
=B12/$B$3
8.7
10.6
12.4
Propylene
Carbonate
Propylene Glycol
30.2
38.1
45.6
52.6
Propylene
Glycol
288
=$G$25/H12
Xmax out
Temperature
298
308
=$G$25/I12=$G$25/J12
318
=$G$25/K12
=$G$25/I13=$G$25/J13
Propylene Glycol
=$G$25/I14=$G$25/J14
Solvent
Water
Solvent
Water
Group 31
288
125.1
=$G$25/H14
total density
=H2*G2
Dynamic Visc
=I2*10^-6
=N83/H2
total viscosity
(m2/s)
=K2*G2
=H3*G3
=I3*10^-6
=N84/H3
=K3*G3
=H4*G4
=H5*G5
=SUM(I2:I5)
=I4*10^-6
=N85/H4
=I5*10^-6
=N86/H5
=K4*G4
=K5*G5
=SUM(L2:L5)
avg
298
=C12/$B$3
318
=E12/$B$3
=B13/$B$3
=C13/$B$3
=D13/$B$3
=E13/$B$3
=B14/$B$3
=C14/$B$3
=D14/$B$3
=E14/$B$3
Solvent
Water
288
=($B$5*($G$25-$G$26))/B20
Lmin (kmol/s)
Temperature
298
308
=($B$5*($G$25-$G$26))/C20
=($B$5*($G$25-$G$26))/D20
318
=($B$5*($G$25-$G$26))/E20
=$G$25/K13
Propylene
Carbonate
=($B$5*($G$25-$G$26))/B21
=($B$5*($G$25-$G$26))/C21
=($B$5*($G$25-$G$26))/D21
=($B$5*($G$25-$G$26))/E21
=$G$25/K14
Propylene
Glycol
=($B$5*($G$25-$G$26))/B22
=($B$5*($G$25-$G$26))/C22
=($B$5*($G$25-$G$26))/D22
=($B$5*($G$25-$G$26))/E22
Page 21
Best Temperature
Best Solvent
Propylene carbonate
288K
L actual (kmol/s)
=H21*1.2
X out actual
=((B5*($G$25-$G$26))/A29)
Lmin/G Ratio
CO2 Absorbed
=($B$7/$C$29)*0.02
=$B$6-$D$29
=B6-D30
Hoy Calculations
Yin
Yout
Y*in
0.0978
0.02
=H13*B29
=((B5/F44)/G50)
0
Y*out
Log Mean
Noy
0
=((G25-G27)-(G26-G28))/(LN((G25-G27)/(G26-G28)))
=(G25-G26)/G29
xin*
xout
xout*
log mean x
Nox
Kxa
=(0.02/H13)
=B29
=B21
=((J27-J28)-(J29-J30))/(LN((J27-J28)/(J29-J30)))
=(J27-J29)/J31
=((A29/F44)/(J46/J32))
K4
0.35
Packing Parameters
mass flow
m
=B87*102.9
=H13
GdotY
=SQRT(F34/(J43*J44*J40*13.1))
henry's constant
a
E
118.4
0.925
=B5
=H87
characteristic
Ch
0.881
=A29
rohG
=I6
characteristic
CL
1.553
height of gas tu
Hg
=(1/J39)*(J36-C41)^(1/2)*(4*J36/(J35^4))^(1/2)*C49^(-3/4)*C50^(-1/3)*C51/G45*4
rohL
=F87
characteristic
Cv
0.369
height of liquid tu
specific liquid hold up
diffusity of Co2 in liquid
liquid velocity
=1/J38*(1/12)^(1/6)*(4*C41*J36/C42/J35/C43)^(1/2)*C43/J35*4
=(12*C45/C46)^(1/3)*(C47)^(2/3)
0.0000000022
=C35/F39/F44
=0.25*J35
=C43^2*J35/C48
=C43*G48*G49/(1-J36)/H87
V
L
FLV
pressure drop
A
Adjusted diffusivity
viscosity of gas
=K84
=C35
=F41/F40*(F38/F39)^0.5
35.6900674542274
=K84/F35
Dg
mewG
Packing Factor
Fp
52
HL
hL
DL
uL
aPh
NfrL
NreL
Visc ^0.1
py(px-py)^-1
Diameter
Height
=L6^0.1
=(F38*(F39-F38))^-1
=(F44*4/PI())^0.5
=G50*G30
hydraulic/packing area
acceleration
reynold number gas
schmidt number
gas velocity
diffusity of Co2 in gas
ah/a
g
NreG
NscG
uG
DG
=J37*C46^0.15*C45^0.1
9.81
=C51*G48*G49/(1-J36)/L6
=G46/(G47*C52)
=K84/I6/F44
0.000016
density of gas
=J46/J45
Group 31
rohG
dp
K
Height of Transfer Units Hoy
=(C52*1.83)/F38
=L6
=I6
=6*(1-J36)/J35
=1/(1+2/3*1*G48/(1-J36)/J45)
=C39+C36*(C37/C38)*C40
Page 22
Solvent
Temperature (K)
288
298
308
318
Equilibrium CO2 mole fractions in solvent outlet (-)
3.91E-03
3.14E-03
2.65E-03
2.01E-3
Water
0.076
0.056
0.046
0.039
0.016
0.013
0.011
9.3E-3
Propylene Carbonate
Propylene Glycol
Table 12 Minimum solvent flow rate required to absorb CO2
Solvent
Water
Propylene
Carbonate
Propylene Glycol
Group 31
288
732.4
Temperature (K)
Lmin (kmol/s)
298
308
913.4
1082.0
37.47
176.8
50.9
223.1
62.1
267.0
318
1422.7
72.6
308.0
Page 23
Figure 6 The K4 vs FLV chart with the operating value and flooding values marked
Group 31
Page 24
Parameters
a (surface area per unit
volume of packing)
(voidage)
Ch, CL, Cv
(packing characteristics)
Fp
(packing factor)
DL (diffusivity of CO2 in
solvent)
DG (diffusivity of CO2 in gas
at 1atm)
Dg (modified gas diffusivity at
5 MPa)
g (gravitational acceleration)
Velocity of liquid
Velocity of gas
Values
118.4 m2/m3
Sources
Billet and Schultes, Table 2a.
0.925
0.881, 1.553, 0.369
52
2.2E-09m2/s
Perrys Chemical
Handbook
Cussler, Diffusion
1.6E-5 m2/s
Cussler, Diffusion
4.28E-07 m2/s
Calculated
9.81 m/s2
0.059 m/s
0.264 m/s
Calculated
Calculated
Engineering
Equation 14
Where HL is the height of transfer units in the liquid phase
Equation 15
Where
, the ratio of phase interface area to the packing surface area is assumed to be 0.25 (Kotta,
Group 31
Page 25
Equation 23
Where: Zt is the height of packing (m), Nox is the number of transfer units in the liquid phase, xout is
the mole fraction of CO2 in outlet solvent and xin is the mole fraction of CO2 in the inlet.
Group 31
Page 26
Table 14Reactor product stream composition, flow rate, temperature and pressure
Phase:
Component Mole Fraction
Carbon Dioxide
Carbon Monoxide
Hydrogen
Methane
Methanol
Water
Mole Flow (Kmol/s)
Temperature (oC)
Pressure (MPa)
Vapour Feed
Zi
0.10
0.01
0.56
0.11
0.15
0.07
16000
150
2
0.7
1.2
1.7
Figure 7 Graph of methanol loss in vapour against flash drum operating pressure
500
0
0
20
40
60
80
100
120
140
160
Temperature (oC)
Group 31
Page 27
Operating Parameters
Minimum reflux ratio (-)
Optimum reflux ratio (-)
Actual number of stages (-)
Feed stage (-)
Condenser pressure (MPa)
Reboiler pressure (MPa)
Distillate to feed ratio for methanol (-)
Methanol product purity (%)
0.307
0.46
13
9
0.1
0.103
0.99
99.3
Data
Heat duty of reboiler (kJ/s)
Steam heat of vaporisation at 30 PSIG (kJ/mol)
Molecular weight of steam/water (kg/kmol)
Value
166323925
38.93
18
Source
ASPEN PLUS
NIST
NIST
To calculate the minimum required flow of steam, several design assumptions were impletmented.
Assumptions
Group 31
Page 28
Convert the mass flow rate of steam to tonnes per second to reduce significant digits:
1.01
1
0.99
0.98
0.97
0.96
0.95
0.94
0.93
0.92
0.91
0.9
2250
2200
2150
2100
2050
2000
0
0.5
1.5
2.5
Methanol Product Purity
Methanol Product Flow
Figure 9 Graph of methanol product purity and flow against reflux ratio
Group 31
Page 29
0.98
2150
0.96
2100
0.94
2050
0.92
2000
0.9
1950
0.88
1900
0.86
0.84
1850
8
10
11
12
13
14
Figure 10 Graph of methanol product purity and flow against number of stages
0.98
2150
0.96
2100
0.94
2050
0.92
2000
0.9
1950
0.88
1900
0.86
0.84
0
10
1850
12
14
Methanol Product Purity
Methanol Product Flow
Figure 11 Graph of methanol product purity and flow against location of feed stage
Group 31
Page 30